CN103619898A - 硬质聚氨酯泡沫 - Google Patents

硬质聚氨酯泡沫 Download PDF

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Publication number
CN103619898A
CN103619898A CN201280026932.2A CN201280026932A CN103619898A CN 103619898 A CN103619898 A CN 103619898A CN 201280026932 A CN201280026932 A CN 201280026932A CN 103619898 A CN103619898 A CN 103619898A
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China
Prior art keywords
rigid polyurethane
polyurethane foam
polyol
foam according
flame retardant
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Pending
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CN201280026932.2A
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English (en)
Chinese (zh)
Inventor
王亚云
赵贺猛
邓伏起
姚荣兴
张鹏
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BASF SE
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BASF SE
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Priority to CN201280026932.2A priority Critical patent/CN103619898A/zh
Publication of CN103619898A publication Critical patent/CN103619898A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/425—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids the polyols containing one or two ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0038—Use of organic additives containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201280026932.2A 2011-05-31 2012-05-31 硬质聚氨酯泡沫 Pending CN103619898A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201280026932.2A CN103619898A (zh) 2011-05-31 2012-05-31 硬质聚氨酯泡沫

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CNPCT/CN2011/074988 2011-05-31
CN2011074988 2011-05-31
PCT/CN2012/076322 WO2012163279A1 (en) 2011-05-31 2012-05-31 Polyurethane rigid foams
CN201280026932.2A CN103619898A (zh) 2011-05-31 2012-05-31 硬质聚氨酯泡沫

Publications (1)

Publication Number Publication Date
CN103619898A true CN103619898A (zh) 2014-03-05

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CN201280026932.2A Pending CN103619898A (zh) 2011-05-31 2012-05-31 硬质聚氨酯泡沫

Country Status (7)

Country Link
JP (1) JP6026518B2 (https=)
KR (1) KR101970842B1 (https=)
CN (1) CN103619898A (https=)
AU (1) AU2012265397A1 (https=)
BR (1) BR112013030712A2 (https=)
RU (1) RU2013158466A (https=)
WO (1) WO2012163279A1 (https=)

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CN106147205A (zh) * 2015-04-27 2016-11-23 天津奇才科技发展有限公司 扦插复合型高阻燃聚异氰脲酸酯硬质泡沫材料
CN106220809A (zh) * 2016-08-05 2016-12-14 潍坊远航聚氨酯保温材料有限公司 一种高阻燃石墨喷涂聚氨酯及其制备方法和施工方法
CN107428899A (zh) * 2015-03-20 2017-12-01 井上株式会社 聚氨酯泡沫
CN108484863A (zh) * 2018-04-13 2018-09-04 西安增材制造国家研究院有限公司 一种用于3d打印的聚合物建筑材料
CN111393833A (zh) * 2020-04-02 2020-07-10 张家港长泰汽车饰件材料有限公司 高开孔率耐水解聚氨酯泡沫及其制备方法和用途
CN112585185A (zh) * 2018-08-23 2021-03-30 美国圣戈班性能塑料公司 聚氨酯泡沫及其形成方法
CN114127149A (zh) * 2019-07-22 2022-03-01 巴斯夫欧洲公司 低tvoc的阻燃聚氨酯喷涂泡沫体系
CN116217861A (zh) * 2023-02-23 2023-06-06 山东奥卓新材料有限公司 一种高阻燃无燃烧滴落物/微粒的聚氨酯减振隔声垫及其制备方法

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JP2016136998A (ja) * 2015-01-26 2016-08-04 ホーチキ株式会社 消火法及び消火器
CN104558483B (zh) * 2015-02-04 2017-07-04 哈尔滨工业大学（威海） 一种喷涂型聚氨酯硬质泡沫及其制备方法
JP6480775B2 (ja) * 2015-03-26 2019-03-13 積水化学工業株式会社 ウレタン樹脂組成物、建材の耐火補強方法、および建材の耐火補強構造
CN104877102A (zh) * 2015-06-03 2015-09-02 威海云山科技有限公司 一种阻燃聚氨酯硬质泡沫保温板材
CN105237704A (zh) * 2015-09-18 2016-01-13 扬中市天正合成材料研究中心 一种环保高阻燃高速列车吧台用pu发泡材料及其制备方法
CN106084169A (zh) * 2016-07-07 2016-11-09 扬中市天正合成材料研究中心 一种绿化树皮造型环保高阻燃发泡材料及其制备方法
CN106084167A (zh) * 2016-07-07 2016-11-09 扬中市天正合成材料研究中心 一种半硬质弹性体环保高阻燃发泡材料及其制备方法
CN106188460A (zh) * 2016-07-07 2016-12-07 扬中市天正合成材料研究中心 一种卫生洁具环保高阻燃发泡材料及其制备方法
CN106046306A (zh) * 2016-07-07 2016-10-26 扬中市天正合成材料研究中心 一种油罐车罐体用环保高阻燃聚氨酯发泡材料及其制备方法
CN106432669A (zh) * 2016-07-07 2017-02-22 扬中市天正合成材料研究中心 一种拖拉机水箱用环保高阻燃高密度发泡材料及其制备方法
CN106046296A (zh) * 2016-07-07 2016-10-26 扬中市天正合成材料研究中心 一种垃圾箱环保高阻燃发泡材料及其制备方法
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CN106008886A (zh) * 2016-07-07 2016-10-12 扬中市天正合成材料研究中心 一种环保高阻燃硬泡聚氨酯门窗内胆填充发泡材料及制备方法
CN106084165A (zh) * 2016-07-07 2016-11-09 扬中市天正合成材料研究中心 一种包装用环保高阻燃发泡材料及其制备方法
CN106084168A (zh) * 2016-07-07 2016-11-09 扬中市天正合成材料研究中心 一种输油管环保高阻燃发泡材料及其制备方法
CN106046297A (zh) * 2016-07-07 2016-10-26 扬中市天正合成材料研究中心 一种汽车油箱用环保高阻燃聚氨酯发泡材料及其制备方法
CN106146793A (zh) * 2016-07-07 2016-11-23 扬中市天正合成材料研究中心 一种硬质旅行箱环保高阻燃发泡材料及其制备方法
CN106008874A (zh) * 2016-07-07 2016-10-12 扬中市天正合成材料研究中心 一种货架环保高阻燃发泡材料及其制备方法
ES3063896T3 (en) * 2016-10-25 2026-04-21 Ele Corp Low-viscosity phosphate polyols
JP6974672B2 (ja) * 2017-03-14 2021-12-01 ディディピー スペシャルティ エレクトロニック マテリアルズ ユーエス，エルエルシー 熱膨張性コーティング系
CN111378197A (zh) * 2020-03-27 2020-07-07 山东省云山鼎节能工程有限公司 一种喷涂型聚氨酯硬质泡沫及其制备方法
JP2022048708A (ja) * 2020-09-15 2022-03-28 積水化学工業株式会社 難燃性ウレタン樹脂組成物
CN112250814A (zh) * 2020-10-10 2021-01-22 上海东大聚氨酯有限公司 一种经济环保型聚氨酯保温泡沫及其制备方法
JP7545867B2 (ja) * 2020-10-30 2024-09-05 株式会社イノアックコーポレーション ポリウレタンフォームとその製造方法
CN113637142B (zh) * 2021-07-13 2022-05-10 广东图恩新材料有限公司 一种喷涂型阻燃聚氨酯组合料及其制备方法与使用方法
WO2023249800A1 (en) 2022-06-21 2023-12-28 Basf Se Polyurethane products with digital functionality through use of embedded sensor devices
EP4497769A1 (en) * 2023-07-24 2025-01-29 RAMPF Advanced Polymers GmbH & Co. KG Flame-retardant polyurethane composition

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Cited By (13)

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US11072704B2 (en) 2015-03-20 2021-07-27 Inoac Corporation Polyurethane foam
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US11655365B2 (en) 2015-03-20 2023-05-23 Inoac Corporation Polyurethane foam
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CN112585185A (zh) * 2018-08-23 2021-03-30 美国圣戈班性能塑料公司 聚氨酯泡沫及其形成方法
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CN111393833A (zh) * 2020-04-02 2020-07-10 张家港长泰汽车饰件材料有限公司 高开孔率耐水解聚氨酯泡沫及其制备方法和用途
CN116217861A (zh) * 2023-02-23 2023-06-06 山东奥卓新材料有限公司 一种高阻燃无燃烧滴落物/微粒的聚氨酯减振隔声垫及其制备方法
CN116217861B (zh) * 2023-02-23 2024-03-12 山东奥卓新材料有限公司 一种高阻燃无燃烧滴落物/微粒的聚氨酯减振隔声垫及其制备方法

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