CN103555204B - Thick matter waterproof paint of modified-high polymer water-latex type asphaltic base and preparation method thereof - Google Patents
Thick matter waterproof paint of modified-high polymer water-latex type asphaltic base and preparation method thereof Download PDFInfo
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- CN103555204B CN103555204B CN201310416370.9A CN201310416370A CN103555204B CN 103555204 B CN103555204 B CN 103555204B CN 201310416370 A CN201310416370 A CN 201310416370A CN 103555204 B CN103555204 B CN 103555204B
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- 229920000126 latex Polymers 0.000 title claims abstract description 30
- 239000004816 latex Substances 0.000 title claims abstract description 24
- 239000003973 paint Substances 0.000 title claims abstract description 15
- 229920000642 polymer Polymers 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000010426 asphalt Substances 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000098 polyolefin Polymers 0.000 claims abstract description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 28
- 239000000344 soap Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 16
- 239000001913 cellulose Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 8
- 239000011295 pitch Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical group CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 150000004985 diamines Chemical class 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 238000009775 high-speed stirring Methods 0.000 claims description 4
- 239000012764 mineral filler Substances 0.000 claims description 4
- 239000011301 petroleum pitch Substances 0.000 claims description 4
- 230000003068 static effect Effects 0.000 claims description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 3
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 6
- 229910004298 SiO 2 Inorganic materials 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 2
- 150000002367 halogens Chemical class 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000000725 suspension Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- XPVIQPQOGTVMSU-UHFFFAOYSA-N (4-acetamidophenyl)arsenic Chemical compound CC(=O)NC1=CC=C([As])C=C1 XPVIQPQOGTVMSU-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229920013640 amorphous poly alpha olefin Polymers 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- -1 Ursol D Chemical compound 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention belongs to thick matter waterproof paint of a kind of modified-high polymer water-latex type asphaltic base and preparation method thereof, this anion-modified emulsified bitumen of material high-concentration super-fine microactuator suspension emulsion-type and polyolefins properties-correcting agent, neoprene latex or SBR emulsion etc. the multiple synthesising macromolecule copolymer such as rubber latex, epoxy resin and SiO
2, the inorganic powder such as wilkinite as raw material, use special producing technique to be mixed with and makes, after tested, low temperature-20 DEG C of not embrittlement after film forming, high temperature of 120 DEG C does not trickle, and elastic recovery rate is up to 90%, and Absorbable organic halogens stores more than 1 year.
Description
Technical field
The present invention relates to water-proof building material, specifically refer to thick matter waterproof paint of a kind of modified-high polymer water-latex type asphaltic base and preparation method thereof.
Background technology
As a kind of traditional water-proof material, pitch has good hydrophobic nature, watertightness, plasticity and cementability, is the cheap architectural waterproof material generally used both at home and abroad, but it also exists low temperature brittleness, high temperature trickling, poor flexibility and the ageing-resistant defect such as bad.
At present, in China's soluble asphalt base waterproof coating, modified waterproof asphalt material is mostly Bao Zhixing, and thick coating is not all modified.For thick coating, because pitch is not modified, unit elongation is low, low temperature flexibility is poor, although can form thick coating, its waterproof effect is still limited.
In China, modified asphalt waterproof material, generally based on waterproof roll, mostly adopts the method for flax silk or glass yarn reinforcement to improve tensile strength, the unit elongation of material will be caused so greatly to reduce, meanwhile, the adhesion of coiled material and basic unit is also a large problem on constructing always.
On market, high performance modified waterproof asphalt material is also rare.Common mostly be simple by adding polychloroprene latex to carry high performance modified waterproof asphalt material, simultaneously in order to improve high-temperature behavior, add the linking agents such as MgO, ZnO in coating more, but because the consistency of neoprene latex and pitch is poor, make coating less stable in storage process, and oxide compound soluble in water also can have a strong impact on the water resistance of film.
Summary of the invention
The technical problem to be solved in the present invention is, provides a kind of high temperature performance good, has excellent storage stability, the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base of brushing of can directly constructing.
For solving the problems of the technologies described above, technical scheme provided by the invention is: the thick matter waterproof paint of a kind of modified-high polymer water-latex type asphaltic base, and this coating is prepared by each feed composition of following weight percent:
Described petroleum pitch is 60# pitch or 70# pitch, described polyolefins properties-correcting agent is amorphous propylene multipolymer (APAO), Atactic Polypropelene (APP) or styrene-butadiene-styrene block copolymer (SBS), improve the high-temperature behavior of coating after adding polyolefins properties-correcting agent, after film forming, high temperature does not trickle, does not drip.
Described rubber latex is one or both of neoprene latex or SBR emulsion, and improve the low-temperature performance of coating, low temperature not embrittlement after film forming, elasticity is good.
Described epoxy resin is epoxy resin E44 or epoxy resin E51, and described diamine crosslinking and curing agent is the wherein one of quadrol, propylene diamine, hexanediamine, Ursol D, 2 methyl pentamethylenediamine.After the present invention with the addition of epoxy resin and solidifying agent, further increase high temperature resistant, water tolerance, preservative property and the adhesion of coating.
Described stablizer is fatty alcohol-polyoxyethylene ether, polyoxypropyleneglycol or polytetrahydrofuran diol, and described Mierocrystalline cellulose is the wherein a kind of of Natvosol, carboxymethyl cellulose or Vltra tears.After the present invention with the addition of stablizer or Mierocrystalline cellulose, coating standing storage is not emanated, store and open packaging after 1 year and still can normally use, improve the stability in storage of coating.
Described rosined soap class emulsifying agent is disproportionated rosin potassium soap or rosin sodium soap.
Described mineral filler is the SiO of 1-3%
2with the wilkinite of 1-3%.
The present invention with the addition of SiO
2, after wilkinite and Mierocrystalline cellulose, improve viscosity and plasticity, the use properties of coating be protected, directly can brush, be coated with thickness, the thick film of formation still has excellent high/low temperature flexibility, improve weathering resistance and the anti-ultraviolet aging function of coating simultaneously, and extend work-ing life.
Described PH conditioning agent is NaOH or KOH.
The present invention also discloses the preparation method of the thick matter waterproof paint of a kind of modified-high polymer water-latex type asphaltic base, and preparation process comprises:
1) petroleum pitch pumped into asphalt tank and be heated to 150 DEG C ~ 180 DEG C, drop into polyolefins properties-correcting agent, high-speed stirring, then adds epoxy resin, with colloidal mill grinding after stirring, stirs and de-soak the polymer-modified asphalt prepared;
2) water, rosined soap class emulsifying agent, diamine crosslinking and curing agent and stablizer Hybrid Heating to 60 DEG C, and with PH conditioning agent, pH value is adjusted to 10-12, makes soap lye;
3) polymer-modified asphalt and soap lye are made modified emulsifying asphalt emulsion, add rubber latex, mineral filler, Mierocrystalline cellulose successively, stir and static froth breaking.
The present invention adopts the multiple synthesising macromolecule copolymer such as rubber latex, epoxy resin and the SiO such as the anion-modified emulsified bitumen of high-concentration super-fine microactuator suspension emulsion-type and polyolefins properties-correcting agent, neoprene latex or SBR emulsion
2, the inorganic powder such as wilkinite as raw material, use special producing technique to be mixed with and makes, after tested, low temperature-20 DEG C of not embrittlement after film forming, high temperature of 120 DEG C does not trickle, and elastic recovery rate is up to 90%, and Absorbable organic halogens stores more than 1 year.
Embodiment
Below by embodiment, the present invention is described in further detail.
Embodiment 1
60# water-proof material special asphalt is pumped into asphalt tank and is heated to 160 DEG C ~ 180 DEG C, drop into the APP of 3%, high-speed stirring 2 hours, then the epoxy resin E51 of 2% is added, stir through colloidal mill grinding after 30 minutes, the polymer-modified asphalt material prepared stirs 2 hours de-soaks, stand-by.In Soap liquid pot, pump into the hot water of 60 DEG C, drop into rosined soap class emulsifying agent 1%, the amount of AEO-9 is 0.02% and quadrol 0.6%, reconcile pH value to 11 with NaOH simultaneously, make soap lye.The polymer-modified asphalt prepared and soap lye are made through high-speed shearing machine the modified emulsifying asphalt emulsion that concentration is about 60% simultaneously, in this emulsion, add the polychloroprene latex of 25%, then successively 2% SiO
2, the wilkinite of 3% and the Mierocrystalline cellulose of 0.2%, to not stop lentamente to stir to be uniformly dispersed in reinforced process, after having fed intake, keep stirring 30 minutes, then stop stirring, add a small amount of defoamer and finished product barrelling after carrying out defoaming treatment for static 30 minutes.
Embodiment 2
70# heavy traffic paving asphalt is pumped into asphalt tank and be heated to 150 DEG C ~ 170 DEG C, drop into the APAO of 3%, high-speed stirring 2 hours, then the epoxy resin E44 of 2% is added, stir through colloidal mill grinding after 30 minutes, the polymer-modified asphalt material prepared stirs 2 hours de-soaks, stand-by.In Soap liquid pot, pump into the hot water of 60 DEG C, drop into rosined soap class emulsifying agent 1%, the amount of AEO-9 is 0.02% and quadrol 0.4%, reconcile pH value to 11 with NaOH simultaneously, make soap lye.The polymer-modified asphalt prepared and soap lye are made through high-speed shearing machine the modified emulsifying asphalt emulsion that concentration is about 60% simultaneously, in this emulsion, add polychloroprene latex and 10% styrene-butadiene latex of 15%, then successively 2% SiO
2, the wilkinite of 3% and the Mierocrystalline cellulose of 0.2%, to not stop lentamente to stir to be uniformly dispersed in reinforced process, after having fed intake, keep stirring 30 minutes, then stop stirring, add a small amount of defoamer and finished product barrelling after carrying out defoaming treatment for static 30 minutes.
The weight percent sum of each component of above-described embodiment is 100%.
By the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base of above-described embodiment gained, according to " Test methods for building waterproof coatings " GB/T16777-2008, it is tested.Its main performance testing results is:
The thick matter waterproof paint of table 1 modified-high polymer water-latex type asphaltic base
Claims (6)
1. the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base, is characterized in that: raw materials comprises:
Described petroleum pitch is 60# pitch or 70# pitch, and described polyolefins properties-correcting agent is amorphous propylene multipolymer, Atactic Polypropelene or styrene-butadiene-styrene block copolymer;
Described rosined soap class emulsifying agent is disproportionated rosin potassium soap or rosin sodium soap;
Described mineral filler is the SiO of 1-3%
2with the wilkinite of 1-3%.
2. the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base according to claim 1, is characterized in that: described rubber latex is one or both of neoprene latex and SBR emulsion.
3. the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base according to claim 1, it is characterized in that: described epoxy resin is epoxy resin E44 or epoxy resin E51, and described diamine crosslinking and curing agent is quadrol, propylene diamine, hexanediamine, Ursol D or 2 methyl pentamethylenediamine.
4. the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base according to claim 1, it is characterized in that: described stablizer is fatty alcohol-polyoxyethylene ether, polyoxypropyleneglycol or polytetrahydrofuran diol, described Mierocrystalline cellulose is Natvosol, carboxymethyl cellulose or Vltra tears.
5. the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base according to claim 1, is characterized in that: described PH conditioning agent is NaOH or KOH.
6. a preparation method for the thick matter waterproof paint of modified-high polymer water-latex type asphaltic base according to claim 1, is characterized in that:
(1) petroleum pitch pumped into asphalt tank and be heated to 150 DEG C ~ 180 DEG C, drop into polyolefins properties-correcting agent, high-speed stirring, then adds epoxy resin, with colloidal mill grinding after stirring, stirs and de-soak the polymer-modified asphalt prepared;
(2) water, rosined soap class emulsifying agent, diamine crosslinking and curing agent and stablizer Hybrid Heating to 60 DEG C, and with PH conditioning agent, pH value is adjusted to 10-12, makes soap lye;
(3) modified emulsifying asphalt emulsion made by the soap lye that polymer-modified asphalt step (1) prepared and step (2) prepare, and adds rubber latex, mineral filler, Mierocrystalline cellulose successively, stirs and static froth breaking.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310416370.9A CN103555204B (en) | 2013-09-12 | 2013-09-12 | Thick matter waterproof paint of modified-high polymer water-latex type asphaltic base and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310416370.9A CN103555204B (en) | 2013-09-12 | 2013-09-12 | Thick matter waterproof paint of modified-high polymer water-latex type asphaltic base and preparation method thereof |
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| CN103555204A CN103555204A (en) | 2014-02-05 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083506A (en) * | 1993-09-01 | 1994-03-09 | 王化岐 | Mastic neoprene water-proof paint and production technique |
| CN101117443A (en) * | 2006-08-04 | 2008-02-06 | 深圳市海川实业股份有限公司 | Modified asphalt material and preparation method thereof |
| CN102898947A (en) * | 2012-11-10 | 2013-01-30 | 广西金雨伞防水装饰有限公司 | Reaction bonding modified emulsified asphalt waterproof paint and preparation method thereof |
| CN102965017A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Saline-alkaline resistant spray fast-setting rubber asphalt waterproof material |
-
2013
- 2013-09-12 CN CN201310416370.9A patent/CN103555204B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083506A (en) * | 1993-09-01 | 1994-03-09 | 王化岐 | Mastic neoprene water-proof paint and production technique |
| CN101117443A (en) * | 2006-08-04 | 2008-02-06 | 深圳市海川实业股份有限公司 | Modified asphalt material and preparation method thereof |
| CN102898947A (en) * | 2012-11-10 | 2013-01-30 | 广西金雨伞防水装饰有限公司 | Reaction bonding modified emulsified asphalt waterproof paint and preparation method thereof |
| CN102965017A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Saline-alkaline resistant spray fast-setting rubber asphalt waterproof material |
Non-Patent Citations (1)
| Title |
|---|
| 环氧橡胶沥青及其混合料的性能研究;路彦等;《公路》;20111130(第11期);第160-163页 * |
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