CN103396660A - 一种制造abs/pla合金材料用的大分子相容剂的制备方法 - Google Patents
一种制造abs/pla合金材料用的大分子相容剂的制备方法 Download PDFInfo
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- CN103396660A CN103396660A CN2013103107237A CN201310310723A CN103396660A CN 103396660 A CN103396660 A CN 103396660A CN 2013103107237 A CN2013103107237 A CN 2013103107237A CN 201310310723 A CN201310310723 A CN 201310310723A CN 103396660 A CN103396660 A CN 103396660A
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- Prior art keywords
- pla
- abs
- preparation
- alloy material
- polylactic acid
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- Granted
Links
- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 62
- 239000004626 polylactic acid Substances 0.000 title claims abstract description 34
- 239000000956 alloy Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title abstract description 28
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title abstract description 28
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 8
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims abstract description 7
- 238000012662 bulk polymerization Methods 0.000 claims abstract description 6
- 239000004593 Epoxy Substances 0.000 claims abstract description 5
- 239000003999 initiator Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 13
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 12
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 12
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 9
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 9
- -1 diacrylate glycidyl ester Chemical class 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 6
- 125000003700 epoxy group Chemical group 0.000 claims description 5
- CRDXYYZBHXDEKG-UHFFFAOYSA-N C=C.C1=CC=CC=C1.Cl Chemical compound C=C.C1=CC=CC=C1.Cl CRDXYYZBHXDEKG-UHFFFAOYSA-N 0.000 claims description 4
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 claims description 4
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 4
- XNYYNDAEXFUXBD-UHFFFAOYSA-N tert-butylbenzene ethene Chemical compound C=C.C(C)(C)(C)C1=CC=CC=C1 XNYYNDAEXFUXBD-UHFFFAOYSA-N 0.000 claims description 4
- SDAXRHHPNYTELL-UHFFFAOYSA-N heptanenitrile Chemical compound CCCCCCC#N SDAXRHHPNYTELL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 9
- 239000004793 Polystyrene Substances 0.000 abstract description 4
- 229920002223 polystyrene Polymers 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract 2
- 238000003754 machining Methods 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 9
- 238000004821 distillation Methods 0.000 description 8
- 239000002244 precipitate Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000001953 recrystallisation Methods 0.000 description 8
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000034530 PLAA-associated neurodevelopmental disease Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Images
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- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310310723.7A CN103396660B (zh) | 2013-07-18 | 2013-07-18 | 一种制造abs/pla合金材料用的大分子相容剂的制备方法 |
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CN201310310723.7A CN103396660B (zh) | 2013-07-18 | 2013-07-18 | 一种制造abs/pla合金材料用的大分子相容剂的制备方法 |
Publications (2)
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CN103396660A true CN103396660A (zh) | 2013-11-20 |
CN103396660B CN103396660B (zh) | 2015-05-13 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105504656A (zh) * | 2016-01-04 | 2016-04-20 | 王文广 | 一种生物质塑料合金材料 |
CN107118309A (zh) * | 2017-06-26 | 2017-09-01 | 浙江海轩科技有限公司 | 一种生物可降解聚酯合金及其制备方法 |
CN116554608A (zh) * | 2023-05-04 | 2023-08-08 | 博特尔包装(江苏)有限公司 | 一种可降解聚苯乙烯包装材料的制备工艺 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010070628A (ja) * | 2008-09-18 | 2010-04-02 | Toagosei Co Ltd | 相溶化剤 |
CN102040813A (zh) * | 2010-12-29 | 2011-05-04 | 深圳市科聚新材料有限公司 | 一种聚乳酸-abs树脂复合材料及其制备方法 |
CN102597108A (zh) * | 2009-10-30 | 2012-07-18 | 普立万公司 | 耐热性pla-abs组合物 |
-
2013
- 2013-07-18 CN CN201310310723.7A patent/CN103396660B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010070628A (ja) * | 2008-09-18 | 2010-04-02 | Toagosei Co Ltd | 相溶化剤 |
CN102597108A (zh) * | 2009-10-30 | 2012-07-18 | 普立万公司 | 耐热性pla-abs组合物 |
CN102040813A (zh) * | 2010-12-29 | 2011-05-04 | 深圳市科聚新材料有限公司 | 一种聚乳酸-abs树脂复合材料及其制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105504656A (zh) * | 2016-01-04 | 2016-04-20 | 王文广 | 一种生物质塑料合金材料 |
CN107118309A (zh) * | 2017-06-26 | 2017-09-01 | 浙江海轩科技有限公司 | 一种生物可降解聚酯合金及其制备方法 |
CN116554608A (zh) * | 2023-05-04 | 2023-08-08 | 博特尔包装(江苏)有限公司 | 一种可降解聚苯乙烯包装材料的制备工艺 |
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CN103396660B (zh) | 2015-05-13 |
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Address after: Yuhang District of the city of Hangzhou in West Zhejiang province 311121 high-level personnel innovation park of Zhejiang Province Overseas No. 998 building 19 floor 6 Room 606 Hangzhou CXS new Mstar Technology Ltd Patentee after: HANGZHOU ECODOUBLE HEALTH TECHNOLOGY CO., LTD. Address before: Yuhang District of the city of Hangzhou in West Zhejiang province 311121 high-level personnel innovation park of Zhejiang Province Overseas No. 998 building 19 floor 6 Room 606 Hangzhou CXS new Mstar Technology Ltd Patentee before: Hangzhou Xusheng New Material Science & Technology Co., Ltd. |
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Address after: Futian District Shenzhen City, Guangdong province 518000 Shennan Road No. 6031 HANGGANG Fuchun business building room 2521 Patentee after: Shenzhen Lvtang Technology Co., Ltd. Address before: 518000 Guangdong city of Shenzhen province Futian District Shennan Road South Tairan nine Road West hi center A block 1505 years Patentee before: SHENZHEN LYUTANG COMMODITY CO., LTD. |
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Address after: 511455 Guangdong Province Nansha District Huangge Town South Highway Huangge Section 230 self-compiled four alloy 206 Patentee after: Guangdong Green Sugar Technology Co., Ltd. Address before: Room 2521, Fuchun Business Building, Hangzhou Steel, 6031 Shennan Avenue, Futian District, Shenzhen City, Guangdong Province, 518000 Patentee before: Shenzhen Lvtang Technology Co., Ltd. |
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