CN103265368A - Paste type water-soluble fertilizer with potassium fulvic acid serving as matrix - Google Patents
Paste type water-soluble fertilizer with potassium fulvic acid serving as matrix Download PDFInfo
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- CN103265368A CN103265368A CN2013102018626A CN201310201862A CN103265368A CN 103265368 A CN103265368 A CN 103265368A CN 2013102018626 A CN2013102018626 A CN 2013102018626A CN 201310201862 A CN201310201862 A CN 201310201862A CN 103265368 A CN103265368 A CN 103265368A
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Abstract
The invention discloses a paste type water-soluble fertilizer with potassium fulvic acid serving as a matrix. The paste type water-soluble fertilizer comprises the following components in parts by weight: 80 to 100 parts of potassium fulvic acid, 200 to 650 parts of potassium nitrate, 100 to 460 parts of monoammonium phosphate, 60 to 90 parts of urea, 130 to 160 parts of water, 2.1 to 3.8 parts of calcium magnesium phosphate fertilizer, 1.6 to 2.4 parts of manganese sulfate, 0.7 to 1.2 parts of ferrous sulfate, 0.8 to 1.3 parts of zinc sulfate, 0.8 to 1.4 parts of copper sulfate, and 0.6 to 1.2 parts of ammonium molybdate. A paste type water-soluble material with potassium fulvic acid serving as the matrix can bring the colloid effect, complexing effect, acid-base equilibrium effect for all components, and interspersion effect for all material of the potassium fulvic acid into full play in the whole compound fertilizer, so that the dissolution velocity of all the materials during being diluted with water can be increased, and the content of each nutritional ingredient in the fertilizer is increased; and the paste type water-soluble fertilizer has the characteristics of being free of precipitating, hardening, crystallizing and bleeding, and can be applied to foliage spray, fertigation, etc.
Description
Technical field
The present invention relates to a kind of humic-acid kind mixed fertilizer, relate in particular to that a kind of what be mainly used in blade spraying and fertigation is the paste water-soluble fertilizer of matrix with the potassium fulvate.
Background technology
Humic acids is the larger molecular organics matter that occurring in nature extensively exists, and is widely used in every field such as agricultural are herded, oil, chemical industry, building materials, medical and health, environmental protection, across tens industries.Particularly advocate ecological agriculture construction, pollution-less agriculture production, green food, pollution-free environmentfriendly products etc. now, more make " humic acids " to enjoy high praise.
Potassium fulvate is the active potassium element fertilizer of a kind of pure natural mineral substance, potassium fulvate includes multiple nutritional components such as trace element, rare earth element, plant-growth regulator, viral inhibitors, make that nutrient is more sufficient, supply is more reasonable, thereby avoided crop because of the generation of the various physiological disturbances that lack element and cause, make the more vigorous leaf look of crop plant type more dark green, lodging tolerance is stronger.Potassium fulvate can replenish the nutrient that runs off in the soil timely, make soil activating, have vitality, reduced the continuous cropping disease that nutrient is caused by taken in excess in the soil, product can replace the identical vitriolate of tartar of content or Repone K and potassium magnesium sulfate fully, and natural, environmental protection.
The humic acid fertilizer of forming by humic acids and other inorganic elementss has vital role in agriculture production.1, uses humic acids, can change that saliferous is too high in the soil, alkalescence is strong, the physicochemical character of grogs high dispersing, Soil structure difference with excessivelying, promote the formation of soil agreegate, make it become good order and condition, thereby be the good condition of plant root growth growth creation; 2, use the humic acids topsoil soils of can loosening, destroy the accumulation of salt, reduce the native saltiness of table, play every salt action, improve seedling rate, reduce weak seedling, dead seedling, plant health is grown up; 3, humic acids has higher positively charged ion converted quantity, and is higher more than 10 times than general soil.After being manured into soil, soil is significantly improved to the negatively charged ion adsorptive power, capping salt content is reduced; 4, particularly alkaline earth pH value is too high in saline and alkaline soil, directly damage to crops growth, even cause death, the too high validity that also has influence on nutritive elements such as phosphorus in the soil, iron, manganese, boron, zinc of pH value in addition, and humic acids pH value is 6.8, slant acidity, alkalescence can neutralize, alleviate and eliminate alkalescence to the harm of soil and plant, make the low yield saltings obtain improvement, for good edaphic condition is created in the crop seedling growth; 5, use humic acids and make the quantity increase of aerobic bacteria, actinomycetes, cellulose-decomposing bacteria more, to accelerating organic mineralising, promote that the release of nutritive element is favourable; 6, humic acids contains multiple functional group, humic acids after being activated becomes the efficient bio-active material, crop growth and body physiological metabolism there is hormesis, this specific character is that general fertilizers is not available, humic acid highly effective biologically active substance after the activation is pressed finite concentration and is adopted seed soaking, soak root, dip in root, sprinkling, water, do modes such as base fertilizer, various crops there is tangible effect of stimulation, general performance is in the promotion to root system development, to the good influence of crop yield, quality factor; 7, humic acids can make plant leaf stomatal opening degree reduce, the blade transpiration rate reduces, water loss reduces, water regime in the plant body improves, leaf water content is improved, thereby for dividing fringe and lay a good foundation at seed, humic acids can also improve chlorophyllous content and photosyntheticly normally carry out, and is very important for the accumulation of material and the raising of thousand seed weight.
The fertilizer that contains humic acid substance in the market mainly contains two kinds of formulations, be solid (pulvis) and liquid (aqua), the former is easy moisture absorption caking in the transportation stacking process, dissolubility is poor during use, humic acid substance can not be brought into play complexing action well, deposited phenomenon takes place easily, so the solid kind humic acid fertilizer should not be as drip irrigation fertilizer and foliar applied fertilizer under acid, alkali influence, and be used for dashing fertilising more.The latter with water as matrix, but owing to be subjected to the influence of each composition solubleness, nutrient content is lower, and multiple composition combines together crystallization or deposited phenomenon easily takes place, and in temperature in the higher and transportation, the flatulence phenomenon easily takes place in pail pack, so it is having certain limitation aspect production, storage, the use.
Summary of the invention
At above-mentioned prior art, the invention provides a kind of is the water-soluble material of paste of matrix with the potassium fulvate, because each raw material all passes through fine powder, its solvability is good, and under normal temperature (20 ℃), the 1:250 concentration dilution can dissolve in 1 minute fully; Total nutrient content height such as nitrogen phosphorus potassium, reasonable ratio, and have do not precipitate, do not harden, non-crystallizable, the characteristics of bleed not, can be used for foliage-spray and fertigation etc.
The present invention is achieved by the following technical solutions:
A kind of is the water-soluble material of paste of matrix with the potassium fulvate, is made up of the component that comprises following weight part: 80～100 parts of potassium fulvates, saltpetre (KNO
3) 200～650 parts, monoammonium phosphate (NH
4H
2PO
4) 100～460 parts, urea (OC(NH
2)
2) 60～90 parts, 130～160 parts in water.
Further, also comprise the component of following weight part: 2.1～3.8 parts in fused(calcium magnesium)phosphate, manganous sulfate (MnSO
4H
2O) 1.6～2.4 parts, ferrous sulfate (FeSO
47H
2O) 0.7～1.2 part, zinc sulfate (ZnSO
47H
2O) 0.8～1.3 part, copper sulfate (CuSO
45H
2O) 0.8～1.4 part, ammonium molybdate ((NH
3) 2MoO
4) 0.6～1.2 part.
Described is that the preparation method of the water-soluble material of paste of matrix is with the potassium fulvate: earlier potassium fulvate is mixed with water, obtain mobile soup compound after the stirring, be slurry; Other component is ground into particle more than 60 orders, gets meal; With slurry this as matrix, add meal, stir, namely being able to potassium fulvate is the water-soluble material of paste of matrix.
Of the present invention is the water-soluble material of paste of matrix with the potassium fulvate, soak into the slurry form as matrix with potassium fulvate with suitable quantity of water, and according in advance the design prescription add other corresponding pulverulent material after, can give full play to the colloid action of potassium fulvate in whole compound manure, complexing action, the acid base equilibrium effect of each composition, the mutual dissemination of each material, dissolution rate when improving each material thin up, improve the content in the fertilizer of each nutritive ingredient, and can when descending, temperature easily precipitate or crystallization by the common aqua fertilizer of fine solution, and common pulvis problem such as in transportation the other side process, harden, improve the effect of fertilizer.The present invention does not add any supplementary additive, and the preparation method is simple, need not specific installation.
Of the present invention is the water-soluble material of paste of matrix with the potassium fulvate, because each raw material all passes through fine powder, its solvability is good, and under normal temperature (20 ℃), the 1:250 concentration dilution can dissolve in 1 minute fully; Total nutrient content height such as nitrogen phosphorus potassium, reasonable ratio, and have do not precipitate, do not harden, non-crystallizable, the characteristics of bleed not, can be used for foliage-spray and fertigation etc.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1 preparation is that the paste water solubles material formula of matrix is as shown in table 1 with the potassium fulvate.
Table 1
The preparation method is:
1, in stirrer constantly stirs, potassium fulvate is added to the water, until being even pulpous state, becomes matrix, standby;
2, saltpetre, urea, monoammonium phosphate are pulverized with high speed disintegrator respectively, read in detail and reach more than 60 orders, standby;
3, above pulverulent material is slowly joined in the soup compound (matrix) one by one, stirred 30 minutes with the stirrer rapid strong, leave standstill the back paste.
Above finished product are the instant paste-form fertilizer of macroelement that contains potassium fulvate, wherein N, P
2O
5, K
2The total amount of O is that 50%, pH is that 6～7(1:250 measures).
The paste-form fertilizer that present embodiment prepares, more as shown in table 2 with the stability of existing product of the same type, as shown in Table 2, the paste-form fertilizer that present embodiment prepares, have nonhygroscopic, do not precipitate, not flatulence, do not harden, non-crystallizable, characteristics such as bleed not.
Table 2
Application effect:
The paste-form fertilizer of present embodiment is to the influence of celery output
Test is carried out in Yantai City, Shandong Province Fushan District one warmhouse booth, and experimental field physical features is smooth, fertility is even, and good irrigation conditions is arranged.Supplying to study thing is celery, and kind is the glass kingfisher.Test area is 3 mu, contrasts 1 mu.
Handle 1: conventional fertilizer application+spray and processing 2 equivalent clear water (CK);
Handle 2: the conventional processing+water-soluble fertilizer of humic acid liquid of the same type (product is called " Ai Feite ", and middleization (Yantai) crop alimentary company limited produces, and the product registration card number faces word No. 4916 for farming fertile (2010)) (600-800 times of diluent);
Handle 3: conventional fertilizer application+the spray paste-form fertilizer (1000-1200 times of diluent) of present embodiment;
Conventional fertilizer application is the basic sealing fertilizer 50kg(15-15-15 of mu before the field planting), fertilizer 500kg.Growth imposes 5kg/ mu urea once mid-term.
Spray to be treated to and in whole growing, spray three times and contain humic acid paste-form fertilizer, spray to be respectively for three times of processing 2 and spray 800 times, 600 times and 600 times of diluents, spray to be respectively for three times of processing 3 and spray 1200 times, 1000 times and 1000 times of diluents, handle 1 contemporaneity and spray the equivalent clear water, each treatment group is done three parallel (repetition), and test-results is as shown in table 3:
Table 3 celery output contrast table
Find out that from last table handle 3 and spray humic acid paste-form fertilizer and handle 1 and handle 2 and increase production 193.2kg/ mu and 90kg/ mu respectively, stimulation ratio is respectively 6.5% and 2.9%.The fertile contrast of humic acid paste-form and product of the same type have certain yield increasing effect as can be seen.
Embodiment 2 preparations are that the paste water solubles material formula of matrix is as shown in table 4 with the potassium fulvate.
Table 4
The preparation method is:
1, in stirrer constantly stirs, potassium fulvate is added to the water, until being even pulpous state, becomes matrix, standby;
2, saltpetre, urea, monoammonium phosphate, fused(calcium magnesium)phosphate (phosphorus phosphate fertilizer company limited in river, Jiangxi produces, powdery), manganous sulfate, ferrous sulfate, zinc sulfate, copper sulfate, ammonium molybdate are pulverized with high speed disintegrator respectively, read in detail and reach more than 60 orders, standby;
3, above pulverulent material is slowly joined in the soup compound (matrix) one by one, stirred 60 minutes with the stirrer rapid strong, leave standstill the back paste.
Application effect
The humic acids lotion fertilizer of present embodiment preparation is to the influence of tomato yield
Test connects in ditch one warmhouse booth Xin Zhuan town, Zhaoyuan City, Shandong Province horse to be carried out.Supplying to study thing is tomato, and kind is Beijing-Tianjin.Test area is 5 mu, contrasts 1 mu.
Handle 1: conventional fertilizer application+spray potassium fulvate paste fertilizer
Handle 2: conventional processing+spray and handle 1 equivalent clear water (contrast);
Conventional fertilizer application is the basic sealing fertilizer 150kg of mu before the field planting, farm manure 5000kg.Growth imposes 5kg/ mu urea once mid-term.Impose composite fertilizer 6 times in the middle of the whole growing, each 50kg/ mu.
Spray to be treated to and in whole growing, spray 5 times and contain humic acid paste-form fertilizer, spray to be respectively for five times of processing 1 and spray 1200 times, 1200 times, 1000 times, 1000 times and 1000 times of diluents, handle 2 contemporaneities and spray the equivalent clear water, each treatment group is done four parallel (repetition).Test-results such as following table 5:
The contrast of the fertile tomato test of table 5 potassium fulvate paste output
As can be seen from the table, humic acid paste-form is fertile in the average volume increase 9.87kg/ mu of contrast, stimulation ratio 5.42%.
Claims (5)
1. one kind is the water-soluble material of paste of matrix with the potassium fulvate, it is characterized in that: formed by the component that comprises following weight part: 80～100 parts of potassium fulvates, 200～650 parts in saltpetre, 100～460 parts of monoammonium phosphates, 60～90 parts in urea, 130～160 parts in water.
2. according to claim 1 is the water-soluble material of paste of matrix with the potassium fulvate, it is characterized in that: be made up of the component of following weight part: 80 parts of potassium fulvates, 218 parts in saltpetre, 460 parts of monoammonium phosphates, 82 parts in urea, 160 parts in water.
3. according to claim 1 is the water-soluble material of paste of matrix with the potassium fulvate, it is characterized in that: the component that also comprises following weight part: 2.1～3.8 parts in fused(calcium magnesium)phosphate, 1.6～2.4 parts of manganous sulfates, 0.7～1.2 part in ferrous sulfate, 0.8～1.3 part in zinc sulfate, 0.8～1.4 part in copper sulfate, 0.6～1.2 part of ammonium molybdate.
4. according to claim 3 is the water-soluble material of paste of matrix with the potassium fulvate, it is characterized in that: formed by the component of following weight part: 80 parts of potassium fulvates, 610 parts in saltpetre, 100 parts of monoammonium phosphates, 64 parts in urea, 136 parts in water, 3.74 parts in fused(calcium magnesium)phosphate, 2.4 parts of manganous sulfates, 1.12 parts in ferrous sulfate, 1.26 parts in zinc sulfate, 0.82 part in copper sulfate, 0.66 part of ammonium molybdate.
In the claim 1～4 each described be the preparation method of the water-soluble material of paste of matrix with the potassium fulvate, it is characterized in that: earlier potassium fulvate is mixed with water, obtain mobile soup compound after the stirring, be slurry; Other component is ground into particle more than 60 orders, gets meal; With slurry this as matrix, add meal, stir, namely being able to potassium fulvate is the water-soluble material of paste of matrix.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103553826A (en) * | 2013-11-11 | 2014-02-05 | 双赢集团有限公司 | Fertilizer |
| CN103570474A (en) * | 2013-11-11 | 2014-02-12 | 双赢集团有限公司 | Fertilizer |
| CN103896685A (en) * | 2014-04-17 | 2014-07-02 | 张彬 | Organic-inorganic water-soluble fertilizer and preparation method thereof |
| CN103964924A (en) * | 2014-05-14 | 2014-08-06 | 张铭强 | Biological carbon energy water-soluble fertilizer |
| CN104446803A (en) * | 2014-12-08 | 2015-03-25 | 四川陶普唯农农化有限公司 | High-nitrogen type water-soluble fertilizer containing fulvic acid |
| CN104628467A (en) * | 2015-01-26 | 2015-05-20 | 张彬 | Long-acting water-soluble fertilizer and preparation method thereof |
| CN104926446A (en) * | 2015-06-05 | 2015-09-23 | 柳州市宝杨种植专业合作社 | Colloid type growth substrate for haworthia cooperivar |
| CN105130676A (en) * | 2015-07-03 | 2015-12-09 | 河南晋开化工投资控股集团有限责任公司 | Liquid fertilizer for resisting drought and preserving moisture and fertility and preparation method thereof |
| CN106365728A (en) * | 2016-08-28 | 2017-02-01 | 河北九五新材料科技有限公司 | Quick-acting water-soluble pasty fertilizer and preparation method thereof |
| CN106892769A (en) * | 2015-12-19 | 2017-06-27 | 衡阳智源农业科技有限公司 | A kind of preparation method of tea oil tree drip irrigation special fertilizer |
| CN106892711A (en) * | 2015-12-19 | 2017-06-27 | 衡阳智源农业科技有限公司 | A kind of tea oil tree drip irrigation special fertilizer |
| CN110078558A (en) * | 2019-05-16 | 2019-08-02 | 东北农业大学 | A kind of production method of thixotropic paste compound fertilizer |
| CN112159292A (en) * | 2020-11-10 | 2021-01-01 | 中化农业生态科技(湖北)有限公司 | High-water-solubility compound fertilizer and preparation method thereof |
| CN112409071A (en) * | 2020-11-24 | 2021-02-26 | 南宁九禾测土配肥有限责任公司 | Water-soluble high-tower nitro-sulfenyl compound fertilizer suitable for high-pressure sprinkling irrigation equipment and preparation method thereof |
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| CN1530352A (en) * | 2003-03-13 | 2004-09-22 | 马之龙 | Instant fertilizer paste with humic water immersed materials as basic substance |
| CN102898247A (en) * | 2012-11-13 | 2013-01-30 | 赵显民 | Method for preparing organic and inorganic blended fertilizer |
| CN102951964A (en) * | 2012-10-29 | 2013-03-06 | 安华芳 | Gel biological fertilizer |
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Patent Citations (3)
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| CN1530352A (en) * | 2003-03-13 | 2004-09-22 | 马之龙 | Instant fertilizer paste with humic water immersed materials as basic substance |
| CN102951964A (en) * | 2012-10-29 | 2013-03-06 | 安华芳 | Gel biological fertilizer |
| CN102898247A (en) * | 2012-11-13 | 2013-01-30 | 赵显民 | Method for preparing organic and inorganic blended fertilizer |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103570474A (en) * | 2013-11-11 | 2014-02-12 | 双赢集团有限公司 | Fertilizer |
| CN103553826A (en) * | 2013-11-11 | 2014-02-05 | 双赢集团有限公司 | Fertilizer |
| CN103553826B (en) * | 2013-11-11 | 2015-04-08 | 双赢集团有限公司 | Fertilizer |
| CN103896685B (en) * | 2014-04-17 | 2015-11-11 | 张彬 | A kind of organic-inorganic Water soluble fertilizer and preparation method thereof |
| CN103896685A (en) * | 2014-04-17 | 2014-07-02 | 张彬 | Organic-inorganic water-soluble fertilizer and preparation method thereof |
| CN103964924A (en) * | 2014-05-14 | 2014-08-06 | 张铭强 | Biological carbon energy water-soluble fertilizer |
| CN103964924B (en) * | 2014-05-14 | 2016-04-20 | 张铭强 | Biological carbon energy Water soluble fertilizer |
| CN104446803A (en) * | 2014-12-08 | 2015-03-25 | 四川陶普唯农农化有限公司 | High-nitrogen type water-soluble fertilizer containing fulvic acid |
| CN104446803B (en) * | 2014-12-08 | 2017-03-29 | 四川陶普唯农农化有限公司 | high nitrogen type water-soluble fertilizer containing fulvic acid |
| CN104628467A (en) * | 2015-01-26 | 2015-05-20 | 张彬 | Long-acting water-soluble fertilizer and preparation method thereof |
| CN104926446A (en) * | 2015-06-05 | 2015-09-23 | 柳州市宝杨种植专业合作社 | Colloid type growth substrate for haworthia cooperivar |
| CN105130676A (en) * | 2015-07-03 | 2015-12-09 | 河南晋开化工投资控股集团有限责任公司 | Liquid fertilizer for resisting drought and preserving moisture and fertility and preparation method thereof |
| CN106892769A (en) * | 2015-12-19 | 2017-06-27 | 衡阳智源农业科技有限公司 | A kind of preparation method of tea oil tree drip irrigation special fertilizer |
| CN106892711A (en) * | 2015-12-19 | 2017-06-27 | 衡阳智源农业科技有限公司 | A kind of tea oil tree drip irrigation special fertilizer |
| CN106365728A (en) * | 2016-08-28 | 2017-02-01 | 河北九五新材料科技有限公司 | Quick-acting water-soluble pasty fertilizer and preparation method thereof |
| CN110078558A (en) * | 2019-05-16 | 2019-08-02 | 东北农业大学 | A kind of production method of thixotropic paste compound fertilizer |
| CN112159292A (en) * | 2020-11-10 | 2021-01-01 | 中化农业生态科技(湖北)有限公司 | High-water-solubility compound fertilizer and preparation method thereof |
| CN112409071A (en) * | 2020-11-24 | 2021-02-26 | 南宁九禾测土配肥有限责任公司 | Water-soluble high-tower nitro-sulfenyl compound fertilizer suitable for high-pressure sprinkling irrigation equipment and preparation method thereof |
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Application publication date: 20130828 |