ES2068625T3 - Reactivacion de catalizadores de hidroformilacion. - Google Patents

Reactivacion de catalizadores de hidroformilacion.

Info

Publication number
ES2068625T3
ES2068625T3 ES92104607T ES92104607T ES2068625T3 ES 2068625 T3 ES2068625 T3 ES 2068625T3 ES 92104607 T ES92104607 T ES 92104607T ES 92104607 T ES92104607 T ES 92104607T ES 2068625 T3 ES2068625 T3 ES 2068625T3
Authority
ES
Spain
Prior art keywords
hydroformilation
reactivation
catalysts
rhodium
ina
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92104607T
Other languages
English (en)
Inventor
David Robert Bryant
James Edward Babin
James Clair Nicholson
Donald John Weintritt Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Application granted granted Critical
Publication of ES2068625T3 publication Critical patent/ES2068625T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/20—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction
    • C07C27/22—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction with the use of catalysts which are specific for this process
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

UN PROCESO PARA MEJORAR LA ACTIVIDAD CATALITICA DE UN CATALIZADOR DE HIDROFORMILACION DE COMPLEJO DE RODIO INA TERCIARIO SOLUBILIZADO ACTIVADO.
ES92104607T 1991-03-18 1992-03-17 Reactivacion de catalizadores de hidroformilacion. Expired - Lifetime ES2068625T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/670,874 US5183943A (en) 1991-03-18 1991-03-18 Reactivation of hydroformylation catalysts

Publications (1)

Publication Number Publication Date
ES2068625T3 true ES2068625T3 (es) 1995-04-16

Family

ID=24692246

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92104607T Expired - Lifetime ES2068625T3 (es) 1991-03-18 1992-03-17 Reactivacion de catalizadores de hidroformilacion.

Country Status (23)

Country Link
US (1) US5183943A (es)
EP (1) EP0504814B1 (es)
JP (1) JP2557767B2 (es)
KR (1) KR960012697B1 (es)
CN (1) CN1032243C (es)
AR (1) AR247496A1 (es)
AT (1) ATE117976T1 (es)
AU (1) AU641853B2 (es)
BR (1) BR9200911A (es)
CA (1) CA2063168A1 (es)
CS (1) CS80292A3 (es)
DE (1) DE69201309T2 (es)
ES (1) ES2068625T3 (es)
FI (1) FI921149A (es)
HU (1) HUT63971A (es)
MX (1) MX9201189A (es)
NO (1) NO921028L (es)
PL (1) PL168896B1 (es)
RO (1) RO111738B1 (es)
SA (1) SA92120449B1 (es)
TW (1) TW229166B (es)
YU (1) YU26692A (es)
ZA (1) ZA921957B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5237106A (en) * 1992-01-24 1993-08-17 Union Carbide Chemicals & Plastics Technology Corporation Reactivation of hydroformylation catalysts
DE4408950A1 (de) * 1994-03-16 1995-09-21 Basf Ag Verfahren zur Herstellung von Alkoholen und/oder Aldehyden
CZ283697A3 (cs) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Způsob přípravy roztoku komplexu rhodia a jeho použití
EP1531163A4 (en) * 2002-08-19 2006-06-28 Japan Polypropylene Corp PROCESS FOR THE PREPARATION OF POLYOLEFIN
US8586800B2 (en) 2009-10-16 2013-11-19 Dow Technology Investments Llc Gas phase hydroformylation process
SA112330271B1 (ar) * 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
CN102950027B (zh) * 2011-08-30 2015-03-25 中国石油化工股份有限公司 用于羰基化反应的失活铑配合物催化剂的再生方法
CN102950028B (zh) * 2011-08-31 2015-02-25 中国石油化工股份有限公司 用于羰基化反应的失活铑膦配合物催化剂的再生方法
CN103814006B (zh) * 2012-06-04 2015-08-12 Lg化学株式会社 在反应中具有改善的催化剂稳定性的氢甲酰化方法
CN104248994B (zh) * 2013-06-25 2018-03-20 中国石油化工股份有限公司 羰基化铑膦催化剂的活性恢复方法
JP6560248B2 (ja) 2014-03-31 2019-08-14 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
JP6694396B2 (ja) 2014-05-14 2020-05-13 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 安定化された有機リン化合物
CN104028311B (zh) * 2014-07-02 2016-06-15 天津渤化永利化工股份有限公司 一种丁辛醇羰基合成催化剂化学再生方法
CA2993161C (en) 2015-07-28 2023-09-26 Dow Technology Investments Llc Method for the preparation of a stabilized organophosphorous compound solution
RU2020115090A (ru) 2017-10-25 2021-10-29 Дау Текнолоджи Инвестментс Ллк Способ уменьшения образования тяжелых фракций в растворе, содержащем альдегидные соединения, образованные в процессе гидроформилирования
EP3710161B1 (en) * 2017-11-13 2024-10-16 Dow Technology Investments LLC Processes for recovery of rhodium from a hydroformylation process

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1219763A (en) * 1967-02-02 1971-01-20 Johnson Matthey & Company Improvements in catalytic hydrogenation or hydroformylation
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
JPS5114482A (ja) * 1974-07-26 1976-02-04 Atsugi Kinzoku Kogyo Kk Kanguchiseizohoho
JPS5633040A (en) * 1979-08-27 1981-04-03 Mitsubishi Chem Ind Ltd Activation of rhodium complex catalyst
US4292196A (en) * 1979-12-10 1981-09-29 Uop Inc. Catalyst recovery
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4845306A (en) * 1987-04-24 1989-07-04 Eastman Kodak Company Catalyst material recovery or concentration process
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts

Also Published As

Publication number Publication date
NO921028L (no) 1992-09-21
TW229166B (es) 1994-09-01
PL168896B1 (pl) 1996-04-30
CN1066009A (zh) 1992-11-11
HU9200886D0 (en) 1992-05-28
EP0504814A3 (en) 1992-11-25
BR9200911A (pt) 1992-11-17
FI921149A0 (fi) 1992-03-17
SA92120449B1 (ar) 2004-01-25
RO111738B1 (ro) 1997-01-30
ATE117976T1 (de) 1995-02-15
PL293883A1 (en) 1992-11-30
DE69201309D1 (de) 1995-03-16
CS80292A3 (en) 1992-10-14
CA2063168A1 (en) 1992-09-19
CN1032243C (zh) 1996-07-10
FI921149A (fi) 1992-09-19
ZA921957B (en) 1992-12-30
HUT63971A (en) 1993-11-29
KR920017712A (ko) 1992-10-21
AU1296192A (en) 1992-09-24
US5183943A (en) 1993-02-02
EP0504814B1 (en) 1995-02-01
EP0504814A2 (en) 1992-09-23
DE69201309T2 (de) 1995-06-08
YU26692A (sh) 1994-06-10
MX9201189A (es) 1993-08-01
AU641853B2 (en) 1993-09-30
JPH05131141A (ja) 1993-05-28
NO921028D0 (no) 1992-03-17
AR247496A1 (es) 1995-01-31
KR960012697B1 (ko) 1996-09-24
JP2557767B2 (ja) 1996-11-27

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