CN1032243C - 羰基化反应催化剂的再活化 - Google Patents

羰基化反应催化剂的再活化 Download PDF

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Publication number
CN1032243C
CN1032243C CN92102956A CN92102956A CN1032243C CN 1032243 C CN1032243 C CN 1032243C CN 92102956 A CN92102956 A CN 92102956A CN 92102956 A CN92102956 A CN 92102956A CN 1032243 C CN1032243 C CN 1032243C
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CN
China
Prior art keywords
catalyst
rhodium
oxonation
aldehyde
carbonylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN92102956A
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English (en)
Chinese (zh)
Other versions
CN1066009A (zh
Inventor
D·R·布赖恩
J·C·尼科尔森
J·E·巴宾
小·D·J魏因特里特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Dow Technology Investments LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of CN1066009A publication Critical patent/CN1066009A/zh
Application granted granted Critical
Publication of CN1032243C publication Critical patent/CN1032243C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/20—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction
    • C07C27/22—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction with the use of catalysts which are specific for this process
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN92102956A 1991-03-18 1992-03-17 羰基化反应催化剂的再活化 Expired - Lifetime CN1032243C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/670,874 US5183943A (en) 1991-03-18 1991-03-18 Reactivation of hydroformylation catalysts
US670,874 1991-03-18

Publications (2)

Publication Number Publication Date
CN1066009A CN1066009A (zh) 1992-11-11
CN1032243C true CN1032243C (zh) 1996-07-10

Family

ID=24692246

Family Applications (1)

Application Number Title Priority Date Filing Date
CN92102956A Expired - Lifetime CN1032243C (zh) 1991-03-18 1992-03-17 羰基化反应催化剂的再活化

Country Status (23)

Country Link
US (1) US5183943A (OSRAM)
EP (1) EP0504814B1 (OSRAM)
JP (1) JP2557767B2 (OSRAM)
KR (1) KR960012697B1 (OSRAM)
CN (1) CN1032243C (OSRAM)
AR (1) AR247496A1 (OSRAM)
AT (1) ATE117976T1 (OSRAM)
AU (1) AU641853B2 (OSRAM)
BR (1) BR9200911A (OSRAM)
CA (1) CA2063168A1 (OSRAM)
CS (1) CS80292A3 (OSRAM)
DE (1) DE69201309T2 (OSRAM)
ES (1) ES2068625T3 (OSRAM)
FI (1) FI921149L (OSRAM)
HU (1) HUT63971A (OSRAM)
MX (1) MX9201189A (OSRAM)
NO (1) NO921028L (OSRAM)
PL (1) PL168896B1 (OSRAM)
RO (1) RO111738B1 (OSRAM)
SA (1) SA92120449B1 (OSRAM)
TW (1) TW229166B (OSRAM)
YU (1) YU26692A (OSRAM)
ZA (1) ZA921957B (OSRAM)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5237106A (en) * 1992-01-24 1993-08-17 Union Carbide Chemicals & Plastics Technology Corporation Reactivation of hydroformylation catalysts
DE4408950A1 (de) * 1994-03-16 1995-09-21 Basf Ag Verfahren zur Herstellung von Alkoholen und/oder Aldehyden
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
USD400786S (en) 1997-01-17 1998-11-10 The Procter & Gamble Company Upper portion of a container
WO2004016661A1 (ja) * 2002-08-19 2004-02-26 Japan Polypropylene Corporation ポリオレフィンの製造方法
CN102574878A (zh) 2009-10-16 2012-07-11 陶氏技术投资有限责任公司 气相加氢甲酰化方法
SA112330271B1 (ar) * 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
CN102950027B (zh) * 2011-08-30 2015-03-25 中国石油化工股份有限公司 用于羰基化反应的失活铑配合物催化剂的再生方法
CN102950028B (zh) * 2011-08-31 2015-02-25 中国石油化工股份有限公司 用于羰基化反应的失活铑膦配合物催化剂的再生方法
US8884071B2 (en) * 2012-06-04 2014-11-11 Lg Chem, Ltd. Hydroformylation method having improved catalyst stability in reaction
CN104248994B (zh) * 2013-06-25 2018-03-20 中国石油化工股份有限公司 羰基化铑膦催化剂的活性恢复方法
CN106103400B (zh) 2014-03-31 2020-03-03 陶氏技术投资有限责任公司 氢甲酰化方法
US10501486B2 (en) 2014-05-14 2019-12-10 Dow Technology Investments Llc Stabilized organophosphorous compounds
CN104028311B (zh) * 2014-07-02 2016-06-15 天津渤化永利化工股份有限公司 一种丁辛醇羰基合成催化剂化学再生方法
US10487020B2 (en) 2015-07-28 2019-11-26 Dow Technology Investments Llc Method for the preparation of a stabilized organophosphorous compound solution
US10981851B2 (en) 2017-10-25 2021-04-20 Dow Technology Investments Llc Hydroformylation process
WO2019094290A1 (en) * 2017-11-13 2019-05-16 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1219763A (en) * 1967-02-02 1971-01-20 Johnson Matthey & Company Improvements in catalytic hydrogenation or hydroformylation
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
JPS5114482A (ja) * 1974-07-26 1976-02-04 Atsugi Kinzoku Kogyo Kk Kanguchiseizohoho
JPS5633040A (en) * 1979-08-27 1981-04-03 Mitsubishi Chem Ind Ltd Activation of rhodium complex catalyst
US4292196A (en) * 1979-12-10 1981-09-29 Uop Inc. Catalyst recovery
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4845306A (en) * 1987-04-24 1989-07-04 Eastman Kodak Company Catalyst material recovery or concentration process
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts

Also Published As

Publication number Publication date
ZA921957B (en) 1992-12-30
AU641853B2 (en) 1993-09-30
PL293883A1 (en) 1992-11-30
SA92120449B1 (ar) 2004-01-25
NO921028D0 (no) 1992-03-17
JP2557767B2 (ja) 1996-11-27
FI921149A0 (fi) 1992-03-17
MX9201189A (es) 1993-08-01
RO111738B1 (ro) 1997-01-30
CN1066009A (zh) 1992-11-11
ATE117976T1 (de) 1995-02-15
ES2068625T3 (es) 1995-04-16
NO921028L (no) 1992-09-21
CA2063168A1 (en) 1992-09-19
JPH05131141A (ja) 1993-05-28
FI921149A7 (fi) 1992-09-19
HU9200886D0 (en) 1992-05-28
FI921149L (fi) 1992-09-19
AR247496A1 (es) 1995-01-31
HUT63971A (en) 1993-11-29
PL168896B1 (pl) 1996-04-30
EP0504814A2 (en) 1992-09-23
AU1296192A (en) 1992-09-24
BR9200911A (pt) 1992-11-17
KR920017712A (ko) 1992-10-21
DE69201309T2 (de) 1995-06-08
US5183943A (en) 1993-02-02
DE69201309D1 (de) 1995-03-16
CS80292A3 (en) 1992-10-14
EP0504814B1 (en) 1995-02-01
TW229166B (OSRAM) 1994-09-01
KR960012697B1 (ko) 1996-09-24
YU26692A (sh) 1994-06-10
EP0504814A3 (en) 1992-11-25

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
OR01 Other related matters
ASS Succession or assignment of patent right

Owner name: TAOSHI TECHNOLOGY INVESTMENT CO., LTD.

Free format text: FORMER OWNER: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY CO., CO.LTD.

Effective date: 20080801

C41 Transfer of patent application or patent right or utility model
C56 Change in the name or address of the patentee

Owner name: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY CO

Free format text: FORMER NAME OR ADDRESS: UNION CARBIDE CHEMICALS + PLASTICS TECHNOLOGY CORP.

CP03 Change of name, title or address

Address after: Michigan

Patentee after: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC

Address before: American Connecticut

Patentee before: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY Corp.

TR01 Transfer of patent right

Effective date of registration: 20080801

Address after: Michigan

Patentee after: DOW TECHNOLOGY INVESTMENTS LLC

Address before: Michigan

Patentee before: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC

C17 Cessation of patent right
CX01 Expiry of patent term

Expiration termination date: 20120317

Granted publication date: 19960710