CN106633351A - Anti-ultraviolet and anti-static color master batch and manufacturing method thereof - Google Patents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Polymers & Plastics (AREA)
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Abstract
The invention relates to an anti-ultraviolet and anti-static color master batch and a manufacturing method thereof. The anti-ultraviolet and anti-static color master batch is prepared from the following components in parts by mass: 40 to 46 parts of EVA, 1.5 to 1.7 parts of a dispersing agent, 20 to 26 parts of 2,4-dyhydroxy-diphenyl ketone, 19 to 24 parts of methyl p-hydroxycinnamate, 10 to 16 parts of nanometer antimony oxide, 12 to 17 parts of stannic anhydride, 1.5 to 2.0 parts of a lubricating agent and 20 to 24 parts of kieselguhr. The manufacturing method of the anti-ultraviolet and anti-static color master batch comprises material preparation, material mixing, tape casting and slicing. The color master batch disclosed by the invention can resist ultraviolet rays and static electricity, and has a flame retardant effect.
Description
Technical field
The invention belongs to master batch preparing technical field, more particularly to a kind of uvioresistant Anti-static electricity color master batch and its making
Method.
Background technology
Masterbatch is that face (dye) material of super quantity is uniformly attached in resin and obtained aggregation.Masterbatch can make face
Material has preferably dispersiveness in product, it is ensured that product color is stablized.
As reform and opening-up, the development in an all-round way of China's economy, the yield of plastic products are continuously increased, kind and quality have greatly
The raising of amplitude, has higher requirement to the performance requirement of Masterbatch therewith, and some medium-to-high grade plastic products are not only to color masterbatch
Grain tinctorial property has high demands, and for other performances also should mutually have a higher requirement, thus design one kind can uvioresistant, anti-
Electrostatic, and the Masterbatch with flame retardant effect and preparation method thereof.
The Chinese patent of Application No. 201310049834.7 discloses a kind of Anti-static electricity color master batch and preparation method thereof,
Its formula is made up of following weight percentage：Masterbatch base material 50～72%, carbon black 9～13%, antistatic additive 8～13%, horse
Maleic anhydride grafted compatilizer 7～15%, soap lye 9～15%, antioxidant 7～13%, the antistatic additive is fatty alcohol polyoxy
Vinethene, the antioxidant can be butylated hydroxy anisole, or dibutyl hydroxy toluene, using with antistatic
The use of the reagent, the reagent of ultraviolet radiation absorption function and stabilizer of agent function so that product has the function, but it is present
Following deficiency：
Due to the use of simple function reagent, product in actual use, can cause its stability weak, effect
Fruit is strong, thus provide one kind can uvioresistant, antistatic, and the Masterbatch with flame retardant effect and preparation method thereof,
The content of the invention
The purpose of the present invention is to overcome the deficiencies in the prior art, there is provided one kind can uvioresistant, antistatic, and with fire-retardant
Masterbatch of effect and preparation method thereof, the Masterbatch of the present invention is by the antistatic additive of independent research and the place of UV resistant agent
Reason so as to antistatic and anti-ultraviolet function, cause batch mixing uniform by additives such as the diatomite of addition, effect is more
It is good.
The present invention can be achieved through the following technical solutions：
Uvioresistant Anti-static electricity color master batch, including the following component according to mass fraction meter：40～46 parts of EVA, dispersant
1.5～1.7 parts, 30～35 parts of antistatic additive, 30～35 parts of UV resistant agent, 10～16 parts of nanometer antimony oxide, tin ash 12
～16 parts, 1.5～2.0 parts of lubricant, 20～24 parts of diatomite.
Further, including the following component according to mass fraction meter：43 parts of EVA, 1.6 parts of dispersant, antistatic additive 33
Part, 33 parts of UV resistant agent, 14 parts of nanometer antimony oxide, 14 parts of tin ash, 1.7 parts of lubricant, 22 parts of diatomite.
Further, the antistatic additive is included according to the following component of mass fraction meter：12～17 parts of tin ash, charcoal
Black 5～9 parts, 5～16 parts of polypyrrole, 7～12 parts of silane coupler, 8～11 parts of dodecyl sodium sulfate, 2～4 parts of glycerine, water
45～55 parts.
Further, the UV resistant agent is included according to the following component of mass fraction meter：2,4- dihydroxy-hexichol first
14～17 parts of ketone, 17～20 parts of p-Coumaric Acid methyl esters, 4～7 parts of BTA, 6～10 parts of Tea Polyphenols, ethanol 10～15
Part, 45～55 parts of water.
Further, the dispersant is sodium lignin sulfonate, and the lubricant is white oil or the one kind in Tissuemat E.
The preparation method of described uvioresistant Anti-static electricity color master batch, comprises the steps：
Step one, gets the raw materials ready：
To melt according to the EVA of the mass fraction meter, obtain bed material, wherein, the melt temperature is 150 DEG C～170 DEG C；
Step 2, batch mixing：
Will according to one gained bed material the step of the mass fraction meter, the dispersant, antistatic additive, UV resistant agent,
Nanometer antimony oxide, tin ash, lubricant and diatomite add stirred into high-speed mixer successively, obtain blend glue stuff,
Wherein, in mixed process, rotating speed is 400～500r/min, and incorporation time is 2～3h；
Step 3, flow casting molding and section：
Step 2 gained blend glue stuff is carried out into flow casting molding, and is cut into slices, obtain uvioresistant Anti-static electricity color master batch, its
In, the body temperature of flow casting molding is 180-200-220-225-230 DEG C.
Further, the preparation method of the antistatic additive is：By according to the water of mass fraction meter, tin ash,
Carbon black, polypyrrole, silane coupler, dodecyl sodium sulfate and glycerine are sequentially added and be heated in mixer 40～50 DEG C of stirrings
It is well mixed, obtains final product antistatic additive.
Further, the preparation method of the UV resistant agent is：By according to the water of mass fraction meter, 2,4- dihydroxies
Base-benzophenone, p-Coumaric Acid methyl esters, BTA, Tea Polyphenols and ethanol sequentially adds and be heated in mixer 40～
50 DEG C are uniformly mixed, and obtain final product UV resistant agent.
Further, melt temperature described in step one is 160 DEG C, and in mixed process described in step 2, rotating speed is 450r/
Min, incorporation time is 2h.
Compared with prior art, its advantage is the present invention：
1st, uvioresistant Anti-static electricity color master batch of the invention in process of production, the original such as polypyrrole and dodecyl sodium sulfate
The antistatic additive that obtained by proportioning of material has an excellent antistatic property, 2,4- dihydroxy-benzophenone and to hydroxy cinnamate
The raw materials such as sour methyl esters have excellent anti-ultraviolet property by the UV resistant agent that proportioning is obtained, by test result,
Effect is more higher than commercially available reagent performance.
2nd, the preparation method of Masterbatch of the invention is easy, easily promotes, and is adapted to extensive industrialization.
Specific embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, whereby how skill is applied to the present invention
Art means solving technical problem, and reach technique effect realize that process can fully understand and implement according to this.
Raw material of the present invention is commercially available product；
Wherein, 2,4- dihydroxy-benzophenone is purchased from the enzyme-linked detection technique Co., Ltd in Shanghai；
P-Coumaric Acid methyl esters is purchased from Yancheng City Mai Dike chemicals Manufacturing Co., Ltd.
Embodiment 1
Uvioresistant Anti-static electricity color master batch, including the following component according to mass fraction meter：40 parts of EVA, dispersant 1.5
Part, 30 parts of antistatic additive, 30 parts of UV resistant agent, 10 parts of nanometer antimony oxide, 12 parts of tin ash, 1.5 parts of lubricant, diatomite
20 parts.
The antistatic additive is included according to the following component of mass fraction meter：12 parts of tin ash, 5 parts of carbon black, polypyrrole 5
Part, 7 parts of silane coupler, 8 parts of dodecyl sodium sulfate, 2 parts of glycerine, 45 parts of water.
The UV resistant agent is included according to the following component of mass fraction meter：14 parts of 2,4- dihydroxy-benzophenone, it is right
17 parts of hydroxy-methyl cinnamate, 4 parts of BTA, 6 parts of Tea Polyphenols, 10 parts of ethanol, 45 parts of water.
The dispersant is sodium lignin sulfonate, and the lubricant is white oil or the one kind in Tissuemat E.
The preparation method of described uvioresistant Anti-static electricity color master batch, it is characterised in that comprise the steps：
Step one, gets the raw materials ready：
To melt according to the EVA of the mass fraction meter, obtain bed material, wherein, the melt temperature is 150 DEG C；
Step 2, batch mixing：
Will according to one gained bed material the step of the mass fraction meter, the dispersant, antistatic additive, UV resistant agent,
Nanometer antimony oxide, tin ash, lubricant and diatomite add stirred into high-speed mixer successively, obtain blend glue stuff,
Wherein, in mixed process, rotating speed is 400r/min, and incorporation time is 2h；
Step 3, flow casting molding and section：
Step 2 gained blend glue stuff is carried out into flow casting molding, and is cut into slices, obtain uvioresistant Anti-static electricity color master batch, its
In, the body temperature of flow casting molding is 180-200-220-225-230 DEG C.
The preparation method of the antistatic additive is：By according to the water of mass fraction meter, tin ash, carbon black, poly- pyrrole
Cough up, silane coupler, dodecyl sodium sulfate and glycerine sequentially add and be heated in mixer 40 DEG C and be uniformly mixed, obtain final product
Antistatic additive.
The preparation method of the UV resistant agent is：By according to the water of mass fraction meter, 2,4- dihydroxy-hexichol first
Ketone, p-Coumaric Acid methyl esters, BTA, Tea Polyphenols and ethanol are sequentially added and be heated in mixer 40 DEG C of stirring mixing
It is even, obtain final product UV resistant agent.
Embodiment 2
Uvioresistant Anti-static electricity color master batch, including the following component according to mass fraction meter：43 parts of EVA, dispersant 1.6
Part, 33 parts of antistatic additive, 33 parts of UV resistant agent, 14 parts of nanometer antimony oxide, 14 parts of tin ash, 1.7 parts of lubricant, diatomite
22 parts.
The antistatic additive is included according to the following component of mass fraction meter：15 parts of tin ash, 7 parts of carbon black, polypyrrole
11 parts, 10 parts of silane coupler, 10 parts of dodecyl sodium sulfate, 3 parts of glycerine, 50 parts of water.
The UV resistant agent is included according to the following component of mass fraction meter：15 parts of 2,4- dihydroxy-benzophenone, it is right
18 parts of hydroxy-methyl cinnamate, 5 parts of BTA, 8 parts of Tea Polyphenols, 13 parts of ethanol, 50 parts of water.
The dispersant is sodium lignin sulfonate, and the lubricant is white oil or the one kind in Tissuemat E.
The preparation method of described uvioresistant Anti-static electricity color master batch, it is characterised in that comprise the steps：
Step one, gets the raw materials ready：
To melt according to the EVA of the mass fraction meter, obtain bed material, wherein, the melt temperature is 160 DEG C；
Step 2, batch mixing：
Will according to one gained bed material the step of the mass fraction meter, the dispersant, antistatic additive, UV resistant agent,
Nanometer antimony oxide, tin ash, lubricant and diatomite add stirred into high-speed mixer successively, obtain blend glue stuff,
Wherein, in mixed process, rotating speed is 450r/min, and incorporation time is 2h；
Step 3, flow casting molding and section：
Step 2 gained blend glue stuff is carried out into flow casting molding, and is cut into slices, obtain uvioresistant Anti-static electricity color master batch, its
In, the body temperature of flow casting molding is 180-200-220-225-230 DEG C.
The preparation method of the antistatic additive is：By according to the water of mass fraction meter, tin ash, carbon black, poly- pyrrole
Cough up, silane coupler, dodecyl sodium sulfate and glycerine sequentially add and be heated in mixer 45 DEG C and be uniformly mixed, obtain final product
Antistatic additive.
The preparation method of the UV resistant agent is：By according to the water of mass fraction meter, 2,4- dihydroxy-hexichol first
Ketone, p-Coumaric Acid methyl esters, BTA, Tea Polyphenols and ethanol are sequentially added and be heated in mixer 45 DEG C of stirring mixing
It is even, obtain final product UV resistant agent.
Step 3, flow casting molding and section：
Step 2 gained blend glue stuff is carried out into flow casting molding, and is cut into slices, obtain uvioresistant Anti-static electricity color master batch.
Embodiment 3
Uvioresistant Anti-static electricity color master batch, including the following component according to mass fraction meter：46 parts of EVA, dispersant 1.7
Part, 35 parts of antistatic additive, 35 parts of UV resistant agent, 16 parts of nanometer antimony oxide, 16 parts of tin ash, 2.0 parts of lubricant, diatomite
24 parts.
The antistatic additive is included according to the following component of mass fraction meter：17 parts of tin ash, 9 parts of carbon black, polypyrrole
16 parts, 12 parts of silane coupler, 17 parts of dodecyl sodium sulfate, 4 parts of glycerine, 55 parts of water.
The UV resistant agent is included according to the following component of mass fraction meter：17 parts of 2,4- dihydroxy-benzophenone, it is right
20 parts of hydroxy-methyl cinnamate, 7 parts of BTA, 10 parts of Tea Polyphenols, 15 parts of ethanol, 55 parts of water.
The dispersant is sodium lignin sulfonate, and the lubricant is white oil or the one kind in Tissuemat E.
The preparation method of described uvioresistant Anti-static electricity color master batch, it is characterised in that comprise the steps：
Step one, gets the raw materials ready：
To melt according to the EVA of the mass fraction meter, obtain bed material, wherein, the melt temperature is 170 DEG C；
Step 2, batch mixing：
Will according to one gained bed material the step of the mass fraction meter, the dispersant, antistatic additive, UV resistant agent,
Nanometer antimony oxide, tin ash, lubricant and diatomite add stirred into high-speed mixer successively, obtain blend glue stuff,
Wherein, in mixed process, rotating speed is 500r/min, and incorporation time is 3h；
Step 3, flow casting molding and section：
Step 2 gained blend glue stuff is carried out into flow casting molding, and is cut into slices, obtain uvioresistant Anti-static electricity color master batch, its
In, the body temperature of flow casting molding is 180-200-220-225-230 DEG C.
The preparation method of the antistatic additive is：By according to the water of mass fraction meter, tin ash, carbon black, poly- pyrrole
Cough up, silane coupler, dodecyl sodium sulfate and glycerine sequentially add and be heated in mixer 50 DEG C and be uniformly mixed, obtain final product
Antistatic additive.
The preparation method of the UV resistant agent is：By according to the water of mass fraction meter, 2,4- dihydroxy-hexichol first
Ketone, p-Coumaric Acid methyl esters, BTA, Tea Polyphenols and ethanol are sequentially added and be heated in mixer 50 DEG C of stirring mixing
It is even, obtain final product UV resistant agent.
The antistatic detection of uvioresistant is carried out to the uvioresistant Anti-static electricity color master batch of this product：
Uvioresistant is detected：This product 2*2*2cm square is intercepted, is with product surface distance height with quartz burner
9cm is irradiated, and daily 8:30 and 16:The color change of this product is observed in 30 timings, in this mode to embodiment 1～3
Product of the present invention and commercially available common EVA are detected；
Antistatic detection：The product of the present invention and commercially available common Masterbatch of embodiment 1～3 are examined with sheet resistance instrument
Survey.
The testing result such as following table of the present invention：
Table 1：The test result of uvioresistant Anti-static electricity color master batch
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Commercially available common Masterbatch |
| Color change situation | Color is unchanged | Color is unchanged | Color is unchanged | Lighter |
| Surface specific resistance/Ω/m2 | 5×103 | 4.9×103 | 4.9×103 | 3×1010 |
As shown in Table 1, after uv irradiation, color is unchanged for Masterbatch of the invention, and commercially available common Masterbatch face
Discoloration is shallow, and resistivity difference in surface is larger, thus can obtain Masterbatch of the invention and have the anlistatig premium properties of uvioresistant.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (9)
1. uvioresistant Anti-static electricity color master batch, it is characterised in that include according to the following component of mass fraction meter：EVA 40~46
Part, 1.5 ~ 1.7 parts of dispersant, 30 ~ 35 parts of antistatic additive, 30 ~ 35 parts of UV resistant agent, 10 ~ 16 parts of nanometer antimony oxide, titanium dioxide
12 ~ 16 parts of tin, 1.5 ~ 2.0 parts of lubricant, 20 ~ 24 parts of diatomite.
2. uvioresistant Anti-static electricity color master batch according to claim 1, it is characterised in that include according to mass fraction meter
Following component：43 parts of EVA, 1.6 parts of dispersant, 33 parts of antistatic additive, 33 parts of UV resistant agent, 14 parts of nanometer antimony oxide, dioxy
Change 14 parts of tin, 1.7 parts of lubricant, 22 parts of diatomite.
3. uvioresistant Anti-static electricity color master batch according to claim 1 and 2, it is characterised in that the antistatic additive includes
According to the following component of mass fraction meter：12 ~ 17 parts of tin ash, 5 ~ 9 parts of carbon black, 5 ~ 16 parts of polypyrrole, silane coupler 7 ~
12 parts, 8 ~ 11 parts of dodecyl sodium sulfate, 2 ~ 4 parts of glycerine, 45 ~ 55 parts of water.
4. uvioresistant Anti-static electricity color master batch according to claim 1 and 2, it is characterised in that the UV resistant agent bag
Include according to the following component of mass fraction meter：14 ~ 17 parts of 2,4- dihydroxy-benzophenone, p-Coumaric Acid methyl esters 17 ~ 20
Part, 4 ~ 7 parts of BTA, 6 ~ 10 parts of Tea Polyphenols, 10 ~ 15 parts of ethanol, 45 ~ 55 parts of water.
5. uvioresistant Anti-static electricity color master batch according to claim 1 and 2, it is characterised in that the dispersant is wooden
Plain sodium sulfonate, the lubricant is white oil or the one kind in Tissuemat E.
6. the preparation method of the uvioresistant Anti-static electricity color master batch described in claim 1, it is characterised in that comprise the steps：
Step one, gets the raw materials ready：
To melt according to the EVA of the mass fraction meter, obtain bed material, wherein, the melt temperature is 150 DEG C ~ 170 DEG C；
Step 2, batch mixing：
Will be according to one gained bed material, the dispersant, antistatic additive, UV resistant agent, nanometer the step of the mass fraction meter
Antimony oxide, tin ash, lubricant and diatomite add stirred into high-speed mixer successively, obtain blend glue stuff, wherein,
In mixed process, rotating speed is 400 ~ 500r/min, and incorporation time is 2 ~ 3h；
Step 3, flow casting molding and section：
Step 2 gained blend glue stuff is carried out into flow casting molding, and is cut into slices, obtain uvioresistant Anti-static electricity color master batch, wherein,
The body temperature of flow casting molding is 180-200-220-225-230 DEG C.
7. the preparation method of uvioresistant Anti-static electricity color master batch according to claim 6, it is characterised in that described antistatic
The preparation method of agent is：By according to the water of mass fraction meter, tin ash, carbon black, polypyrrole, silane coupler, 12
Sodium alkyl sulfonate and glycerine sequentially add and be heated in mixer 40 ~ 50 DEG C and be uniformly mixed, and obtain final product antistatic additive.
8. the preparation method of uvioresistant Anti-static electricity color master batch according to claim 6, it is characterised in that the uvioresistant
The preparation method of line agent is：By according to the water of mass fraction meter, 2,4- dihydroxy-benzophenone, p-Coumaric Acid first
Ester, BTA, Tea Polyphenols and ethanol sequentially add and be heated in mixer 40 ~ 50 DEG C and be uniformly mixed, and obtain final product uvioresistant
Line agent.
9. the preparation method of uvioresistant Anti-static electricity color master batch according to claim 6, it is characterised in that described in step one
Melt temperature is 160 DEG C, and in mixed process described in step 2, rotating speed is 450r/min, and incorporation time is 2h.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674411A (en) * | 2017-11-16 | 2018-02-09 | 福建鑫邦新材料科技有限公司 | A kind of thermoplastic polyurethane Masterbatch and preparation method thereof |
| CN109608897A (en) * | 2018-10-29 | 2019-04-12 | 赵建平 | A kind of Plastics Antistatic Agent |
| TWI708804B (en) * | 2019-09-18 | 2020-11-01 | 大陸商漢達精密電子（昆山）有限公司 | Uv-resistant high density polyethylene mother particle and product thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402753A (en) * | 2008-10-31 | 2009-04-08 | 浙江七色鹿色母粒有限公司 | Begin-color flame-proof antistatic polyolefin master batch |
| CN102181094A (en) * | 2011-04-26 | 2011-09-14 | 中山市铁鹰塑胶有限公司 | Antistatic and anti-aging white masterbatch for polypropylene (PP) resin and preparation method thereof |
| CN103694686A (en) * | 2013-12-28 | 2014-04-02 | 宁波金富亮塑料科技有限公司 | Color master batch for blue anti-UV (ultraviolet) nylon |
-
2016
- 2016-12-13 CN CN201611145877.5A patent/CN106633351A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402753A (en) * | 2008-10-31 | 2009-04-08 | 浙江七色鹿色母粒有限公司 | Begin-color flame-proof antistatic polyolefin master batch |
| CN102181094A (en) * | 2011-04-26 | 2011-09-14 | 中山市铁鹰塑胶有限公司 | Antistatic and anti-aging white masterbatch for polypropylene (PP) resin and preparation method thereof |
| CN103694686A (en) * | 2013-12-28 | 2014-04-02 | 宁波金富亮塑料科技有限公司 | Color master batch for blue anti-UV (ultraviolet) nylon |
Non-Patent Citations (3)
| Title |
|---|
| 王文广 主编: "《塑料配方设计》", 30 September 1998, 化学工业出版社 * |
| 王梦蛟 等主编: "《橡胶工业手册 修订版 第二分册 配合剂》", 31 October 1989, 化学工业出版社 * |
| 雷炳新 等编著: "《无机反应与无机材料研究》", 30 April 2015, 中国水利水电出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674411A (en) * | 2017-11-16 | 2018-02-09 | 福建鑫邦新材料科技有限公司 | A kind of thermoplastic polyurethane Masterbatch and preparation method thereof |
| CN109608897A (en) * | 2018-10-29 | 2019-04-12 | 赵建平 | A kind of Plastics Antistatic Agent |
| TWI708804B (en) * | 2019-09-18 | 2020-11-01 | 大陸商漢達精密電子（昆山）有限公司 | Uv-resistant high density polyethylene mother particle and product thereof |
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