CN103289389A - Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch - Google Patents
Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch Download PDFInfo
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- CN103289389A CN103289389A CN2013102135367A CN201310213536A CN103289389A CN 103289389 A CN103289389 A CN 103289389A CN 2013102135367 A CN2013102135367 A CN 2013102135367A CN 201310213536 A CN201310213536 A CN 201310213536A CN 103289389 A CN103289389 A CN 103289389A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a color master batch of chinlon a BCF (bulked continuous filament) carpet yarn. The color master batch comprises the following components in percent by weight: 60-90% of a thermoplastic polymer, 1-10% of an additive and 9-30% of a coloring agent. The invention also discloses a preparation method of the color master batch of the chinlon BCF carpet yarn. Compared with the prior art, the color master batch disclosed by the invention is good in temperature resistance, excellent in filtering performance and long in spinning period, is high in fastness to washing and colour fastness to light when being applied in a carpet, is rich in colour and variety, and completely meets the application requirement of the chinlon BCF carpet yarn.
Description
Technical field
The present invention relates to a kind of Masterbatch and preparation method thereof, particularly a kind of polyamide fibre BCF carpet silk Masterbatch and preparation method thereof.
Background technology
The nylon industry of China has the development history of decades, and its product is mainly weaving and industrial long filament.Bulked continuous filament (BCF), it is a kind of new chemical fibre carpet yarn, it has broken through carpet in the past mainly based on the situation of nylon, wool and polypropylene fibre, compare with nylon, wool and polypropylene fibre that cost is higher, it has good fluffiness, elasticity and spreadability, and is corrosion-resistant, intensity is higher, absorbing dye that can be more deep, product have more gorgeous color, and with low cost.State such as the U.S., Japan, emerging terylene BCF yarn has replacement nylon greatly as the trend of senior carpet fabric.
BCF/ fiber and engineering plastics aspect are used few, and this has also caused present Chinese nylon proportion in synthon less, is 8.5% only at present, are lower than the ratio that nylon in the world accounts for synthon total amount 19.4%.This development imbalances mainly is that the hysteresis owing to the development of Nylon BCF and carpet produces, and this has also caused the Technology maturation, investment is low, raw material is easy to get, performance get well and the nylon of recyclable utilization real its due investment value of embodiment not.Along with the rapid growth of China's economy, the polyamide fibre BCF carpet of developing china has far-reaching strategic importance.Carpet was almost all made with wool before synthon inventions, and this is because it has natural performance: rebound resilience preferably.But the wear resistance of wool is general, for making carpet have certain work-ing life, often need to increase the height of pile, the carpet of woolmark is made by 100% pure wool, minimum pile grammes per square metre 915g/m2, mostly pure wool carpet product is more closely knit circle suede or clipping structure, but great majority are high pile woven carpets.The cost of material height, the pile grammes per square metre is big, inefficient weaves the production cost that the course of processing has increased carpet.
Compare with other synthon such as polypropylene fibre, polyester etc., the advantage of polyamide fibre BCF carpet yarn is the balance of its performance, and its every index all is good or fine, and other any fiber does not all possess this advantage.
The METHOD FOR POLYPROPYLENE BCF carpet occupies bigger proportion in Chinese market at present, can only produce more low-grade product but the shortcoming of its lodging resistance difference has also limited its range of application.
At present domesticly be applied to Masterbatch that polyamide fibre BCF carpet uses seldom, and level is irregular differs, it is poor mainly to show as spinning property, water-fastness, and colour fastness to light is poor, can not well satisfy the painted requirement of polyamide fibre BCF.
Therefore, need a kind of preparation method of polyamide fibre BCF carpet silk special color master batch especially, to solve the above-mentioned existing problem that exists.
Summary of the invention
The object of the present invention is to provide a kind of polyamide fibre BCF carpet silk Masterbatch and preparation method thereof, at the deficiencies in the prior art, the Masterbatch temperature tolerance that produces is good, strainability is excellent, the spinning cycle is long, be applied to water-fastness in the carpet, colour fastness to light is high, color is wide in variety, is fit to the application requiring of polyamide fibre BCF carpet silk fully.
Technical problem solved by the invention can realize by the following technical solutions:
As a first aspect of the present invention, the invention provides a kind of polyamide fibre BCF carpet silk Masterbatch, it is characterized in that, comprise following components in weight percentage: thermoplastic polymer 60%-90%, additive 1-10% and tinting material 9%-30%.
In one embodiment of the invention, described thermoplastic polymer is any or combination in poly-sebacic acid decamethylene diamine (nylon 1010), nylon 11 (Ni Long11), poly-lauramide (nylon 12), polycaprolactam (nylon 6), polyhexamethylene sebacamide (NYLON610), nylon 612 (nylon 612), polyhexamethylene adipamide (nylon 66), poly-decoylamide (nylon 8), the poly-9 aminononanoic acid (nylon 9).
In one embodiment of the invention, described additive is triethylene glycol ether-two (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester, 3,9-two [1,1-dimethyl-2-[(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionyloxy] ethyl]-2,4,8,10-four oxaspiros [5.5] undecane, ethyl-3,5-di-t-butyl-4-acrinyl calcium phosphate, three (3,5-di-t-butyl-4-acrinyl) isocyanuric acid ester, four (2,4-di-t-butyl, eight alkoxyl groups-4, the 4-xenyl) phosphoric acid ester, 4,6-two (hot thiomethyl) ortho-cresol, N, any in two [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl] hydrazines of N'-or combination.
In one embodiment of the invention, described tinting material be that Pigment red 179, pigment blue 60, pigment green 36, Pigment Yellow 73 214, pigment orange 43, pigment orange 68, pigment brown 41, Pigment Yellow 73 184, solvent violet 59, solvent violet 37, solvent red 143, solvent red 181, solvent blue 94, solvent blue 19 32, solvent are green 29, any or combination of solvent yellow 135, solvent yellow 16 7.
In one embodiment of the invention, the moisture of described Masterbatch is less than 1%(wt), aberration is the 4-5 level, and fusing point is 160 ℃-265 ℃, and thermotolerance is 200 ℃-300 ℃, and filterableness (DF value) is less than 1bar * cm
2/ g.
As a second aspect of the present invention, the invention provides a kind of preparation method of polyamide fibre BCF carpet silk Masterbatch, it is characterized in that it comprises the steps: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing.
In one embodiment of the invention, described fusion batch mixing is to melt extrude by twin screw extruder, and described screw speed is 300rpm-350rpm, and mixing time is 400-700 second, and mixture temperature is 15 ℃-50 ℃.
In one embodiment of the invention, the mode of described cooling is water cooling, and cooling temperature is 20 ℃-90 ℃.
Beneficial effect of the present invention:
Compared with prior art, the Masterbatch temperature tolerance that the present invention produces is good, strainability is excellent, the spinning cycle is long, be applied to water-fastness in the carpet, colour fastness to light is high, color is wide in variety, is fit to the application requiring of polyamide fibre BCF carpet silk fully.
Characteristics of the present invention can be consulted the detailed description of the following better embodiment of this case and be obtained to be well understood to.
Embodiment
For technique means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with specifically, further set forth the present invention.
In the present invention, thermoplastic polymer comprises poly-sebacic acid decamethylene diamine (nylon 1010), nylon 11 (Ni Long11), poly-lauramide (nylon 12), polycaprolactam (nylon 6), polyhexamethylene sebacamide (NYLON610), nylon 612 (nylon 612), polyhexamethylene adipamide (nylon 66), poly-decoylamide (nylon 8), poly-9 aminononanoic acid (nylon 9) is Dupont Zytel Nylon-1010, Polyplastics Novamid Nylon-11, Polyplastics Novamid Nylon-12, U.S.A reaches polyamide fibre nylon 6, Dupont Zytel Nylon-610, Dupont Zytel Nylon-612, refreshing horse nylon 66, Dupont Zytel Nylon-8, Dupont Zytel Nylon-9.
In the present invention, additive comprises triethylene glycol ether-two (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester, 3,9-two [1,1-dimethyl-2-[(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionyloxy] ethyl]-2,4,8,10-four oxaspiros [5.5] undecane, ethyl-3,5-di-t-butyl-4-acrinyl calcium phosphate, three (3,5-di-t-butyl-4-acrinyl) isocyanuric acid ester, four (2,4-di-t-butyl eight alkoxyl groups-4, the 4-xenyl) phosphoric acid ester, 4,6-two (hot thiomethyl) ortho-cresol, N, two [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl] hydrazines of N'-are Basf Irganox245, Japan rising sun electrification Mark AO-80, Basf Irganox1425, Basf Irganox3114, Japan rising sun electrification MarkHP-10, Basf Irganox1520, Basf Irganox MD1024.
In the present invention, tinting material comprises Pigment red 179, pigment blue 60, pigment green 36, Pigment Yellow 73 214, pigment orange 43, pigment orange 68, pigment brown 41, Pigment Yellow 73 184, solvent violet 59, solvent violet 37, solvent red 143, solvent red 181, solvent blue 94, solvent blue 19 32, solvent green 29, solvent yellow 135, solvent yellow 16 7 is BASF Paliogen Red K4180, BASF Paliogen Blue L6385, BASF Heliogen Green K9360, Clariant PV Fast Yellow H9G, DIC Fastogen Super Orange6200, Crompton﹠amp; Knowles Sandorin Orange5RLT, Crompton﹠amp; Knowles Sandorin Brown RL, BASF Sicopal Yellow L1100, Solvaperm Red Violet R Hoechst, Sandoplast Violet FBL CLH, Setas Sumiplast Red AS, Nippon Kayaset Red2B, Hodogaya Aizen SOT Blue-3, Basf Filamid Blue R, Nippon Kayaset Green952, DyStar Macrolex Fluorescent Yellow FP, Keystone Keyplast Yellow167.
Embodiment 1
In the present embodiment, polyamide fibre BCF carpet silk Masterbatch, according to weight percent meter, its component is: thermoplastic polymer 60%, additive 10% and tinting material 30%; Thermoplastic resin is polycaprolactam, and additive is three (3,5-di-t-butyl-4-acrinyl) isocyanuric acid ester, and tinting material comprises solvent red 14314%, solvent red 18116%.
The preparation method of polyamide fibre BCF carpet silk Masterbatch adopts following technical process: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing.
The fusion batch mixing is to melt extrude by the twin-screw mixer forcing machine, and screw speed is 350rpm, and mixing time is 700 seconds, and mixture temperature is 50 ℃.
The mode of cooling is water cooling, and cooling temperature is 90 ℃.
The moisture of Masterbatch is 0.9%(wt), aberration is the 4-5 level, and fusing point is 215 ℃, and thermotolerance is 300 ℃, and filterableness (DF value) is 0.7bar * cm
2/ g.
Embodiment 2
In the present embodiment, polyamide fibre BCF carpet silk Masterbatch, according to weight percent meter, its component is: thermoplastic polymer 75%, additive 5% and tinting material 20%; Thermoplastic resin is polyhexamethylene adipamide, and additive is ethyl-3,5-di-t-butyl-4-acrinyl calcium phosphate, and tinting material comprises pigment brown 4117%, Pigment Yellow 73 1841%, Pigment red 1792%.
The preparation method of polyamide fibre BCF carpet silk Masterbatch adopts following technical process: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing.
The fusion batch mixing is to melt extrude by the twin-screw mixer forcing machine, and screw speed is 300rpm, and mixing time is 600 seconds, and mixture temperature is 40 ℃.
The type of cooling is water cooling, and cooling temperature is 50 ℃.
The moisture of Masterbatch is 0.5%(wt), aberration is the 4-5 level, and fusing point is 265 ℃, and thermotolerance is 290 ℃, and filterableness (DF value) is 0.4bar * cm
2/ g.
Embodiment 3
In the present embodiment, polyamide fibre BCF carpet silk Masterbatch, according to weight percent meter, its component is: thermoplastic polymer 85%, additive 5% and tinting material 10%; Thermoplastic resin is poly-sebacic acid decamethylene diamine, and additive is N, and two [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl] hydrazines of N'-, tinting material comprise that solvent is green 290.5%, pigment green 36 8%, solvent blue 19 321.5%.
The preparation method of polyamide fibre BCF carpet silk Masterbatch adopts following technical process: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing.
The fusion batch mixing is to melt extrude by the twin-screw mixer forcing machine, and screw speed is 300rpm, and mixing time is 500 seconds, and mixture temperature is 30 ℃.
The mode of cooling is water cooling, and cooling temperature is 35 ℃.
The moisture of Masterbatch is 0.3%(wt), aberration is the 4-5 level, and fusing point is 210 ℃, and thermotolerance is 290 ℃, and filterableness (DF value) is 0.5bar * cm
2/ g.
Embodiment 4
In the present embodiment, polyamide fibre BCF carpet silk Masterbatch, according to weight percent meter, its component is: thermoplastic polymer 90%, additive 1% and tinting material 9%; Thermoplastic resin is poly-lauramide, and additive is 4, and 6-two (hot thiomethyl) ortho-cresol, tinting material comprise pigment orange 688%, solvent yellow 16 70.5%, solvent yellow 1350.5%.
The preparation method of polyamide fibre BCF carpet silk Masterbatch adopts following technical process: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing.
The fusion batch mixing is to melt extrude by the twin-screw mixer forcing machine, and screw speed is 300rpm, and mixing time is 400 seconds, and mixture temperature is 15 ℃.
The type of cooling is water cooling, and cooling temperature is 20 ℃.
The moisture of Masterbatch is 0.2%(wt), aberration is the 4-5 level, and fusing point is 160 ℃, and thermotolerance is 200 ℃, and filterableness (DF value) is 0.4bar * cm
2/ g.
Comparative Examples
In this Comparative Examples, contrast polyamide fibre BCF carpet silk Masterbatch, according to weight percent meter, its component is: thermoplastic polymer 85%, additive 3% and tinting material 12%; Thermoplastic resin is polycaprolactam, and additive is triphenyl phosphite, and tinting material comprises Pigment black 71.5%, pigment Yellow 12 10.5%.
Contrast is adopted following technical process: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing with the preparation method of polyamide fibre BCF carpet silk Masterbatch.
The fusion batch mixing is to melt extrude by the twin-screw mixer forcing machine, and screw speed is 300rpm, and mixing time is 500 seconds, and mixture temperature is 30 ℃.
The type of cooling is water cooling, and cooling temperature is 20 ℃.
The moisture of Masterbatch is 0.6%(wt), aberration is 4 grades, and fusing point is 215 ℃, and thermotolerance is 160 ℃, and filterableness (DF value) is 1.4bar * cm
2/ g
The result is as shown in table 1.
The performance perameter of table 1 the present invention and prior art
As can be drawn from Table 1, the present invention compared with prior art, the Masterbatch temperature tolerance that produces is good, strainability is excellent, colour fastness to light is high, the spinning cycle is long, meets the requirement of polyamide fibre BCF carpet silk industry.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.
Claims (8)
1. a polyamide fibre BCF carpet silk Masterbatch is characterized in that, comprises following components in weight percentage: thermoplastic polymer 60%-90%, additive 1-10% and tinting material 9%-30%.
2. polyamide fibre BCF carpet silk Masterbatch as claimed in claim 1, it is characterized in that described thermoplastic polymer is any or combination in poly-sebacic acid decamethylene diamine (nylon 1010), nylon 11 (Ni Long11), poly-lauramide (nylon 12), polycaprolactam (nylon 6), polyhexamethylene sebacamide (NYLON610), nylon 612 (nylon 612), polyhexamethylene adipamide (nylon 66), poly-decoylamide (nylon 8), the poly-9 aminononanoic acid (nylon 9).
3. polyamide fibre BCF carpet silk Masterbatch as claimed in claim 1, it is characterized in that, described additive is triethylene glycol ether-two (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester, 3,9-two [1,1-dimethyl-2-[(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionyloxy] ethyl]-2,4,8,10-four oxaspiros [5.5] undecane, ethyl-3,5-di-t-butyl-4-acrinyl calcium phosphate, three (3,5-di-t-butyl-4-acrinyl) isocyanuric acid ester, four (2,4-di-t-butyl eight alkoxyl groups-4, the 4-xenyl) phosphoric acid ester, 4,6-two (hot thiomethyl) ortho-cresol, N, in two [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl] hydrazines of N'-any or combination.
4. polyamide fibre BCF carpet silk Masterbatch as claimed in claim 1, it is characterized in that described tinting material is that Pigment red 179, pigment blue 60, pigment green 36, Pigment Yellow 73 214, pigment orange 43, pigment orange 68, pigment brown 41, Pigment Yellow 73 184, solvent violet 59, solvent violet 37, solvent red 143, solvent red 181, solvent blue 94, solvent blue 19 32, solvent are green 29, any or combination of solvent yellow 135, solvent yellow 16 7.
5. polyamide fibre BCF carpet silk Masterbatch as claimed in claim 1 is characterized in that the moisture of described Masterbatch is less than 1%(wt), aberration is the 4-5 level, and fusing point is 160 ℃-265 ℃, and thermotolerance is 200 ℃-300 ℃, and filterableness (DF value) is less than 1bar * cm
2/ g.
6. the preparation method of a polyamide fibre BCF carpet silk Masterbatch as claimed in claim 1 is characterized in that, comprises the steps: batch mixing → blanking → fusion batch mixing → cooling → pelletizing → air-dry → packing.
7. the preparation method of polyamide fibre BCF carpet silk Masterbatch as claimed in claim 6, it is characterized in that described fusion batch mixing is to melt extrude by twin screw extruder, described screw speed is 300rpm-350rpm, mixing time is 400-700 second, and mixture temperature is 15 ℃-50 ℃.
8. the preparation method of polyamide fibre BCF carpet silk Masterbatch as claimed in claim 6 is characterized in that, the mode of described cooling is water cooling, and cooling temperature is 20 ℃-90 ℃.
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