CN103415563B - 含有无机盐的激光透明聚酯 - Google Patents
含有无机盐的激光透明聚酯 Download PDFInfo
- Publication number
- CN103415563B CN103415563B CN201280012442.7A CN201280012442A CN103415563B CN 103415563 B CN103415563 B CN 103415563B CN 201280012442 A CN201280012442 A CN 201280012442A CN 103415563 B CN103415563 B CN 103415563B
- Authority
- CN
- China
- Prior art keywords
- laser
- weight
- acid
- moulded product
- welding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 37
- 229910017053 inorganic salt Inorganic materials 0.000 title description 4
- 239000000203 mixture Substances 0.000 claims abstract description 47
- -1 basic metal oxo aluminate Chemical class 0.000 claims abstract description 38
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 13
- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 9
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052728 basic metal Inorganic materials 0.000 claims abstract description 6
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 4
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002075 main ingredient Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 48
- 238000003466 welding Methods 0.000 claims description 43
- 238000010521 absorption reaction Methods 0.000 claims description 12
- 230000005540 biological transmission Effects 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 230000033001 locomotion Effects 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- ZVCDLGYNFYZZOK-UHFFFAOYSA-M sodium cyanate Chemical compound [Na]OC#N ZVCDLGYNFYZZOK-UHFFFAOYSA-M 0.000 claims description 3
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 claims description 3
- 241001269238 Data Species 0.000 claims description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003818 basic metals Chemical class 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 2
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 description 32
- 239000000178 monomer Substances 0.000 description 29
- 150000001875 compounds Chemical class 0.000 description 21
- 229920001971 elastomer Polymers 0.000 description 18
- 229920001707 polybutylene terephthalate Polymers 0.000 description 18
- 239000004417 polycarbonate Substances 0.000 description 15
- 229920000515 polycarbonate Polymers 0.000 description 14
- 125000003118 aryl group Chemical group 0.000 description 12
- 150000002148 esters Chemical class 0.000 description 12
- 239000000206 moulding compound Substances 0.000 description 12
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
- 229920000139 polyethylene terephthalate Polymers 0.000 description 11
- 239000005020 polyethylene terephthalate Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 229910052736 halogen Inorganic materials 0.000 description 9
- 150000002367 halogens Chemical class 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 229930185605 Bisphenol Natural products 0.000 description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 239000000945 filler Substances 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 7
- 239000000975 dye Substances 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 150000002118 epoxides Chemical group 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- 239000012815 thermoplastic material Substances 0.000 description 6
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 229920002943 EPDM rubber Polymers 0.000 description 5
- 239000003365 glass fiber Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 230000001360 synchronised effect Effects 0.000 description 5
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000004908 Emulsion polymer Substances 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000012764 mineral filler Substances 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 2
- QHZLMUACJMDIAE-UHFFFAOYSA-N 1-monopalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 2
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 2
- 241000931526 Acer campestre Species 0.000 description 2
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical class C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920006644 PBT+PC Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000001118 alkylidene group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 2
- 229940059574 pentaerithrityl Drugs 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 150000003509 tertiary alcohols Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- VMPHSYLJUKZBJJ-UHFFFAOYSA-N trilaurin Chemical compound CCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC VMPHSYLJUKZBJJ-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- UXUFTKZYJYGMGO-CMCWBKRRSA-N (2s,3s,4r,5r)-5-[6-amino-2-[2-[4-[3-(2-aminoethylamino)-3-oxopropyl]phenyl]ethylamino]purin-9-yl]-n-ethyl-3,4-dihydroxyoxolane-2-carboxamide Chemical compound O[C@@H]1[C@H](O)[C@@H](C(=O)NCC)O[C@H]1N1C2=NC(NCCC=3C=CC(CCC(=O)NCCN)=CC=3)=NC(N)=C2N=C1 UXUFTKZYJYGMGO-CMCWBKRRSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- DSAYAFZWRDYBQY-UHFFFAOYSA-N 2,5-dimethylhexa-1,5-diene Chemical class CC(=C)CCC(C)=C DSAYAFZWRDYBQY-UHFFFAOYSA-N 0.000 description 1
- XSXWOBXNYNULJG-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1O XSXWOBXNYNULJG-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical compound OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- BLDLRWQLBOJPEB-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfanylphenol Chemical compound OC1=CC=CC=C1SC1=CC=CC=C1O BLDLRWQLBOJPEB-UHFFFAOYSA-N 0.000 description 1
- XSVZEASGNTZBRQ-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfinylphenol Chemical compound OC1=CC=CC=C1S(=O)C1=CC=CC=C1O XSVZEASGNTZBRQ-UHFFFAOYSA-N 0.000 description 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical compound OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
- KAIRTVANLJFYQS-UHFFFAOYSA-N 2-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=CC=C1O KAIRTVANLJFYQS-UHFFFAOYSA-N 0.000 description 1
- JJRUAPNVLBABCN-UHFFFAOYSA-N 2-(ethenoxymethyl)oxirane Chemical compound C=COCC1CO1 JJRUAPNVLBABCN-UHFFFAOYSA-N 0.000 description 1
- LSWYGACWGAICNM-UHFFFAOYSA-N 2-(prop-2-enoxymethyl)oxirane Chemical compound C=CCOCC1CO1 LSWYGACWGAICNM-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- ZDWSNKPLZUXBPE-UHFFFAOYSA-N 3,5-ditert-butylphenol Chemical class CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1 ZDWSNKPLZUXBPE-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- WNLHHAAYHRAAKQ-UHFFFAOYSA-N 4-(2-methylbutyl)phenol Chemical compound CCC(C)CC1=CC=C(O)C=C1 WNLHHAAYHRAAKQ-UHFFFAOYSA-N 0.000 description 1
- CUAUDSWILJWDOD-UHFFFAOYSA-N 4-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=C(O)C=C1 CUAUDSWILJWDOD-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical group C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- NIRYBKWMEWFDPM-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)-3-methylbutyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)CCC1=CC=C(O)C=C1 NIRYBKWMEWFDPM-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- RBVMDQYCJXEJCJ-UHFFFAOYSA-N 4-trimethoxysilylbutan-1-amine Chemical compound CO[Si](OC)(OC)CCCCN RBVMDQYCJXEJCJ-UHFFFAOYSA-N 0.000 description 1
- NWPQAENAYWENSD-UHFFFAOYSA-N 5-butylidenebicyclo[2.2.1]hept-2-ene Chemical group C1C2C(=CCCC)CC1C=C2 NWPQAENAYWENSD-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CAWFQMQBSLHCAC-UHFFFAOYSA-N ClC=1C(=C(C(=C(C1)Cl)O)C(C)(C)C1=C(C(=CC(=C1O)Cl)Cl)O)O Chemical compound ClC=1C(=C(C(=C(C1)Cl)O)C(C)(C)C1=C(C(=CC(=C1O)Cl)Cl)O)O CAWFQMQBSLHCAC-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical compound O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 description 1
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical group CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920006801 PBT+PET Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 description 1
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 1
- MLGZSUJIRZZGNG-UHFFFAOYSA-N [Na].C(CCCCCCCCCCCCCCCCCCCCCCCCCCC)(=O)O Chemical compound [Na].C(CCCCCCCCCCCCCCCCCCCCCCCCCCC)(=O)O MLGZSUJIRZZGNG-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000000746 allylic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 150000004646 arylidenes Chemical group 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RELIZYGLMJFIOW-UHFFFAOYSA-N butyl prop-2-enoate;oxiran-2-ylmethyl prop-2-enoate Chemical compound CCCCOC(=O)C=C.C=CC(=O)OCC1CO1 RELIZYGLMJFIOW-UHFFFAOYSA-N 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- SDFUXTFVRHBXPH-UHFFFAOYSA-N calcium;octacosanoic acid Chemical compound [Ca].CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O SDFUXTFVRHBXPH-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- IMHDGJOMLMDPJN-UHFFFAOYSA-N dihydroxybiphenyl Natural products OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- VVYDVQWJZWRVPE-UHFFFAOYSA-L dimethyltin(2+);diiodide Chemical compound C[Sn](C)(I)I VVYDVQWJZWRVPE-UHFFFAOYSA-L 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- UHUSDOQQWJGJQS-UHFFFAOYSA-N glycerol 1,2-dioctadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCCCC UHUSDOQQWJGJQS-UHFFFAOYSA-N 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical class C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000004313 potentiometry Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003336 secondary aromatic amines Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000000207 volumetry Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1603—Laser beams characterised by the type of electromagnetic radiation
- B29C65/1609—Visible light radiation, e.g. by visible light lasers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1603—Laser beams characterised by the type of electromagnetic radiation
- B29C65/1612—Infrared [IR] radiation, e.g. by infrared lasers
- B29C65/1616—Near infrared radiation [NIR], e.g. by YAG lasers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
- B29C65/1635—Laser beams characterised by the way of heating the interface at least passing through one of the parts to be joined, i.e. laser transmission welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
- B29C65/1654—Laser beams characterised by the way of heating the interface scanning at least one of the parts to be joined
- B29C65/1658—Laser beams characterised by the way of heating the interface scanning at least one of the parts to be joined scanning once, e.g. contour laser welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
- B29C65/1654—Laser beams characterised by the way of heating the interface scanning at least one of the parts to be joined
- B29C65/1661—Laser beams characterised by the way of heating the interface scanning at least one of the parts to be joined scanning repeatedly, e.g. quasi-simultaneous laser welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
- B29C65/1664—Laser beams characterised by the way of heating the interface making use of several radiators
- B29C65/1667—Laser beams characterised by the way of heating the interface making use of several radiators at the same time, i.e. simultaneous laser welding
- B29C65/167—Laser beams characterised by the way of heating the interface making use of several radiators at the same time, i.e. simultaneous laser welding using laser diodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
- B29C65/1674—Laser beams characterised by the way of heating the interface making use of laser diodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1696—Laser beams making use of masks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
Abstract
本发明涉及热塑性模塑体用于制备激光透明模制品的用途,所述热塑性模塑体包含如下主要组分:A)29至99.95重量%的聚酯;B)0.25至3.0重量%的碱金属氧代铝酸盐、或氰酸、异氰酸、硫氰酸或偏硼酸的碱金属盐、或其混合物,基于100重量%的A)和B)计;以及C)0至70重量%的其他添加剂,A)至C)的重量%之和为100%。
Description
本发明涉及热塑性模塑组合物用于制备任何类型的激光透明模制品的用途,所述组合物包含以下主要组分:
A)29至99.95重量%的聚酯,
B)0.25至3.0重量%的碱金属氧代铝酸盐(alkali metaloxoaluminate)、或氰酸、异氰酸、硫氰酸或偏硼酸的碱金属盐、或这些物质的混合物,
基于100重量%的A)和B)计,以及
C)0至70重量%的其他添加剂,其中A)至C)的重量%值之和为100%。
本发明还涉及通过激光透射焊接(laser transmission welding)方法用激光透明模制品制备模制品的用途、生产该类模制品的方法以及它们在各种应用领域中的用途。
这类组分B)为PET和相关聚酯的成核剂。例如,硫氰酸钠在PET中的用途记载于US4405741并且亚硝酸钠在PET中的用途记载于US4349505。没有研究所述复合材料的光学性能。
存在各种焊接塑料模制品的方法(Kunststoffe87,(1997),11,1632–1640)。对于广泛使用的(例如汽车进气歧管的)热烙铁焊接方法和振动焊接方法而言,稳定焊接的前提是在产生接合的实际步骤之前使接触区中的粘合体充分软化。
激光透射焊接是一种提供振动焊接和热烙铁焊接的替代选择的方法,并且其应用在近期不断增长,特别是使用二极管激光器。
技术文献记载了激光透射焊接的基本原理(Kunststoffe87,(1997)3,348–350;Kunststoffe88,(1998),2,210–212;Kunststoffe87(1997)11,1632–1640;Plastverarbeiter50(1999)4,18–19;Plastverarbeiter46(1995)9,42-46)。
使用激光透射焊接的前提是由激光器发射的辐射首先穿过对所用波长的激光具有足够透明度的模制品(该模制品在下文称为激光透明模制品),然后所述辐射在薄层中被与所述激光透明模制品接触并且在下文中称为激光吸收模制品的另一个模制品吸收。在吸收所述激光的薄层内,激光的能量转化为热,这导致在该接触区内熔融并最终通过焊接而连接所述激光透明模制品和激光吸收模制品。
激光透射焊接通常使用波长范围为600至1200nm的激光器。在用于热塑性材料焊接的激光的波长范围内,通常使用Nd:YAG激光器(1064nm)或高功率二极管激光器(800至1000nm)。当在下文使用术语激光透明和激光吸收时,其总是指上述波长范围。
与激光吸收模制品相比,对激光透明模制品的要求是在优选波长范围内的高的激光透明度,从而使得激光束能够穿透到达焊接区域并具有所需的能量。例如,IR激光的透射率通过使用分光光度计和积分光度计球测量。该测量系统也检测透射辐射的漫射部分。该测量不仅在一个波长下进行,而且在包括目前用于该焊接步骤的所有激光波长的光谱范围内进行。
用户目前可使用多种基于透射原理的激光焊接方法的变型。例如,周线焊接(contour welding)是一种顺序焊接方法,其中激光束沿着可自由设计的焊接周线而进行或者组件相对于静止的激光移动。在同步焊接方法中,由单个高功率二极管发射的线性辐射沿着待焊接的焊接周线排布。因此,整个周线的熔融和焊接同时进行。准同步焊接方法是周线焊接和同步焊接的结合。检流计反射镜(Galvanometric mirror)(扫描器)用于在10m/s以上的非常高的速度下沿着焊接的周线传导激光束。该高的横移速率提供了接合区域的渐进式加热和熔融。与同步焊接方法相比,焊接周线的改变具有高的灵活性。掩模焊接(mask welding)是一种线性激光束穿过粘合体横向运动的方法。掩模用于辐射的受控筛选,这仅影响其中将进行焊接的待接合区域。该方法可产生非常精确定位的焊接。这些方法是本领域技术人员已知的并且记载于例如"HandbuchKunststoff-Verbindungstechnik"[Handbook of plastics bondingtechnology](G.W.Ehrenstein,Hanser,ISBN3-446-22668-0)和/或DVS-Richtlinie2243"Laserstrahlschweiβen thermoplastischerKunststoffe"[German Welding Society Guideline2243“Laser welding ofthermoplastics"]”。
与所用方法变型无关,激光焊接方法高度依赖于两种粘合体的材料性能。透明组分的激光透明度(LT)通过每单位时间可以引入的能量的量直接影响该方法的速度。半结晶热塑性材料的固有微结构(大多呈球晶形式)通常使它们具有相对低的激光透明度。这些球晶比纯无定形热塑性材料的内部结构更大程度地散射入射的激光:反向散射导致透射能量的总量降低,而漫(侧向)散射通常导致激光束变宽并因此导致焊接精度受损。这些现象在聚对苯二甲酸丁二醇酯(PBT)中特别明显,与其他良好结晶的热塑性材料如PA相比,PBT显示出特别低的激光透明度和高的光束展宽程度。因此,尽管PBT的性能特征的其他方面(例如良好的尺寸稳定性和低吸水性)使得其对于这类应用非常有吸收力,但是其一直较少用作激光焊接组分的材料。尽管半结晶形态通常对高的激光透明度无益,但就其他性能而言提供了优点。例如,半结晶材料在玻璃化转变点之上一直都具有机械强度且通常具有比无定形材料更好的耐化学品性。快速结晶的材料也提供了加工优点,特别是快速脱模性和因此具有短的循环时间。因此,希望将半结晶性与快速结晶和高的激光透明度结合起来。
对于聚酯、特别是PBT的激光透明度改进存在各种已知方法。原则上可以将这些方法分成共混物/混合物法和折射率匹配法。
使用共混物/混合物的方法基于通过在该共混物/混合物中使用高的激光透明度配对组分而“稀释”低的激光透明度PBT。其实例见于下列说明书中:JP2004/315805A1(PBT+PC/PET/SA+填料+弹性体)、DE-A1-10330722(半结晶热塑性材料与无定形热塑性材料的广义共混物,以提高LT;具体为PBT+PET/PC+玻璃纤维)、JP2008/106217A(PBT+与1,4-环己烷二甲醇的共聚物;LT由16%提高至28%)。此时的缺点是所得聚合物共混物的性能不可避免地明显不同于主要基于PBT作为基体的产品的性能。
折射率匹配方法基于无定形和结晶PBT以及填料的不同折射率。例如,这里使用了共聚单体:JP2008/163167(PBT和硅氧烷的共聚物)、JP2007/186584(PBT+双酚A二缩水甘油醚)和JP2005/133087(PBT+PC+弹性体+高折射率硅油)可以作为实例提及。尽管这导致激光透明度增加,但这是在损失机械性能下实现的。也可以降低填料和基体之间的折射率差,参见JP2009/019134(环氧树脂涂覆于玻璃纤维上以在填料和基体之间光学界面处提供匹配)、或JP2007/169358(具有高折射率玻璃纤维的PBT)。然而,这类原料由于其高成本和/或它们在该生产方法内所要求的另外的步骤而是不利的。
相对于激光透明度增加所实现的效果总体而言也相对小且因此并不完全令人满意。
因此,本发明的目的是改进聚酯的激光透明度。因此发现了在引言中所定义的模塑组合物。从属权利要求给出了优选的实施方案。
作为组分A),本发明的模塑组合物包括29至99.75重量%、优选98.0至99.7重量%、特别是99.0至99.65重量%的至少一种热塑性聚合物,基于组分A)和B)计。
组分A)的聚酯中的至少一种为半结晶聚酯。优选的是包含至少50重量%半结晶聚酯的组分A)。所述比例特别优选为70重量%(各自基于100重量%A)计)。
基于100%由A)至C)(即包括C))构成的模塑组合物,这些组合物包括
30至100重量%的A)+B),优选50至100重量%,以及
0至70重量%的C),优选0至50重量%。
上述相对量级的基本要素是组分B)的比例总是基于聚酯,这是因为所述比例意欲位于所述限度内。添加剂C)可影响激光透明度。这一影响实质上取决于添加剂的散射性能和吸收性能。复合材料的光学性能实质上是本发明基体(组分A+B)的光学性能和添加剂(组分C)的光学性能的总和。
所用的聚酯A)通常基于芳族二羧酸和基于脂族或芳族二羟基化合物。
第一类优选的聚酯为在醇部分特别是具有2至10个碳原子的聚对苯二甲酸亚烷基酯的聚酯。
这类聚对苯二甲酸亚烷基酯本身是已知的并且记载于文献中。它们的主链包括衍生自芳族二羧酸的芳族环。芳族环上还可以被例如,卤素(如氯或溴)取代、或者被C1-C4烷基基团(如甲基、乙基、异丙基或正丙基、或正丁基、异丁基或叔丁基)所取代。
这些聚对苯二甲酸亚烷基酯可以通过使芳族二羧酸或其酯或其他成酯衍生物与脂族二羟基化合物以本身已知的方式反应而制备。
优选的二羧酸为2,6-萘二羧酸、对苯二甲酸和间苯二甲酸或这些二羧酸的混合物。最高达30摩尔%、优选不多于10摩尔%的芳族二羧酸可以被脂族或脂环族二羧酸(例如己二酸、壬二酸、癸二酸、十二烷二羧酸和环己烷二羧酸)替代。
优选的脂族二羟基化合物是具有2至6个碳原子的二醇,特别是1,2-乙二醇、1,3-丙二醇、1,4-丁二醇、1,6-己二醇、1,4-己二醇、1,4-环己二醇、1,4-环己烷二甲醇和新戊二醇和这些二醇的混合物。
特别优选的聚酯(A)是衍生自具有2至6个碳原子的烷二醇的聚对苯二甲酸亚烷基酯。其中特别优选的是聚对苯二甲酸乙二醇酯、聚对苯二甲酸丙二醇酯和聚对苯二甲酸丁二醇酯和它们的混合物。还优选的是包括最高达1重量%、优选最高达0.75重量%的1,6-己二醇和/或2-甲基-1,5-戊二醇作为其它单体单元的PET和/或PBT。
聚酯(A)的特性粘度通常为50至220、优选80至160(根据ISO1628(于25℃在浓度为0.5重量%的重量比为1:1的苯酚/邻二氯苯混合物的溶液中测定)。
特别优选的是端羧基含量为0至100meq/kg聚酯、优选10至50meq/kg聚酯、特别是15至40meq/kg聚酯的聚酯。这类聚酯例如可以通过DE-A4401055的方法而制备。端羧基含量通常通过滴定法(例如电位分析法)测定。
作为组分A),特别优选的模塑组合物包括聚酯的混合物,其中至少一种为PBT。该混合物中聚对苯二甲酸乙二醇酯的比例的实例优选为最高达50重量%,特别是10至35重量%,基于100重量%的A)计。
还有利的是使用任选地与聚对苯二甲酸亚烷基酯如PBT混合的PET回收材料(也称为废料PET)。
回收材料通常是:
1)已知为工业后回收材料的那些:这些材料是在缩聚或加工过程中的生产废料,例如来自注塑的浇口废料、来自注塑或挤出的起始材料、或来自挤出片材或膜的边切料。
2)消费后的回收材料:这些材料是在最终消费者使用后收集和处理的塑料物品。矿泉水、软饮料和果汁的吹塑PET瓶子就数量而言是容易占主导的物品。
两种类型的回收材料都可以作为再磨料或者以粒料形式使用。在以粒料形式使用的情况下,分离并纯化粗回收材料,然后使用挤出机将其熔融并造粒。这通常有利于处理和自由流动性能,以及有利于在加工的其它步骤中计量加入。
使用的回收材料可被粒化或呈再磨料的形式。其边长不得超过10mm并且应优选小于8mm。
因为聚酯在加工过程中(由于痕量的水的原因)经历水解裂解,所以将回收材料预干燥是有利的。干燥后的残余水分含量优选<0.2%,特别是<0.05%。
另一类可提及的聚酯是衍生自芳族二羧酸和芳族二羟基化合物的全芳族聚酯。
合适的芳族二羧酸是前面对聚对苯二甲酸亚烷基酯所述的化合物。优选使用的混合物由5至100摩尔%的间苯二甲酸和0至95摩尔%的对苯二甲酸制成,特别是由约50至约80%的对苯二甲酸和20至约50%的间苯二甲酸制成。
所述芳族二羟基化合物优选具有如下通式:
其中Z为具有最高达8个碳原子的亚烷基或亚环烷基、具有最高达12个碳原子的亚芳基、羰基、磺酰基、氧原子或硫原子、或为化学键,且其中m的值为0至2。在该化合物中的亚苯基也可以被C1-C6烷基或烷氧基、氟、氯或溴所取代。
这些化合物的母体化合物的实例为
二羟基联苯、
二(羟基苯基)烷烃、
二(羟基苯基)环烷烃、
二(羟基苯基)硫醚、
二(羟基苯基)醚、
二(羟基苯基)酮、
二(羟基苯基)亚砜、
α,α’-二(羟基苯基)二烷基苯、
二(羟基苯基)砜、二(羟基苯甲酰基)苯、
间苯二酚和对苯二酚,以及这些化合物的环上烷基化和环上卤代的衍生物。
其中优选的是
4,4'-二羟基联苯、
2,4-二(4'-羟基苯基)-2-甲基丁烷、
α,α'-二(4-羟基苯基)-对二异丙基苯、
2,2-二(3'-甲基-4'-羟基苯基)丙烷、和
2,2-二(3'-氯-4'-羟基苯基)丙烷,
特别是
2,2-二(4'-羟基苯基)丙烷、
2,2-二(3',5-二氯二羟基苯基)丙烷、
1,1-二(4'-羟基苯基)环己烷、
3,4'-二羟基二苯甲酮、
4,4'-二羟基二苯基砜、和
2,2-二(3',5'-二甲基-4'-羟基苯基)丙烷
或这些化合物的混合物。
当然,还可以使用聚对苯二甲酸亚烷基酯和全芳族聚酯的混合物。这些通常包括20至98重量%的聚对苯二甲酸亚烷基酯和2至80重量%的全芳族聚酯。
当然,还可以使用聚酯嵌段共聚物,例如共聚醚酯。这类产品本身是已知的并且记载于文献中,例如记载于US-A3651014中。相应的产品还是市售可得的,例如(DuPont)。
在本发明中,术语聚酯包括不含卤素的聚碳酸酯。合适的不含卤素的聚碳酸酯的实例是基于如下通式的双酚的聚碳酸酯:
其中Q为单键、C1至C8亚烷基(alkylene)基团、C2至C3亚烷基(alkylidene)基团、C3至C6亚环烷基、C6至C12亚芳基或-O-、-S-或-SO2-,且m为0至2的整数。
双酚的亚苯基还可具有取代基,例如,C1-至C6-烷基或C1-至C6-烷氧基。
该式的优选的双酚的实例为对苯二酚、间苯二酚、4,4'-二羟基联苯、2,2-双(4-羟基苯基)丙烷、2,4-双(4-羟基苯基)-2-甲基丁烷和1,1-双(4-羟基苯基)环己烷。特别优选的是2,2-双(4-羟基苯基)丙烷和1,1-双(4-羟基苯基)环己烷,以及1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷。
均聚碳酸酯或共聚碳酸酯适合作为组分A,优选的是双酚A的共聚碳酸酯,以及双酚A均聚物。
合适的聚碳酸酯可以以已知的方式支化,具体而言优选通过引入基于所用双酚的总量计为0.05至2.0摩尔%的至少三官能化合物,例如具有三个或多个酚OH基团的化合物进行支化。
已经证实特别合适的聚碳酸酯具有1.10至1.50、特别是1.25至1.40的相对粘度η相对。这对应于10000至200000g/mol、优选20000至80000g/mol的平均摩尔质量Mw(重均)。
该通式的双酚本身是已知的或者可以通过已知方法制备。
所述聚碳酸酯可以例如通过使双酚与光气在界面方法中反应而制备,或者使双酚与光气在均相方法(已知为吡啶方法)中反应而制备,在每种情况下可以通过使用合适量的已知链终止剂而以已知方式获得所需的分子量。(对于含有聚二有机硅氧烷的聚碳酸酯,例如参见DE-A3334782。)
合适链终止剂的实例是苯酚、对叔丁基苯酚、或者长链烷基苯酚,如DE-A2842005中的4-(l,3-四甲基丁基)苯酚、或者如DE-A-3506472中的在烷基取代基中共计具有8-20个碳原子的单烷基苯酚或二烷基苯酚,例如对壬基苯酚、3,5-二叔丁基苯酚、对叔辛基苯酚、对十二烷基苯酚、2-(3,5-二甲基庚基)苯酚和4-(3,5-二甲基庚基)苯酚。
对于本发明而言,不含卤素的聚碳酸酯是由不含卤素的双酚、不含卤素的链终止剂和任选地不含卤素的支化剂制成的聚碳酸酯,其中ppm水平的少量水解氯(例如,用光气在界面方法中制备聚碳酸酯而产生)含量对于本发明而言不认为具有术语含卤素的意义。这类具有ppm水平的水解氯含量的聚碳酸酯对于本发明而言是不含卤素的聚碳酸酯。
可以提及的其他合适的组分A)是无定形的聚酯碳酸酯,其中在制备过程中光气由芳族二羧酸单元如间苯二甲酸和/或对苯二甲酸单元替代。对于这一点,另外的细节可以参考EP-A711810。
以环烷基作为单体单元的其他合适的共聚碳酸酯记载于EP-A365916。
还可以用双酚TMC替代双酚A。这类聚碳酸酯可以商标APEC购自Bayer。
作为组分B),本发明的模塑组合物包括0.25至3.0重量%、优选0.3至2重量%、特别是0.35至1重量%的碱金属氧代铝酸盐、或氰酸、异氰酸、硫氰酸或偏硼酸的碱金属盐、或这些的混合物,基于100重量%的A)+B)计。
聚酯A)的端羧基通常与盐化合物B)反应,此时碳酸盐的金属阳离子由碳酸盐转移至端基。即使在极低的浓度下也可检测到组分B)的成核作用。令人惊奇的是,激光透明度在组分B)的浓度非常低时下降,并且直至达到较高浓度时激光透明度才上升。
优选聚酯A)包括35至250mmol/kg聚酯,优选40至200mmol/kg聚酯(基于A)+B)计),其中这些浓度数据基于氧代铝酸盐、氰酸盐、异氰酸盐、硫氰酸盐和偏硼酸盐各自的阴离子计。
优选的碱金属是钠和/或钾。
优选的无机盐B)为偏铝酸钠、氰酸钠、异氰酸钠、硫氰酸钠、偏硼酸钠或这些的混合物。
铝酸钠是水溶性白色粉末,其通常通过将过量氢氧化钠溶液作用于Al盐上而制备。
制造所提及的其他无机盐的方法是本领域技术人员已知的。
作为组分C),本发明的模塑组合物可以包含0至70重量%、特别是最高达50重量%的其他添加剂和加工助剂,基于100重量%的A)、B)和C)计,所述添加剂和加工助剂不同于B)和/或A)。
常规添加剂C)的实例为含量最高达40重量%、优选最高达15重量%的弹性体聚合物(也常称为冲击改性剂、弹性体或橡胶)。
这些非常概括地涉及共聚物,其优选由下列单体中的至少两种构成:乙烯、丙烯、丁二烯、异丁烯、异戊二烯、氯丁二烯、乙酸乙烯酯、苯乙烯、丙烯腈和分别在醇组分中具有1至18个碳原子的丙烯酸酯和甲基丙烯酸酯。
这类聚合物记载于例如Houben-Weyl,Methoden der organischenChemie,第14/1卷(Georg Thieme Verlag,Stuttgart,Germany,1961),第392-406页和C.B.Bucknall的专著“Toughened Plastics”(AppliedScience Publishers,London,1977)中。
这类弹性体中的某些优选类型如下所述。
该类弹性体的优选类型是已知为乙烯-丙烯(EPM)橡胶和乙烯-丙烯-二烯(EPDM)橡胶的弹性体。
EPM橡胶通常基本没有残留双键,而EPDM橡胶每100个碳原子可以具有1-20个双键。
可以提及的用于EPDM橡胶的二烯单体的实例是共扼二烯,例如异戊二烯和丁二烯;具有5至25个碳原子的非共扼二烯,如1,4-戊二烯、1,4-己二烯、1,5-己二烯、2,5-二甲基-1,5-己二烯和1,4-辛二烯;环状二烯,如环戊二烯、环己二烯、环辛二烯和二环戊二烯;以及烯基降冰片烯,如5-亚乙基-2-降冰片烯、5-亚丁基-2-降冰片烯、2-甲代烯丙基-5-降冰片烯和2-异丙烯基-5-降冰片烯;和三环二烯,例如3-甲基三环[5.2.1.02,6]-3,8-癸二烯或这些的混合物。优选1,5-己二烯、5-亚乙基降冰片烯和二环戊二烯。EPDM橡胶中的二烯含量优选为0.5至50重量%,特别是1至8重量%,基于橡胶的总重量计。
EPM和EPDM橡胶优选还可以用反应性羧酸或者用其衍生物接枝。这些化合物的实例是丙烯酸、甲基丙烯酸及其衍生物,例如(甲基)丙烯酸缩水甘油酯,以及马来酸酐。
乙烯与丙烯酸和/或甲基丙烯酸和/或与这些酸的酯的共聚物是另一类优选的橡胶。该橡胶还可以包含二羧酸,例如马来酸和富马酸,或这些酸的衍生物如酯和酸酐,和/或含有环氧基团的单体。优选通过将包含二羧酸基团和/或环氧基团且具有通式I、II、III或IV的单体加入单体混合物中而将这些包含二羧酸衍生物或包含环氧基团的单体引入橡胶中:
其中R1至R9为氢或具有1至6个碳原子的烷基,并且m为0至20的整数,g为0至10的整数且p为0至5的整数。
R1至R9优选为氢,其中m为0或1且g为1。对应的化合物是马来酸、富马酸、马来酸酐、烯丙基缩水甘油醚和乙烯基缩水甘油醚。
优选的式I、II和IV的化合物是马来酸、马来酸酐和包含环氧基团的(甲基)丙烯酸酯,如丙烯酸缩水甘油酯和甲基丙烯酸缩水甘油酯,以及与叔醇的酯,如丙烯酸叔丁酯。尽管与叔醇的酯没有游离羧基,但它们的性能类似于游离酸,因此将它们称为具有潜在羧基的单体。
所述共聚物有利地由50至98重量%的乙烯、0.1至20重量%的包含环氧基团和/或甲基丙烯酸的单体和/或包含酸酐基团的单体构成,剩余量为(甲基)丙烯酸酯。
特别优选的是由下列物质构成的共聚物:
50至98重量%、特别是55至95重量%的乙烯,
0.1至40重量%、特别是0.3至20重量%的丙烯酸缩水甘油酯和/或甲基丙烯酸缩水甘油酯、(甲基)丙烯酸和/或马来酸酐,和
1至45重量%、特别是10至40重量%的丙烯酸正丁酯和/或丙烯酸2-乙基己酯。
其他优选的(甲基)丙烯酸酯是(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丙酯、(甲基)丙烯酸异丁酯和(甲基)丙烯酸叔丁酯。
除了这些以外,还可以使用的共聚单体是乙烯基酯和乙烯基醚。
上述乙烯共聚物可以通过本身已知的方法制备,优选在高压和高温下通过无规共聚制备。合适的方法是公知的。
其他优选的弹性体是乳液聚合物,其制备例如由Blackley记载于专著“Emulsion polymerization”中。可以使用的乳化剂和催化剂本身是已知的。
原则上可以使用具有均匀结构的弹性体或具有壳结构的弹性体。壳型结构通过各个单体的加入顺序确定。该聚合物的形态也受到该加入顺序的影响。
这里可以仅作为实例提到的用于生产弹性体的橡胶部分的单体是丙烯酸酯,如丙烯酸正丁酯和丙烯酸2-乙基己酯;相应的甲基丙烯酸酯;丁二烯和异戊二烯,以及这些的混合物。这些单体可以与其他单体(如苯乙烯、丙烯腈、乙烯基醚)以及与其他丙烯酸酯或甲基丙烯酸酯(如甲基丙烯酸甲酯、丙烯酸甲酯、丙烯酸乙酯或丙烯酸丙酯)共聚。
弹性体的软相或橡胶相(玻璃化转变温度低于0℃)可以是核、外壳(outer envelope)或中间壳(对于在弹性体结构中具有多于2个壳的情况)。具有多于1个壳的弹性体还可以具有多于1个由橡胶相构成的壳。
如果在弹性体的结构中除了橡胶相以外还包括一种或多种硬组分(玻璃化转变温度高于20℃),则这些硬组分通常通过聚合作为主要单体的苯乙烯、丙烯腈、甲基丙烯腈、α-甲基苯乙烯、对甲基苯乙烯或者丙烯酸酯或甲基丙烯酸酯如丙烯酸甲酯、丙烯酸乙酯或甲基丙烯酸甲酯而制备。除这些以外,在此还可以使用相对小比例的其他共聚单体。
在某些情况下已证明有利的是使用在其表面上具有反应性基团的乳液聚合物。这类基团的实例是环氧基团、羧基、潜在羧基、氨基和酰胺基,以及可以通过同时使用如下通式的单体而引入的官能团:
其中取代基的定义如下:
R10为氢或C1-C4-烷基,
R11为氢或C1-C8-烷基或芳基,尤其是苯基,
R12为氢、C1-C10-烷基或C6-C12-芳基或–OR13,
R13为C1-C8-烷基或C6-C12-芳基,各自任选被含O或含N基团取代,
X为化学键或C1-C10-亚烷基或C6-C12-亚芳基,或
Y为O-Z或NH-Z,和
Z为C1-C10-亚烷基或C6-C12-亚芳基。
在EP-A208187中记载的接枝单体也适合用于在表面引入反应性基团。
可以提及的其他实例是丙烯酰胺、甲基丙烯酰胺和取代的丙烯酸酯或甲基丙烯酸酯,例如甲基丙烯酸(N-叔丁基氨基)乙酯、丙烯酸(N,N-二甲氨基)乙酯、丙烯酸(N,N-二甲氨基)甲酯和丙烯酸(N,N-二乙氨基)乙酯。
橡胶相的颗粒也可以被交联。交联单体的实例是1,3-丁二烯、二乙烯基苯、邻苯二甲酸二烯丙酯和丙烯酸二氢二环戊二烯基酯,以及EP-A50265中记载的化合物。
还可以使用已知为接枝连接单体的单体,即具有两个以上在聚合过程中以不同速率反应的可聚合双键的单体。优选的是使用其中至少一个反应性基团以大约与其他单体相同的速率聚合,而其他反应性基团(或多个反应性基团),例如,明显更慢地聚合的这类化合物。不同的聚合速率在橡胶中产生特定比例的不饱和双键。若随后将另一相接枝到这类橡胶上,则橡胶中存在的至少某些双键与接枝单体发生反应形成化学键,即被接枝的相与接枝基质至少具有某种程度的化学键合。
这类接枝连接单体的实例是含有烯丙基的单体,特别是烯键式不饱和羧酸的烯丙酯,例如丙烯酸烯丙酯、甲基丙烯酸烯丙酯、马来酸二烯丙酯、富马酸二烯丙酯和衣康酸二烯丙酯,以及这些二羧酸的相应单烯丙酯化合物。除了这些以外,还有各种其他合适的接枝连接单体。对于进一步的细节,在此可以参考例如US-A4148846。
在抗冲改性聚合物中这些交联单体的比例通常是最高达5重量%,优选不超过3重量%,基于抗冲改性聚合物计。
一些优选的乳液聚合物列举如下。在此首先可以提及具有核和至少一个外壳且具有下列结构的接枝聚合物:
这些枝接聚合物,特别是ABS聚合物和/或ASA聚合物优选用量最高达40重量%,对于PBT抗冲改性而言,任选地与最高达40重量%的聚对苯二甲酸乙二醇酯混合。合适的共混产品可以以商标S(之前是购自BASF AG的S)获得。
除了具有多于一个壳结构的接枝聚合物外,还可使用均匀的(即单壳)弹性体,其由1,3-丁二烯、异戊二烯和丙烯酸正丁酯制备或者由这些的共聚物制备。这些产物也可以通过同时使用交联单体或具有反应性基团的单体而制备。
优选的乳液聚合物实例是丙烯酸正丁酯-(甲基)丙烯酸共聚物、丙烯酸正丁酯-丙烯酸缩水甘油酯或者丙烯酸正丁酯-甲基丙烯酸缩水甘油酯共聚物、具有由丙烯酸正丁酯构成或基于丁二烯的内核且具有由上述共聚物构成的外壳的接枝聚合物、以及乙烯与提供反应性基团的共聚单体的共聚物。
所述弹性体还可以通过其他常规方法如通过悬浮聚合而制备。
同样优选的是硅橡胶,如DE-A3725576、EP-A235690、DE-A3800603和EP-A319290中所述。
当然还可以使用以上列举的各类橡胶的混合物。
可提及的纤维状或颗粒状填料C)是玻璃纤维、玻璃珠、无定形二氧化硅、石棉、硅酸钙、偏硅酸钙、碳酸镁、高岭土、白垩、粉末石英、云母、硫酸钡和长石。使用的纤维状填料C)的用量最高达60重量%,特别是最高达35重量%,且使用的颗粒状填料的用量最高达30重量%,特别是最高达10重量%。
可以提及的优选纤维状填料是芳族聚酰胺纤维和钛酸钾纤维,在此特别优选的是E玻璃形式的玻璃纤维。这些材料可以作为粗纱或以市售的短切玻璃纤维形式使用。
具有高的激光吸收性的填料,例如碳纤维、碳黑、石墨、石墨烯或碳纳米管的用量优选小于1重量%,特别优选小于0.05重量%。
纤维状填料可以用硅烷化合物进行表面预处理以改进与热塑性材料的相容性。
合适的硅烷化合物是如下通式的那些:
(X–(CH2)n)k–Si–(O–CmH2m+1)4–k
其中取代基的定义如下:
X NH2-、HO-,
n为2至10、优选3至4的整数
m为1至5、优选1至2的整数
k为1至3、优选1的整数。
优选的硅烷化合物是氨基丙基三甲氧基硅烷、氨基丁基三甲氧基硅烷、氨基丙基三乙氧基硅烷和氨基丁基三乙氧基硅烷,以及包含作为取代基X的缩水甘油基的相应的硅烷。
通常用于表面涂覆的硅烷化合物的用量为0.05至5重量%,优选0.1至1.5重量%,特别是0.2至0.5重量%(基于C计)。
针状矿物填料也是合适的。
对于本发明而言,针状矿物填料是具有显著针状特征的矿物填料。可以提及的实例是针状硅灰石。该矿物的L/D比(长度与直径之比)优选为8:1至35:1,优选8:1至11:1。该矿物填料任选地可以用上述硅烷化合物预处理;然而,所述预处理不是必需的。
作为组分C),本发明的热塑性模塑组合物可以包含常规加工助剂,如稳定剂、氧化抑制剂、用于抵抗热分解和紫外光分解的试剂、润滑剂和脱模剂、着色剂如染料和颜料、增塑剂等。
可以提及的氧化抑制剂和热稳定剂的实例是空间位阻酚和/或亚磷酸盐、对苯二酚、芳族仲胺如二苯胺,以及所述组的各种取代物,以及这些的混合物,其浓度最高达1重量%,基于热塑性模塑组合物的重量计。
可以提及的UV稳定剂为各种取代的间苯二酚、水杨酸酯、苯并三唑和二苯甲酮,其用量通常最高达2重量%,基于模塑组合物计。
可以加入的着色剂包括无机颜料和有机颜料,以及染料,例如苯胺黑和蒽醌。特别合适的着色剂提及于例如EP1722984B1、EP1353986B1或DE10054859A1。
进一步优选的是具有10至40个、优选16至22个碳原子的饱和或不饱和脂族羧酸与包含2至40个、优选2至6个碳原子的饱和脂族醇或胺的酯或酰胺。
所述羧酸可以是一元或二元的。可以提及的实例是壬酸、棕榈酸、月桂酸、十七烷酸、十二烷二酸、山萮酸,特别优选硬脂酸、癸酸以及褐煤酸(具有30-40个碳原子的脂肪酸的混合物)。
所述脂族醇可以是一元至四元的。醇的实例是正丁醇、正辛醇、硬脂醇、乙二醇、丙二醇、新戊二醇和季戊四醇,在此优选的是甘油和季戊四醇。
所述脂族胺可以是单官能至三官能的。这些的实例是硬脂胺、乙二胺、丙二胺、己二胺和二(6-氨基己基)胺,在此特别优选的是乙二胺和己二胺。相应地,优选的酯或酰胺是二硬脂酸甘油酯、三硬脂酸甘油酯、乙二胺二硬脂酸酯、单棕榈酸甘油酯、三月桂酸甘油酯、单山萮酸甘油酯和四硬脂酸季戊四醇酯。
还可以以任何所需混合比使用各种酯或酰胺的混合物,或者酯和酰胺的结合物。
其他润滑剂和脱模剂的常规用量通常为最高达1重量%。优选使用长链脂肪酸(例如硬脂酸或山萮酸)、所述长链脂肪酸的盐(例如硬脂酸钙或硬脂酸锌)、或褐煤蜡(由具有28至32个碳原子的链长的直链饱和羧酸制成的混合物)、或褐煤酸钙或褐煤酸钠、或低分子量聚乙烯蜡或低分子量聚丙烯蜡。
可以提及的增塑剂实例是邻苯二甲酸二辛酯、邻苯二甲酸二苄酯、邻苯二甲酸丁基苄基酯、烃油和N-(正丁基)苯磺酰胺。
本发明的模塑组合物还可以包含0至2重量%的含氟乙烯聚合物。其为氟含量为55至76重量%、优选70至76重量%的乙烯聚合物。
在此实例是聚四氟乙烯(PTFE)、四氟乙烯-六氟丙烯共聚物或具有相对小比例(通常最高达50重量%)的可共聚烯键式不饱和单体的四氟乙烯共聚物。这些例如由Schildknecht记载于“Vinyl and Related Polymers”,Wiley Verlag,1952,第484至494页中,和由Wall记载于“Fluoropolymers”(Wiley Interscience,1972)中。
这些含氟乙烯聚合物在模塑组合物中的存在形式为均匀分散体,且其d50(数均)粒径优选为0.05至10μm,特别是0.1至5μm。这些小粒径特别优选可以通过使用含氟乙烯聚合物的水性分散体并将这些掺入聚酯熔体中而实现。
本发明的热塑性模塑组合物可以通过本身已知的方法,通过在常规混合设备如螺杆挤出机、Brabender混合机或Banbury混合机中混合起始组分,随后将其挤出而制备。可以在挤出后将挤出物冷却并粉碎。还可以预混合各组分(例如将组分B)施用于粒料,例如在转鼓中),然后单独加入剩余的原料和/或在同样将它们混合之后加入。混合温度通常为230至290℃。组分B)也可以优选通过热进料或直接方法加入挤出机入口中。
在另一优选操作方法中,组分B)和任选地C)可以与聚酯预聚物混合、复合并造粒。然后在惰性气体中在低于组分A)熔点的温度下将所得粒料连续或间歇地进行固相缩合直至达到所需粘度。
可以用于本发明中的模塑组合物适合生产激光透明模制品。这些激光透明模制品的激光透明度优选为至少33%,特别是至少40%(通过实施例中所述测试方法对厚度为2mm的模制品在1064nm下测量)。
本发明通过激光透射焊接方法使用这类激光透明模制品来制备模制品。
所用激光吸收模制品通常可以包含由任何激光吸收性材料制成的模制品。例如,这些模制品可以是复合物质、热固性材料,或优选由特定热塑性模塑组合物制成的模制品。合适的热塑性模塑组合物是在所用波长范围内具有足够激光吸收的模塑组合物。例如,合适的热塑性模塑组合物优选可以为通过加入无机颜料如碳黑和/或通过加入有机颜料或其他添加剂而呈激光吸收性的热塑性材料。实现激光吸收的适合的有机颜料的实例优选是IR吸收性有机化合物,如DE19916104A1中所记载那些。
本发明还提供了通过激光透射焊接方法而接合于本发明的模制品的模制品和/或模塑结合物。
本发明的模制品极佳地适于通过激光透射焊接方法而以长期且稳定的方式用于激光吸收模制品。因此,它们特别适合用于覆盖物、外壳、添加组件和传感器的材料,例如用于汽车、电子产品、电信、信息技术、计算机、家用、运动、医疗、或娱乐领域中。
实施例
组分A/1:
特性粘度为130m1/g且端羧基含量为34meq/kg的聚对苯二甲酸丁二醇酯(购自BASF SE的B4500)(根据ISO1628在25℃下在浓度为0.5重量%的1:1苯酚/邻二氯苯混合物溶液中测量的IV)。
组分B:
该模塑组合物在具有250至260℃的平台温度分布且具有造粒作用的ZSK25中制备。
激光透明度测量
使用热电功率测量确定在波长1064nm处的激光透射率。测量几何结构按如下设置:使用光束分配器(购自Laseroptik GmbH的SQ2非偏振光束分配器)在与总功率为2瓦特的激光束(波长为1064nm的二极管抽运Nd-YAG激光,FOBA DP50)呈90°的角度处分出功率为1瓦特的参比光束。该参比光束冲击参比传感器。穿过光束分配器的那部分原始光束提供了功率同样为1瓦特的测量光束。该光束经由在该光束分配器后面的模隔板(mode diaphragm)(5.0)而聚焦至0.18μm的焦点直径。激光透明度(LT)测量传感器位于焦点以下80mm处。测试片材位于LT测量传感器以上2mm处。所使用的注塑测试片材尺寸为60*60*2mm3且其边缘已进行浇口(gating)。在片材中央(两条对角线的交点)进行测量。所用注塑参数设定为下值:
总测量时间为30秒,并且测量结果在最后5秒内确定。同步记录来自参比传感器和测量传感器的信号。插入样品后开始所述测量过程。
由下列公式得到透射率并因此得到激光透明度:
LT=(信号(测量传感器)/信号(参比传感器))×100%。
该测量方法排除了激光器系统的变化和主观读取误差。
所述片材的平均LT值由至少5个测量值计算。对于每种材料,平均值基于10块片材计算。使用对各片材的测量值的平均值来计算该材料平均值并且计算标准偏差。
根据ISO527进行拉伸测试,并且根据ISO179测量耐冲击性。
根据ISO11357使用DSC,加热和冷却速率为20K/min进行热量研究。在第一冷却过程中测定结晶峰温度TPC。
表1:
*)用于对比
表2:
*)用于对比
Claims (7)
1.热塑性模塑组合物用于通过激光透射焊接方法而制备任何类型的激光透明模制品的用途,所述组合物包含以下主要组分:
A)29至99.95重量%的聚酯,
B)0.25至3.0重量%的碱金属氧代铝酸盐、或氰酸、异氰酸、硫氰酸或偏硼酸的碱金属盐、或其混合物,
基于100重量%的A)和B)计,以及
C)0至70重量%的其他添加剂,其中A)至C)的重量%值之和为100%。
2.权利要求1的用途,包含的组分B)的量为35至250mmol/kg聚酯,基于A)和B)计,其中这些浓度数据基于各酸的阴离子计。
3.权利要求1或2的用途,其中所述模制品的激光透明度为至少33%,在1064nm下对厚度为2mm的模制品进行测量。
4.权利要求1或2的用途,其中组分B)的碱金属为钠。
5.权利要求1或2的用途,其中组分B)由氰酸钠、硫氰酸钠、偏硼酸钠、铝酸钠、或其混合物组成。
6.一种制备焊接模制品的方法,所述方法包括使用激光透射焊接将权利要求1至5之一的用途的激光透明模制品与激光吸收模制品接合。
7.根据权利要求1至5之一的用途的或根据权利要求6的方法获得的焊接模制品,所述模制品适用于电气、电子、电信、信息技术、计算机、家用、运动、医疗、汽车或娱乐领域。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11157270.7 | 2011-03-08 | ||
EP11157270 | 2011-03-08 | ||
PCT/EP2012/053694 WO2012119967A1 (de) | 2011-03-08 | 2012-03-05 | Lasertransparente polyester mit anorganischen salzen |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103415563A CN103415563A (zh) | 2013-11-27 |
CN103415563B true CN103415563B (zh) | 2015-09-16 |
Family
ID=45787212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201280012442.7A Active CN103415563B (zh) | 2011-03-08 | 2012-03-05 | 含有无机盐的激光透明聚酯 |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP2683765B1 (zh) |
JP (1) | JP5868434B2 (zh) |
KR (1) | KR101925654B1 (zh) |
CN (1) | CN103415563B (zh) |
BR (1) | BR112013021248B1 (zh) |
MY (1) | MY163123A (zh) |
WO (1) | WO2012119967A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2949703A1 (de) | 2014-05-28 | 2015-12-02 | Basf Se | Lasertransparente polyester |
JP6993971B2 (ja) * | 2016-07-15 | 2022-01-14 | ポリプラスチックス株式会社 | レーザー溶着用樹脂組成物及び成形品、複合成形品及びその製造方法、並びにレーザー光透過性向上方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1863870A (zh) * | 2003-10-07 | 2006-11-15 | 胜技高分子株式会社 | 激光熔敷用树脂组合物和成形品 |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3651014A (en) | 1969-07-18 | 1972-03-21 | Du Pont | Segmented thermoplastic copolyester elastomers |
US4148846A (en) | 1970-09-10 | 1979-04-10 | Rohm And Haas Company | Acrylic modifiers for polycarbonamides |
DE2842005A1 (de) | 1978-09-27 | 1980-04-10 | Bayer Ag | Polycarbonate mit alkylphenyl-endgruppen, ihre herstellung und ihre verwendung |
US4349505A (en) | 1980-07-01 | 1982-09-14 | The United States Of America As Represented By The Department Of Energy | Neutral beamline with ion energy recovery based on magnetic blocking of electrons |
DE3039114A1 (de) | 1980-10-16 | 1982-05-13 | Bayer Ag, 5090 Leverkusen | Thermoplastische polyester-formmassen mit verbesserter zaehigkeit |
US4405741A (en) | 1982-09-20 | 1983-09-20 | Plastics Engineering Company | Fast crystallizing polyalkyleneterephthalate resin compositions |
DE3334782A1 (de) | 1983-04-19 | 1984-10-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von polydiorganosiloxanen mit hydroxyaryloxy-endgruppen |
DE3506472A1 (de) | 1985-02-23 | 1986-08-28 | Bayer Ag, 5090 Leverkusen | Neue polydiorganosiloxan-polycarbonat-blockcopolymere |
DE3524234A1 (de) | 1985-07-06 | 1987-01-08 | Bayer Ag | Neue pfropfpolymerisate und deren abmischungen mit polyamiden |
DE3606982A1 (de) | 1986-03-04 | 1987-09-10 | Bayer Ag | Pfropfpolymerisate auf kautschukpolymeren mit blockartiger struktur |
DE3725576A1 (de) | 1987-08-01 | 1989-02-09 | Bayer Ag | Formmassen aus aromatischem polyester und gepfropftem silikonkautschuk |
JPH01146958A (ja) | 1987-12-04 | 1989-06-08 | Polyplastics Co | 熱可塑性樹脂組成物 |
DE3800603A1 (de) | 1988-01-12 | 1989-07-20 | Bayer Ag | Formmassen aus aromatischen polyestern, vinyl-copolymerisaten und gepfropftem siliconkautschuk |
DE3836176A1 (de) | 1988-10-24 | 1990-05-03 | Bayer Ag | Polymermischungen |
JPH03100017A (ja) * | 1989-09-12 | 1991-04-25 | Diafoil Co Ltd | ポリエステルの製造方法 |
JP3146049B2 (ja) * | 1992-01-14 | 2001-03-12 | 電気化学工業株式会社 | 熱可塑性樹脂組成物 |
DE4401055A1 (de) | 1994-01-15 | 1995-07-20 | Basf Ag | Verfahren zur Herstellung von thermoplastischen Polyestern mit niedrigem Carboxylendgruppengehalt |
US5521258A (en) | 1994-11-14 | 1996-05-28 | General Electric Company | Autoclave resistant blends of poly(ester-carbonate) and polyetherimide resins |
JPH09208810A (ja) * | 1996-01-31 | 1997-08-12 | Polyplastics Co | ポリエステル樹脂組成物 |
US6151180A (en) | 1998-04-15 | 2000-11-21 | Samsung Electronics Co., Ltd. | Method and apparatus for detecting defects on a disk in a hard disk drive |
DE10054859A1 (de) | 2000-11-06 | 2002-05-08 | Basf Ag | Verfahren zum Verbinden von Formteilen |
CN1244620C (zh) | 2000-11-13 | 2006-03-08 | 纳幕尔杜邦公司 | 适合激光焊接的着色热塑性树脂组合物,其所用蒽醌着色剂及其模塑制品 |
DE10151847A1 (de) * | 2001-10-24 | 2003-05-08 | Bayer Ag | Laserabsorbierende russarme Formmassen |
JP4456392B2 (ja) | 2003-03-28 | 2010-04-28 | ウィンテックポリマー株式会社 | レーザー溶着用樹脂組成物及び成形品 |
DE10330722A1 (de) | 2003-07-08 | 2005-02-10 | Bayer Ag | Laserdurchstrahlschweißbare thermoplastische Formmassen auf Basis einer Mischung von mindestens zwei Thermoplasten |
JP4565958B2 (ja) * | 2003-10-07 | 2010-10-20 | ウィンテックポリマー株式会社 | レーザ溶着用樹脂組成物及び成形品 |
BRPI0508433B1 (pt) | 2004-03-04 | 2012-12-25 | materiais plÁsticos tingidos por corantes de modo transparente, translécido ou opaco, uso de partÍculas em nanoescala e processos para produÇço e solda do mesmo. | |
JP2007169358A (ja) | 2005-12-20 | 2007-07-05 | Mitsubishi Engineering Plastics Corp | レーザー溶着用ポリエステル樹脂組成物およびこれを用いた成形品 |
JP2007186584A (ja) | 2006-01-13 | 2007-07-26 | Mitsubishi Engineering Plastics Corp | レーザー溶着用ポリエステル樹脂組成物およびこれを用いた成形品 |
JP5245265B2 (ja) | 2006-09-27 | 2013-07-24 | 東レ株式会社 | レーザー溶着用ポリエステル樹脂組成物および複合成形体 |
JP2008163167A (ja) | 2006-12-28 | 2008-07-17 | Toray Ind Inc | レーザー溶着用変性ポリエステル樹脂組成物およびそれを用いた複合成形体 |
CN102850730B (zh) * | 2007-06-13 | 2014-10-15 | 胜技高分子株式会社 | 激光透射性树脂成形品及其复合成形品 |
DE102007029239A1 (de) * | 2007-06-22 | 2008-12-24 | Grafe Color Batch Gmbh | Mechanisch verstärktes thermoplastisches Kunststofferzeugnis für laserbasierte Fügeverfahren |
JP2009019134A (ja) | 2007-07-12 | 2009-01-29 | Mitsubishi Engineering Plastics Corp | レーザー溶着用ポリエステル樹脂組成物及びそれを用いた成形品 |
FR2922149B1 (fr) * | 2007-10-10 | 2011-06-10 | Alstom Transport Sa | Procede de soudage de deux elements en materiau polymere opaques et resistant a haute temperature |
JP5107793B2 (ja) * | 2008-05-27 | 2012-12-26 | 花王株式会社 | ポリ乳酸樹脂射出成形体の製造方法 |
-
2012
- 2012-03-05 EP EP12706854.2A patent/EP2683765B1/de active Active
- 2012-03-05 BR BR112013021248-9A patent/BR112013021248B1/pt active IP Right Grant
- 2012-03-05 MY MYPI2013003089A patent/MY163123A/en unknown
- 2012-03-05 CN CN201280012442.7A patent/CN103415563B/zh active Active
- 2012-03-05 KR KR1020137026085A patent/KR101925654B1/ko active IP Right Grant
- 2012-03-05 JP JP2013557055A patent/JP5868434B2/ja active Active
- 2012-03-05 WO PCT/EP2012/053694 patent/WO2012119967A1/de active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1863870A (zh) * | 2003-10-07 | 2006-11-15 | 胜技高分子株式会社 | 激光熔敷用树脂组合物和成形品 |
Also Published As
Publication number | Publication date |
---|---|
CN103415563A (zh) | 2013-11-27 |
KR101925654B1 (ko) | 2019-02-27 |
EP2683765A1 (de) | 2014-01-15 |
EP2683765B1 (de) | 2014-11-26 |
KR20140013016A (ko) | 2014-02-04 |
JP5868434B2 (ja) | 2016-02-24 |
BR112013021248B1 (pt) | 2021-04-20 |
WO2012119967A1 (de) | 2012-09-13 |
BR112013021248A2 (pt) | 2020-06-30 |
JP2014507540A (ja) | 2014-03-27 |
MY163123A (en) | 2017-08-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102892819B (zh) | 激光透明性聚酯 | |
CN103415565A (zh) | 含有羧酸盐的激光透明聚酯 | |
CN102939195B (zh) | 包含有机添加剂的激光透明性pbt | |
CN103619931A (zh) | 含有碱金属亚硝酸盐的激光透明聚酯 | |
CN103415563B (zh) | 含有无机盐的激光透明聚酯 | |
CN105073863B (zh) | 用于型材挤出和/或管材挤出的聚酯 | |
US9562143B2 (en) | Laser-transparent polyesters with carboxylic salts | |
CN103415566B (zh) | 激光透明性聚酯 | |
US8859664B2 (en) | Laser-transparent polyesters with alkali metal nitrites | |
US8791179B2 (en) | Laser-transparent polyesters | |
CN105658716A (zh) | 阻燃聚酯 | |
US8618201B2 (en) | Laser-transparent polyesters with inorganic salts |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |