CN103582525B - 水-煤气变换催化剂 - Google Patents

水-煤气变换催化剂 Download PDF

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Publication number
CN103582525B
CN103582525B CN201280027529.1A CN201280027529A CN103582525B CN 103582525 B CN103582525 B CN 103582525B CN 201280027529 A CN201280027529 A CN 201280027529A CN 103582525 B CN103582525 B CN 103582525B
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catalyst
titania
oxide
catalyst precursor
support
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Expired - Fee Related
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CN201280027529.1A
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Chinese (zh)
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CN103582525A (zh
Inventor
P·E·J·艾伯特
M·福尔斯
A·C·拉尔拉
N·麦克里奥德
J·J·G·佩雷斯
E·M·瓦斯
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Johnson Matthey PLC
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Johnson Matthey PLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN201280027529.1A 2011-06-06 2012-05-22 水-煤气变换催化剂 Expired - Fee Related CN103582525B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1109376.2A GB201109376D0 (en) 2011-06-06 2011-06-06 Water-gas shift catalyst
GB1109376.2 2011-06-06
PCT/GB2012/051157 WO2012168690A1 (en) 2011-06-06 2012-05-22 Water-gas shift catalyst

Publications (2)

Publication Number Publication Date
CN103582525A CN103582525A (zh) 2014-02-12
CN103582525B true CN103582525B (zh) 2016-04-13

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CN201280027529.1A Expired - Fee Related CN103582525B (zh) 2011-06-06 2012-05-22 水-煤气变换催化剂

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Country Link
US (1) US20140158942A1 (enExample)
JP (1) JP2014519976A (enExample)
KR (1) KR20140032463A (enExample)
CN (1) CN103582525B (enExample)
AU (1) AU2012266009A1 (enExample)
CA (1) CA2835569A1 (enExample)
DE (1) DE112012002361T5 (enExample)
DK (1) DK201470002A (enExample)
GB (2) GB201109376D0 (enExample)
WO (1) WO2012168690A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104507572B (zh) * 2012-12-28 2018-06-22 三菱重工业株式会社 Co转化催化剂、co转化反应装置及气化气的精制方法
WO2014114824A1 (es) * 2013-01-28 2014-07-31 Abengoa Bioenergía Nuevas Tecnologías, S. A. Catalizadores y su uso en la obtención de alcoholes superiores
US9403152B2 (en) * 2013-11-25 2016-08-02 Clariant Corporation Catalyst materials useful for sour gas shift reactions and methods for using them
CN104841435A (zh) * 2014-02-18 2015-08-19 中国石油化工股份有限公司 一种碱金属掺杂改性煤制天然气甲烷合成催化剂及其制备方法
KR101738486B1 (ko) * 2016-01-13 2017-06-08 한국에너지기술연구원 촉매 지지체 표면에 금속산화물 코팅층을 형성하는 방법과 금속산화물 코팅층을 포함하는 촉매 지지체 및 촉매장치
CN109794257B (zh) * 2017-11-16 2022-03-22 国家能源投资集团有限责任公司 耐硫变换催化剂及其制备方法
EP3689451A1 (en) * 2019-01-29 2020-08-05 Evonik Operations GmbH Catalyst for the synthesis of alkyl mercaptan and process for its preparation
CN114100624B (zh) * 2020-08-31 2023-08-11 中国石油化工股份有限公司 高岭土改性耐硫变换催化剂及其制备方法
CN114177912B (zh) * 2020-09-14 2024-02-13 中国石油化工股份有限公司 一种钙钛矿型耐硫变换催化剂及其制备方法与应用
CN114425395B (zh) * 2020-10-10 2024-02-20 中国石油化工股份有限公司 一种多孔钙钛矿型耐硫变换催化剂及其制备方法与应用
CN112221485A (zh) * 2020-11-13 2021-01-15 重庆新华化工有限公司 一种降低烧损的Ti-Mo或Ti-Mo-V催化剂钛白粉的制备方法
JP2025516126A (ja) * 2022-04-13 2025-05-27 アイイーティー エコロジー エス．エル． 水素を得ることによる廃棄物の材料有価化方法及びそれを実施するシステム
CN118874480A (zh) * 2024-07-09 2024-11-01 青岛联信催化材料有限公司 一种耐硫变换催化剂及其制备方法
CN120381846B (zh) * 2025-06-27 2025-09-12 江西师范大学 Ni-MoOx/HTO纳米催化剂及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1281051A (en) * 1968-06-18 1972-07-12 Exxon Research Engineering Co Low temperature shift reaction involving an alkali metal compound and a hydrogenation dehydrogenation component
GB1325173A (en) * 1969-11-10 1973-08-01 Exxon Research Engineering Co Shift process for catalyst
EP0062912A1 (en) * 1981-04-14 1982-10-20 United Catalysts, Inc. Process for the catalytic conversion of carbon monoxide and sulfactive CO conversion catalyst
US4452854A (en) * 1981-04-14 1984-06-05 United Catalysts, Inc. Catalyst and process for carbon monoxide conversion in sour gas

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB961860A (en) * 1960-07-20 1964-06-24 Metallgesellschaft Ag Improvements in or relating to the catalytic conversion of carbon monoxide with steam
DE1667386C3 (de) 1967-04-15 1975-12-11 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Wasserstoff und Kohlendioxid durch katalytische Umsetzung von Kohlenmonoxid mit Wasserdampf
US3850841A (en) * 1969-11-10 1974-11-26 Exxon Research Engineering Co Shift process for new catalyst
GB1491499A (en) * 1973-11-23 1977-11-09 Exxon Research Engineering Co Process and catalyst for conversion of carbon monoxide and steam to hydrogen and carbon dioxide
US4661525A (en) * 1984-03-28 1987-04-28 Texaco Inc. Process for producing lower aliphatic alcohols
US4752623A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Mixed alcohols production from syngas
US4983638A (en) * 1989-07-17 1991-01-08 Texaco Inc. Catalyst and method for producing lower aliphatic alcohols
CN1087192C (zh) * 1998-07-15 2002-07-10 中国石化齐鲁石油化工公司 一种抗水合的耐硫变换催化剂及制备方法
GB0222240D0 (en) * 2002-09-25 2002-10-30 Ici Plc Cobalt catalysts
RU2011102051A (ru) * 2008-07-03 2012-08-10 Синтенол Энерджи Корпорейшн (CA) Биметаллический мо/со катализатор для получения спиртов из газа, содержащего водород и монооксид углерода
JP5404774B2 (ja) * 2009-04-10 2014-02-05 三菱重工業株式会社 Ｃｏシフト触媒、ｃｏシフト反応装置及びガス化ガスの精製方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1281051A (en) * 1968-06-18 1972-07-12 Exxon Research Engineering Co Low temperature shift reaction involving an alkali metal compound and a hydrogenation dehydrogenation component
GB1325173A (en) * 1969-11-10 1973-08-01 Exxon Research Engineering Co Shift process for catalyst
EP0062912A1 (en) * 1981-04-14 1982-10-20 United Catalysts, Inc. Process for the catalytic conversion of carbon monoxide and sulfactive CO conversion catalyst
US4452854A (en) * 1981-04-14 1984-06-05 United Catalysts, Inc. Catalyst and process for carbon monoxide conversion in sour gas

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US20140158942A1 (en) 2014-06-12

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