CN109054360A - The preparation method of PA fiber master batch - Google Patents

The preparation method of PA fiber master batch Download PDF

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Publication number
CN109054360A
CN109054360A CN201810835848.4A CN201810835848A CN109054360A CN 109054360 A CN109054360 A CN 109054360A CN 201810835848 A CN201810835848 A CN 201810835848A CN 109054360 A CN109054360 A CN 109054360A
Authority
CN
China
Prior art keywords
pigment
parts
master batch
preparation
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810835848.4A
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Chinese (zh)
Inventor
徐毅明
杨军辉
李林
谢伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Baoli Di Material Polytron Technologies Inc
Original Assignee
Suzhou Baoli Di Material Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Baoli Di Material Polytron Technologies Inc filed Critical Suzhou Baoli Di Material Polytron Technologies Inc
Priority to CN201810835848.4A priority Critical patent/CN109054360A/en
Publication of CN109054360A publication Critical patent/CN109054360A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/04—Pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a kind of preparation methods of PA fiber master batch, and by weight, the master batch is composed of the following components: 32 parts of PA; 17 parts of pigment, 1.8 parts of sodium potassium tartrate tetrahydrates, 1.4 parts of titanium acetylacetones; 2.1 parts of polyoxyethylene ether; 0.8 part of dipotassium tetraborate, 0.6 part of tin tetrachloride, 2.3 parts of laruyl alcohol oleates; 1.4 parts of sodium tartrates; 0.9 part of zinc stearate, 1.5 parts of N- acyl amino hydrochlorates, 2.7 parts of vinyltrimethoxysilanes.Master batch prepared by the present invention is suitable for PA fiber, and the flame retardant property of master batch is good.

Description

The preparation method of PA fiber master batch
Technical field
The present invention relates to the preparation methods of PA fiber master batch.
Background technique
Polyamide (PA) fiber is using wider fiber, and industrially PA fiber is largely used to manufacture cord fabric thread, industry With cloth, hawser, conveyer belt, tent, fishing net etc., parachute and other army fabrics are mainly used as in national defence.
The approach two for obtaining PLA colored fibre now has item: one is traditional printing and dyeing method, and another is recent two decades The Masterbatch original liquid coloring mode that have developed rapidly.Wherein printing and dyeing method is due to that can generate a large amount of colorful wastewater, and the energy disappears Consumption is big, is replaced step by step by master batch original liquid coloring mode.
Purposes with color master-batch original liquid coloring fiber is more and more wider, also more and more to the various performance requirements of fiber. The obtained colored fiber of Masterbatch generally produced with solvent dye due to high temperature washing fastness, high-temperature shaping fastness and high temperature again The color fastness such as dyeing and printing are bad, it may appear that the problems such as serious colour fading and distillation migrate viscous color pollution ring, using by very much Limitation.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation method of PA fiber master batch, it is fine that the master batch of preparation is suitable for PA Dimension, and the flame retardant property of master batch is good.
To achieve the above object, the technical scheme is to design a kind of preparation methods of PA fiber master batch, by weight Part meter is measured, the master batch is composed of the following components:
32 parts of PA,
17 parts of pigment,
1.8 parts of sodium potassium tartrate tetrahydrates,
1.4 parts of titanium acetylacetones,
2.1 part polyoxyethylene ether,
0.8 part of dipotassium tetraborate,
0.6 part of tin tetrachloride,
2.3 parts of laruyl alcohol oleates,
1.4 parts of sodium tartrates,
0.9 part of zinc stearate,
1.5 parts of N- acyl amino hydrochlorates,
2.7 parts of vinyltrimethoxysilanes；
The preparation method includes the following steps:
1) pigment first carries out wet grinding decentralized processing, and pigment and liquid phase medium are isolated after partial size is qualified, is taken off under vacuum clean Decentralized medium is spare；
2) each component is mixed, is squeezed out in double screw extruder, water cooling bracing pelletizing obtains master batch.
Preferably, control pigment particle size D50 is 0.7 hereinafter, D90 is at 0.9 micron or less.
Preferably, the pigment include pigment red 122, pigment red 149, paratonere 202, pigment orange 68, pigment yellow 110, Pigment yellow 150, pigment yellow 192, pigment Green 7, pigment blue 15: 1, pigment blue 15: 3, pigment blue 60, pigment violet 19, pigment Violet 23, One or more of pigment black 7.
The advantages and beneficial effects of the present invention are: master batch prepared by the present invention is suitable for PA fiber, and master batch is fire-retardant Performance is good.
The performance and purposes of master batch are to be determined by its component and proportion, and the different component in master batch can mutual shadow Sound, component and its proportion can determine the final performance of master batch, and if fruit component and its proportion be not mutually coordinated, single component is brought Beneficial effect, can even be eliminated by other components abatement, when serious, different component is mutually contradicted, and is not had whole comprehensive Cooperation is used, and negative interaction and substandard products are generated.The present invention passes through a large amount of creative works, verifies repeatedly, obtains the optimal component of master batch And proportion, so that multiple components combine, are mutually coordinated and generate positive comprehensive effect.
By test, the flame retarding efficiency of master batch is high, and addition 6-8% can reach 1.6 millimeters of fire-retardant UL94-V0 ranks, and master batch Suitable for PA fiber.
The present invention handles pigment using wet grinding dispersing method, and Masterbatch is then made together with other various ingredients, Masterbatch is provided to chemical fibre factory and is spun into colored fiber, can be very good to solve spinning processing problems and downstream Hou Dao factory plus The Fastness Problems such as migration, colour fading, viscous color pollution are alleviated or avoided in work problem.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
The technical solution that the present invention embodies is:
A kind of preparation method of PA fiber master batch, by weight, the master batch is composed of the following components:
32 parts of PA,
17 parts of pigment,
1.8 parts of sodium potassium tartrate tetrahydrates,
1.4 parts of titanium acetylacetones,
2.1 parts of polyoxyethylene ether,
0.8 part of dipotassium tetraborate,
0.6 part of tin tetrachloride,
2.3 parts of laruyl alcohol oleates,
1.4 parts of sodium tartrates,
0.9 part of zinc stearate,
1.5 parts of N- acyl amino hydrochlorates,
2.7 parts of vinyltrimethoxysilanes；
The preparation method includes the following steps:
1) pigment first carries out wet grinding decentralized processing, and pigment and liquid phase medium are isolated after partial size is qualified, is taken off under vacuum clean Decentralized medium is spare；
2) each component is mixed, is squeezed out in double screw extruder, water cooling bracing pelletizing obtains master batch.
Pigment particle size D50 is controlled 0.7 hereinafter, D90 is at 0.9 micron or less.
The pigment includes pigment red 122, pigment red 149, paratonere 202, pigment orange 68, pigment yellow 110, pigment yellow 150, pigment yellow 192, pigment Green 7, pigment blue 15: 1, pigment blue 15: 3, pigment blue 60, pigment violet 19, pigment Violet 23, pigment black One or more of 7.
By test, the flame retarding efficiency of master batch is high, and addition 6-8% can reach 1.6 millimeters of fire-retardant UL94-V0 ranks, and master batch Suitable for PA fiber.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (3)

  1. The preparation method of 1.PA fiber master batch, it is characterised in that:
    By weight, the master batch is composed of the following components:
    32 parts of PA,
    17 parts of pigment,
    1.8 parts of sodium potassium tartrate tetrahydrates,
    1.4 parts of titanium acetylacetones,
    2.1 parts of polyoxyethylene ether,
    0.8 part of dipotassium tetraborate,
    0.6 part of tin tetrachloride,
    2.3 parts of laruyl alcohol oleates,
    1.4 parts of sodium tartrates,
    0.9 part of zinc stearate,
    1.5 parts of N- acyl amino hydrochlorates,
    2.7 parts of vinyltrimethoxysilanes；
    The preparation method includes the following steps:
    1) pigment first carries out wet grinding decentralized processing, and pigment and liquid phase medium are isolated after partial size is qualified, is taken off under vacuum clean Decentralized medium is spare；
    2) each component is mixed, is squeezed out in double screw extruder, water cooling bracing pelletizing obtains master batch.
  2. 2. the preparation method of PA fiber master batch according to claim 1, which is characterized in that control pigment particle size D50 exists 0.7 hereinafter, D90 at 0.9 micron or less.
  3. 3. the preparation method of PA fiber master batch according to claim 2, which is characterized in that the pigment includes paratonere 122, pigment red 149, paratonere 202, pigment orange 68, pigment yellow 110, pigment yellow 150, pigment yellow 192, pigment Green 7, pigment blue 15:1, pigment blue 15: 3, one or more of pigment blue 60, pigment violet 19, pigment Violet 23, pigment black 7.
CN201810835848.4A 2018-07-26 2018-07-26 The preparation method of PA fiber master batch Pending CN109054360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810835848.4A CN109054360A (en) 2018-07-26 2018-07-26 The preparation method of PA fiber master batch

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810835848.4A CN109054360A (en) 2018-07-26 2018-07-26 The preparation method of PA fiber master batch

Publications (1)

Publication Number Publication Date
CN109054360A true CN109054360A (en) 2018-12-21

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289389A (en) * 2013-05-31 2013-09-11 上海彩艳实业有限公司 Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch
CN103571179A (en) * 2012-08-01 2014-02-12 山东道恩高分子材料股份有限公司 Environment-friendly red color masterbatch for nylon
CN105400184A (en) * 2015-12-21 2016-03-16 慈溪康氏新材料有限公司 Polyamide color master batch, and preparation method thereof
CN106589923A (en) * 2016-12-06 2017-04-26 上海彩艳实业有限公司 Polyamide ecological environmental masterbatch and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103571179A (en) * 2012-08-01 2014-02-12 山东道恩高分子材料股份有限公司 Environment-friendly red color masterbatch for nylon
CN103289389A (en) * 2013-05-31 2013-09-11 上海彩艳实业有限公司 Color master batch of chinlon BCF (bulked continuous filament) carpet yarn and preparation method of color master batch
CN105400184A (en) * 2015-12-21 2016-03-16 慈溪康氏新材料有限公司 Polyamide color master batch, and preparation method thereof
CN106589923A (en) * 2016-12-06 2017-04-26 上海彩艳实业有限公司 Polyamide ecological environmental masterbatch and preparation method thereof

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
刘正超: "《染化药剂》", 31 August 2001, 中国纺织出版社 *
姜懋武 等: "《配合饲料原料实用手册》", 31 August 2000, 辽宁科学技术出版社 *
殷宗泰: "《精细化工概论》", 31 October 1985, 化学工业出版社 *
萧莹 等: "《致富化工产品生产技术》", 31 August 1995, 安徽科学技术出版社 *
韩长日 等: "《化工小商品生产法（第十七集）》", 31 August 1996, 湖南科学技术出版社 *
韩长日 等: "《皮革纺织及造纸化学品制造技术》", 30 November 2004, 科学技术文献出版社 *
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Application publication date: 20181221