CN103474243A - 基于硫化镍纳米片的染料敏化太阳能电池对电极制备方法 - Google Patents
基于硫化镍纳米片的染料敏化太阳能电池对电极制备方法 Download PDFInfo
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- CN103474243A CN103474243A CN2013104519978A CN201310451997A CN103474243A CN 103474243 A CN103474243 A CN 103474243A CN 2013104519978 A CN2013104519978 A CN 2013104519978A CN 201310451997 A CN201310451997 A CN 201310451997A CN 103474243 A CN103474243 A CN 103474243A
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- nickel
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- xanthic acid
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- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002135 nanosheet Substances 0.000 title abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 17
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims description 24
- 239000005357 flat glass Substances 0.000 claims description 6
- 238000000137 annealing Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 4
- FHLLXKWLZMOECC-UHFFFAOYSA-N ethoxymethanedithioic acid;nickel Chemical compound [Ni].CCOC(S)=S FHLLXKWLZMOECC-UHFFFAOYSA-N 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 4
- UWNXTLKLPYIBSO-UHFFFAOYSA-L nickel(2+);propan-2-yloxymethanedithioate Chemical compound [Ni+2].CC(C)OC([S-])=S.CC(C)OC([S-])=S UWNXTLKLPYIBSO-UHFFFAOYSA-L 0.000 claims description 4
- 239000002985 plastic film Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 206010070834 Sensitisation Diseases 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000008313 sensitization Effects 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- CONMNFZLRNYHIQ-UHFFFAOYSA-N 3-methylbutoxymethanedithioic acid Chemical compound CC(C)CCOC(S)=S CONMNFZLRNYHIQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 2
- 239000007784 solid electrolyte Substances 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 239000011521 glass Substances 0.000 abstract description 14
- 239000000463 material Substances 0.000 abstract description 9
- 230000008569 process Effects 0.000 abstract description 8
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000002243 precursor Substances 0.000 abstract description 4
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 abstract 2
- 239000012991 xanthate Substances 0.000 abstract 2
- 239000008151 electrolyte solution Substances 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 21
- 229910052697 platinum Inorganic materials 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 238000003491 array Methods 0.000 description 9
- 239000000975 dye Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- 238000011031 large-scale manufacturing process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- -1 carbon nano tube compound Chemical class 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- JCBJVAJGLKENNC-UHFFFAOYSA-M potassium ethyl xanthate Chemical compound [K+].CCOC([S-])=S JCBJVAJGLKENNC-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- RZFBEFUNINJXRQ-UHFFFAOYSA-M sodium ethyl xanthate Chemical compound [Na+].CCOC([S-])=S RZFBEFUNINJXRQ-UHFFFAOYSA-M 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
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- Hybrid Cells (AREA)
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CN201310451997.8A CN103474243B (zh) | 2013-09-27 | 2013-09-27 | 基于硫化镍纳米片的染料敏化太阳能电池对电极制备方法 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103938188A (zh) * | 2014-04-30 | 2014-07-23 | 齐鲁工业大学 | 一种硫化镍薄膜的简单高效制备方法 |
CN103938189A (zh) * | 2014-04-30 | 2014-07-23 | 齐鲁工业大学 | 一种快速高效制备硫化铜纳米薄膜的方法 |
CN104157456A (zh) * | 2014-07-23 | 2014-11-19 | 河南大学 | 一种用于柔性染料敏化太阳能电池的高催化活性硫化物杂化对电极及其制备方法 |
CN104616900A (zh) * | 2015-01-23 | 2015-05-13 | 三峡大学 | 一种钴镍双金属硫化物,制备方法及其应用 |
CN105355437A (zh) * | 2015-11-21 | 2016-02-24 | 河南师范大学 | 一种柔性敏化太阳能电池对电极的制备方法 |
CN107230551A (zh) * | 2017-05-26 | 2017-10-03 | 桂林理工大学 | 一种TiO2/GQDs/NiS异质结光阳极及其制备方法 |
CN107376945A (zh) * | 2017-07-24 | 2017-11-24 | 吉林大学 | 一种铁基催化剂、制备方法及其在高效电催化水裂解方面的应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102237200A (zh) * | 2011-03-04 | 2011-11-09 | 中国科学院物理研究所 | 用于敏化太阳能电池的金属硫化物对电极及其制备方法 |
CN103117173A (zh) * | 2013-03-11 | 2013-05-22 | 武汉大学 | 可双面进光的量子点敏化太阳能电池及其制备方法 |
-
2013
- 2013-09-27 CN CN201310451997.8A patent/CN103474243B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102237200A (zh) * | 2011-03-04 | 2011-11-09 | 中国科学院物理研究所 | 用于敏化太阳能电池的金属硫化物对电极及其制备方法 |
CN103117173A (zh) * | 2013-03-11 | 2013-05-22 | 武汉大学 | 可双面进光的量子点敏化太阳能电池及其制备方法 |
Non-Patent Citations (2)
Title |
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NAVEED ALAM ET AL: "Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide", 《CHEMISTRY OF MATERIALS》, vol. 20, no. 19, 18 September 2008 (2008-09-18) * |
WEI ZHAO ET AL: "Novel two-step synthesis of NiS nanoplatelet arrays as efficient counter electrodes for dye-sensitized solar cells", 《JOURNAL OF POWER SOURCES》, vol. 242, no. 35, 21 May 2013 (2013-05-21) * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103938188A (zh) * | 2014-04-30 | 2014-07-23 | 齐鲁工业大学 | 一种硫化镍薄膜的简单高效制备方法 |
CN103938189A (zh) * | 2014-04-30 | 2014-07-23 | 齐鲁工业大学 | 一种快速高效制备硫化铜纳米薄膜的方法 |
CN104157456A (zh) * | 2014-07-23 | 2014-11-19 | 河南大学 | 一种用于柔性染料敏化太阳能电池的高催化活性硫化物杂化对电极及其制备方法 |
CN104157456B (zh) * | 2014-07-23 | 2017-02-08 | 河南大学 | 一种用于柔性染料敏化太阳能电池的高催化活性硫化物杂化对电极及其制备方法 |
CN104616900A (zh) * | 2015-01-23 | 2015-05-13 | 三峡大学 | 一种钴镍双金属硫化物,制备方法及其应用 |
CN104616900B (zh) * | 2015-01-23 | 2017-11-10 | 三峡大学 | 一种钴镍双金属硫化物,制备方法及其应用 |
CN105355437A (zh) * | 2015-11-21 | 2016-02-24 | 河南师范大学 | 一种柔性敏化太阳能电池对电极的制备方法 |
CN105355437B (zh) * | 2015-11-21 | 2018-01-23 | 河南师范大学 | 一种柔性敏化太阳能电池对电极的制备方法 |
CN107230551A (zh) * | 2017-05-26 | 2017-10-03 | 桂林理工大学 | 一种TiO2/GQDs/NiS异质结光阳极及其制备方法 |
CN107230551B (zh) * | 2017-05-26 | 2019-10-11 | 桂林理工大学 | 一种TiO2/GQDs/NiS异质结光阳极及其制备方法 |
CN107376945A (zh) * | 2017-07-24 | 2017-11-24 | 吉林大学 | 一种铁基催化剂、制备方法及其在高效电催化水裂解方面的应用 |
CN107376945B (zh) * | 2017-07-24 | 2019-10-11 | 吉林大学 | 一种铁基催化剂、制备方法及其在高效电催化水裂解方面的应用 |
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