CN103710999A - Novel environmental protection composite dye and preparation method therefor - Google Patents
Novel environmental protection composite dye and preparation method therefor Download PDFInfo
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- CN103710999A CN103710999A CN201310644112.6A CN201310644112A CN103710999A CN 103710999 A CN103710999 A CN 103710999A CN 201310644112 A CN201310644112 A CN 201310644112A CN 103710999 A CN103710999 A CN 103710999A
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Abstract
The invention discloses a novel environmental protection composite dye. The composite dye is characterized in that the dye is prepared from the following raw materials, by weight, 100-110 parts of organic dye raw materials, 5-6 parts of xylitol, 2-3 parts of sorbitol, 4-5 parts of octadecanol, 2-3 parts of oleic acid, 1-2 parts of sodium ascorbate, 1-2 parts of tea polyphenol, 1-2 parts of phenolic resin, 3-4 parts of sodium lauryl sulfate, 1-2 parts of sodium persulfate, 4-5 parts of retinoic acid, 1-2 parts of sodium thiosulfate, 2-3 parts of sodium sulfite, 4-5 parts of auxiliary agents and 150 parts of water. The composite dye has excellent high temperature stability, has good dyeing effects on pure cotton, blended fabrics and polyester-cotton fabrics, and can raise the quality of fabrics greatly. The composite dye has good dissolvability, good level-dyeing properties, and little salt dosage, and is a new and environmentally-friendly product.
Description
Technical field
The present invention relates to staining technique field, particularly a kind of novel environment friendly composite dye and preparation method thereof.
Background technology
Dyestuff is to make certain color be attached to the material on fiber, and difficult drop-off, variable color.Dyestuff is conventionally soluble in water, and a part of dyestuff needs mordant that dyestuff can be attached on fiber.Affinity between the color of dyestuff and it and tissue is that the molecular structure by dyestuff itself determines, colorific chromophoric group and and organize between produce affinity auxochrome group jointly determined the dyeing property of coloring agent.As dye substance, except having chromophoric group, also need to have a kind of auxochrome group that makes compound generation ionization.As often formed chromophoric group by nitro (NO2), azo group (N=N-), vinyl etc. in dye composition, and by-the acidic-group such as OH ,-SO3H ,-COOH and-basic group such as NH2 ,-NHCH3 ,-N (CH3) 2 formed auxochrome group.Their existence makes dye substance ionization, and polarity strengthens, and promotes to have an effect between dyestuff and tissue, produces Color.We are called acidity or basic stain the dyestuff in auxochrome group with acidity or basic group.
Dyeing is the important step in printing and dyeing production process, conventionally can use ACID DYES to dye, and the object of the invention is to for the problems referred to above of dye level, provides a kind of good stability, and firmly environmental protection coloring composition and production method dye.
Summary of the invention
The object of this invention is to provide a kind of novel environment friendly composite dye and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A novel environment friendly composite dye, is made by the raw material of following weight portion: organic dyeing raw material 100-110, xylitol 5-6, sorbierite 2-3,18 alcohol 4-5, oleic acid 2-3, sodium ascorbate 1-2, Tea Polyphenols 1-2, phenolic resins 1-2, sodium lauryl sulfate 3-4, sodium peroxydisulfate 1-2, vitamin A acid 4-5, sodium thiosulfate 1-2, sodium sulfite 2-3, auxiliary agent 4-5, water 150;
Described auxiliary agent is made by the raw material of following weight portion: Silane coupling agent KH550 1-2, penetrating agent JFC 1-2, citric acid 1-2, neopentyl glycol 3-4, methacrylic acid-2-hydroxy methacrylate 10-12, water 10-12; Preparation method, after each raw material is mixed, is heated to 60-70 ℃, and stirring reaction 30-45 minute, obtains.
Novel environment friendly composite dye of the present invention, by following concrete steps, made:
(1) organic dyeing raw material, xylitol, sorbierite, 18 alcohol, oleic acid, sodium ascorbate, Tea Polyphenols, phenolic resins, sodium lauryl sulfate are put into the reactor with agitator, mix and blend 15-25 minute;
(2) in reactor, add sodium peroxydisulfate again, be heated to 90-100 ℃, and be incubated 30-40 minute;
(3) finally add auxiliary agent and all the other residual componentss, stir 1-2 hour, cross leaching filtrate and get final product.
Excellent effect of the present invention is: the present invention has excellent high-temperature stability, the dyeing of cotton textiles, BLENDED FABRIC, polyester-cotton fabric is had good result, the quality of fabric can be significantly provided, and dyestuff dissolubility is good, good level-dyeing property, few by salt amount, be environment amenable new product.
The specific embodiment
Below by instantiation, the present invention is described in detail.
A novel environment friendly composite dye, by following weight portion (kilogram) raw material make: organic dyeing raw material 100, xylitol 5, sorbierite 2,18 alcohol 4, oleic acid 2, sodium ascorbate 1, Tea Polyphenols 1, phenolic resins 1, sodium lauryl sulfate 3, sodium peroxydisulfate 1, vitamin A acid 4, sodium thiosulfate 1, sodium sulfite 2, auxiliary agent 4, water 150;
Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling agent KH550 1, penetrating agent JFC 1, citric acid 2, neopentyl glycol 3, methacrylic acid-2-hydroxy methacrylate 10, water 10; Preparation method, after each raw material is mixed, is heated to 60-70 ℃, and stirring reaction 30-45 minute, obtains.
Novel environment friendly composite dye of the present invention, by following concrete steps, made:
(1) organic dyeing raw material, xylitol, sorbierite, 18 alcohol, oleic acid, sodium ascorbate, Tea Polyphenols, phenolic resins, sodium lauryl sulfate are put into the reactor with agitator, mix and blend 15-25 minute;
(2) in reactor, add sodium peroxydisulfate again, be heated to 90-100 ℃, and be incubated 30-40 minute;
(3) finally add auxiliary agent and all the other residual componentss, stir 1-2 hour, cross leaching filtrate and get final product.
After testing, the light fastness of dyestuff of the present invention is 6 grades, and soaping fastness is 4 grades, and crock fastness is 4 grades, and chlorine floats 4 grades of fastness.
Claims (2)
1. a novel environment friendly composite dye, it is characterized in that, by the raw material of following weight portion, made: organic dyeing raw material 100-110, xylitol 5-6, sorbierite 2-3,18 alcohol 4-5, oleic acid 2-3, sodium ascorbate 1-2, Tea Polyphenols 1-2, phenolic resins 1-2, sodium lauryl sulfate 3-4, sodium peroxydisulfate 1-2, vitamin A acid 4-5, sodium thiosulfate 1-2, sodium sulfite 2-3, auxiliary agent 4-5, water 150;
Described auxiliary agent is made by the raw material of following weight portion: Silane coupling agent KH550 1-2, penetrating agent JFC 1-2, citric acid 1-2, neopentyl glycol 3-4, methacrylic acid-2-hydroxy methacrylate 10-12, water 10-12; Preparation method, after each raw material is mixed, is heated to 60-70 ℃, and stirring reaction 30-45 minute, obtains.
2. novel environment friendly composite dye according to claim 1, is characterized in that, by following concrete steps, is made:
(1) organic dyeing raw material, xylitol, sorbierite, 18 alcohol, oleic acid, sodium ascorbate, Tea Polyphenols, phenolic resins, sodium lauryl sulfate are put into the reactor with agitator, mix and blend 15-25 minute;
(2) in reactor, add sodium peroxydisulfate again, be heated to 90-100 ℃, and be incubated 30-40 minute;
(3) finally add auxiliary agent and all the other residual componentss, stir 1-2 hour, cross leaching filtrate and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310644112.6A CN103710999B (en) | 2013-12-05 | 2013-12-05 | A kind of environmental protection composite dye and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310644112.6A CN103710999B (en) | 2013-12-05 | 2013-12-05 | A kind of environmental protection composite dye and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103710999A true CN103710999A (en) | 2014-04-09 |
| CN103710999B CN103710999B (en) | 2016-02-10 |
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| CN201310644112.6A Expired - Fee Related CN103710999B (en) | 2013-12-05 | 2013-12-05 | A kind of environmental protection composite dye and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104389201A (en) * | 2014-11-14 | 2015-03-04 | 安徽宏祥丝绸织造有限公司 | Silk dyeing auxiliary |
| CN106046853A (en) * | 2016-05-27 | 2016-10-26 | 无锡润新染料有限公司 | Organic composite dye and preparation method thereof |
| CN107177993A (en) * | 2017-07-03 | 2017-09-19 | 吴江市意胜纺织有限公司 | A kind of textile dyestuff added with chitosan and preparation method thereof |
| CN107266930A (en) * | 2017-07-03 | 2017-10-20 | 吴江市意胜纺织有限公司 | A kind of modified environment-friendly textile dyestuff and preparation method thereof |
| CN107383935A (en) * | 2017-07-07 | 2017-11-24 | 苏州市晨彩纺织研发有限公司 | A kind of artificial complex staining agent for textile and preparation method thereof |
| CN107474586A (en) * | 2017-09-05 | 2017-12-15 | 南通冠洲国际贸易有限公司 | A kind of yarn dye formulation |
| CN107700250A (en) * | 2017-10-19 | 2018-02-16 | 无为县荣华鬃刷制品有限公司 | A kind of antiultraviolet dyestuff for the printing and dyeing of pig hair |
| CN107815893A (en) * | 2017-10-19 | 2018-03-20 | 无为县荣华鬃刷制品有限公司 | A kind of anti-dyestuff and preparation method thereof that fades for the printing and dyeing of pig hair |
| CN107829319A (en) * | 2017-10-19 | 2018-03-23 | 无为县荣华鬃刷制品有限公司 | A kind of water-proof stain-resistant dyestuff for the printing and dyeing of pig hair and preparation method thereof |
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| CN103205136A (en) * | 2013-03-07 | 2013-07-17 | 山东上开化学原色乳液有限公司 | Dye monomer and preparation method and application thereof, and chromatic polymer emulsion and preparation method and application thereof |
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| JP2010530008A (en) * | 2007-05-10 | 2010-09-02 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | Pigment aqueous dispersion |
| US20110020742A1 (en) * | 2009-07-24 | 2011-01-27 | Lg Chem, Ltd. | Process for preparing polymerized toner |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104389201A (en) * | 2014-11-14 | 2015-03-04 | 安徽宏祥丝绸织造有限公司 | Silk dyeing auxiliary |
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| CN106046853A (en) * | 2016-05-27 | 2016-10-26 | 无锡润新染料有限公司 | Organic composite dye and preparation method thereof |
| CN107177993A (en) * | 2017-07-03 | 2017-09-19 | 吴江市意胜纺织有限公司 | A kind of textile dyestuff added with chitosan and preparation method thereof |
| CN107266930A (en) * | 2017-07-03 | 2017-10-20 | 吴江市意胜纺织有限公司 | A kind of modified environment-friendly textile dyestuff and preparation method thereof |
| CN107383935A (en) * | 2017-07-07 | 2017-11-24 | 苏州市晨彩纺织研发有限公司 | A kind of artificial complex staining agent for textile and preparation method thereof |
| WO2019006940A1 (en) * | 2017-07-07 | 2019-01-10 | 苏州市晨彩纺织研发有限公司 | Artificial compound staining agent for textiles and preparation method therefor |
| CN107474586A (en) * | 2017-09-05 | 2017-12-15 | 南通冠洲国际贸易有限公司 | A kind of yarn dye formulation |
| CN107700250A (en) * | 2017-10-19 | 2018-02-16 | 无为县荣华鬃刷制品有限公司 | A kind of antiultraviolet dyestuff for the printing and dyeing of pig hair |
| CN107815893A (en) * | 2017-10-19 | 2018-03-20 | 无为县荣华鬃刷制品有限公司 | A kind of anti-dyestuff and preparation method thereof that fades for the printing and dyeing of pig hair |
| CN107829319A (en) * | 2017-10-19 | 2018-03-23 | 无为县荣华鬃刷制品有限公司 | A kind of water-proof stain-resistant dyestuff for the printing and dyeing of pig hair and preparation method thereof |
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| CN103710999B (en) | 2016-02-10 |
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Granted publication date: 20160210 Termination date: 20181205 |