CN103402866A - 用于保护表面免受附着物的方法 - Google Patents

用于保护表面免受附着物的方法 Download PDF

Info

Publication number
CN103402866A
CN103402866A CN2012800056701A CN201280005670A CN103402866A CN 103402866 A CN103402866 A CN 103402866A CN 2012800056701 A CN2012800056701 A CN 2012800056701A CN 201280005670 A CN201280005670 A CN 201280005670A CN 103402866 A CN103402866 A CN 103402866A
Authority
CN
China
Prior art keywords
fiber
described method
paper tinsel
item
flocking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012800056701A
Other languages
English (en)
Inventor
S·希尔勒雷乌克斯
T·阿加德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UNIFLOCKAGE SAS
Renolit SE
UNIFLOCKAGE S SA
Original Assignee
UNIFLOCKAGE SAS
Renolit SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UNIFLOCKAGE SAS, Renolit SE filed Critical UNIFLOCKAGE SAS
Publication of CN103402866A publication Critical patent/CN103402866A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B59/00—Hull protection specially adapted for vessels; Cleaning devices specially adapted for vessels
    • B63B59/04—Preventing hull fouling
    • B63B59/045—Preventing hull fouling by wrapping the submerged hull or part of the hull with an impermeable sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0017—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor characterised by the choice of the material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1618—Non-macromolecular compounds inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3067—Ships
    • B29L2031/307—Hulls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B32B2037/1215—Hot-melt adhesive
    • B32B2037/1223—Hot-melt adhesive film-shaped
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2248—Oxides; Hydroxides of metals of copper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
    • C08K5/47—Thiazoles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/204—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Ocean & Marine Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Toxicology (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Dentistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paper (AREA)

Abstract

本发明涉及用于保护通常位于水下的表面免受附着物的方法，其中根据本发明，可变形的自粘合箔用纤维植绒并且施用在表面上。

Description

用于保护表面免受附着物的方法
本发明涉及用于保护通常位于水下，特别是位于海水下的表面免受附着物的方法。
船体和其他通常设置在水下的表面具有固着的植物和动物生物体例如藻类、贝壳类、藤壶类的附着物是巨大的问题。已经存在许多用于保护免受附着物的不同提议。例如“Antifouling Produktliste2010”（Bewuchs-Atlas e.V.，第1版，2010年发行）提供了概述。
特别感兴趣的是不需要或至少仅需要少量化学有效成分的保护方法。其中包括具有纤维的涂层，例如上述公开物第31/32页或EP643657以及EP1964620中所述。然而，将纤维施用于船体是昂贵的。
因此,进一步的目的在于提供有效的保护免受附着物，所述保护可以简单和廉价地施用，足够长期地生效并且需要尽可能少的进入环境并且可能损害环境的有效成分。
目前出人意料地发现，有可能通过可变形的自粘合箔通过植绒（Beflockung）实现所述目的。
因此，本发明通过用于保护通常位于水下的表面免受附着物的方法实现上述目的，其中提供可变形的自粘合箔、植绒并且将箔粘合在表面上。
由于箔可变形，其也可以精确粘合在弯曲表面例如船体上。用粘合剂涂布间隙然后在船体上植绒（例如EP1964620）是不必要的。不同于EP643657，仅需要借助于粘着剂使箔与表面结合的操作过程。
用于保护免受附着物的可变形的自粘合箔本身是已知的。然而，根据现有技术所述箔配置有尽可能平滑的表面，从而避免附着物生物体的粘附并且保证较低的流动阻力。所有足够耐磨、耐盐水和UV-稳定的塑料适合作为所述箔的材料。用于根据本发明的箔的优选材料为聚氯乙烯（PVC）、聚氨酯（PU）、丁二烯和异戊二烯基聚合物、聚烯烃例如聚乙烯（PE）和聚丙烯（PP）。特别优选基于乙烯基单体的聚合物，特别是聚氯乙烯（PVC）。也良好适用的是基于PVC和/或乙烯乙酸乙烯酯（EVA）的箔。
箔可以以本身已知的方式具有以常规量使用的添加剂和添加物。优选地，在PVC-箔的情况下，例如包含增塑剂、稳定剂和（如果需要）颜料和/或染料。在悬浮体-PVC（S-PVC）中，通常为例如60–70重量%的PVC；5–10重量%的EVA；15–25重量%的聚合物增塑剂，2.0–3.0重量%的钡/锌稳定剂；5–10重量%的改性剂和0.5–1.0重量%的遮光剂。颜料/染料的量取决于期望的颜色。有可能在箔材料中加入杀生物剂有效成分。
在本发明的范围内，可变形意指箔具有至少200%的断裂伸长。2%模量为15至25N/15mm。抗张强度为25至40N/15mm。断裂伸长、2%模量和抗张强度根据DIN EN5273/2/200测量。
根据本发明的箔的制备以本身已知的方式例如在压延机上进行。可以具有二、三或更多层的多层箔通过共挤出、直接挤出或层压而获得。这些方法是本领域技术人员已知的。
箔用粘着剂涂布，使其可以直接粘合在待保护的表面上。原则上，显示出足够的耐海水性以及与箔和与金属、木材、油漆等表面的良好粘着的所有粘合剂都适合。优选使用基于丙烯酸酯的粘着剂。在一个优选的实施方案中，在粘着剂中加入杀生物剂有效成分，例如Cu2O、异噻唑啉酮和/或吡硫翁。
为了植绒，使用适合与水长期接触的粘合剂和纤维。例如聚酰胺纤维和聚酯纤维良好适合作为纤维。然而，铜纤维、银纤维或在纤维中和/或在纤维上具有杀生物剂有效成分的纤维也是有利的。具有杀生物剂有效成分的纤维是本身已知的并且目前用于药学。根据本发明适合的是这种纤维，所述纤维具有一定含量的氧化亚铜、异噻唑啉酮、吡硫翁和其他本身已知的杀生物剂（特别是杀藻剂）的有效成分，和/或具有包含氧化亚铜、异噻唑啉酮、吡硫翁和其他本身已知的杀生物剂（特别是杀藻剂）的有效成分的涂层。在纤维中构入一种或多种有效成分保证作用时间的延长，因为表面上由于冲洗而损失的有效成分随后可以从纤维内部渗出。同样有可能的是，在纤维中构入第一种有效成分并且以涂层的形式施用另一种有效成分。
在一个优选的变体中使用纤维混合物，从而获得具有疏水纤维和亲水纤维的纤维网。在此，亲水纤维的表面张力（根据DIN53364测量）应为>50dyn，优选>60dyn，疏水纤维的表面张力（根据DIN53364测量）应为<30dyn，优选<20dyn。
通常的纤维长度为0.1至8mm，优选0.3至5mm和特别优选0.5至3mm。聚合物纤维的纤维强度应为1.5至100dtex，优选2至50dtex，金属纤维的纤维强度应为5至100dtex。优选的直径为10至100μm，优选30至70μm。
植绒以100至500纤维/mm2，优选150至250纤维/mm2的纤维密度进行。
作为用于固定纤维的粘合剂，选择与箔匹配的耐海水的粘合剂。适用于PVC-箔的为例如常规用于制备植绒T恤的塑料溶胶。通常的配方包含PVC、增塑剂、填料和增粘剂。
在一个优选的变体中，在纤维固定于其中的粘合剂中加入杀生物剂，例如氧化亚铜或异噻唑啉酮例如4,5-二氯-2-正辛基-异噻唑啉-3-酮。杀生物剂的混合物也是可能的。
为了制备根据本发明的用于保护所使用的箔，首先用粘着剂自粘合地配置可变形的箔。粘着剂优选用剥离衬里例如硅化纸覆盖。然后用用于固定纤维的粘合剂涂布自粘合的箔，然后以本身已知的方式植绒。然后通常将箔卷绕在辊子上并储存。
为了施用于待保护的表面，在必要时对表面进行清洗，从而除去粘附性附着物和/或污物。表面应干净、无油脂和干燥。任选在剪裁和/或揭除剥离衬里之后，将箔铺设在表面上并且施压。
箔优选接缝粘合。可以通过相应剪裁的箔片简单并迅速地封闭相邻箔幅面之间的空隙。为此无需具有粘合剂的涂层，因此在已经施用的经植绒的箔中，也不存在纤维被粘合剂粘合的危险。同样有可能的是，形成无纤维的窄条形式的箔的边缘，并且以重叠方式粘合箔。在另一个变体中可想到的是，在粘合之后在跨越接缝的条中除去纤维，并且用经植绒的箔条覆盖接缝。在此，所述条可以具有与箔相同的构造，或者例如在使用杀生物剂时具有更高的杀生物剂浓度或者尤其是具有杀生物剂。
根据本发明的箔特别适合用于保护接触海水的部件，例如船舶、离岸设备、浮标等。由于粘着剂和可变形性，所述箔可以容易地施用。另一优点在于，需要时所述箔可以比常规涂层更容易地从表面去除。必要时所述箔可以通过热作用而揭除。
借助于如下实施例解释本发明，但是不将本发明限制于具体描述的实施方案。除非另有声明或者上下文中另有强制性解释，百分数以重量计，不确定时以混合物的总重量计。
本发明还涉及优选实施方案的全部组合，除非这些实施方案相互矛盾。与数值结合的表述“约”或“大约”意指包括至少高或低10%的值，或高或低5%的值，和无论如何高或低1%的值。
实施例1
在压延机上制备箔。箔配方包含：K-值为80的54.7重量%的PVC；8.5重量%的乙烯-乙酸乙烯酯共聚物；1.8重量%的丙烯酸酯-改性剂；21.5重量%的聚合物增塑剂；2.5重量%的稳定剂；1.7重量%的共稳定剂；8.5重量%的二氧化钛；0.7重量%的遮光剂和0.1重量%的润滑剂。所述箔首先用基于丙烯酸酯的粘着剂涂布，并且所述粘着剂用硅化纸覆盖。然后为了固定纤维，施用由100份PVC（Solvin NA）、52份DIDP和40份CaCO3（包含7%的含异氰酸酯的助粘剂）组成的塑料溶胶。在塑料溶胶中，20份填料CaCO3用氧化亚铜部分地替代，所述氧化亚铜与约1%的Cu2O量的异噻唑啉酮或吡硫翁混合。以本身已知的方式用表1中给出的纤维对箔进行植绒。
表1
Figure BDA00003527901700051
*4,5-二氯-2-正辛基-异噻唑啉-3-酮
所述箔可以良好施用于船体。
实施例2
将编号1、4、5、9、10和11的箔粘合在金属板上并研究防附着作用。为此，将这些板固定在可旋转盘的周围，所述可旋转盘设置在东南印度洋中。为了进行研究，所述盘连续旋转或者交替地一个月旋转一个月不旋转。在旋转时通过盘的转速和周长得出这些板上流过的水的速度为20海里/小时（约38/小时）。每个月将这些板和盘从水中取出一次并且研究表面的附着物。拍摄照片，计数藤壶类的数量并且记录具有藻类以及其他海生生物的附着物。然后再次将所述盘放置在海洋中直至下一次研究。结果同样列于表2中。
表2
Figure BDA00003527901700061
在一些情况（箔4、9和10）下发现少量藻类，在四种情况（箔9和10）下发现具有藻类的稍多的附着物。所有情况下均未附着藤壶类，而未用根据本发明的箔进行保护的板的边缘分别在更短的时间内（通常3个月后，部分地仅在一个月后）就被藤壶类附着。
箔9（动态）和10（交替）的照片显示在图1和2中。

Claims (15)

1.用于保护通常位于水下的表面免受附着物的方法，其特征在于，可变形的自粘合箔用纤维植绒并且施用在表面上。
2.根据权利要求1所述的方法，其特征在于，所述表面为船体。
3.根据权利要求1或2所述的方法，其特征在于，纤维配置有一种或多种杀生物剂。
4.根据权利要求1至3至少一项所述的方法，其特征在于，植绒所使用的粘合剂配置有一种或多种杀生物剂。
5.根据权利要求1至4至少一项所述的方法，其特征在于，使箔自粘合的粘着剂配置有一种或多种杀生物剂。
6.根据权利要求1至5至少一项所述的方法，其特征在于，箔配置有一种或多种杀生物剂。
7.根据权利要求3至6至少一项所述的方法，其特征在于，杀生物剂选自氧化亚铜（I）、异噻唑啉酮、吡硫翁及其混合物。
8.根据权利要求1至7至少一项所述的方法，其特征在于，作为纤维使用聚酰胺纤维、聚酯纤维、银纤维或铜纤维或其混合物。
9.根据权利要求1至8至少一项所述的方法，其特征在于，使用纤维混合物从而获得具有疏水纤维和亲水纤维的纤维网，其中亲水纤维的表面张力（根据DIN53364测量）>50dyn且疏水纤维的表面张力（根据DIN53364测量）<30dyn。
10.根据权利要求1至9至少一项所述的方法，其特征在于，选择长度为0.1至8mm，优选0.3至5mm且特别优选0.5至3mm的纤维。
11.根据权利要求1至10至少一项所述的方法，其特征在于，选择直径为10至100μm，优选30至70μm的纤维。
12.根据权利要求1至11至少一项所述的方法，其特征在于，植绒以100至500纤维/mm2的纤维密度进行。
13.根据权利要求1至12至少一项所述的方法，其特征在于，箔接缝粘合。
14.根据权利要求13所述的方法，其特征在于，在接缝范围内除去纤维或者不施用纤维，并且用条遮掩接缝。
15.根据权利要求1至12至少一项所述的方法，其特征在于，箔形成有不含纤维的边缘区域并且以重叠方式粘合。
CN2012800056701A 2011-02-25 2012-02-22 用于保护表面免受附着物的方法 Pending CN103402866A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102011012517.5 2011-02-25
DE102011012517A DE102011012517A1 (de) 2011-02-25 2011-02-25 Verfahren zum Schutz von Oberflächen vor Bewuchs
PCT/EP2012/000799 WO2012113562A1 (de) 2011-02-25 2012-02-22 Verfahren zum schutz von oberflächen vor bewuchs

Publications (1)

Publication Number Publication Date
CN103402866A true CN103402866A (zh) 2013-11-20

Family

ID=45771773

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012800056701A Pending CN103402866A (zh) 2011-02-25 2012-02-22 用于保护表面免受附着物的方法

Country Status (7)

Country Link
US (1) US20130048211A1 (zh)
EP (1) EP2678218A1 (zh)
KR (1) KR20140005173A (zh)
CN (1) CN103402866A (zh)
CA (1) CA2827149A1 (zh)
DE (1) DE102011012517A1 (zh)
WO (1) WO2012113562A1 (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10064273B2 (en) 2015-10-20 2018-08-28 MR Label Company Antimicrobial copper sheet overlays and related methods for making and using
US20230235196A1 (en) * 2020-06-09 2023-07-27 Kegham Alex DANTZIGUIAN Anti-bacterial and/or anti-viral tape
KR102475472B1 (ko) * 2021-07-23 2022-12-06 함명수 선박 도장면 보호용 필름
EP4321425A1 (en) * 2022-08-11 2024-02-14 OCEAN-Tape GmbH Roll with self-fusing and antifouling protection tape and use of the tape for wrapping objects

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668323A (en) * 1984-04-17 1987-05-26 Uniroyal Englebert Textilcord S.A. Method of making flexible, fiber-covered, sheet-like textile article
US4895881A (en) * 1976-11-25 1990-01-23 Extensor Ab Coating composition
US5116655A (en) * 1988-07-28 1992-05-26 Tuguo Ezoe Preventive method against apposition of a marine organism and a preventive sheet against apposition of a marine organism
US5618588A (en) * 1992-06-05 1997-04-08 Sealflock Aktiebolag Coating on marine constructions
US20020009555A1 (en) * 1997-06-26 2002-01-24 Weder Donald E. Ribbon material formed of polymeric materials having a texture or appearance simulating the texture or appearance of paper
US20070289688A1 (en) * 2000-07-24 2007-12-20 High Voltage Graphics, Inc. Processes for precutting laminated flocked articles
EP1964620A1 (en) * 2007-03-02 2008-09-03 Kjell K. Alm Method for providing a fouling preventing coating
CN101443230A (zh) * 2006-03-21 2009-05-27 材料创新中心有限公司 用于水下结构的防污纤维包覆层

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57104492A (en) * 1980-12-19 1982-06-29 Hiromi Koga Device to prevent adhesion of barnacle etc. to ship
JPS6051106A (ja) * 1983-08-31 1985-03-22 Yamanouchi Pharmaceut Co Ltd 塩酸アモスラロ−ル持続性製剤
KR920008843B1 (ko) * 1987-04-30 1992-10-10 도오레 가부시끼가이샤 생물부착 방지성이 뛰어난 수산자재와 그의 제조방법
JPH02274911A (ja) * 1989-04-17 1990-11-09 Tsugio Ezoe 貝類付着防止シート
SE503048C2 (sv) * 1994-07-28 1996-03-18 Seal Flock Ab Beväxningsskydd för marina konstruktioner
US20080176036A1 (en) * 2003-04-25 2008-07-24 Mitchell Melvin G Micro-perforated laminae and method
US20040241433A1 (en) * 2003-06-02 2004-12-02 Raytheon Company Antifouling tape and method of application and removal
US20070224395A1 (en) * 2006-03-24 2007-09-27 Rowitsch Robert W Sprayable water-based adhesive
FR2912417A1 (fr) * 2007-02-08 2008-08-15 Hexis Sa Methode de protection antimicrobienne d'une surface d'un objet a l'aide d'un film plastique auto adhesif antimicorbien

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4895881A (en) * 1976-11-25 1990-01-23 Extensor Ab Coating composition
US4668323A (en) * 1984-04-17 1987-05-26 Uniroyal Englebert Textilcord S.A. Method of making flexible, fiber-covered, sheet-like textile article
US5116655A (en) * 1988-07-28 1992-05-26 Tuguo Ezoe Preventive method against apposition of a marine organism and a preventive sheet against apposition of a marine organism
US5618588A (en) * 1992-06-05 1997-04-08 Sealflock Aktiebolag Coating on marine constructions
US20020009555A1 (en) * 1997-06-26 2002-01-24 Weder Donald E. Ribbon material formed of polymeric materials having a texture or appearance simulating the texture or appearance of paper
US20070289688A1 (en) * 2000-07-24 2007-12-20 High Voltage Graphics, Inc. Processes for precutting laminated flocked articles
CN101443230A (zh) * 2006-03-21 2009-05-27 材料创新中心有限公司 用于水下结构的防污纤维包覆层
EP1964620A1 (en) * 2007-03-02 2008-09-03 Kjell K. Alm Method for providing a fouling preventing coating

Also Published As

Publication number Publication date
CA2827149A1 (en) 2012-08-30
DE102011012517A1 (de) 2012-08-30
WO2012113562A1 (de) 2012-08-30
US20130048211A1 (en) 2013-02-28
EP2678218A1 (de) 2014-01-01
KR20140005173A (ko) 2014-01-14

Similar Documents

Publication Publication Date Title
RU2012123715A (ru) Покрытие для силоса
EP3470476B1 (en) Self adhesive fouling release coating composition
CN103402866A (zh) 用于保护表面免受附着物的方法
EP3521389A1 (en) Coating film for structure, coating material set for forming coating film, coating material for undercoat layer, and coating method
JP5161201B2 (ja) 海洋構築物のための防汚性繊維被覆
US7887654B2 (en) Biocide-free anti-fouling coating containing a fabric based on basalt fibers
Lin et al. Submerged surfaces exposed to marine biofouling–Experimental investigation of cleaning parameters effectiveness
US20100050924A1 (en) Method for providing a fouling preventing coating
EP1360107B1 (en) Structure that counteracts bio-fouling in aquatic environments
JPH11279456A (ja) 防汚シート
JP4551963B1 (ja) 貝類付着防止方法及び貝類付着防止塗布構造体
JP6963459B2 (ja) コンクリート養生テープ
JP2016023306A (ja) 水生生物付着防止粘着テープまたはシート
KR20110136191A (ko) 선박용 자기 마모형 방오 필름테이프 제조 방법
JP2014234413A (ja) 防汚用粘着シート
CN202671479U (zh) 表面保护片
EP4321425A1 (en) Roll with self-fusing and antifouling protection tape and use of the tape for wrapping objects
US20230391428A1 (en) An anti-fouling protective cover
CN104417729A (zh) 一种船用海洋生物附着防治装置
EP3778810A1 (en) Undercoat layer-forming composition, undercoat layer, and coating film
JPH10259258A (ja) 熱収縮フィルム
NL2012036C2 (en) Antifouling foil.
WO2023118480A1 (en) Self adhesive fouling release coating composition
JP2013129725A (ja) 水生生物付着防止粘着テープ
JPS5929603A (ja) 水中防汚方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20131120