CN109537315A - A kind of colouring method of fabric - Google Patents
A kind of colouring method of fabric Download PDFInfo
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- CN109537315A CN109537315A CN201811451616.5A CN201811451616A CN109537315A CN 109537315 A CN109537315 A CN 109537315A CN 201811451616 A CN201811451616 A CN 201811451616A CN 109537315 A CN109537315 A CN 109537315A
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- colouring method
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- 239000004744 fabric Substances 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000004040 coloring Methods 0.000 title claims abstract description 24
- 238000004043 dyeing Methods 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000000284 extract Substances 0.000 claims abstract description 22
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 11
- 239000010445 mica Substances 0.000 claims abstract description 9
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 9
- 239000007921 spray Substances 0.000 claims abstract description 8
- 238000009955 starching Methods 0.000 claims abstract description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000003086 colorant Substances 0.000 claims description 24
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 20
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 13
- 229920001353 Dextrin Polymers 0.000 claims description 11
- 239000004375 Dextrin Substances 0.000 claims description 11
- 235000019425 dextrin Nutrition 0.000 claims description 11
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 10
- 238000006555 catalytic reaction Methods 0.000 claims description 10
- 235000019441 ethanol Nutrition 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 229940037003 alum Drugs 0.000 claims description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 5
- 229940043237 diethanolamine Drugs 0.000 claims description 5
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 238000002137 ultrasound extraction Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000011964 heteropoly acid Substances 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 239000013049 sediment Substances 0.000 claims 1
- 244000018716 Impatiens biflora Species 0.000 abstract description 8
- 235000015912 Impatiens biflora Nutrition 0.000 abstract description 8
- 235000005155 Tanacetum balsamita Nutrition 0.000 abstract description 8
- 239000004753 textile Substances 0.000 abstract description 7
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000975 dye Substances 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Coloring (AREA)
Abstract
A kind of colouring method of fabric, includes the following steps: step 1, pretreatment；Step 2 absorbs dyeing；Step 3: salt is washed；Step 4: washing and starching；Step 5: spray treatment.The present invention is using iron oxide red and nail flower extract cooperation mica powder, coupling agent, levelling agent and color fixing agent use as textile dyeing, it overcomes iron oxide red and is easy to appear spot in coloring process, uneven color one, garden balsam dyeing, which is easy to appear part, the case where color difference, keeps fabric colouring uniform.
Description
Technical field
The present invention relates to field of printing and dyeing, more particularly, to a kind of colouring method of fabric.
Background technique
Technical process based on being chemically treated is carried out to textile material (fiber, yarn and fabric), the modern times are also commonly referred to as
Printing and dyeing.Dyeing and finishing together, forms the overall process of textile fabric production with spinning, woven or knitting production.Dyeing and finishing includes pretreatment, dye
Color, stamp and arrangement.The superiority and inferiority of dyeing and finishing quality has important influence to the use value of textile.Pretreatment is also known as scouringed and bleaching,
Main purpose is to remove the impurity on textile material, makes subsequent dyeing, stamp, arranges and process smooth, acquisition
Expected processing effect.Dyeing is that physics or chemical combination occurs by dyestuff and fiber to have textile material centainly
Color.Arrangement is to improve the appearances such as gloss, the form of fabric by physical action or using chemical agent；Improve the clothes of fabric
With performance or make fabric have water repellent, refuse the characteristics such as oil.
But the phenomenon that dyeing is uneven, fugitive color and color are more dim is clearly present in existing dyeing and printing process.
Summary of the invention
In view of this, in view of the deficiencies of the prior art, it is an object of the present invention to provide a kind of colouring methods of fabric, so that
The color of fabric is bright and beautiful after dyeing, color is uniform and effect not easy to fade.
In order to achieve the above objectives, the invention adopts the following technical scheme:
A kind of colouring method of fabric, includes the following steps:
Pretreatment: step 1 after design on fabric surface is singed, is placed in acidic aqueous solution and impregnates 30-50 minutes, take out, dry in the air
It is dry；The pH=4-5 of the acidic aqueous solution；
Step 2 absorbs dyeing: coloring agent being dissolved in pH=9-10 alkaline aqueous solution and forms dyeing liquor, and step 1 is pre-
Treated, and design on fabric surface is sticked with blotting paper, is placed in dyeing liquor, and 50-60 DEG C is taken out after immersion 5-8 hours, takes water suction off
Paper, 80-100 DEG C of drying；Bath raio: 15-20:1；The mass fraction of coloring agent is 15-20wt% in dyeing liquor；
Step 3: salt is washed: the NaCl aqueous solution soaking of step 2 treated fabric 1-2mol/L is washed 1-3 times,
Each 20-30min；
Step 4: washing and starching: the cloth after step 3 salt is washed is placed in amidin, is washed and starched 30-50 minutes, take out,
It is dry to stretch Pingliang；
Step 5: spray treatment: the cloth even application fluorescer after being washed and starched to step 4,80-90 DEG C drying 50-60 points
Zhong Hou, washing remove the slurry and part fluorescer on cloth.
Optionally, the composition of the coloring agent and its parts by weight are 15-20 parts of mica powder, 10-15 parts of iron oxide red,
20-25 parts of nail flower extract, 2-3 parts of coupling agent, 1-2 parts of levelling agent and 1-3 parts of color fixing agent；
Preparation method is the raw material for taking the parts by weight, and in the deionized water of parts by weight such as addition, ultrasonic disperse surpasses
The sound time is 50 minutes, supersonic frequency 220-250KW；The ethyl alcohol of parts by weight such as add, it is back flow reaction 20-30 minutes, cold
But, compression spraying obtains powdered coloring agent finished product.
Optionally, the nail flower extract is that garden balsam crushes the alum that 1-1.5wt% parts by weight are added, and 100- is added
The water of 150wt% parts by weight at -15~-25 DEG C, is lyophilized, crushes, after ultramicro grinding, is warming up to 50-60 DEG C, ultrasonic extraction 10-
20 minutes, water phase and solid residue are separated, solid residue is extracted with the ethyl alcohol that volumetric concentration is 75%, extract liquor is condensed into
Paste is dried to powder and both obtained.
Optionally, the coupling agent is vinyltriethoxysilane.
Optionally, the levelling agent is aliphatic alcohol sulfate.
Optionally, the color fixing agent the preparation method is as follows: the diethanol amine of equimolar number, triethanolamine are dissolved in DMF
Polyethers, polyethers and epoxychloropropane are generated under the catalysis of solid heteropoly acid generates color fixing agent under the catalysis of KOH.The epoxy
Chloropropane additional amount is the 10-35wt% of polyethers weight；The additional amount of the KOH is 1-3 times of epoxychloropropane molal quantity.
Optionally, the group of amidin becomes 5-10g starch/kg water.
Optionally, the composition of the fluorescer and its parts by weight are 20-30 parts of dextrin, 20-30 parts of silver nitrate, sulfuric acid
20-30 parts of barium, 15-20 parts of pearl powder, 10-20 parts of glycerol, 10-15 parts of inorganic gel, 100-150 parts and DMF80-100 parts of water.
Preparation method is that the silver nitrate, barium sulfate, pearl powder of the parts by weight are placed in ball mill and are ground to granularity
20-50 μm, water and DMF is added in addition dextrin, inorganic gel after mixing, is finally added with stirring glycerol, both.
The beneficial effects of the present invention are:
1. being made in the present invention with iron oxide red and nail flower extract cooperation mica powder, coupling agent, levelling agent and color fixing agent
With for textile dyeing, overcome iron oxide red in coloring process in be easy to appear spot, uneven color one, garden balsam dyeing is held
Easily there is the bad situation of color brightness, makes fabric colouring uniformly, it is beautiful in colour.
2. colouring method step of the invention is fine, color is more bright-coloured and colour-fast after spray treatment, after spray coated
Color is more firm, is not in discolouration phenomena, and improves the oil resistant of fabric, water-fast, high and low temperature resistance.
3. fabric surface sticks one layer of blotting paper, through blotting paper penetration dyeing, dyeing kinetics are slack-off, and dyeing course is more thin
It causes, dyeing is more uniform, and color fastness is higher.
Specific embodiment
Embodiment 1
A kind of colouring method of fabric, includes the following steps:
Pretreatment: step 1 after design on fabric surface is singed, is placed in acidic aqueous solution and impregnates 30 minutes, take out, dry；
The pH=4 of the acidic aqueous solution；
Step 2 absorbs dyeing: coloring agent being dissolved in pH=9 alkaline aqueous solution and forms dyeing liquor, step 1 is located in advance
Design on fabric surface after reason is sticked with blotting paper, is placed in dyeing liquor, 50 DEG C impregnate 5 hours after take out, take blotting paper off, 80 DEG C of bakings
It is dry；Bath raio: 15:1；The mass fraction of coloring agent is 15wt% in dyeing liquor；
Step 3: salt is washed: the NaCl aqueous solution soaking of step 2 treated fabric 1mol/L being washed 1 time, every time
20min；
Step 4: washing and starching: the cloth after step 3 salt is washed is placed in amidin, is washed and starched 30 minutes, take out, stretch it is flat
Airing；The group of the amidin becomes 5g starch/kg water；
Step 5: spray treatment: the cloth even application fluorescer after being washed and starched to step 4, after 80 DEG C dry 50 minutes,
Washing removes slurry and part fluorescer on cloth.
The composition and its parts by weight of the coloring agent are 15 parts of mica powder, 10 parts of iron oxide red, nail flower extract 20
Part, 2 parts of coupling agent, 1 part of levelling agent and 1 part of color fixing agent；
Preparation method is the raw material for taking the parts by weight, and in the deionized water of parts by weight such as addition, ultrasonic disperse surpasses
The sound time is 50 minutes, supersonic frequency 220KW；The ethyl alcohol of parts by weight such as add, back flow reaction 20 minutes, cooling, compression
It is spraying, obtain powdered coloring agent finished product.
The nail flower extract is that garden balsam crushes the alum that 1wt% parts by weight are added, and 100wt% parts by weight are added
Water at -15 DEG C, is lyophilized, crushes, and after ultramicro grinding, is warming up to 50 DEG C, ultrasonic extraction 10 minutes, separates water phase and solid residue,
Solid residue is extracted with the ethyl alcohol that volumetric concentration is 75%, extract liquor is condensed into paste, powder is dried to and both obtained.
The coupling agent is vinyltriethoxysilane.
The levelling agent is aliphatic alcohol sulfate.
The color fixing agent the preparation method is as follows: that the diethanol amine of equimolar number, triethanolamine are dissolved in DMF is miscellaneous in solid
Polyethers, polyethers and epoxychloropropane are generated under the catalysis of polyacid generates color fixing agent under the catalysis of KOH.The epoxychloropropane adds
Enter the 10wt% that amount is polyethers weight；The additional amount of the KOH is 1 times of epoxychloropropane molal quantity.
The composition and its parts by weight of the fluorescer are 20 parts of dextrin, 20 parts of silver nitrate, 20 parts of barium sulfate, and pearl powder
15 parts, 10 parts of glycerol, 10 parts of inorganic gel, 100 parts and DMF80 parts of water.
Preparation method is that the silver nitrate, barium sulfate, pearl powder of the parts by weight are placed in ball mill and are ground to granularity
20 μm, water and DMF is added in addition dextrin, inorganic gel after mixing, is finally added with stirring glycerol, both.
Embodiment 2
A kind of colouring method of fabric, includes the following steps:
Pretreatment: step 1 after design on fabric surface is singed, is placed in acidic aqueous solution and impregnates 50 minutes, take out, dry；
The pH=5 of the acidic aqueous solution；
Step 2 absorbs dyeing: coloring agent being dissolved in pH=10 alkaline aqueous solution and forms dyeing liquor, step 1 is located in advance
Design on fabric surface after reason is sticked with blotting paper, is placed in dyeing liquor, 60 DEG C impregnate 8 hours after take out, take blotting paper off, 100 DEG C
Drying；Bath raio: 20:1；The mass fraction of coloring agent is 20wt% in dyeing liquor；
Step 3: salt is washed: the NaCl aqueous solution soaking of step 2 treated fabric 2mol/L being washed 3 times, every time
30min；
Step 4: washing and starching: the cloth after step 3 salt is washed is placed in amidin, is washed and starched 50 minutes, take out, stretch it is flat
Airing；The group of amidin becomes 10g starch/kg water；
Step 5: spray treatment: the cloth even application fluorescer after washing and starching to step 4,90 DEG C dry after sixty minutes,
Washing removes slurry and part fluorescer on cloth.
The composition and its parts by weight of the coloring agent are 20 parts of mica powder, 15 parts of iron oxide red, nail flower extract 25
Part, 3 parts of coupling agent, 2 parts of levelling agent and 3 parts of color fixing agent；
Preparation method is the raw material for taking the parts by weight, and in the deionized water of parts by weight such as addition, ultrasonic disperse surpasses
The sound time is 50 minutes, supersonic frequency 250KW；The ethyl alcohol of parts by weight such as add, back flow reaction 30 minutes, cooling, compression
It is spraying, obtain powdered coloring agent finished product.
Optionally, the nail flower extract is that garden balsam crushes the alum that 1.5wt% parts by weight are added, and is added
The water of 150wt% parts by weight at -25 DEG C, is lyophilized, crushes, and after ultramicro grinding, is warming up to 60 DEG C, and ultrasonic extraction 20 minutes, separation
Solid residue is extracted with the ethyl alcohol that volumetric concentration is 75%, extract liquor is condensed into paste, is dried to by water phase and solid residue
Powder both obtained.
The coupling agent is vinyltriethoxysilane.
The levelling agent is aliphatic alcohol sulfate.
The color fixing agent the preparation method is as follows: that the diethanol amine of equimolar number, triethanolamine are dissolved in DMF is miscellaneous in solid
Polyethers, polyethers and epoxychloropropane are generated under the catalysis of polyacid generates color fixing agent under the catalysis of KOH.The epoxychloropropane adds
Enter the 35wt% that amount is polyethers weight；The additional amount of the KOH is 3 times of epoxychloropropane molal quantity.
The composition and its parts by weight of the fluorescer are 30 parts of dextrin, 30 parts of silver nitrate, 30 parts of barium sulfate, and pearl powder
20 parts, 20 parts of glycerol, 15 parts of inorganic gel, 150 parts and DMF100 parts of water.
Preparation method is that the silver nitrate, barium sulfate, pearl powder of the parts by weight are placed in ball mill and are ground to granularity
50 μm, water and DMF is added in addition dextrin, inorganic gel after mixing, is finally added with stirring glycerol, both.
Embodiment 3
A kind of colouring method of fabric, includes the following steps:
Pretreatment: step 1 after design on fabric surface is singed, is placed in acidic aqueous solution and impregnates 40 minutes, take out, dry；
The pH=4.5 of the acidic aqueous solution；
Step 2 absorbs dyeing: coloring agent being dissolved in pH=9.5 alkaline aqueous solution and forms dyeing liquor, and step 1 is pre-
Treated, and design on fabric surface is sticked with blotting paper, is placed in dyeing liquor, 55 DEG C impregnate 6 hours after take out, take blotting paper off, 90 DEG C
Drying；Bath raio: 17:1；The mass fraction of coloring agent is 17wt% in dyeing liquor；
Step 3: salt is washed: the NaCl aqueous solution soaking of step 2 treated fabric 1.5mol/L being washed 2 times, often
Secondary 25min；
Step 4: washing and starching: the cloth after step 3 salt is washed is placed in amidin, is washed and starched 40 minutes, take out, stretch it is flat
Airing；The group of amidin becomes 8g starch/kg water；
Step 5: spray treatment: the cloth even application fluorescer after being washed and starched to step 4, after 85 DEG C dry 55 minutes,
Washing removes slurry and part fluorescer on cloth.
The coloring agent composition and its parts by weight are 17 parts of mica powder, 12 parts of iron oxide red, nail flower extract 22
Part, 2.5 parts of coupling agent, 1.5 parts of levelling agent and 2 parts of color fixing agent；
Preparation method is the raw material for taking the parts by weight, and in the deionized water of parts by weight such as addition, ultrasonic disperse surpasses
The sound time is 50 minutes, supersonic frequency 230KW；The ethyl alcohol of parts by weight such as add, back flow reaction 25 minutes, cooling, compression
It is spraying, obtain powdered coloring agent finished product.
The nail flower extract is that garden balsam crushes the alum that 1.2wt% parts by weight are added, and 125wt% parts by weight are added
Water, at -20 DEG C, be lyophilized, crush, after ultramicro grinding, be warming up to 55 DEG C, ultrasonic extraction 15 minutes, separate water phase and solid is residual
Solid residue is extracted with the ethyl alcohol that volumetric concentration is 75%, extract liquor is condensed into paste, powder is dried to and both obtained by slag.
The coupling agent is vinyltriethoxysilane.
The levelling agent is aliphatic alcohol sulfate.
The color fixing agent the preparation method is as follows: that the diethanol amine of equimolar number, triethanolamine are dissolved in DMF is miscellaneous in solid
Polyethers, polyethers and epoxychloropropane are generated under the catalysis of polyacid generates color fixing agent under the catalysis of KOH.The epoxychloropropane adds
Enter the 25wt% that amount is polyethers weight；The additional amount of the KOH is 2 times of epoxychloropropane molal quantity.
The composition and its parts by weight of the fluorescer are 25 parts of dextrin, 25 parts of silver nitrate, 25 parts of barium sulfate, and pearl powder
17 parts, 15 parts of glycerol, 12 parts of inorganic gel, 125 parts and DMF90 parts of water.
Preparation method is that the silver nitrate, barium sulfate, pearl powder of the parts by weight are placed in ball mill and are ground to granularity
35 μm, water and DMF is added in addition dextrin, inorganic gel after mixing, is finally added with stirring glycerol, both.
Embodiment 4
A kind of colouring method of fabric, step is substantially the same manner as Example 3, the difference is that: the coloring agent
Composition and its parts by weight are 16 parts of mica powder, 11 parts of iron oxide red, 21 parts of nail flower extract, and 2 parts of coupling agent, levelling agent 1
Part and 3 parts of color fixing agent；
The composition and its parts by weight of the fluorescer are 22 parts of dextrin, 23 parts of silver nitrate, 24 parts of barium sulfate, and pearl powder
16 parts, 12 parts of glycerol, 11 parts of inorganic gel, 110 parts and DMF85 parts of water.
Embodiment 5
A kind of colouring method of fabric, step is substantially the same manner as Example 3, the difference is that: the coloring agent
Composition and its parts by weight are 19 parts of mica powder, 14 parts of iron oxide red, 24 parts of nail flower extract, and 3 parts of coupling agent, levelling agent 2
Part and 1 part of color fixing agent；
The composition and its parts by weight of the fluorescer are 28 parts of dextrin, 29 parts of silver nitrate, 27 parts of barium sulfate, and pearl powder
18 parts, 19 parts of glycerol, 14 parts of inorganic gel, 140 parts and DMF95 parts of water.
Comparative example 1
Comparative example 1 is substantially the same manner as Example 3, the difference is that, blotting paper is not added in step 2.Dye uniformity
It is slightly lower.
Comparative example 2
Comparative example 2 is substantially the same manner as Example 3, the difference is that, in coloring agent with etc. weight iron oxide red generation
For nail flower extract.The color of printing and dyeing gained fabric is more dull.
Comparative example 3
Comparative example 3 is substantially the same manner as Example 3, the difference is that, in coloring agent with etc. weight garden balsam extract
Object replaces iron oxide red.There is deep mixed spot on the surface of printing and dyeing gained fabric.
The Apparent Depth and fastness of the fabric of each embodiment are shown in Table 1.
The Apparent Depth and fastness of 1 fabric of table
| Sample | K/S | Dry grinding fastness | Wet fastness of rubbing |
| Embodiment 1 | 10.41 | 4-5 | 4-5 |
| Embodiment 2 | 10.43 | 4-5 | 4-5 |
| Embodiment 3 | 10.50 | 4-5 | 4-5 |
| Embodiment 4 | 10.45 | 4-5 | 4-5 |
| Embodiment 5 | 10.46 | 4-5 | 4-5 |
| Comparative example 1 | 10.55 | 3-4 | 3-4 |
| Comparative example 2 | 10.35 | 4 | 4 |
| Comparative example 3 | 10.55 | 4 | 4 |
As shown in Table 1, coloring agent provided by the invention has excellent dry, wet fastness of rubbing, apparent deep at 4 grades or more
Degree is uniform, between 10.41-10.50；Apparent Depth is deeper compared with Example 3 for comparative example 1, but its dry, wet fastness of rubbing
It reduces, illustrates to print and dye by blotting paper, there is higher dry, wet fastness of rubbing；The dry of comparative example 2,3, wet fastness of rubbing are equal
It reduces, it is more secured to illustrate that garden balsam cooperates with dyeing to dye than one-component with iron oxide red.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, this field is common
Other modifications or equivalent replacement that technical staff makes technical solution of the present invention, without departing from technical solution of the present invention
Spirit and scope, be intended to be within the scope of the claims of the invention.
Claims (8)
1. a kind of colouring method of fabric, which comprises the steps of:
Pretreatment: step 1 after design on fabric surface is singed, is placed in acidic aqueous solution and impregnates 30-50 minutes, take out, dry；Institute
State pH=4-5 of acidic aqueous solution；
Step 2 absorbs dyeing: coloring agent being dissolved in pH=9-10 alkaline aqueous solution and forms dyeing liquor, step 1 is pre-processed
Design on fabric surface afterwards is sticked with blotting paper, is placed in dyeing liquor, and 50-60 DEG C is taken out after immersion 5-8 hours, takes blotting paper, 80- off
100 DEG C of drying；Bath raio: 15-20:1；The mass fraction of coloring agent is 15-20wt% in dyeing liquor；
Step 3: salt is washed: the NaCl aqueous solution soaking of step 2 treated fabric 1-2mol/L being washed 1-3 times, every time
20-30min；
Step 4: washing and starching: the cloth after step 3 salt is washed is placed in amidin, is washed and starched 30-50 minutes, take out, stretch it is flat
Airing；
Step 5: spray treatment: the cloth even application fluorescer after being washed and starched to step 4,80-90 DEG C drying 50-60 minutes
Afterwards, it washes, removes the slurry and part fluorescer on cloth.
2. the colouring method of fabric according to claim 1, which is characterized in that the composition and its parts by weight of the coloring agent
Number is 15-20 parts of mica powder, 10-15 parts of iron oxide red, 20-25 parts of nail flower extract, and 2-3 parts of coupling agent, levelling agent 1-2
Part and color fixing agent 1-3 parts.
3. the colouring method of fabric according to claim 1, which is characterized in that the nail flower extract is nail pollen
The broken alum that 1-1.5wt% parts by weight are added, is added the water of 100-150wt% parts by weight, at -15 ~ -25 DEG C, is lyophilized, crushes, surpasses
After Crushing of Ultrafine, it is warming up to 50-60 DEG C, ultrasonic extraction 10-20 minutes, water phase and solid residue are separated, by solid residue with volume
The ethyl alcohol that concentration is 75% extracts, and extract liquor is condensed into paste, is dried to powder and both obtained.
4. the colouring method of fabric according to claim 2, which is characterized in that the coupling agent is vinyl triethoxyl
Silane.
5. the colouring method of fabric according to claim 2, which is characterized in that the levelling agent is aliphatic alcohol sulfate.
6. the colouring method of fabric according to claim 2, which is characterized in that the color fixing agent the preparation method is as follows:
The diethanol amine of equimolar number, triethanolamine are dissolved in DMF and generate polyethers, polyethers and epoxy chlorine under the catalysis of solid heteropoly acid
Propane generates color fixing agent under the catalysis of KOH.
7. the colouring method of fabric according to claim 1, which is characterized in that the group of amidin is formed sediment as 5-10g
Powder/kg water.
8. the colouring method of fabric according to claim 1, which is characterized in that the composition and its parts by weight of the fluorescer
Number is 20-30 parts of dextrin, 20-30 parts of silver nitrate, 20-30 parts of barium sulfate, 15-20 parts of pearl powder, 10-20 parts of glycerol, inorganic solidifying
10-15 parts of glue, 100-150 parts and DMF80-100 parts of water.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116144199A (en) * | 2022-12-16 | 2023-05-23 | 湖南肆玖科技有限公司 | Preparation method of dyed mica |
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