CN103710999B - A kind of environmental protection composite dye and preparation method thereof - Google Patents
A kind of environmental protection composite dye and preparation method thereof Download PDFInfo
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- CN103710999B CN103710999B CN201310644112.6A CN201310644112A CN103710999B CN 103710999 B CN103710999 B CN 103710999B CN 201310644112 A CN201310644112 A CN 201310644112A CN 103710999 B CN103710999 B CN 103710999B
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Abstract
The invention discloses a kind of novel environment friendly composite dye, it is characterized in that, be made up of the raw material of following weight portion: organic dye raw material 100-110, xylitol 5-6, sorbierite 2-3, octadecyl alcolol 4-5, oleic acid 2-3, sodium ascorbate 1-2, Tea Polyphenols 1-2, phenolic resins 1-2, sodium lauryl sulfate 3-4, sodium peroxydisulfate 1-2, vitamin A acid 4-5, sodium thiosulfate 1-2, sodium sulfite 2-3, auxiliary agent 4-5, water 150; The present invention has excellent high-temperature stability, and the dyeing of cotton textiles, BLENDED FABRIC, polyester-cotton fabric is had to good result, significantly can provide the quality of fabric, and dye solubility is good, good level-dyeing property, salt dosage is few, is environment amenable new product.
Description
Technical field
The present invention relates to staining technique field, particularly a kind of environmental protection composite dye and preparation method thereof.
Background technology
Dyestuff to make certain color be attached to material on fiber, and difficult drop-off, variable color.Dyestuff is usually soluble in water, and a part of dyestuff needs mordant that dyestuff can be attached on fiber.The color of dyestuff and the affinity between it and tissue are determined by the molecular structure of dyestuff itself, colorific chromophoric group and and the auxochrome group that produces affinity between organizing jointly determine the dyeing property of coloring agent.As dye substance, except having chromophoric group, also need a kind of auxochrome group making compound generation ionization.As often defined chromophoric group by nitro (-NO2), azo group (-N=N-), vinyl etc. in dye composition, and constitute auxochrome group by the acidic-groups such as-OH ,-SO3H ,-COOH and the basic group such as-NH2 ,-NHCH3 ,-N (CH3) 2.Their existence makes dye substance ionization, and polarity strengthens, and promotes to have an effect between dyestuff and tissue, produces Color.We are called acidity or basic stain the dyestuff in auxochrome group with acidity or basic group.
Dyeing be printing and dyeing production process in important step, ACID DYES usually can be used to dye, dye level the object of the invention is to for the problems referred to above, provide a kind of good stability, dye firmly environmental protection coloring composition and production method.
Summary of the invention
The object of this invention is to provide a kind of environmental protection composite dye and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of environmental protection composite dye, is made up of the raw material of following weight portion: organic dye raw material 100-110, xylitol 5-6, sorbierite 2-3, octadecyl alcolol 4-5, oleic acid 2-3, sodium ascorbate 1-2, Tea Polyphenols 1-2, phenolic resins 1-2, sodium lauryl sulfate 3-4, sodium peroxydisulfate 1-2, vitamin A acid 4-5, sodium thiosulfate 1-2, sodium sulfite 2-3, auxiliary agent 4-5, water 150;
Described auxiliary agent is made up of the raw material of following weight portion: Silane coupling agent KH550 1-2, penetrating agent JFC 1-2, citric acid 1-2, neopentyl glycol 3-4, methacrylic acid-2-hydroxy methacrylate 10-12, water 10-12; Preparation method is that be heated to 60-70 DEG C, stirring reaction 30-45 minute, to obtain final product by after each raw material mixing.
Environmental protection composite dye of the present invention, be made up of following concrete steps:
(1) organic dye raw material, xylitol, sorbierite, octadecyl alcolol, oleic acid, sodium ascorbate, Tea Polyphenols, phenolic resins, sodium lauryl sulfate are put into the reactor with agitator, mix and blend 15-25 minute;
(2) in reactor, add sodium peroxydisulfate again, be heated to 90-100 DEG C, and be incubated 30-40 minute;
(3) finally add auxiliary agent and all the other residual componentss, stir 1-2 hour, cross leaching filtrate and get final product.
Excellent effect of the present invention is: the present invention has excellent high-temperature stability, the dyeing of cotton textiles, BLENDED FABRIC, polyester-cotton fabric is had to good result, significantly can provide the quality of fabric, and dye solubility is good, good level-dyeing property, salt dosage is few, is environment amenable new product.
Detailed description of the invention
Below by instantiation, the present invention is described in detail.
A kind of environmental protection composite dye, is made up of the raw material of following weight portion (kilogram): organic dye raw material 100, xylitol 5, sorbierite 2, octadecyl alcolol 4, oleic acid 2, sodium ascorbate 1, Tea Polyphenols 1, phenolic resins 1, sodium lauryl sulfate 3, sodium peroxydisulfate 1, vitamin A acid 4, sodium thiosulfate 1, sodium sulfite 2, auxiliary agent 4, water 150;
Described auxiliary agent is made up of the raw material of following weight portion (kilogram): Silane coupling agent KH550 1, penetrating agent JFC 1, citric acid 2, neopentyl glycol 3, methacrylic acid-2-hydroxy methacrylate 10, water 10; Preparation method is that be heated to 60-70 DEG C, stirring reaction 30-45 minute, to obtain final product by after each raw material mixing.
Environmental protection composite dye of the present invention, be made up of following concrete steps:
(1) organic dye raw material, xylitol, sorbierite, octadecyl alcolol, oleic acid, sodium ascorbate, Tea Polyphenols, phenolic resins, sodium lauryl sulfate are put into the reactor with agitator, mix and blend 15-25 minute;
(2) in reactor, add sodium peroxydisulfate again, be heated to 90-100 DEG C, and be incubated 30-40 minute;
(3) finally add auxiliary agent and all the other residual componentss, stir 1-2 hour, cross leaching filtrate and get final product.
After testing, the light fastness of dyestuff of the present invention is 6 grades, and soaping fastness is 4 grades, and crock fastness is 4 grades, chlorine drift fastness 4 grades.
Claims (2)
1. an environmental protection composite dye, it is characterized in that, be made up of the raw material of following weight portion: organic dye raw material 100-110, xylitol 5-6, sorbierite 2-3, octadecyl alcolol 4-5, oleic acid 2-3, sodium ascorbate 1-2, Tea Polyphenols 1-2, phenolic resins 1-2, sodium lauryl sulfate 3-4, sodium peroxydisulfate 1-2, vitamin A acid 4-5, sodium thiosulfate 1-2, sodium sulfite 2-3, auxiliary agent 4-5, water 150;
Described auxiliary agent is made up of the raw material of following weight portion: Silane coupling agent KH550 1-2, penetrating agent JFC 1-2, citric acid 1-2, neopentyl glycol 3-4, methacrylic acid-2-hydroxy methacrylate 10-12, water 10-12; Preparation method is that be heated to 60-70 DEG C, stirring reaction 30-45 minute, to obtain final product by after each raw material mixing.
2. environmental protection composite dye according to claim 1, is characterized in that, be made up of following concrete steps:
(1) organic dye raw material, xylitol, sorbierite, octadecyl alcolol, oleic acid, sodium ascorbate, Tea Polyphenols, phenolic resins, sodium lauryl sulfate are put into the reactor with agitator, mix and blend 15-25 minute;
(2) in reactor, add sodium peroxydisulfate again, be heated to 90-100 DEG C, and be incubated 30-40 minute;
(3) finally add auxiliary agent and all the other residual componentss, stir 1-2 hour, cross leaching filtrate and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310644112.6A CN103710999B (en) | 2013-12-05 | 2013-12-05 | A kind of environmental protection composite dye and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310644112.6A CN103710999B (en) | 2013-12-05 | 2013-12-05 | A kind of environmental protection composite dye and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103710999A CN103710999A (en) | 2014-04-09 |
| CN103710999B true CN103710999B (en) | 2016-02-10 |
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| CN201310644112.6A Expired - Fee Related CN103710999B (en) | 2013-12-05 | 2013-12-05 | A kind of environmental protection composite dye and preparation method thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104389201B (en) * | 2014-11-14 | 2016-06-08 | 安徽宏祥丝绸织造有限公司 | A kind of silk dyeing auxiliary |
| CN106046853A (en) * | 2016-05-27 | 2016-10-26 | 无锡润新染料有限公司 | Organic composite dye and preparation method thereof |
| CN107266930A (en) * | 2017-07-03 | 2017-10-20 | 吴江市意胜纺织有限公司 | A kind of modified environment-friendly textile dyestuff and preparation method thereof |
| CN107177993A (en) * | 2017-07-03 | 2017-09-19 | 吴江市意胜纺织有限公司 | A kind of textile dyestuff added with chitosan and preparation method thereof |
| CN107383935A (en) * | 2017-07-07 | 2017-11-24 | 苏州市晨彩纺织研发有限公司 | A kind of artificial complex staining agent for textile and preparation method thereof |
| CN107474586A (en) * | 2017-09-05 | 2017-12-15 | 南通冠洲国际贸易有限公司 | A kind of yarn dye formulation |
| CN107829319A (en) * | 2017-10-19 | 2018-03-23 | 无为县荣华鬃刷制品有限公司 | A kind of water-proof stain-resistant dyestuff for the printing and dyeing of pig hair and preparation method thereof |
| CN107700250A (en) * | 2017-10-19 | 2018-02-16 | 无为县荣华鬃刷制品有限公司 | A kind of antiultraviolet dyestuff for the printing and dyeing of pig hair |
| CN107815893A (en) * | 2017-10-19 | 2018-03-20 | 无为县荣华鬃刷制品有限公司 | A kind of anti-dyestuff and preparation method thereof that fades for the printing and dyeing of pig hair |
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| CN101851867A (en) * | 2010-06-02 | 2010-10-06 | 黄文泉 | Textile printing and dyeing ink and preparation method thereof |
| CN102030919A (en) * | 2010-11-12 | 2011-04-27 | 杭州中富彩新材料科技有限公司 | Environmental-friendly surface polymer modified water-borne coloring agent and preparation method thereof |
| CN102464915A (en) * | 2010-11-05 | 2012-05-23 | 中国科学院化学研究所 | Oily ink for inkjet computer to plate, preparation method and application thereof |
| CN103205136A (en) * | 2013-03-07 | 2013-07-17 | 山东上开化学原色乳液有限公司 | Dye monomer and preparation method and application thereof, and chromatic polymer emulsion and preparation method and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007021870A1 (en) * | 2007-05-10 | 2008-11-20 | Clariant International Limited | Aqueous pigment preparations |
| US8530127B2 (en) * | 2009-07-24 | 2013-09-10 | Lg Chem, Ltd. | Process for preparing polymerized toner |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851867A (en) * | 2010-06-02 | 2010-10-06 | 黄文泉 | Textile printing and dyeing ink and preparation method thereof |
| CN102464915A (en) * | 2010-11-05 | 2012-05-23 | 中国科学院化学研究所 | Oily ink for inkjet computer to plate, preparation method and application thereof |
| CN102030919A (en) * | 2010-11-12 | 2011-04-27 | 杭州中富彩新材料科技有限公司 | Environmental-friendly surface polymer modified water-borne coloring agent and preparation method thereof |
| CN103205136A (en) * | 2013-03-07 | 2013-07-17 | 山东上开化学原色乳液有限公司 | Dye monomer and preparation method and application thereof, and chromatic polymer emulsion and preparation method and application thereof |
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| CN103710999A (en) | 2014-04-09 |
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Granted publication date: 20160210 Termination date: 20181205 |