CN102304289B - Road asphalt prepared by adding plant asphalt to petroleum asphalt and production method thereof - Google Patents
Road asphalt prepared by adding plant asphalt to petroleum asphalt and production method thereof Download PDFInfo
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- CN102304289B CN102304289B CN 201110289149 CN201110289149A CN102304289B CN 102304289 B CN102304289 B CN 102304289B CN 201110289149 CN201110289149 CN 201110289149 CN 201110289149 A CN201110289149 A CN 201110289149A CN 102304289 B CN102304289 B CN 102304289B
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- asphalt
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- plant asphalt
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- 239000010426 asphalt Substances 0.000 title claims abstract description 85
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000003208 petroleum Substances 0.000 title abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 6
- 229920002472 Starch Polymers 0.000 claims abstract description 6
- 239000001913 cellulose Substances 0.000 claims abstract description 6
- 229920002678 cellulose Polymers 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- 235000019698 starch Nutrition 0.000 claims abstract description 6
- 239000008107 starch Substances 0.000 claims abstract description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000011301 petroleum pitch Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 6
- 230000008719 thickening Effects 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000010008 shearing Methods 0.000 claims description 3
- 239000011384 asphalt concrete Substances 0.000 abstract description 3
- 238000004891 communication Methods 0.000 abstract description 2
- 238000013461 design Methods 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 20
- 239000011295 pitch Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 7
- 239000010902 straw Substances 0.000 description 7
- 239000002699 waste material Substances 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 4
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 4
- 235000009973 maize Nutrition 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004567 concrete Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
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- 239000006227 byproduct Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
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- 239000010779 crude oil Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010034719 Personality change Diseases 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
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- 235000019219 chocolate Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
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- 239000004035 construction material Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012407 engineering method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008521 reorganization Effects 0.000 description 1
- 239000011387 rubberized asphalt concrete Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
The invention relates to a road asphalt prepared by adding plant asphalt to petroleum asphalt and a production method thereof, belonging to the field of communications and transportation. The road asphalt is prepared from the following raw materials in parts by weight: 100 parts of petroleum asphalt, 20-100 parts of plant asphalt, cellulose or starch, and rosin, wherein the ratio of cellulose or starch to plant asphalt is 0.01-0.1, and the ratio of rosin to plant asphalt is 0.01-0.03. The plant asphalt and petroleum asphalt (or rubber asphalt, rubber modified asphalt) have favorable compatibility under the actions of the stabilizer and tackifier, thereby improving the service performance of the asphalt and asphalt mixture; and thus, the invention provides a new way and new method for substituting for part of petroleum asphalt. The road asphalt provided by the invention has high viscosity and high softening point; and the on the premise of good mix design, the asphalt mixture has certain high-temperature stability, and can enhance the rutting deformation resistance of an asphalt concrete pavement with high temperature and heavy-load traffic.
Description
Technical field
The invention belongs to traffic and transport field, relate to a kind of improvement of road construction material.
Background technology
" communications and transportation " the 12 " development program " of Department of Transportation's issue, China plans 12 ends, the motorway total kilometrage reaches 10.8 ten thousand kilometers, covers 200,000 above urban population cities more than 90%, and China's population will all couple together with motorway above 200,000 city.Secondary and above highway mileage reach 650,000 kilometers, and state's provincial highway general technical situation reaches the level such as good, and the rural highway total kilometrage reaches 3,900,000 kilometers.And the year ends 2010, China's motorway mileage open to traffic has reached 7.4 ten thousand kilometers, 450,000 kilometers on the above highway of secondary.On the other hand, in recent years, along with building up of high-grade highway net, the volume of traffic has had larger increase, because developing rapidly of road construction, passenger-cargo freight volume that transport by road is finished and passenger-cargo volume of the circular flow proportion increase substantially, and have promoted the rapid growth of Chinese national economy.A lot of built highways are because heavy traffic, road conditions are destroyed more serious, overhaul and reorganization and expansion phase have been entered, in the near future, to changing of existing highway, expansion project can get more and more, secondly consequent heavy duty, overloading is on the rise, the large percentage of traction engine during particularly the traffic of the trunk lines of national expressways of some outbalances forms, and overloading is very serious, along with the volume of traffic increases and heavy duty, the increase road surface early damage of overloaded vehicle is serious, cause the thickness of domestic bituminous pavement constantly to increase, asphalt content continues to increase, the road surface cost constantly rises, and along with the long-term run at high level of International Petroleum Price, causes domestic asphalt price higher.China is the poor countries of petroleum resources, and now petrochemical industry can be the further cracking of most of pitch fuel oil and other technical oilss, fat, so in the long term, the pitch resource will be shorter, most pitch dependence on import.
At present, the plant asphalt in market mostly is the waste after the vegetables oil refining, accounts for about 3～5% of vegetables oil massfraction.Its main component is 60～80% lipid acid and pohytol, oil soluble and pitch approach, mainly for the production of casting binder, Rubber Softener, concrete prefabricated separant, black printing printing ink, bituminous composition, coating, surface activity carbon, leather agent and low-volatility fuel etc.
Also having a kind of plant asphalt is to utilize starchiness material or maize straw, wheat straw etc. to refine remaining waste behind the materials such as xylogen, vegetable-protein, these wastes are mostly thrown away at present, having wasted ample resources, namely is plant asphalt but become macromolecular cpd material afterwards through simple process.
Summary of the invention
The objective of the invention is: provide a kind of plant asphalt that utilizes to be added into petroleum pitch as road asphalt and production method, it utilizes the byproduct of straw processing is plant asphalt, replaces part petroleum pitch, is used for building of highway.
Road asphalt of the present invention is:
Petroleum pitch: 100
Plant asphalt: 20～100
Mierocrystalline cellulose or starch (stablizer): 0.01～0.1 of plant asphalt umber
Rosin (thickening material): 0.01～0.03 of plant asphalt umber
Above-mentioned raw materials is weight ratio.
Wherein petroleum pitch also comprises rubber asphalt or the rubber modified asphalt that road is used.
If petroleum pitch replaces with rubber asphalt or rubber modified asphalt, the additive that needs to add is that sulphur is 0.005～0.01 of rubber asphalt or rubber modified asphalt umber.
Plant asphalt is to utilize starchiness material or maize straw, wheat straw etc. to refine remaining waste behind the materials such as xylogen, vegetable-protein, through being processed into the material after the macromolecular cpd.
Petroleum pitch is a kind of byproduct of Crude Oil Processing, liquid, semisolid or the solid of the thickness of black or chocolate at normal temperatures, mainly contain the hydro carbons and the non-hydrocarbons derivative that dissolve in trieline, its character changes with the different of production method with forming with the crude oil source.
Rubber asphalt is with the dispersion agent of pitch as rubber powder, with rubber powder and petroleum pitch miscible a kind of modifying asphalt of making under hot conditions of high dosage.Claim again asphalt rubber.
Rubber modified asphalt refers to rubber powder and matrix petroleum pitch, added SBS, PE or other additives, at batch production finished product asphaltum that produce, that have higher storage stability.SBS, PE or other additives are 1%～2% (weight ratio) of rubber powder.
Production method of the present invention is:
A. with plant asphalt and petroleum pitch (or rubber asphalt, rubber modified asphalt) heating, temperature is at 140 ℃～190 ℃;
The plant asphalt that b. will heat and petroleum pitch (or rubber asphalt, rubber modified asphalt) are by weight proportion, pump into respectively in the tank with high-speed shearing equipment, and the adding stablizer stirs 10-20min, add thickening material again and additive stirs 5-10min, the mixture that mixes that obtains is finished product.Should continue when depositing to stir for, the finished product temperature is not less than 140 ℃, the finished product that mixes pumps into asphalt tank for the Asphalt concrete mixing machine.
The invention has the beneficial effects as follows: adopt plant asphalt and petroleum pitch (or rubber asphalt, rubber modified asphalt) under the effect of stablizer and tackifier, make it have preferably intermiscibility, improving the use properties of pitch and asphalt, is a new approach and the new method of Substitute For Partial petroleum pitch.
The pitch that present technique is produced has high viscosity, high softening-point, and under the prerequisite of carrying out good mix-design, asphalt has certain high-temperature stability, can improve the ability of the anti-rutting deformation of bituminous concrete pavement high temperature and Heavy Traffic.Improved the anti-low-temperature cracking ability under cold district and the heavy load; Make that pitch is anti-aging, antioxidant property improves, have the ability of higher fatigue resistance and opposing reflection crack, be conducive to prolongs life; take full advantage of renewable resources and substitute day by day exhausted petroleum pitch; have good energy-conserving and environment-protective performance, protection of the environment has realized utilization of waste material.
Compare the refinement of vegetable oil residue, the renewable pitch of bioid engineering method refining has possessed the requirement that large-scale industrialization is produced, measuring and calculating according to pertinent data, useful C5, the C6 sugar of maize straw accounts for greatly about 60% of its quality proportion, can directly refine into alcohol fuel or the polyvalent alcohol of high added value, remaining 30% part can directly be refined into plant asphalt, is equivalent to 18% of maize straw per ton and can refines into plant asphalt.
Utilize plant asphalt petroleum replacing pitch, the comprehensive utilization refuse, can not only improve the pavement performance of bituminous pavement, prolonging service life of pavement, reduce the road construction cost, and play and administer the effect of polluting, economize on resources, fully utilize a large amount of junks, meet national environmental protection policy and the requirement of developing a circular economy, building a conservation-minded society, implement especially the concrete practice of the strategy of sustainable development and implement scientific view of development.Have obvious economic and social benefit, therefore apply this investigative technique tool and be of great significance.
Embodiment 1
(1) with plant asphalt and petroleum pitch heating, temperature is at 160～170 ℃;
The plant asphalt that (2) will heat and petroleum pitch pump into respectively in the tank with high-speed shearing equipment in 3: 7 ratios, and add the stablizer of 3% (weight ratio) of plant asphalt, stir 10-20min.
(3) 1% (weight ratio) thickening material that adds again plant asphalt stirs 5-10min, and the mixture that mixes that obtains is finished product.
Should continue when depositing to stir for, the finished product temperature is not less than 140 ℃, the finished product that mixes pumps into asphalt tank for the Asphalt concrete mixing machine.
Embodiment 2
Petroleum pitch is become rubber asphalt, add 0.9% sulphur of rubber asphalt weight again, other is identical with embodiment 1.
Embodiment 3
Petroleum pitch is become rubber modified asphalt, add 0.6% sulphur of rubber asphalt weight again, other is identical with embodiment 1.
Claims (2)
1. one kind is added into the road asphalt of petroleum pitch with plant asphalt, and wherein said road asphalt is:
Petroleum pitch:
100
Plant asphalt:
20～100
Stablizer Mierocrystalline cellulose or starch: the plant asphalt umber
0.01～0.1
Thickening material rosin: the plant asphalt umber
0.01～0.03
Above-mentioned raw materials is weight ratio.
2. the production method of a road asphalt, its method is:
Rubber modified asphalt:
100
Plant asphalt:
20～100
Stablizer Mierocrystalline cellulose or starch: the plant asphalt umber
0.01～0.1
Thickening material rosin: the plant asphalt umber
0.01～0.03
Above-mentioned raw materials is weight ratio;
A. with plant asphalt and rubber modified asphalt heating, temperature is at 140 ℃～190 ℃;
The plant asphalt that b. will heat and rubber modified asphalt are by weight proportion, pump into respectively in the tank with high-speed shearing equipment, and add the stablizer Mierocrystalline cellulose or starch stirs 10-20min, add again thickening material rosin and additive sulphur stirs 5-10min, the mixture that mixes that obtains is finished product, and described additive sulphur is the rubber modified asphalt umber
0.005～0.01
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110289149 CN102304289B (en) | 2011-09-27 | 2011-09-27 | Road asphalt prepared by adding plant asphalt to petroleum asphalt and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110289149 CN102304289B (en) | 2011-09-27 | 2011-09-27 | Road asphalt prepared by adding plant asphalt to petroleum asphalt and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102304289A CN102304289A (en) | 2012-01-04 |
| CN102304289B true CN102304289B (en) | 2013-03-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110289149 Expired - Fee Related CN102304289B (en) | 2011-09-27 | 2011-09-27 | Road asphalt prepared by adding plant asphalt to petroleum asphalt and production method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104441290A (en) * | 2014-11-13 | 2015-03-25 | 交通运输部公路科学研究所 | Mixing method for modified biological asphalt mixture |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660124A (en) * | 2012-05-07 | 2012-09-12 | 哈尔滨工业大学 | Bio-asphalt material for road and preparation method for bio-asphalt material |
| CN102703103B (en) * | 2012-06-20 | 2014-01-29 | 东华大学 | A kind of method that uses plant raw material to prepare environment-friendly waterproof plant asphalt |
| CN102718439B (en) * | 2012-06-20 | 2014-09-24 | 上海睿志贸易有限公司 | Method for road engineering by mixing plant asphalt and petroleum asphalt |
| CN102766340A (en) * | 2012-08-13 | 2012-11-07 | 交通运输部公路科学研究所 | Modified biological asphalt material, biological asphalt mixture, preparation method thereof and applications |
| EP2883914B1 (en) * | 2012-08-13 | 2019-07-10 | Research Institute of Highway Ministry of Transport | Biological asphalt and preparation method thereof |
| CN104109397B (en) * | 2013-04-19 | 2017-08-11 | 厦门大学 | A kind of preparation of fiber composite powder and the novel technique that component is added as modified pitch |
| CN103483836B (en) * | 2013-09-24 | 2015-07-15 | 交通运输部公路科学研究所 | Modified asphalt and preparation method thereof as well as mixture containing same |
| CN103664061B (en) * | 2013-11-15 | 2016-01-20 | 交通运输部公路科学研究所 | A kind of rollable asphalt, Preparation Method And The Use |
| CN103628388B (en) * | 2013-12-06 | 2015-10-28 | 东华大学 | A kind of equipment and method preparing the matrix pitch of building the road |
| CN104629392A (en) * | 2015-03-06 | 2015-05-20 | 西安公路研究院 | Environment-friendly type high-permeability emulsified asphalt based on plant asphalt |
| CN112126406A (en) * | 2020-09-30 | 2020-12-25 | 邵阳市建国防水材料厂 | Two-component non-curing waterproof sealant and preparation method thereof |
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| CN101205382A (en) * | 2006-12-21 | 2008-06-25 | 上海群康沥青科技有限公司 | Rubber asphalt composition |
| CN101765641A (en) * | 2007-07-26 | 2010-06-30 | 阿克佐诺贝尔股份有限公司 | adhesion and cohesion modifiers for asphalt |
-
2011
- 2011-09-27 CN CN 201110289149 patent/CN102304289B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205382A (en) * | 2006-12-21 | 2008-06-25 | 上海群康沥青科技有限公司 | Rubber asphalt composition |
| CN101765641A (en) * | 2007-07-26 | 2010-06-30 | 阿克佐诺贝尔股份有限公司 | adhesion and cohesion modifiers for asphalt |
Non-Patent Citations (2)
| Title |
|---|
| 中国表面活性剂网.http://www.surfactant.com.cn/news/show-8442.html.《植物炼制沥青具有广阔的发展前景》.2010,第1-2页. * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104441290A (en) * | 2014-11-13 | 2015-03-25 | 交通运输部公路科学研究所 | Mixing method for modified biological asphalt mixture |
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| CN102304289A (en) | 2012-01-04 |
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