CN107177993A - A kind of textile dyestuff added with chitosan and preparation method thereof - Google Patents
A kind of textile dyestuff added with chitosan and preparation method thereof Download PDFInfo
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- CN107177993A CN107177993A CN201710531320.3A CN201710531320A CN107177993A CN 107177993 A CN107177993 A CN 107177993A CN 201710531320 A CN201710531320 A CN 201710531320A CN 107177993 A CN107177993 A CN 107177993A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
Abstract
The invention discloses a kind of textile dyestuff added with chitosan and preparation method thereof, it is made from the following raw materials in parts by weight：30 50 parts of natural dye raw material, 13 parts of organic dye raw material, 10 15 parts of chitosan, 15 parts of ethyl cellulose, 24 parts of sodium lauryl sulfate, 48 parts of diethanol amine, 14 parts of malic acid, 47 parts of 12 hydrazine aluminum sulfate potassium, 13 parts of polyvinylpyrrolidone, 48 parts of OPEO, 12 parts of amylopectin, 13 parts of dibutyl tin laurate, 36 parts of oxygen iron oxide red, 13 parts of sulfonated oil, 14 parts of soap powder, 25 parts of oxalic acid, 25 parts of coupling agent, 14 parts of auxiliary agent.The textile dyestuff added with chitosan being prepared from, it is printed and dyed, and effect is good, and to fabric, close friend is harmless.Meanwhile, also disclose the preparation method of this textile dyestuff added with chitosan.
Description
Technical field
The present invention relates to coloring agent field, a kind of textile dyestuff added with chitosan and its preparation side are related specifically to
Method.
Background technology
Dyestuff is that certain color can be made to be attached to the material on fiber, and difficult for drop-off, discoloration.Dyestuff is generally soluble in water
In, a part of dyestuff needs mordant dyestuff is attached on fiber.The color of dyestuff and it tissue between affinity
It is to be determined by the molecular structure of dyestuff in itself, produces the chromophoric group of color and the auxochrome group of affinity is produced between tissue
The dyeing property of coloring agent is together decided on.With developing rapidly for science and technology, the composition and institutional framework of textile also change very
It hurry up, particularly the blending of multiple fiber, intertexture and composite fabric are more and more more, this requirement just to coloring agent is also increasingly
Height, in the prior art, the fabric of dyeing out fade more obvious during long-term washing Exposure to Sunlight, and dyeing is insecure, fit
Requirement of the people to color is not answered.But the most dye affinity of existing in the market is not enough, in high temperature and soda acid
In the environment of, level-dyeing property difference is caused while easily occurring discolouration phenomena.So developing a spinning added with chitosan now
Dyestuff is knitted, it is printed and dyed, and effect is good, and close friend is harmless to fabric, to human body and Environmental security environmental protection, market can be better met
Demand.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of textile dyestuff added with chitosan and preparation method thereof,
It is combined by using specified raw material, coordinates corresponding production technology, the obtained textile dyestuff added with chitosan, its print
Dye effect is good, and to fabric, close friend is harmless, disclosure satisfy that the requirement of industry, with preferable application prospect.
The purpose of the present invention can be achieved through the following technical solutions：
Textile dyestuff added with chitosan, is made from the following raw materials in parts by weight：It is 30-50 parts of natural dye raw material, organic
Dye 1-3 parts of raw material, 10-15 parts of chitosan, 1-5 parts of ethyl cellulose, 2-4 parts of sodium lauryl sulfate, 4-8 parts of diethanol amine,
1-4 parts of malic acid, 4-7 parts of 12 hydrazine aluminum sulfate potassium, 1-3 parts of polyvinylpyrrolidone, 4-8 parts of OPEO,
1-2 parts of amylopectin, 1-3 parts of dibutyl tin laurate, 3-6 parts of oxygen iron oxide red, 1-3 parts of sulfonated oil, 1-4 parts of soap powder, oxalic acid 2-5
Part, 2-5 parts of coupling agent, 1-4 parts of auxiliary agent.
Preferably, the natural dye raw material be indigo plant, woaded blue, hispid arthraxon, turmeric, Asian puccoon, rough gentian, madder, balsamine,
One or more in dye yam, Chinese gall.
Preferably, the coupling agent is γ-aminopropyltrimethoxysilane, VTES, vinyl three
（'beta '-methoxy ethyoxyl）Any one in silane, 3- aminopropyl trimethoxysilanes.
Preferably, the auxiliary agent in citric acid, neopentyl glycol, tartaric acid, sodium lignin sulfonate any one or
It is several.
The preparation method of the described textile dyestuff added with chitosan, comprises the following steps：
（1）Each raw material is weighed according to parts by weight；
（2）Natural dye raw material are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 220-250KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
In alkanone, OPEO, amylopectin, coupling agent, auxiliary agent injection reactor, mix, mixing speed is 75-
120 revs/min, the reaction time is 30 minutes, and reaction temperature is 125-165 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
Preferably, the inert gas is carbon dioxide.
Compared with prior art, its advantage is the present invention：
（1）The textile dyestuff added with chitosan of the present invention, with natural dye raw material, chitosan, ethyl cellulose, 12
Alcohol sodium sulphate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidone, OPEO, amylopectin are
Main component, by adding organic dye raw material, malic acid, dibutyl tin laurate, oxygen iron oxide red, sulfonated oil, soap powder, grass
Acid, coupling agent, auxiliary agent, are aided with the works such as grinding sieving, ultrasonic disperse, distillation under pressure, stirring reaction, cooling foaming, compression spraying
Skill so that the textile dyestuff added with chitosan being prepared from, it is printed and dyed, and effect is good, and to fabric, close friend is harmless, Neng Gouman
The requirement of sufficient industry, with preferable application prospect.
（2）Textile dyestuff raw material added with chitosan of the invention is cheap, technique is simple, suitable for heavy industrialization fortune
With practical.
Embodiment
The technical scheme of invention is described in detail with reference to specific embodiment.
Embodiment 1
（1）10 parts of indigo plant, 30 parts of woaded blue, 1 part of organic dye raw material, 10 parts of chitosan, ethyl cellulose 1 are weighed according to parts by weight
Part, 2 parts of sodium lauryl sulfate, 4 parts of diethanol amine, 1- parts of malic acid, 4 parts of 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidone 1
Part, 4 parts of OPEO, 1 part of amylopectin, 1 part of dibutyl tin laurate, 3 parts of oxygen iron oxide red, 1 part of sulfonated oil, soap
1 part of powder, 2 parts of oxalic acid, 2 parts of γ-aminopropyltrimethoxysilane, 1 part of citric acid；
（2）Indigo plant, woaded blue are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 220KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
In alkanone, OPEO, amylopectin, γ-aminopropyltrimethoxysilane, citric acid injection reactor, mixing
Stirring, mixing speed is 75 revs/min, and the reaction time is 30 minutes, and reaction temperature is 125 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
The performance test results of the obtained textile dyestuff added with chitosan are as shown in table 1.
Embodiment 2
（1）15 parts of hispid arthraxon, 30 parts of turmeric, 1 part of organic dye raw material, 12 parts of chitosan, ethyl cellulose 2 are weighed according to parts by weight
Part, 3 parts of sodium lauryl sulfate, 5 parts of diethanol amine, 2 parts of malic acid, 5 parts of 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidone 1
Part, 5 parts of OPEO, 1 part of amylopectin, 2 parts of dibutyl tin laurate, 4 parts of oxygen iron oxide red, 1 part of sulfonated oil, soap
2 parts of powder, 3 parts of oxalic acid, 3 parts of VTES, 2 parts of neopentyl glycol；
（2）Hispid arthraxon, turmeric are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 230KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
In alkanone, OPEO, amylopectin, VTES, neopentyl glycol injection reactor, mixing is stirred
Mix, mixing speed is 100 revs/min, the reaction time is 30 minutes, reaction temperature is 140 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
The performance test results of the obtained textile dyestuff added with chitosan are as shown in table 1.
Embodiment 3
（1）15 parts of Asian puccoon, rough gentian 35 are weighed with part, 2 parts of organic dye raw material, 14 parts of chitosan, ethyl cellulose according to parts by weight
4 parts of element, 3 parts of sodium lauryl sulfate, 6 parts of diethanol amine, 3 parts of malic acid, 6 parts of 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidine
2 parts of ketone, 7 parts of OPEO, 2 parts of amylopectin, 2 parts of dibutyl tin laurate, 5 parts of oxygen iron oxide red, sulfonated oil 2
Part, 3 parts of soap powder, 4 parts of oxalic acid, vinyl three（'beta '-methoxy ethyoxyl）4 parts of silane, 3 parts of tartaric acid；
（2）Asian puccoon, rough gentian are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 240KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
Alkanone, OPEO, amylopectin, vinyl three（'beta '-methoxy ethyoxyl）Silane, tartaric acid injection reactor
In, mix, mixing speed is 110 revs/min, the reaction time is 30 minutes, reaction temperature is 150 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
The performance test results of the obtained textile dyestuff added with chitosan are as shown in table 1.
Embodiment 4
（1）15 parts of dye yam, 30 parts of Chinese gall, 3 parts of organic dye raw material, 15 parts of chitosan, ethyl cellulose are weighed according to parts by weight
5 parts of element, 4 parts of sodium lauryl sulfate, 8 parts of diethanol amine, 4 parts of malic acid, 7 parts of 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidine
3 parts of ketone, 8 parts of OPEO, 2 parts of amylopectin, 3 parts of dibutyl tin laurate, 6 parts of oxygen iron oxide red, sulfonated oil 3
Part, 4 parts of soap powder, 5 parts of oxalic acid, 5 parts of 3- aminopropyl trimethoxysilanes, 4 parts of sodium lignin sulfonate；
（2）Dye yam, Chinese gall are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 250KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
In alkanone, OPEO, amylopectin, 3- aminopropyl trimethoxysilanes, sodium lignin sulfonate injection reactor,
Mix, mixing speed is 120 revs/min, the reaction time is 30 minutes, reaction temperature is 165 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
The performance test results of the obtained textile dyestuff added with chitosan are as shown in table 1.
Comparative example 1
（1）10 parts of indigo plant, 30 parts of woaded blue, 1 part of organic dye raw material, 10 parts of chitosan, lauryl alcohol sulfuric acid are weighed according to parts by weight
2 parts of sodium, 4 parts of diethanol amine, 1- parts of malic acid, 4 parts of 12 hydrazine aluminum sulfate potassium, 1 part of polyvinylpyrrolidone, octyl phenol polyoxy
4 parts of vinethene, 1 part of amylopectin, 1 part of dibutyl tin laurate, 3 parts of oxygen iron oxide red, 1 part of sulfonated oil, 1 part of soap powder, γ-ammonia third
2 parts of base trimethoxy silane, 1 part of citric acid；
（2）Indigo plant, woaded blue are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 220KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidone, octyl phenol
In APEO, amylopectin, γ-aminopropyltrimethoxysilane, citric acid injection reactor, mix, stirring speed
Spend for 75 revs/min, the reaction time is 30 minutes, reaction temperature is 125 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
The performance test results of the obtained textile dyestuff added with chitosan are as shown in table 1.
Comparative example 2
（1）15 parts of dye yam, 30 parts of Chinese gall, 3 parts of organic dye raw material, 15 parts of chitosan, ethyl cellulose are weighed according to parts by weight
5 parts of element, 4 parts of sodium lauryl sulfate, 8 parts of diethanol amine, 4 parts of malic acid, 7 parts of 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidine
3 parts of ketone, 8 parts of OPEO, 3 parts of dibutyl tin laurate, 6 parts of oxygen iron oxide red, 4 parts of soap powder, 5 parts of oxalic acid, 3- ammonia
5 parts of propyl trimethoxy silicane, 4 parts of sodium lignin sulfonate；
（2）Dye yam, Chinese gall are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 250KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
In alkanone, OPEO, 3- aminopropyl trimethoxysilanes, sodium lignin sulfonate injection reactor, mix,
Mixing speed is 120 revs/min, and the reaction time is 30 minutes, and reaction temperature is 165 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
The performance test results of the obtained textile dyestuff added with chitosan are as shown in table 1.
Textile dyestuff added with chitosan made from embodiment 1-4 and comparative example 1-2 is subjected to soaping fastness, chlorine drift
Fastness, surface tension, this several performance tests of viscosity and sensitivity response.
Table 1
| Soaping fastness（Level） | Chlorine floats fastness（Level） | Surface tension（10-3 N/m;20） | Viscosity（CP） | Sensitivity response | |
| Embodiment 1 | 4 | 4 | 70.21 | 1.73 | Nothing |
| Embodiment 2 | 4 | 4 | 70.91 | 1.75 | Nothing |
| Embodiment 3 | 4 | 4 | 69.93 | 1.71 | Nothing |
| Embodiment 4 | 4 | 4 | 69.98 | 1.77 | Nothing |
| Comparative example 1 | 2 | 2 | 75.63 | 1.11 | Nothing |
| Comparative example 2 | 3 | 3 | 74.82 | 1.24 | Nothing |
The textile dyestuff added with chitosan of the present invention, with natural dye raw material, chitosan, ethyl cellulose, lauryl alcohol
Sodium sulphate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinylpyrrolidone, OPEO, based on amylopectin
Want composition, by add organic dye raw material, malic acid, dibutyl tin laurate, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid,
Coupling agent, auxiliary agent, are aided with the techniques such as grinding sieving, ultrasonic disperse, distillation under pressure, stirring reaction, cooling foaming, compression spraying,
So that the textile dyestuff added with chitosan being prepared from, it is printed and dyed, and effect is good, and to fabric, close friend is harmless, disclosure satisfy that row
The requirement of industry, with preferable application prospect.Textile dyestuff raw material added with chitosan of the invention is cheap, technique is simple,
Used suitable for heavy industrialization, it is practical.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (6)
1. a kind of textile dyestuff added with chitosan, it is characterised in that：It is made from the following raw materials in parts by weight：Natural dye is former
30-50 parts of material, 1-3 parts of organic dye raw material, 10-15 parts of chitosan, 1-5 parts of ethyl cellulose, sodium lauryl sulfate 2-4
Part, 4-8 parts of diethanol amine, 1-4 parts of malic acid, 4-7 parts of 12 hydrazine aluminum sulfate potassium, 1-3 parts of polyvinylpyrrolidone, octyl phenol
4-8 parts of APEO, 1-2 parts of amylopectin, 1-3 parts of dibutyl tin laurate, 3-6 parts of oxygen iron oxide red, 1-3 parts of sulfonated oil,
1-4 parts of soap powder, 2-5 parts of oxalic acid, 2-5 parts of coupling agent, 1-4 parts of auxiliary agent.
2. the textile dyestuff according to claim 1 added with chitosan, it is characterised in that：The natural dye raw material
For the one or more in indigo plant, woaded blue, hispid arthraxon, turmeric, Asian puccoon, rough gentian, madder, balsamine, dye yam, Chinese gall.
3. the textile dyestuff according to claim 1 added with chitosan, it is characterised in that：The coupling agent is γ-ammonia
Propyl trimethoxy silicane, VTES, vinyl three（'beta '-methoxy ethyoxyl）Silane, 3- aminopropyl front threes
Any one in TMOS.
4. the textile dyestuff according to claim 1 added with chitosan, it is characterised in that：The auxiliary agent is selected from lemon
Any one or a few in acid, neopentyl glycol, tartaric acid, sodium lignin sulfonate.
5. according to the preparation method of any described textile dyestuff added with chitosan of Claims 1 to 4, it is characterised in that
Comprise the following steps：
（1）Each raw material is weighed according to parts by weight；
（2）Natural dye raw material are cleaned, dry, are ground to powder, 300 mesh sieves are crossed；
（3）By step（2）In powder be dissolved in isometric deionized water, ultrasonic disperse, ultrasonic time be 60 minutes, ultrasound
Frequency is 220-250KW；
（4）By step（3）Ultrasonic disperse mixture be heated to 55 DEG C, add isometric absolute ethyl alcohol, distillation under pressure is obtained
To the filtrate of condensation；
（5）By chitosan, ethyl cellulose, sodium lauryl sulfate, diethanol amine, 12 hydrazine aluminum sulfate potassium, polyvinyl pyrrole
In alkanone, OPEO, amylopectin, coupling agent, auxiliary agent injection reactor, mix, mixing speed is 75-
120 revs/min, the reaction time is 30 minutes, and reaction temperature is 125-165 DEG C；
（6）By step（5）In reactant as being cooled to room temperature under inert gas environment；
（7）Toward step（6）Cooling thing in add step（4）Condensation filtrate and organic dye raw material, malic acid, tin dilaurate
Dibutyl tin, oxygen iron oxide red, sulfonated oil, soap powder, oxalic acid are well mixed, and inject foaming machine, fully heave foaming, stand 90 minutes；
（8）By step（7）In mixed liquor filtering, compression spraying obtains powdered dyestuff finished product, packing.
6. the preparation method of the textile dyestuff according to claim 5 added with chitosan, it is characterised in that：The inertia
Gas is carbon dioxide.
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| CN107724116A (en) * | 2017-09-20 | 2018-02-23 | 安徽省无为县永昌鬃刷制造有限公司 | A kind of bristles coloring agent |
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| CN107724122A (en) * | 2017-09-20 | 2018-02-23 | 安徽省无为县永昌鬃刷制造有限公司 | A kind of colouring method for improving bristles malleable |
| CN107724116A (en) * | 2017-09-20 | 2018-02-23 | 安徽省无为县永昌鬃刷制造有限公司 | A kind of bristles coloring agent |
| CN107747236A (en) * | 2017-09-20 | 2018-03-02 | 安徽省无为县永昌鬃刷制造有限公司 | One kind improves bristles flexibility coloring agent |
| CN109487590A (en) * | 2018-11-20 | 2019-03-19 | 广东精英纺织服饰科技有限公司 | A kind of textile dyestuff and preparation method thereof with the anti-function that fades |
| CN109537315A (en) * | 2018-11-30 | 2019-03-29 | 河南健锋帽业有限公司 | A kind of colouring method of fabric |
| CN110592767A (en) * | 2019-09-19 | 2019-12-20 | 界首市远航织带有限公司 | Mattress edge-covering woven belt and production process thereof |
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