CN103694686A - Color master batch for blue anti-UV (ultraviolet) nylon - Google Patents
Color master batch for blue anti-UV (ultraviolet) nylon Download PDFInfo
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- CN103694686A CN103694686A CN201310738599.4A CN201310738599A CN103694686A CN 103694686 A CN103694686 A CN 103694686A CN 201310738599 A CN201310738599 A CN 201310738599A CN 103694686 A CN103694686 A CN 103694686A
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- Prior art keywords
- nylon
- stabilizer
- antioxidant
- color master
- agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a color master batch for blue anti-UV (ultraviolet) nylon. The color master batch consists of the following components of 15-35 percent of a blue coloring agent, 35-45 percent of polyamide resin, 5-15 percent of a composite stabilizing agent, 10-20 percent of an antistatic agent and 3-10 percent of a dispersing agent. The composite stabilizing agent at least comprises two of a hindered phenol antioxidant, a phosphite antioxidant, a copper halide stabilizer, a hindered amine light stabilizers, a hydrolysis resistant agent, a bnzo phenones ultraviolet absorber and a benzotriazole ultraviolet absorber. Compared with the prior art, the color master match disclosed by the invention has the advantages that various stabilizing agents are mixed, so that all the stabilizing agents generate a synergistic effect, and the stability of materials can be guaranteed during processing and long-time outdoor use; the mechanical properties of the materials are higher; the color master batch is applicable to design and application of high-grade nylon products with long-time weather-resistant requirements; meanwhile, the blue coloring agent is added into the color master batch, so that the color master batch has an antistatic technical effect, and the use safety of the nylon is greatly improved.
Description
Technical field
The invention belongs to the technical field of coloring plastic, relate in particular to the anti-UV nylon of a kind of blueness Masterbatch.
Background technology
Masterbatch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that pigment super quantity is attached in resin and the mixture of the polymkeric substance making uniformly.Masterbatch chief component is tinting material, carrier, dispersion agent three parts.
According to related data, learn that the average annual growth rate of demand about 7%-9% of the other countries of Asia to Masterbatch can China be 20% left and right to the average annual growth rate of demand of Masterbatch.Estimate that China will become the fastest-rising market of Masterbatch demand.Particularly colored and add master batch, China wants dependence on import.China has become the largest production state in Masterbatch market, Asia and has consumed state.Relevant expert thinks, following Masterbatch will be towards multifunction, high color content and high technology content future development.
And common nylon master batch adds in nylon raw material, cannot guarantee the stability in material work in-process and outdoor use, generally all can reduce the mechanical property of material, thereby reduce the design and use life-span of product.
Summary of the invention
The present invention is directed to deficiency of the prior art, provide a kind of color to change, and add rear to the anti-UV nylon of the little blueness of nylon Effect on Mechanical Properties Masterbatch.
In order to solve the problems of the technologies described above, the present invention is solved by following technical proposals: the anti-UV nylon of a kind of blueness Masterbatch, it is characterized in that by weight percentage, composed of the following components: blue colorant 15%-35%, polyamide resin 35%-45%, one package stabilizer 5%-15%, static inhibitor 10%-20%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.Compared with prior art, the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, added static inhibitor, obtained the technique effect of anti-electrostatic, the safety in utilization of nylon is improved greatly.
As preferred version: above-mentioned one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.Hinered phenols antioxidant and hindered amine light stabilizer be hydroperoxide decomposition and Trapped free radical effectively, and both are a bit similar, but hindered amine light stabilizer can cyclic regeneration, and Hinered phenols antioxidant is disposable; UV light absorber can effectively absorb sunlight middle-ultraviolet lamp, reduces by UV-induced photoaging; Phosphite ester kind antioxidant is brought into play antioxidant effect as hydrogen peroxide decomposition agent and radical trapping agent in polymkeric substance, use substantially without obvious effect separately, but play synergy with Hinered phenols antioxidant, obviously reinforcement material neutralizes out of doors and can guarantee stability in life-time service in the course of processing.
As preferably, above-mentioned one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.By Hinered phenols antioxidant, phosphite ester kind antioxidant
,the quaternary system that hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer form has good stabilising effect to the long-term weatherability of nylon product.Only use Hinered phenols antioxidant and hindered amine light stabilizer binary system, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2450 hours, while containing the nylon product tensile strength retention rate 70% that above-mentioned quaternary system forms, the required burn-in test time is 6200 hours, Each performs its own functions for four kinds of stablizers, has significantly collaborative synergistic effect.
As preferably, above-mentioned dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
As preferably, above-mentioned blue colorant is a kind of in phthalocyanine blue, ultramarine blue, cobalt blue.
The present invention compared with prior art, there is following beneficial effect: the present invention mainly adopts the composite of plurality of stable agent, make various stablizers produce synergistic effect, guarantee that material neutralizes out of doors and can guarantee stability in life-time service in the course of processing, the mechanical property of material is better, is applicable to high-end nylon product design and the application of long-term weather-proof requirement.Meanwhile, in the present invention, added static inhibitor, obtained the technique effect of anti-electrostatic, the safety in utilization of nylon is improved greatly.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail: embodiment 1.
The anti-UV nylon of a blueness Masterbatch, by weight percentage, composed of the following components: phthalocyanine blue 20%, polyamide resin 45%, one package stabilizer 10%, static inhibitor 20%, dispersion agent 5%; Wherein, one package stabilizer is comprised of Hinered phenols antioxidant and phosphite ester kind antioxidant, and by weight, Hinered phenols antioxidant is one package stabilizer 60%, and phosphite ester kind antioxidant is one package stabilizer 40%; Dispersion agent is ethene-vinyl acetate wax.
Embodiment 2.
The anti-UV nylon of a blueness Masterbatch, by weight percentage, composed of the following components: cobalt blue 30%, polyamide resin 35%, one package stabilizer 15%, static inhibitor 10%, dispersion agent 10%.
Wherein, one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, wherein Hinered phenols antioxidant 35%, hindered amine light stabilizer 15%, Benzotriazole Ultraviolet Stabilizer 30%, phosphite ester kind antioxidant 20%; Dispersion agent is pentaerythritol stearate.
Comparative example 1.
Cobalt blue 30%, polyamide resin 35%, Hinered phenols antioxidant 15%, static inhibitor 10%, dispersion agent 10%.
Comparative example 2.
Cobalt blue 20%, polyamide resin 45%, phosphite ester kind antioxidant 10%, static inhibitor 20%, dispersion agent 5%.
Experimental result: embodiment 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is 2550 hours; Embodiment 2, and during nylon material tensile strength retention rate 70%, the required burn-in test time is 5740 hours; Comparative example 1, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1760 hours; Comparative example 2, during nylon material tensile strength retention rate 50%, the required burn-in test time is, 1870 hours.
Claims (5)
1. the anti-UV nylon of a blueness Masterbatch, is characterized in that by weight percentage, composed of the following components: blue colorant 15%-35%, polyamide resin 35%-45%, one package stabilizer 5%-15%, static inhibitor 10%-20%, dispersion agent 3%-10%; Described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, phosphite ester kind antioxidant, copper halide class stablizer, hindered amine light stabilizer, hydrolysis-resisting agent, benzophenone, Benzotriazole Ultraviolet Stabilizer.
2. the anti-UV nylon of a kind of blueness according to claim 1 Masterbatch, is characterized in that: described one package stabilizer at least comprises two kinds in Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant.
3. the anti-UV nylon of a kind of blueness according to claim 2 Masterbatch, is characterized in that: described one package stabilizer is comprised of Hinered phenols antioxidant, hindered amine light stabilizer, Benzotriazole Ultraviolet Stabilizer and phosphite ester kind antioxidant; By weight percentage, Hinered phenols antioxidant 25%-35% wherein, hindered amine light stabilizer 15%-25%, Benzotriazole Ultraviolet Stabilizer 20%-30%, phosphite ester kind antioxidant 20%-30%.
4. according to the anti-UV nylon of a kind of blueness Masterbatch described in arbitrary claim in claims 1 to 3, it is characterized in that: described dispersion agent at least comprises a kind of in ethene-vinyl acetate wax, ethylene bis stearic amide, pentaerythritol stearate.
5. the anti-UV nylon of a kind of blueness according to claim 4 Masterbatch, is characterized in that: described blue colorant is a kind of in phthalocyanine blue, ultramarine blue, cobalt blue.
Priority Applications (1)
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CN201310738599.4A CN103694686A (en) | 2013-12-28 | 2013-12-28 | Color master batch for blue anti-UV (ultraviolet) nylon |
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CN201310738599.4A CN103694686A (en) | 2013-12-28 | 2013-12-28 | Color master batch for blue anti-UV (ultraviolet) nylon |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106633351A (en) * | 2016-12-13 | 2017-05-10 | 福建鑫邦新材料科技有限公司 | Anti-ultraviolet and anti-static color master batch and manufacturing method thereof |
CN108314826A (en) * | 2018-03-12 | 2018-07-24 | 宁波色母粒有限公司 | The polyolefin cobalt blue master batch and preparation method thereof of resistance to strong acid corrosion |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
-
2013
- 2013-12-28 CN CN201310738599.4A patent/CN103694686A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1649970A (en) * | 2002-05-01 | 2005-08-03 | 西巴特殊化学品控股有限公司 | Pigment preparations |
CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106633351A (en) * | 2016-12-13 | 2017-05-10 | 福建鑫邦新材料科技有限公司 | Anti-ultraviolet and anti-static color master batch and manufacturing method thereof |
CN108314826A (en) * | 2018-03-12 | 2018-07-24 | 宁波色母粒有限公司 | The polyolefin cobalt blue master batch and preparation method thereof of resistance to strong acid corrosion |
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Application publication date: 20140402 |