CN103833282B - A kind of emulsified bitumen waterproof mortar and preparation method thereof - Google Patents

A kind of emulsified bitumen waterproof mortar and preparation method thereof Download PDF

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CN103833282B
CN103833282B CN201410071878.4A CN201410071878A CN103833282B CN 103833282 B CN103833282 B CN 103833282B CN 201410071878 A CN201410071878 A CN 201410071878A CN 103833282 B CN103833282 B CN 103833282B
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emulsified bitumen
component
waterproof mortar
amine
cement
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CN103833282A (en
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常英
刘金景
段文锋
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Guangdong Dongfang Yuhong Building Materials Co ltd
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Beijing Oriental Yuhong Waterproof Technology Co Ltd
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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of emulsified bitumen waterproof mortar, be made up of component A and B component, wherein component A comprises emulsified bitumen, is made up of the component of following content: pitch 50%-65%; Cationic emulsifier 3%-10%, nonionic emulsifying agent 3%-10%, stablizer 1%-5%, all the other are water; B component comprises cement, filler, auxiliary agent, and the content of each component is cement 40%-75%, filler 20%-55%, auxiliary agent 1%-5%.Emulsified bitumen waterproof mortar preparation provided by the invention is simple, the mineral acid of good waterproof performance, ability lower concentration, alkali and salt corrosion, can be used as auxiliary film waterproof material in kitchen and toilet and skin.

Description

A kind of emulsified bitumen waterproof mortar and preparation method thereof
Technical field
The present invention relates to a kind of emulsified bitumen based waterproof mortar, belong to waterproof chemistry Material Field.
Background technology
Owing to there is the various features such as cheap, easy to use, current sand-cement slurry is one of water-proof material the most frequently used in house decoration between toilet, kitchen etc., but sand-cement slurry exists not water-fast, need maintenance, easily there is problems of crack, especially sand-cement slurry is poor to acid-basicity tolerance, and life-time service easily occurs that corrosion makes it drop or loses water-repellancy.
In order to overcome the problems referred to above, this area was once attempted polymer emulsion, as mixed with sand-cement slurry in SBR emulsion, acrylic ester emulsion etc. with the performance of reinforced cement mortar, but polymer emulsion high cost, and popularization and use are subject to construction and decoration restraint of trade.For this reason, this area also attempts exploring utilizing pitch to improve the performance of sand-cement slurry in recent years, but finds that the consistency of common emulsified bituminous materials and cement is poor in long-term construction, causes the waterproof quality of product, application property is affected.
Summary of the invention
For the defect of prior art, the invention discloses a kind of emulsified bitumen waterproof mortar, coordinate with specific cement slurry by adopting the emulsified bitumen of special development, consistency is better, waterproof quality and application property good, for concrete wall surface, there is excellent binding property, self-healing, protected object is sealed completely, seamless; Acid-alkali-corrosive-resisting; Uvioresistant and biological degradation; Outstanding antistripping ability; The excellent specific property such as nontoxic, tasteless, pollution-free, and low price.
For achieving the above object, the present invention is achieved through the following technical solutions:
A kind of emulsified bitumen waterproof mortar, be made up of component A and B component, wherein component A comprises emulsified bitumen, is made up of the component of following weight content: pitch 50%-65%; Cationic emulsifier 3%-10%, nonionic emulsifying agent 3%-10%, stablizer 1%-5%, all the other are water; B component comprises cement, filler, auxiliary agent, and the content of each component is cement 40%-75%, filler 20%-55%, auxiliary agent 1%-5%.
Preferably, the weight percent of each component composition of emulsified bitumen is: pitch 58%-63%; Cationic emulsifier 3%-6%; Nonionic emulsifying agent 3%-6%; Stablizer 1%-3%, all the other are water.
Preferably, each composition weight percentage composition of B component is cement 45%-55%, filler 43%-53%, auxiliary agent 2%-3%.
In the present invention, described pitch selects one or more the mixture in white rock asphalt, petroleum pitch, coal-tar pitch, preferred heavy traffic paving asphalt, more preferably employing penetration degree is the heavy traffic paving asphalt of 60-100 (1/10mm).
In the present invention, in order to meet the requirement of asphalt waterproofing mortar to emulsified bitumen, HLB scope required for coupling asphalt emulsification, adopts cationic and the composite formation compound emulsifying agent of nonionic two kinds of emulsifying agents.Adopt compound emulsifying agent to be conducive to eliminating alone non-ionic emulsifier and easily produce the low problem of cloud point, also can avoid alone cationic emulsifier, the problem that pitch particle is thick.Use composite emulsifier can reduce profit relative density difference between the two and the difference of viscosity, strengthen the electromotive force of bitumen particle, be easy to form electrostatic double layer, increase the mutual repulsive force between particle, hinder the polymerization tendency of bitumen particle.
Wherein, described cationic emulsifier is selected from one or more the mixture in lauryl amine, tetradecylamine, hexadecylamine, docosyl amine, coconut oleyl amine, tallow amine, hydrogenated tallow amine, oleyl amine, soybean oleyl amine, 1-aminoethyl-2-heptadecyl imidazole quinoline-2 hydrochloride, lignin amine, dodecyl benzyl dimethyl ammonium chloride, dodecyldimethylamine ammonium chloride, cetalkonium chloride; Described nonionic emulsifying agent is selected from one or more the mixture in laurostearic acid single ethanol amide, lauryl diethanol amide, Coconut Fatty Acid Monoethanolamide, lauric acid amide of ethanol, polyoxyethylene sorbitan monolaurate, octadecanoic acid ester of polyethylene glycol, polyoxyethylene nonylphenol ether.
In the present invention, described stablizer is selected from one or more the mixture in inorganic salt, mineral acid, organic acid, tackifier.
Wherein, inorganic salt can be vitriol, nitrate, hydrochloride etc.; Mineral acid or organic acid can be lipid acid, acetic acid, hydrochloric acid, tartrate etc.; Tackifier can be polyvinyl alcohol, Mierocrystalline cellulose, inner complex etc.
In the present invention, described cement is selected from white cement and/or ash concrete; Described filler is selected from one or more the mixture in calcium carbonate, talcum powder, wollastonite powder, quartz sand; Described auxiliary agent is selected from one or more the mixture in water reducer, stablizer, thickening material.
Above-mentioned water reducer, thickening material are all this area customary adjuvant, and such as water reducer can be poly carboxylic acid series water reducer or naphthalene water reducer; Thickening material can be ether of cellulose etc.
Accordingly, the invention also discloses the preparation method of described emulsified bitumen waterproof mortar, comprise the steps:
The preparation method of component A:
1) by pitch dewatering, 130 DEG C-160 DEG C are then heated to;
2) water is heated to 45 DEG C-65 DEG C;
3) cationic emulsifier and nonionic emulsifying agent, stablizer are joined step 2) hot water in, stir, make aqueous emulsion, control temperature is 45 DEG C-65 DEG C;
4) in step 3) aqueous emulsion in pour step 1 into immediately) heated bitumen, namely obtain emulsified bitumen after stirring;
The preparation method of B component: cement, filler and auxiliary agent are stirred.
In above-mentioned preparation method, pitch dewatering can be adopted in any way, preferably adopts pitch at 110 DEG C-130 DEG C dehydration 1-2 hour.
In above-mentioned preparation method, step 4) usually adopt mulser to carry out, first aqueous emulsion is poured in mulser, pours step 1 into immediately) heated bitumen, namely obtain emulsified bitumen after stirring.
In above-mentioned preparation method, the preparation of B component is normally stirred in a mixing bowl high speed.
Two components mix by emulsified bitumen waterproof mortar of the present invention in use, and stirrer usually can be adopted under 30-100r/min to stir 2-10min.
Asphalt waterproofing mortar of the present invention, cheap, application property is excellent, mineral acid, alkali and the salt corrosion of good waterproof performance, ability lower concentration, there is good flexibility.Experiment display, emulsified bitumen waterproof mortar of the present invention at least meets following technical indicator:
Cohesive strength (28d) is not less than 1.2MPa, and impermeability pressure (28d) is not less than 1.5MPa, and ultimate compression strength (28d) is not less than 24MPa, and folding strength (28d) is not less than 8MPa
Embodiment
Embodiment 1
Emulsified bitumen starting material carry out proportioning (weight ratio, lower same) by following (table 1):
Table 1 emulsified bitumen formula table (100 parts of emulsified bitumens)
Emulsified bitumen manufacturing process is as follows:
(1) first dewatered 1 hour-2 hours at 110 DEG C-130 DEG C by pitch, then mild heat is to 130 DEG C-160 DEG C, for subsequent use after metering;
(2), by tap water heating to 45 DEG C-65 DEG C, for subsequent use after metering;
(3), by emulsifying agent, stablizer join in hot water for subsequent use, stir, make aqueous emulsion, control temperature is 45 DEG C-65 DEG C, for subsequent use;
(4), open mulser system, pour in emulsification by the aqueous emulsion meeting temperature requirement, pour the heated bitumen meeting temperature requirement immediately into, prepared by satisfactory emulsified bitumen.
B component carries out proportioning (weight ratio, lower same) by following (table 2):
Table 2 asphalt waterproofing mortar B component (100 parts of coating)
Cement Filler 1 Filler 2 Auxiliary agent
Ash concrete Calcium carbonate Quartz sand Water reducer
50 18 30 2
The manufacturing process of asphalt waterproofing mortar is as follows:
A group technique:
Emulsified bitumen is filtered and packaged.
B component technique:
Cement, filler and auxiliary agent are joined a mixing bowl high speed to stir, stir discharging packaging after 30 minutes.
Using method:
Stirrer stirs 10min under 50r/min.
Its performance is as follows after testing:
Cohesive strength (28d): 1.4MPa, impermeability pressure (28d): 1.7MPa, ultimate compression strength (28d): 26MPa,
Folding strength (28d): 8.3MPa
Embodiment 2
Emulsified bitumen starting material carry out proportioning (weight ratio, lower same) by following (table 3):
Table 3 emulsified bitumen formula table (100 parts of emulsified bitumens)
Emulsified bitumen manufacturing process is as embodiment 1
B component carries out proportioning (weight ratio, lower same) by following (table 4):
Table 4 asphalt waterproofing mortar B component (100 parts of coating)
Cement Filler 1 Filler 2 Auxiliary agent
Ash concrete Wollastonite Quartz sand Water reducer
50 18 30 2
Manufacturing process is as embodiment 1
Using method:
Stirrer stirs 5min under 70r/min.
Its performance is as follows after testing:
Cohesive strength (28d): 1.3MPa, impermeability pressure (28d): 1.65MPa, ultimate compression strength (28d): 25.4MPa, folding strength (28d): 8.2MPa
Embodiment 3
Emulsified bitumen starting material carry out proportioning (weight ratio, lower same) by following (table 5):
Table 5 emulsified bitumen formula table (100 parts of emulsified bitumens)
Emulsified bitumen manufacturing process is as embodiment 1
B component carries out proportioning (weight ratio, lower same) by following (table 6):
Table 6 asphalt waterproofing mortar B component (100 parts of coating)
Cement Filler 1 Filler 2 Auxiliary agent
Ash concrete Talcum powder Quartz sand Water reducer
50 15 33 2
The manufacturing process of asphalt waterproofing mortar is as embodiment 1
Using method:
Stirrer stirs 3min under 80r/min.
Its performance is as follows after testing:
Tensile strength: 1.35MPa, tension set: 293.77%, watertightness (0.3MPa, 30min): waterproof.
Embodiment 4
Emulsified bitumen starting material carry out proportioning (weight ratio, lower same) by following (table 7):
Table 7 emulsified bitumen formula table (100 parts of emulsified bitumens)
Emulsified bitumen manufacturing process is as embodiment 1
B component carries out proportioning (weight ratio, lower same) by following (table 8):
Table 8 asphalt waterproofing mortar B component (100 parts of coating)
Cement Filler 1 Filler 2 Auxiliary agent
Ash concrete Calcium carbonate Quartz sand Water reducer
45 23 30 2
The manufacturing process of asphalt waterproofing mortar is as embodiment 1
Using method:
Stirrer stirs 5min under 80r/min.
Its performance is as follows after testing:
Cohesive strength (28d): 1.24MPa, impermeability pressure (28d): 1.75MPa, ultimate compression strength (28d): 25.3MPa, folding strength (28d): 8.2Mpa.

Claims (8)

1. an emulsified bitumen waterproof mortar, it is characterized in that being made up of component A and B component, wherein component A is emulsified bitumen, is made up of the component of following weight content: pitch 58%-63%; Cationic emulsifier 3%-6%; Nonionic emulsifying agent 3%-6%; Stablizer 1%-3%, all the other are water; B component comprises cement, filler, auxiliary agent, and the content of each component is cement 45%-55%, filler 43%-53%, auxiliary agent 2%-3%.
2. emulsified bitumen waterproof mortar according to claim 1, is characterized in that described pitch is selected from one or more the mixture in rock asphalt, petroleum pitch, coal-tar pitch.
3. emulsified bitumen waterproof mortar according to claim 2, is characterized in that described pitch is selected from heavy traffic paving asphalt.
4. emulsified bitumen waterproof mortar according to claim 1, is characterized in that described cationic emulsifier is selected from one or more the mixture in lauryl amine, tetradecylamine, hexadecylamine, docosyl amine, coconut oleyl amine, tallow amine, hydrogenated tallow amine, oleyl amine, soybean oleyl amine, 1-aminoethyl-2-heptadecyl imidazole quinoline-2 hydrochloride, lignin amine, dodecyl benzyl dimethyl ammonium chloride, dodecyldimethylamine ammonium chloride, cetalkonium chloride; Described nonionic emulsifying agent is selected from one or more the mixture in laurostearic acid single ethanol amide, lauryl diethanol amide, Coconut Fatty Acid Monoethanolamide, lauric acid amide of ethanol, polyoxyethylene sorbitan monolaurate, octadecanoic acid ester of polyethylene glycol, polyoxyethylene nonylphenol ether.
5. emulsified bitumen waterproof mortar according to claim 1, is characterized in that described stablizer is selected from one or more the mixture in inorganic salt, mineral acid, organic acid, tackifier.
6. emulsified bitumen waterproof mortar according to claim 1, is characterized in that described cement is selected from white cement and/or ash concrete.
7. emulsified bitumen waterproof mortar according to claim 1, is characterized in that described filler is selected from one or more the mixture in calcium carbonate, talcum powder, wollastonite powder, quartz sand.
8. emulsified bitumen waterproof mortar according to claim 1, is characterized in that described auxiliary agent is selected from one or more the mixture in water reducer, stablizer, thickening material.
CN201410071878.4A 2014-02-28 2014-02-28 A kind of emulsified bitumen waterproof mortar and preparation method thereof Active CN103833282B (en)

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Cited By (1)

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WO2020238944A1 (en) * 2019-05-27 2020-12-03 山西中润路科科技股份有限公司 Color landscape pavement maintenance material and preparation method thereof

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CN104151844B (en) * 2014-08-06 2016-10-05 中南大学 A kind of cationic emulsified modified asphalt and the application in plate-type ballastless track
CN104496349A (en) * 2014-12-03 2015-04-08 王新荣 Waterproof concrete
CN109400025B (en) * 2018-11-14 2021-06-15 益阳金宙建材科技有限公司 Building exterior wall waterproof mortar and preparation method thereof
CN112708042B (en) * 2019-11-25 2021-11-19 科之杰新材料集团有限公司 Shrinkage-reducing polycarboxylate superplasticizer and preparation method thereof
CN110894153A (en) * 2019-12-04 2020-03-20 北京建筑大学 Waterproof mortar and preparation method thereof
CN115594454B (en) * 2022-11-10 2023-05-02 通辽市公路养护中心 Environment-friendly emulsified asphalt mortar for repairing cracks
CN116639947B (en) * 2023-05-29 2024-02-23 科顺民用建材有限公司 Wear-resistant rigid waterproof mortar composition, waterproof mortar, and preparation method and application thereof

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Effective date of registration: 20210416

Address after: 101309 Shunyi District Shunping road section of Beijing City Area No. 2

Patentee after: BEIJING ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co.,Ltd.

Patentee after: Nantong Dongfang Yuhong building materials Co.,Ltd.

Address before: 101309 Shunyi District Shunping road section of Beijing City Area No. 2

Patentee before: BEIJING ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co.,Ltd.

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Address before: 101309 Sha Ling section 2, Shunping Road, Shunyi District, Beijing

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Patentee before: Nantong Dongfang Yuhong building materials Co.,Ltd.

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