CN103484913B - 铝合金硬质阳极氧化处理工艺 - Google Patents
铝合金硬质阳极氧化处理工艺 Download PDFInfo
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- CN103484913B CN103484913B CN201310421043.2A CN201310421043A CN103484913B CN 103484913 B CN103484913 B CN 103484913B CN 201310421043 A CN201310421043 A CN 201310421043A CN 103484913 B CN103484913 B CN 103484913B
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- hard
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- aluminum alloy
- alkaline etching
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- 238000000034 method Methods 0.000 title claims abstract description 53
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 42
- 230000003647 oxidation Effects 0.000 title claims abstract description 35
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 35
- 239000003792 electrolyte Substances 0.000 claims abstract description 41
- 238000007743 anodising Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 21
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000001117 sulphuric acid Substances 0.000 claims abstract description 17
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 17
- 238000005406 washing Methods 0.000 claims abstract description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 48
- 238000005530 etching Methods 0.000 claims description 32
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 18
- 235000006408 oxalic acid Nutrition 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000005238 degreasing Methods 0.000 claims description 15
- 239000012153 distilled water Substances 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 12
- 239000004310 lactic acid Substances 0.000 claims description 9
- 235000014655 lactic acid Nutrition 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000005237 degreasing agent Methods 0.000 claims description 4
- 239000013527 degreasing agent Substances 0.000 claims description 4
- 230000005611 electricity Effects 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 8
- 230000007797 corrosion Effects 0.000 abstract description 8
- 239000007769 metal material Substances 0.000 abstract description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 5
- 239000011975 tartaric acid Substances 0.000 description 5
- 235000002906 tartaric acid Nutrition 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 4
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 238000000151 deposition Methods 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000002679 ablation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 241000270728 Alligator Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- -1 aluminum ions Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
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- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Photoreceptors In Electrophotography (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
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CN103484913A CN103484913A (zh) | 2014-01-01 |
CN103484913B true CN103484913B (zh) | 2016-08-17 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3079240A1 (fr) * | 2018-03-23 | 2019-09-27 | Dassault Aviation | Procede d'anodisation de piece metallique ou alliage |
Families Citing this family (23)
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CN103899747B (zh) * | 2014-03-26 | 2016-04-13 | 永康市嘉宏工具制造有限公司 | 一种往复式冲击气缸制造工艺 |
CN105506705A (zh) * | 2015-12-31 | 2016-04-20 | 江苏大学 | 一种铝合金硬质阳极氧化膜的制备方法 |
CN105755517B (zh) * | 2016-05-06 | 2017-11-10 | 陕西天元智能再制造股份有限公司 | 一种石油行业用铝基工件表面的耐磨耐腐处理方法 |
CN105839161B (zh) * | 2016-05-10 | 2017-10-27 | 广东长盈精密技术有限公司 | 金属件的染色方法 |
CN105937045A (zh) * | 2016-06-17 | 2016-09-14 | 霍山县龙鑫金属制品有限公司 | 一种压铸铝合金的表面处理方法 |
CN106757261B (zh) * | 2016-11-29 | 2018-11-09 | 中南大学 | 一种铝材表面氧化陶瓷膜和沸石膜复合的耐磨耐蚀涂层及其制备方法 |
CN106400082A (zh) * | 2016-12-14 | 2017-02-15 | 玉林师范学院 | 一种表面具有高硬度阳极氧化膜的铝合金的制备工艺 |
CN108221023A (zh) * | 2016-12-22 | 2018-06-29 | 无锡金科涂装有限公司 | 铝合金阳极氧化工艺 |
CN107164794B (zh) * | 2017-06-14 | 2023-07-04 | 江苏昊科汽车空调有限公司 | 用于空调压缩机铝合金件的硬质阳极氧化电解液添加剂 |
CN107740160A (zh) * | 2017-11-03 | 2018-02-27 | 安徽新合富力科技有限公司 | 一种压铸铝合金阳极氧化方法 |
JP6612373B2 (ja) * | 2018-02-02 | 2019-11-27 | 本田技研工業株式会社 | 陽極酸化皮膜形成処理剤及び陽極酸化皮膜形成方法 |
CN108950639A (zh) * | 2018-07-03 | 2018-12-07 | 南京金城三国机械电子有限公司 | 一种冷挤压成型铝合金零件的硬质阳极化处理工艺 |
CN109161949A (zh) * | 2018-08-02 | 2019-01-08 | 无锡金科涂装有限公司 | 一种压铸铝合金的硬质阳极氧化工艺 |
CN109023471B (zh) * | 2018-10-09 | 2020-08-21 | 长春工业大学 | 一种铝合金及其制备方法 |
CN109633075A (zh) * | 2018-11-16 | 2019-04-16 | 中国航发西安动力控制科技有限公司 | 纯草酸阳极氧化槽液的分析及调控方法 |
CN109267134B (zh) * | 2018-11-28 | 2020-12-01 | 中国航发长春控制科技有限公司 | 一种铸造铝合金高硬度硬质阳极氧化工艺方法 |
CN110438543A (zh) * | 2019-06-28 | 2019-11-12 | 绍兴市上虞和盛纺器有限公司 | 一种纺织筒管铝阳极硬质氧化表面处理方法及产品 |
CN113755923A (zh) * | 2020-09-18 | 2021-12-07 | 英迪那米(徐州)半导体科技有限公司 | 一种铝合金硬质阳极氧化电解液以及制备方法 |
CN112376101A (zh) * | 2020-10-28 | 2021-02-19 | 天长市京发铝业有限公司 | 一种铝板阳极氧化液 |
CN114351209A (zh) * | 2021-12-10 | 2022-04-15 | 辽沈工业集团有限公司 | 一种铝合金常温、低电压硬质阳极氧化工艺方法 |
CN114481255A (zh) * | 2022-01-17 | 2022-05-13 | 北京富创精密半导体有限公司 | 一种纯铝喷砂表面的硬质阳极氧化工艺 |
CN114808075A (zh) * | 2022-05-27 | 2022-07-29 | 重庆臻宝实业有限公司 | 一种制备耐离子体腐蚀、低溢气量的阳极膜层的方法 |
CN115094495B (zh) * | 2022-07-26 | 2023-10-03 | 重庆臻宝科技股份有限公司 | 一种cvd腔室工件的微弧氧化再生制备方法 |
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US3945895A (en) * | 1974-12-05 | 1976-03-23 | Fujisash Industries, Ltd. | Method of producing colored anodic coating on aluminum and its alloys |
CN101575725A (zh) * | 2009-05-26 | 2009-11-11 | 嘉兴中科亚美合金技术有限责任公司 | 用于高硅铝合金硬质阳极氧化的添加剂、溶液和工艺 |
CN102312264A (zh) * | 2011-08-22 | 2012-01-11 | 吴江市精工铝字制造厂 | 铝及铝合金的装饰性氧化法 |
CN102477573A (zh) * | 2010-11-23 | 2012-05-30 | 张家港市华杨金属制品有限公司 | 铝制品阳极氧化的表面处理工艺 |
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US3945895A (en) * | 1974-12-05 | 1976-03-23 | Fujisash Industries, Ltd. | Method of producing colored anodic coating on aluminum and its alloys |
CN101575725A (zh) * | 2009-05-26 | 2009-11-11 | 嘉兴中科亚美合金技术有限责任公司 | 用于高硅铝合金硬质阳极氧化的添加剂、溶液和工艺 |
CN102477573A (zh) * | 2010-11-23 | 2012-05-30 | 张家港市华杨金属制品有限公司 | 铝制品阳极氧化的表面处理工艺 |
CN102312264A (zh) * | 2011-08-22 | 2012-01-11 | 吴江市精工铝字制造厂 | 铝及铝合金的装饰性氧化法 |
Non-Patent Citations (3)
Title |
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2A12 铝合金常温脉冲硬质阳极氧化电解液配方优化;莫伟言 等;《电镀与涂饰》;20100930;第29卷(第9期);第30-32页 * |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3079240A1 (fr) * | 2018-03-23 | 2019-09-27 | Dassault Aviation | Procede d'anodisation de piece metallique ou alliage |
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Effective date of registration: 20170420 Address after: 528000 Foshan, Sanshui District, Leping City, the town of Qi Li Road, south of No. 19, No. Patentee after: FOSHAN GUANGYA METAL & RUBBER PRODUCT CO.,LTD. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170420 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 266000 Shandong province Qingdao city Licang District Road No. 1020 Laoshan two unit 302 Patentee before: Li Shulan |
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