CN103687667B - 包含负载在氧化锌上的铜的脱硫材料 - Google Patents

包含负载在氧化锌上的铜的脱硫材料 Download PDF

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Publication number
CN103687667B
CN103687667B CN201280036034.5A CN201280036034A CN103687667B CN 103687667 B CN103687667 B CN 103687667B CN 201280036034 A CN201280036034 A CN 201280036034A CN 103687667 B CN103687667 B CN 103687667B
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sulfur removal
removal material
copper
zinc oxide
sulfur
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CN103687667A (zh
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N·麦克里奥德
G·E·维尔森
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Johnson Matthey Davy Technologies Ltd
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Johnson Matthey PLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/024—Compounds of Zn, Cd, Hg
    • B01J20/0244—Compounds of Zn
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
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    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Gas Separation By Absorption (AREA)
CN201280036034.5A 2011-07-22 2012-04-12 包含负载在氧化锌上的铜的脱硫材料 Active CN103687667B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1112606.7 2011-07-22
GBGB1112606.7A GB201112606D0 (en) 2011-07-22 2011-07-22 Desulphurisation materials
PCT/GB2012/050808 WO2013014415A1 (en) 2011-07-22 2012-04-12 Desulphurisation material comprising copper supported on zinc oxide

Publications (2)

Publication Number Publication Date
CN103687667A CN103687667A (zh) 2014-03-26
CN103687667B true CN103687667B (zh) 2016-08-17

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US (2) US9539536B2 (https=)
JP (1) JP6043350B2 (https=)
CN (1) CN103687667B (https=)
BR (1) BR112014001139B1 (https=)
DE (1) DE112012003072T5 (https=)
DK (1) DK179793B1 (https=)
GB (2) GB201112606D0 (https=)
RU (1) RU2594283C2 (https=)
WO (1) WO2013014415A1 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6599849B2 (ja) * 2014-04-16 2019-10-30 ニッソーファイン株式会社 乾燥剤組成物
CN105582879B (zh) * 2014-10-24 2018-05-11 中国石油化工股份有限公司 硫砷净化剂及其制备方法
CN104437074B (zh) * 2014-12-31 2017-03-01 沈阳三聚凯特催化剂有限公司 一种同时脱除硫化氢和羰基硫的脱硫剂
SG10201604013RA (en) 2015-05-28 2016-12-29 Evonik Degussa Gmbh Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures
CN106622253A (zh) * 2016-12-23 2017-05-10 温州大学 CuO/ZnO复合纳米催化剂及其制备方法与应用
FR3067265B1 (fr) * 2017-06-13 2019-07-26 IFP Energies Nouvelles Procede de preparation de solides a partir d'un melange d'au moins une poudre de malachite et une poudre d'oxyde et utilisation de ces solides
CN110586028B (zh) * 2019-10-08 2021-11-19 中国石油化工股份有限公司 一种脱硫剂及其制备方法和应用
JP7288420B2 (ja) * 2020-06-10 2023-06-07 石塚硝子株式会社 硫黄系悪臭の消臭剤
CN111545055B (zh) * 2020-06-18 2022-02-11 中国科学院大学 类水滑石衍生复合氧化物材料的应用
JP7493718B2 (ja) * 2020-07-08 2024-06-03 株式会社重松製作所 シアン化水素ガス吸着材及び防毒マスク
CN113856704B (zh) * 2021-11-16 2023-04-07 四川轻化工大学 一种高效降解抗生素的光催化剂及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020182135A1 (en) * 1998-08-04 2002-12-05 M-I L.L.C. Process and composition for increasing the reactivity of sulfur scavenging oxides
WO2009112855A1 (en) * 2008-03-12 2009-09-17 Johnson Matthey Plc Desulphurisation materials
WO2011033280A1 (en) * 2009-09-15 2011-03-24 Johnson Matthey Plc Desulphurisation process

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2053477A5 (https=) 1969-07-07 1971-04-16 Azote & Prod Chim
US4071609A (en) 1975-07-09 1978-01-31 The New Jersey Zinc Company Method for preparing particulate zinc oxide shapes of high surface area and improved strength
GB8714232D0 (en) * 1987-06-17 1987-07-22 Ici Plc Sulphur compounds removal
JP3114325B2 (ja) 1992-02-14 2000-12-04 村田機械株式会社 ファクシミリ装置
GB9405269D0 (en) * 1994-03-17 1994-04-27 Ici Plc Absorbents
JP4161147B2 (ja) * 1998-03-27 2008-10-08 大阪瓦斯株式会社 水素製造装置
UA49430C2 (en) * 2001-12-06 2006-12-15 Alvigo Ks Res And Production C Catalyst for removal of organic and inorganic compounds of sulfur from gas or vapor, process for removal of sulfuric compounds from gases and method for removal of sulfuric compounds from vapor, for example, benzene
PL1843840T3 (pl) * 2005-01-06 2019-11-29 Res Triangle Inst Sorbenty na bazie tlenku cynku oraz procesy ich wytwarzania i stosowania
DE102005004368A1 (de) 2005-01-31 2006-08-03 Süd-Chemie AG Entschwefelungskatalysator
AT505700B1 (de) 2007-08-27 2009-12-15 Mettop Gmbh Verfahren zum betreiben von kupfer-elektrolysezellen
GB0804572D0 (en) 2008-03-12 2008-04-16 Johnson Matthey Plc Preparation of desulphurisation materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020182135A1 (en) * 1998-08-04 2002-12-05 M-I L.L.C. Process and composition for increasing the reactivity of sulfur scavenging oxides
WO2009112855A1 (en) * 2008-03-12 2009-09-17 Johnson Matthey Plc Desulphurisation materials
WO2011033280A1 (en) * 2009-09-15 2011-03-24 Johnson Matthey Plc Desulphurisation process

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WO2013014415A1 (en) 2013-01-31
JP6043350B2 (ja) 2016-12-14
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