CN103665355A - 一种高亲水全生物基聚酯的制备方法 - Google Patents
一种高亲水全生物基聚酯的制备方法 Download PDFInfo
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- CN103665355A CN103665355A CN201210339250.9A CN201210339250A CN103665355A CN 103665355 A CN103665355 A CN 103665355A CN 201210339250 A CN201210339250 A CN 201210339250A CN 103665355 A CN103665355 A CN 103665355A
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- 229920000728 polyester Polymers 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 128
- 238000005886 esterification reaction Methods 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 229920005862 polyol Polymers 0.000 claims abstract description 21
- 150000003077 polyols Chemical class 0.000 claims abstract description 21
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 239000002028 Biomass Substances 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 230000032050 esterification Effects 0.000 claims description 32
- -1 carboxylic acid diester Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 9
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 9
- 230000035484 reaction time Effects 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical group O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 8
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims description 8
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000855 fermentation Methods 0.000 claims description 6
- 230000004151 fermentation Effects 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 5
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000010902 straw Substances 0.000 claims description 4
- 150000003608 titanium Chemical class 0.000 claims description 4
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 235000009973 maize Nutrition 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 abstract 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 1
- 238000003723 Smelting Methods 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 abstract 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000003208 petroleum Substances 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
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- Y02P20/121—
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- Polyesters Or Polycarbonates (AREA)
Abstract
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CN201210339250.9A CN103665355B (zh) | 2012-09-13 | 2012-09-13 | 一种高亲水全生物基聚酯的制备方法 |
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CN103665355A true CN103665355A (zh) | 2014-03-26 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107915833A (zh) * | 2017-11-13 | 2018-04-17 | 东华大学 | 一种纤维级生物基聚酯及其制备方法 |
CN107936237A (zh) * | 2017-11-13 | 2018-04-20 | 东华大学 | 一种生物基可降解聚酯纤维及其制备方法 |
CN113717326A (zh) * | 2021-09-24 | 2021-11-30 | 张家港市顾乐仕生活家居科技有限公司 | 生物基聚酯型亲水绵及其制备方法 |
CN115819744A (zh) * | 2022-11-23 | 2023-03-21 | 河南省生物基材料产业研究院有限公司 | 一种增韧性生物基聚呋喃二甲酸乙二醇酯的合成方法 |
CN116334926A (zh) * | 2023-04-27 | 2023-06-27 | 珠海华大浩宏新材料有限公司 | 一种生物基吸湿速干整理剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1931893A (zh) * | 2006-10-12 | 2007-03-21 | 东华大学 | Pet/ptt共聚酯的制备方法 |
WO2010078328A2 (en) * | 2008-12-30 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Bio-based terephthalate polyesters |
CN101899145A (zh) * | 2010-07-28 | 2010-12-01 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
CN102604053A (zh) * | 2012-03-15 | 2012-07-25 | 泉州海天材料科技股份有限公司 | 一种生物质聚酯的制备方法 |
-
2012
- 2012-09-13 CN CN201210339250.9A patent/CN103665355B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1931893A (zh) * | 2006-10-12 | 2007-03-21 | 东华大学 | Pet/ptt共聚酯的制备方法 |
WO2010078328A2 (en) * | 2008-12-30 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Bio-based terephthalate polyesters |
CN101899145A (zh) * | 2010-07-28 | 2010-12-01 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
CN102604053A (zh) * | 2012-03-15 | 2012-07-25 | 泉州海天材料科技股份有限公司 | 一种生物质聚酯的制备方法 |
Non-Patent Citations (3)
Title |
---|
李素花等: ""PET-PTT共聚酯的结晶和纺丝性能"", 《合成纤维工业》, vol. 29, no. 4, 31 August 2006 (2006-08-31), pages 8 - 10 * |
王德诚: ""PTT纤维的发展现状和前景"", 《聚酯工业》, vol. 14, no. 5, 31 October 2001 (2001-10-31), pages 1 - 5 * |
魏高富等: ""PET-PTT共聚酯的合成及组成和热性能的研究"", 《2004年全国高分子材料科学与工程研讨会论文集》, 1 October 2004 (2004-10-01), pages 53 - 54 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107915833A (zh) * | 2017-11-13 | 2018-04-17 | 东华大学 | 一种纤维级生物基聚酯及其制备方法 |
CN107936237A (zh) * | 2017-11-13 | 2018-04-20 | 东华大学 | 一种生物基可降解聚酯纤维及其制备方法 |
CN107915833B (zh) * | 2017-11-13 | 2020-10-30 | 东华大学 | 一种纤维级生物基聚酯及其制备方法 |
CN113717326A (zh) * | 2021-09-24 | 2021-11-30 | 张家港市顾乐仕生活家居科技有限公司 | 生物基聚酯型亲水绵及其制备方法 |
CN115819744A (zh) * | 2022-11-23 | 2023-03-21 | 河南省生物基材料产业研究院有限公司 | 一种增韧性生物基聚呋喃二甲酸乙二醇酯的合成方法 |
CN116334926A (zh) * | 2023-04-27 | 2023-06-27 | 珠海华大浩宏新材料有限公司 | 一种生物基吸湿速干整理剂及其制备方法 |
CN116334926B (zh) * | 2023-04-27 | 2023-09-22 | 珠海华大浩宏新材料有限公司 | 一种生物基吸湿速干整理剂及其制备方法 |
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Publication number | Publication date |
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CN103665355B (zh) | 2016-01-20 |
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Inventor after: Wang Chaosheng Inventor after: Wang Lejun Inventor after: Wang Huaping Inventor after: Liu Yining Inventor after: Chen Xiangling Inventor after: Wang Huan Inventor before: Wang Chaosheng Inventor before: Wang Huaping Inventor before: Chen Xiangling Inventor before: Wang Huan |
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Effective date of registration: 20171215 Address after: 315336 No. 339 Binhai four road, Hangzhou Bay New District, Zhejiang, Ningbo Co-patentee after: Donghua University Patentee after: Hi Tech bio based materials engineering technology (Ningbo) Co., Ltd. Address before: 201620 Shanghai, North Renmin Road, Songjiang District, No. 2999 Patentee before: Donghua University |
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Effective date of registration: 20210610 Address after: Room 1115, Zhongfu building, 99 Jianguo Road, Chaoyang District, Beijing 100020 Patentee after: HI-TECH FIBER Group Corp. Patentee after: DONGHUA University Address before: 315336 No.339 Binhai 4th Road, Hangzhou Bay New District, Ningbo City, Zhejiang Province Patentee before: HENGTIAN BIO-BASED MATERIALS ENGINEERING TECHNOLOGY (NINGBO) Co.,Ltd. Patentee before: DONGHUA University |
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