CN103347845B - 制造不饱和醛和/或不饱和羧酸的方法 - Google Patents

制造不饱和醛和/或不饱和羧酸的方法 Download PDF

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CN103347845B
CN103347845B CN201280007615.6A CN201280007615A CN103347845B CN 103347845 B CN103347845 B CN 103347845B CN 201280007615 A CN201280007615 A CN 201280007615A CN 103347845 B CN103347845 B CN 103347845B
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catalyzer
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CN103347845A (zh
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仓上龙彦
松本进
须藤渥
白石一男
桥场正
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Nippon Kayaku Co Ltd
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Nippon Kayaku Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280007615.6A 2011-02-02 2012-01-16 制造不饱和醛和/或不饱和羧酸的方法 Active CN103347845B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2011-020783 2011-02-02
JP2011020783 2011-02-02
JP2011-020782 2011-02-02
JP2011020782 2011-02-02
PCT/JP2012/050730 WO2012105304A1 (ja) 2011-02-02 2012-01-16 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法

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CN103347845A CN103347845A (zh) 2013-10-09
CN103347845B true CN103347845B (zh) 2015-04-01

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CN201210023157.7A Active CN102627537B (zh) 2011-02-02 2012-02-02 不饱和醛和/或不饱和羧酸的制造方法

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US (1) US8969618B2 (enExample)
EP (1) EP2671862B1 (enExample)
JP (4) JPWO2012105304A1 (enExample)
CN (2) CN103347845B (enExample)
SA (1) SA112330234B1 (enExample)
TW (1) TWI507387B (enExample)
WO (1) WO2012105304A1 (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2012105304A1 (ja) * 2011-02-02 2014-07-03 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP2014019675A (ja) * 2012-07-20 2014-02-03 Nippon Kayaku Co Ltd 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
CN103772173B (zh) * 2012-10-23 2016-06-08 中国石油天然气股份有限公司 一种丙烯醛的制备方法
EP2990108A4 (en) * 2013-04-25 2017-03-08 Nippon Kayaku Kabushiki Kaisha Catalyst for producing unsaturated aldehyde and/or unsaturated carboxylic acid, method for producing catalyst, and method for producing unsaturated aldehyde and/or unsaturated carboxylic acid using catalyst
CN105209168B (zh) * 2013-05-09 2017-12-19 日本化药株式会社 不饱和醛和/或不饱和羧酸制造用催化剂、其制造方法以及不饱和醛和/或不饱和羧酸的制造方法
KR101819465B1 (ko) * 2013-07-18 2018-01-17 닛뽄 가야쿠 가부시키가이샤 불포화 알데히드 및/또는 불포화 카본산의 제조 방법
CN104649872B (zh) * 2013-11-19 2016-08-17 中国石油天然气股份有限公司 一种低碳烯烃选择性氧化的方法
JP6674441B2 (ja) * 2015-02-27 2020-04-01 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸製造用触媒及びその製造方法並びに不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP2016106082A (ja) * 2015-11-24 2016-06-16 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP6752035B2 (ja) * 2016-03-29 2020-09-09 日本化薬株式会社 再スタートアップ方法
EP3445738B1 (en) * 2016-04-21 2022-02-16 Rohm and Haas Company Methods for using macroporous inert materials in monomer production
WO2018181226A1 (ja) 2017-03-27 2018-10-04 三菱ケミカル株式会社 触媒及び触媒群
RU2735682C1 (ru) 2017-03-27 2020-11-05 Мицубиси Кемикал Корпорейшн Катализатор и катализаторная группа
CN108325534A (zh) * 2018-02-02 2018-07-27 上海东化环境工程有限公司 一种丙烯气相氧化制丙烯醛的催化剂及其应用
ES2922381T3 (es) * 2018-03-30 2022-09-14 Mitsubishi Gas Chemical Co Método para producir nitrilo aromático mediante una reacción de amoxidación
CN113573811B (zh) * 2019-03-29 2023-12-08 日本化药株式会社 不饱和醛的制造方法
CN112871182B (zh) * 2019-11-29 2022-04-12 中国科学院大连化学物理研究所 一种用于异丁烯氧化制备甲基丙烯醛催化剂及制备和应用
JP6932293B1 (ja) * 2020-01-10 2021-09-08 日本化薬株式会社 触媒、それを用いた化合物の製造方法及び化合物
KR102725875B1 (ko) * 2020-01-14 2024-11-01 가부시기가이샤 닛뽕쇼꾸바이 아크릴산의 제조 방법
CN115327252B (zh) * 2022-06-27 2023-08-08 上海轩田工业设备有限公司 一种高低温微波性能测试调度优化方法及系统
CN119303588A (zh) * 2023-07-13 2025-01-14 中国石油天然气股份有限公司 一种多级孔钼铋复合金属氧化物催化剂及其制备方法与应用
WO2025100265A1 (ja) * 2023-11-09 2025-05-15 日本化薬株式会社 不飽和アルデヒドまたは不飽和カルボン酸の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1845785A (zh) * 2003-09-01 2006-10-11 Lg化学株式会社 在具有改进的热控制系统的固定床催化部分氧化反应器中制备不饱和醛和不饱和酸的方法
CN101842341A (zh) * 2007-11-02 2010-09-22 日本化药株式会社 气相催化氧化反应方法
CN101848883A (zh) * 2007-11-06 2010-09-29 日本化药株式会社 异丁烯醛和/或甲基丙烯酸的制造方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2056614C3 (de) * 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
JP2659839B2 (ja) * 1990-01-26 1997-09-30 株式会社日本触媒 メタクロレインおよびメタクリル酸の製造方法
JP3287066B2 (ja) * 1993-06-28 2002-05-27 住友化学工業株式会社 アクリル酸の製造方法
JP3139285B2 (ja) 1994-06-20 2001-02-26 住友化学工業株式会社 アクロレインおよびアクリル酸の製造方法
JP3793317B2 (ja) * 1996-05-14 2006-07-05 日本化薬株式会社 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法
JP3775872B2 (ja) 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
JP4318367B2 (ja) * 2000-02-16 2009-08-19 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
JP3943311B2 (ja) 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
JP3939187B2 (ja) 2002-03-29 2007-07-04 株式会社日本触媒 不飽和アルデヒドの製造方法
JP2005320315A (ja) 2003-10-22 2005-11-17 Nippon Shokubai Co Ltd 接触気相酸化反応
JP4867129B2 (ja) * 2003-12-15 2012-02-01 三菱化学株式会社 （メタ）アクリル酸または（メタ）アクロレインの製造方法
JPWO2012105304A1 (ja) * 2011-02-02 2014-07-03 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1845785A (zh) * 2003-09-01 2006-10-11 Lg化学株式会社 在具有改进的热控制系统的固定床催化部分氧化反应器中制备不饱和醛和不饱和酸的方法
CN101842341A (zh) * 2007-11-02 2010-09-22 日本化药株式会社 气相催化氧化反应方法
CN101848883A (zh) * 2007-11-06 2010-09-29 日本化药株式会社 异丁烯醛和/或甲基丙烯酸的制造方法

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SA112330234B1 (ar) 2015-01-14
TWI507387B (zh) 2015-11-11
US20130310604A1 (en) 2013-11-21
TW201233667A (en) 2012-08-16
JPWO2012105304A1 (ja) 2014-07-03
CN103347845A (zh) 2013-10-09
JP2012176938A (ja) 2012-09-13
US8969618B2 (en) 2015-03-03
JP6527499B2 (ja) 2019-06-05
WO2012105304A1 (ja) 2012-08-09
JP2017088606A (ja) 2017-05-25
EP2671862A1 (en) 2013-12-11
JP2018140993A (ja) 2018-09-13
CN102627537A (zh) 2012-08-08
EP2671862B1 (en) 2018-01-10
CN102627537B (zh) 2016-03-23
EP2671862A4 (en) 2014-10-01

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