CN103354814B - 部分氟化的聚亚磺酸和它们的盐 - Google Patents

部分氟化的聚亚磺酸和它们的盐 Download PDF

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Publication number
CN103354814B
CN103354814B CN201180067281.7A CN201180067281A CN103354814B CN 103354814 B CN103354814 B CN 103354814B CN 201180067281 A CN201180067281 A CN 201180067281A CN 103354814 B CN103354814 B CN 103354814B
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icf
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monomer
composition
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CN103354814A (zh
Inventor
裘再明
格雷格·D·达尔克
福士达夫
沃纳·M·A·格鲁泰尔特
米格尔·A·格拉
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/16—Monomers containing bromine or iodine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/18—Monomers containing fluorine
    • C08F114/185—Monomers containing fluorine not covered by the groups C08F114/20 - C08F114/28
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/16—Monomers containing bromine or iodine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/182—Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/184—Monomers containing fluorine with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C08F28/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201180067281.7A 2010-12-17 2011-12-09 部分氟化的聚亚磺酸和它们的盐 Expired - Fee Related CN103354814B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201061424107P 2010-12-17 2010-12-17
US61/424,107 2010-12-17
PCT/US2011/064136 WO2012082546A1 (en) 2010-12-17 2011-12-09 Partially fluorinated polysulfinic acids and their salts

Publications (2)

Publication Number Publication Date
CN103354814A CN103354814A (zh) 2013-10-16
CN103354814B true CN103354814B (zh) 2017-04-26

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Country Link
US (1) US9580526B2 (enExample)
EP (1) EP2651985B1 (enExample)
JP (1) JP5837610B2 (enExample)
CN (1) CN103354814B (enExample)
WO (1) WO2012082546A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012082703A2 (en) * 2010-12-17 2012-06-21 3M Innovative Properties Company Preparation of oligomers and co-oligomers of highly fluorinated sulfinic acids and salts thereof
CN103443210B (zh) 2010-12-17 2016-04-06 3M创新有限公司 具有侧链含溴部分的氟化低聚物
EP2651988B1 (en) * 2010-12-17 2014-10-22 3M Innovative Properties Company Oligomers and co-oligomers of highly fluorinated sulfinic acid and salts thereof
WO2012082551A2 (en) 2010-12-17 2012-06-21 3M Innovative Properties Company Partially fluorinated sulfinic acid monomers and their salts
JP5866375B2 (ja) 2010-12-17 2016-02-17 スリーエム イノベイティブ プロパティズ カンパニー スルフィネート含有分子を含むフッ素含有ポリマー
US8907125B2 (en) * 2010-12-17 2014-12-09 3M Innovative Properties Company Preparation of perfluorovinyl ether sulfinic acids and their salts
EP2714655B1 (en) 2011-06-03 2017-09-27 3M Innovative Properties Company Allyl ether-terminated fluoroalkanesulfinic acids, salts thereof, and a method of making the same
BR112014013837B1 (pt) 2011-12-16 2021-01-19 3M Innovative Properties Company composição de polímeros processável por fusão, seu artigo e composição de aditivo de fusão de polímero

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN1527845A (zh) * 2001-07-13 2004-09-08 ��Ļ���Ű˾ 生成氟化离聚物的方法
CN1738840A (zh) * 2003-01-24 2006-02-22 大金工业株式会社 可硫化的含氟弹性体的制造方法
CN1878826A (zh) * 2003-10-09 2006-12-13 3M创新有限公司 含氟聚合物的改性方法及其制品
CN101460549A (zh) * 2006-06-01 2009-06-17 纳幕尔杜邦公司 制备含氟聚合物分散体和膜的方法

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FR2388013B1 (fr) * 1977-04-20 1985-08-02 Du Pont Polymeres fluores echangeurs d'ions contenant des groupes carboxyliques, leur preparation et leur utilisation dans des cellules d'electrolyse chlore-alcali
US4267364A (en) * 1977-04-20 1981-05-12 E. I. Dupont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof
JPS5657832A (en) 1979-10-15 1981-05-20 Kanegafuchi Chem Ind Co Ltd Preparation of membrane structure for producing ion exchange membrane
JPS5834805A (ja) * 1981-08-24 1983-03-01 Tokuyama Soda Co Ltd カルボキシル基を有する含弗素化合物の製造方法
US5285002A (en) 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
US5639837A (en) 1996-06-04 1997-06-17 E. I. Du Pont De Nemours And Company Process for making fluoropolymers
DE69610099T2 (de) 1995-06-30 2001-05-10 E.I. Du Pont De Nemours And Co., Wilmington Verfahren zur herstellung von fluor-enthaltenden polymeren
GB9705120D0 (en) * 1997-03-12 1997-04-30 Zeneca Ltd Sulfur-containing acids and derivatives
CN1233668C (zh) * 1999-10-12 2005-12-28 迈克里斯公司 具有亲水官能团的氟烃聚合物及方法
CA2312194A1 (fr) 2000-06-13 2001-12-13 Mario Boucher Elastomeres reticulables fluores bromosulfones a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
DE10209784A1 (de) * 2001-09-01 2003-12-04 Univ Stuttgart Inst Fuer Chemi Sulfinatgruppen enthaltende Oligomere und Polymere und Verfahren zu ihrer Herstellung
JP4189630B2 (ja) * 2002-06-14 2008-12-03 ダイキン工業株式会社 含フッ素フルオロスルホニルアルキルビニルエーテルの製造方法
US7348088B2 (en) 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
JP2005104992A (ja) 2003-01-24 2005-04-21 Daikin Ind Ltd 加硫可能な含フッ素エラストマーの製造方法
JP2006131588A (ja) * 2004-11-09 2006-05-25 Asahi Kasei Corp 含フッ素スルフィン酸塩の製造方法
US8071254B2 (en) 2007-12-27 2011-12-06 E. I. Du Pont De Nemours And Company Crosslinkable fluoropolymer, crosslinked fluoropolymers and crosslinked fluoropolymer membranes
CN101733020B (zh) * 2009-12-10 2011-01-26 山东东岳神舟新材料有限公司 一种纤维增强的含氟交联离子膜及其制备方法
CN101733006B (zh) * 2009-12-10 2011-01-26 山东东岳神舟新材料有限公司 一种掺杂、纤维改性酰亚胺交联全氟离子交换膜
CN101709101B (zh) 2009-12-15 2011-09-07 山东东岳神舟新材料有限公司 高交换容量全氟离子交换树脂及其制备方法和用途
US8907125B2 (en) 2010-12-17 2014-12-09 3M Innovative Properties Company Preparation of perfluorovinyl ether sulfinic acids and their salts
BR112014013837B1 (pt) * 2011-12-16 2021-01-19 3M Innovative Properties Company composição de polímeros processável por fusão, seu artigo e composição de aditivo de fusão de polímero

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1527845A (zh) * 2001-07-13 2004-09-08 ��Ļ���Ű˾ 生成氟化离聚物的方法
CN1738840A (zh) * 2003-01-24 2006-02-22 大金工业株式会社 可硫化的含氟弹性体的制造方法
CN1878826A (zh) * 2003-10-09 2006-12-13 3M创新有限公司 含氟聚合物的改性方法及其制品
CN101460549A (zh) * 2006-06-01 2009-06-17 纳幕尔杜邦公司 制备含氟聚合物分散体和膜的方法

Also Published As

Publication number Publication date
EP2651985A1 (en) 2013-10-23
CN103354814A (zh) 2013-10-16
US9580526B2 (en) 2017-02-28
EP2651985B1 (en) 2016-03-23
JP2014512415A (ja) 2014-05-22
JP5837610B2 (ja) 2015-12-24
US20130281648A1 (en) 2013-10-24
WO2012082546A1 (en) 2012-06-21

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