CN106046853A - Organic composite dye and preparation method thereof - Google Patents
Organic composite dye and preparation method thereof Download PDFInfo
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- CN106046853A CN106046853A CN201610359599.7A CN201610359599A CN106046853A CN 106046853 A CN106046853 A CN 106046853A CN 201610359599 A CN201610359599 A CN 201610359599A CN 106046853 A CN106046853 A CN 106046853A
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- China
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- parts
- organic composite
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- degrees celsius
- emulsifying agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
Abstract
The invention discloses an organic composite dye. The organic composite dye comprises the following components in parts by mass: 60-80 parts of alkylaryl sulfonate, 40-60 parts of triethylene glycol, 30-50 parts of stearic acids, 40-50 parts of amino-o-cresol, 20-40 parts of tea polyphenol, 10-20 parts of an emulsifier and 120-160 parts of water. Meanwhile, the invention further discloses a preparation method of the organic composite dye. Compared with the traditional technology, the organic composite dye comprises a plurality of organic raw material components, the generated dye has various properties, and requirements of diversification can be met.
Description
Technical field
The invention belongs to synthetic leather field, be specifically related to a kind of organic composite dyestuff and preparation method thereof.
Background technology
The dye that organic dyestuff is made up of organic compound.Dye characteristic include sun-proof, resistance to water logging, acidproof, alkaline-resisting,
Organic solvent-resistant, heat-resisting, stable crystal form, dispersibility and covering power etc..Organic dyestuff is generally of higher tinting strength, tinting power, and granule holds
Easy grinding and dispersion, being difficult to precipitation, color is the most bright-coloured, but sun-proof, heat-resisting, weather resistance is poor.Organic pigment is commonly used to
The coloring of the materials such as ink, coating, rubber, plastic, school supply and stationery and construction material.The dye of traditional single performance
Material can not meet the demand of major part enterprise at present, in the excessive unification of aspect of performance, often attends to one thing and lose sight of another.
Summary of the invention
Goal of the invention: present invention aims to the deficiencies in the prior art, it is provided that a kind of organic composite dyestuff.
Another object of the present invention is to provide the preparation method of above-mentioned organic composite dyestuff.
Technical scheme: in order to reach foregoing invention purpose, the present invention is specifically achieved in that a kind of organic composite dye
Material, including the component of following mass fraction: alkarylsulphonic acid of 60 ~ 80 parts, the 2,2'-ethylenedioxybis(ethanol). of 40 ~ 60 parts, the hard of 30 ~ 50 parts
Acid, the amino orthoresol of 40 ~ 50 parts, the tea polyphenols of 20 ~ 40 parts, the emulsifying agent of 10 ~ 20 parts and the water of 120 ~ 160 parts.
Wherein, described emulsifying agent is mixed by arabic gum and sodium alkyl benzene sulfonate 1:3 ~ 5 in mass ratio, is heated to 50 ~ 60
With ultrasonic 20 ~ 30 minutes of ultrasonic machine and get final product after degree Celsius.
The method preparing described organic composite dyestuff, comprises the following steps:
(1) by alkarylsulphonic acid, 2,2'-ethylenedioxybis(ethanol)., stearic acid, amino orthoresol, tea polyphenols and emulsifying agent import in reactor and are heated to
80 degrees Celsius, stirring mixing 30 ~ 40 minutes；
(2) in reactor, continuously add water, do not stop stirring, continue 10 ~ 20 minutes；
(3) step (3) gained mixed liquor is passed through the psychrolusia of less than 5 degrees Celsius；
(4) step (4) gained mixed liquor is filtered, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Beneficial effect: the present invention, compared with conventional art, uses multiple Organic Ingredients component, and the dyestuff of generation possesses multiple
Performance, it is possible to meet more diversified requirement.
Detailed description of the invention
Embodiment 1:
Take alkarylsulphonic acid that mass fraction is 60 parts, the 2,2'-ethylenedioxybis(ethanol). of 40 parts, the stearic acid of 30 parts, the amino orthoresol of 40 parts,
The tea polyphenols of 20 parts, the emulsifying agent of 10 parts imports in reactor and is heated to 80 degrees Celsius, stirring mixing 30 ~ 40 minutes；To reaction
Still continuously adds the water of 120 parts, does not stop stirring, continue 10 ~ 20 minutes；Mixed liquor is passed through the psychrolusia of less than 5 degrees Celsius,
And mixed liquor filters, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Embodiment 2:
Take alkarylsulphonic acid that mass fraction is 80 parts, the 2,2'-ethylenedioxybis(ethanol). of 60 parts, the stearic acid of 50 parts, amino neighbour's first of 50 parts
Phenol, the tea polyphenols of 40 parts, the emulsifying agent of 20 parts imports in reactor and is heated to 80 degrees Celsius, stirring mixing 30 ~ 40 minutes；To
Reactor continuously adds the water of 160 parts, does not stop stirring, continue 10 ~ 20 minutes；By cold by less than 5 degrees Celsius of mixed liquor
Water-bath, and mixed liquor filtration, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Embodiment 3:
Take alkarylsulphonic acid that mass fraction is 70 parts, the 2,2'-ethylenedioxybis(ethanol). of 50 parts, the stearic acid of 40 parts, the amino orthoresol of 45 parts,
The tea polyphenols of 30 parts, the emulsifying agent of 15 parts imports in reactor and is heated to 80 degrees Celsius, stirring mixing 30 ~ 40 minutes；To reaction
Still continuously adds the water of 130 parts, does not stop stirring, continue 10 ~ 20 minutes；Mixed liquor is passed through the psychrolusia of less than 5 degrees Celsius,
And mixed liquor filters, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Embodiment 4:
Take alkarylsulphonic acid that mass fraction is 65 parts, the 2,2'-ethylenedioxybis(ethanol). of 45 parts, the stearic acid of 35 parts, the amino orthoresol of 45 parts,
The tea polyphenols of 35 parts, the emulsifying agent of 20 parts imports in reactor and is heated to 80 degrees Celsius, stirring mixing 30 ~ 40 minutes；To reaction
Still continuously adds the water of 140 parts, does not stop stirring, continue 10 ~ 20 minutes；Mixed liquor is passed through the psychrolusia of less than 5 degrees Celsius,
And mixed liquor filters, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Embodiment 5:
Take alkarylsulphonic acid that mass fraction is 75 parts, the 2,2'-ethylenedioxybis(ethanol). of 55 parts, the stearic acid of 45 parts, the amino orthoresol of 50 parts,
The tea polyphenols of 40 parts, the emulsifying agent of 10 parts imports in reactor and is heated to 80 degrees Celsius, stirring mixing 30 ~ 40 minutes；To reaction
Still continuously adds the water of 150 parts, does not stop stirring, continue 10 ~ 20 minutes；Mixed liquor is passed through the psychrolusia of less than 5 degrees Celsius,
And mixed liquor filters, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Claims (3)
1. an organic composite dyestuff, it is characterised in that include the component of following mass fraction: alkarylsulphonic acid of 60 ~ 80 parts,
The 2,2'-ethylenedioxybis(ethanol). of 40 ~ 60 parts, the stearic acid of 30 ~ 50 parts, the amino orthoresol of 40 ~ 50 parts, the tea polyphenols of 20 ~ 40 parts, 10 ~ 20 parts
Emulsifying agent and the water of 120 ~ 160 parts.
Organic composite dyestuff the most according to claim 1, it is characterised in that described emulsifying agent is by arabic gum and alkylbenzene
Sodium sulfonate 1:3 ~ 5 in mass ratio mix, with ultrasonic 20 ~ 30 minutes of ultrasonic machine and get final product after being heated to 50 ~ 60 degrees Celsius.
3. the method for organic composite dyestuff described in preparation claim 1 or 2, it is characterised in that comprise the following steps:
(1) by alkarylsulphonic acid, 2,2'-ethylenedioxybis(ethanol)., stearic acid, amino orthoresol, tea polyphenols and emulsifying agent import in reactor and are heated to
80 degrees Celsius, stirring mixing 30 ~ 40 minutes；
(2) in reactor, continuously add water, do not stop stirring, continue 10 ~ 20 minutes；
(3) step (3) gained mixed liquor is passed through the psychrolusia of less than 5 degrees Celsius；
(4) step (4) gained mixed liquor is filtered, collect crystallization, packaging warehouse-in after standing 1 ~ 2 day.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610359599.7A CN106046853A (en) | 2016-05-27 | 2016-05-27 | Organic composite dye and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610359599.7A CN106046853A (en) | 2016-05-27 | 2016-05-27 | Organic composite dye and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046853A true CN106046853A (en) | 2016-10-26 |
Family
ID=57174762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610359599.7A Pending CN106046853A (en) | 2016-05-27 | 2016-05-27 | Organic composite dye and preparation method thereof |
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| CN (1) | CN106046853A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815893A (en) * | 2017-10-19 | 2018-03-20 | 无为县荣华鬃刷制品有限公司 | A kind of anti-dyestuff and preparation method thereof that fades for the printing and dyeing of pig hair |
| CN107829319A (en) * | 2017-10-19 | 2018-03-23 | 无为县荣华鬃刷制品有限公司 | A kind of water-proof stain-resistant dyestuff for the printing and dyeing of pig hair and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694737A (en) * | 2013-12-05 | 2014-04-02 | 安徽三喜针织有限公司 | Compound dye and preparation method thereof |
| CN103710999A (en) * | 2013-12-05 | 2014-04-09 | 安徽三喜针织有限公司 | Novel environmental protection composite dye and preparation method therefor |
| CN104277494A (en) * | 2014-09-27 | 2015-01-14 | 无锡市东北塘宏良染色厂 | Acid dye |
-
2016
- 2016-05-27 CN CN201610359599.7A patent/CN106046853A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694737A (en) * | 2013-12-05 | 2014-04-02 | 安徽三喜针织有限公司 | Compound dye and preparation method thereof |
| CN103710999A (en) * | 2013-12-05 | 2014-04-09 | 安徽三喜针织有限公司 | Novel environmental protection composite dye and preparation method therefor |
| CN104277494A (en) * | 2014-09-27 | 2015-01-14 | 无锡市东北塘宏良染色厂 | Acid dye |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815893A (en) * | 2017-10-19 | 2018-03-20 | 无为县荣华鬃刷制品有限公司 | A kind of anti-dyestuff and preparation method thereof that fades for the printing and dyeing of pig hair |
| CN107829319A (en) * | 2017-10-19 | 2018-03-23 | 无为县荣华鬃刷制品有限公司 | A kind of water-proof stain-resistant dyestuff for the printing and dyeing of pig hair and preparation method thereof |
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161026 |