CN103649168B - 颜色稳定的生物可降解的脂肪族-芳香族共聚酯、其制造方法及制品 - Google Patents

颜色稳定的生物可降解的脂肪族-芳香族共聚酯、其制造方法及制品 Download PDF

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Publication number
CN103649168B
CN103649168B CN201280034700.1A CN201280034700A CN103649168B CN 103649168 B CN103649168 B CN 103649168B CN 201280034700 A CN201280034700 A CN 201280034700A CN 103649168 B CN103649168 B CN 103649168B
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Prior art keywords
acid
copolyesters
aromatic
weight
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Expired - Fee Related
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CN201280034700.1A
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English (en)
Chinese (zh)
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CN103649168A (zh
Inventor
许斯尼·阿尔普·阿利代德奥卢
加内什·卡纳安
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Priority claimed from US13/183,786 external-priority patent/US20130018143A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/87—Non-metals or inter-compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Biological Depolymerization Polymers (AREA)
CN201280034700.1A 2011-07-15 2012-07-13 颜色稳定的生物可降解的脂肪族-芳香族共聚酯、其制造方法及制品 Expired - Fee Related CN103649168B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/183,786 2011-07-15
US13/183,786 US20130018143A1 (en) 2011-07-15 2011-07-15 Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US13/432,638 2012-03-28
US13/432,638 US8933162B2 (en) 2011-07-15 2012-03-28 Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
PCT/US2012/046627 WO2013012706A1 (en) 2011-07-15 2012-07-13 Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof

Publications (2)

Publication Number Publication Date
CN103649168A CN103649168A (zh) 2014-03-19
CN103649168B true CN103649168B (zh) 2016-07-20

Family

ID=46551927

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280034700.1A Expired - Fee Related CN103649168B (zh) 2011-07-15 2012-07-13 颜色稳定的生物可降解的脂肪族-芳香族共聚酯、其制造方法及制品

Country Status (5)

Country Link
US (1) US8933162B2 (enExample)
JP (1) JP2014524959A (enExample)
CN (1) CN103649168B (enExample)
AU (1) AU2012284305B2 (enExample)
WO (1) WO2013012706A1 (enExample)

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US8877862B2 (en) 2011-07-15 2014-11-04 Saudi Basic Industries Corporation Method for color stabilization of poly(butylene-co-adipate terephthalate
US8933162B2 (en) 2011-07-15 2015-01-13 Saudi Basic Industries Corporation Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US9334360B2 (en) 2011-07-15 2016-05-10 Sabic Global Technologies B.V. Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8946345B2 (en) 2011-08-30 2015-02-03 Saudi Basic Industries Corporation Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst
US8901273B2 (en) 2012-02-15 2014-12-02 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8969506B2 (en) 2012-02-15 2015-03-03 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8889820B2 (en) 2012-02-15 2014-11-18 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US9034983B2 (en) 2012-03-01 2015-05-19 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof
US8895660B2 (en) 2012-03-01 2014-11-25 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof
US8901243B2 (en) * 2012-03-30 2014-12-02 Saudi Basic Industries Corporation Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
WO2014022197A1 (en) 2012-07-30 2014-02-06 Sabic Innovative Plastics Ip B.V. Method for preparation of modified poly(alkylene terephthalate) employing titanium-containing catalyst complex
US9670313B2 (en) 2012-07-30 2017-06-06 Sabic Global Technologies B.V. Hydrostability of polyester composition
US9487622B2 (en) 2013-07-25 2016-11-08 Sabic Global Technologies B.V. Process for the preparation of modified poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst
CN107189365B (zh) * 2017-05-19 2020-02-18 上海弘睿生物科技有限公司 Pbat生物全降解薄膜组合物及其制备方法
CN110483961B (zh) * 2019-09-30 2021-11-16 苏州中达航材料科技有限公司 一种全降解地膜及其制备方法
CN111349233B (zh) * 2020-03-04 2021-10-26 东华大学 一种生物可降解交替型脂肪族聚酯酰胺及其制备方法
JP7282124B2 (ja) * 2020-05-28 2023-05-26 エコバンス カンパニー・リミテッド 生分解性ポリエステル樹脂組成物、不織布およびフィルム、並びにその製造方法
CN112708115A (zh) * 2020-06-17 2021-04-27 北京化工大学 一种耐高温芳香族-脂肪族生物基聚酯弹性体及制备方法
CN112920388B (zh) * 2021-01-27 2022-10-21 江苏睿安应用生物技术股份有限公司 一种生物降解脂肪-芳香族共聚酯及其制备方法
CN115466378B (zh) * 2021-10-19 2023-12-15 源创核新(北京)新材料科技有限公司 一种钛铝复合催化剂在聚草酸酯合成中的应用
KR102945831B1 (ko) * 2022-06-08 2026-03-27 에스케이리비오 주식회사 생분해성 폴리에스테르 수지 조성물, 이를 포함하는 생분해성 폴리에스테르 필름 및 이를 포함하는 생분해성 성형품
CN115612074A (zh) * 2022-10-17 2023-01-17 南通天洋新材料有限公司 一种可生物降解聚酯的制备方法

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