CN103103358B - 一种利用apt废渣回收金属的方法 - Google Patents
一种利用apt废渣回收金属的方法 Download PDFInfo
- Publication number
- CN103103358B CN103103358B CN201210479906.7A CN201210479906A CN103103358B CN 103103358 B CN103103358 B CN 103103358B CN 201210479906 A CN201210479906 A CN 201210479906A CN 103103358 B CN103103358 B CN 103103358B
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- CN
- China
- Prior art keywords
- tungsten
- filtrate
- apt
- molybdenum
- waste residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002699 waste material Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000002893 slag Substances 0.000 title claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 21
- 239000002184 metal Substances 0.000 title claims abstract description 20
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 title claims abstract description 16
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000010937 tungsten Substances 0.000 claims abstract description 64
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 64
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 37
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000010949 copper Substances 0.000 claims abstract description 36
- 239000011733 molybdenum Substances 0.000 claims abstract description 35
- 229910052802 copper Inorganic materials 0.000 claims abstract description 34
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000011084 recovery Methods 0.000 claims abstract description 26
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 9
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 9
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 9
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 9
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 9
- 238000002386 leaching Methods 0.000 claims abstract description 8
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims abstract description 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 5
- 239000000706 filtrate Substances 0.000 claims description 56
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 23
- 239000003513 alkali Substances 0.000 claims description 20
- 238000001914 filtration Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 239000012065 filter cake Substances 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000007844 bleaching agent Substances 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 claims description 5
- 239000008234 soft water Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000004383 yellowing Methods 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000000227 grinding Methods 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000003190 augmentative effect Effects 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- -1 ferrous metals Chemical class 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
Description
Claims (8)
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CN201210479906.7A CN103103358B (zh) | 2012-11-23 | 2012-11-23 | 一种利用apt废渣回收金属的方法 |
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CN201210479906.7A CN103103358B (zh) | 2012-11-23 | 2012-11-23 | 一种利用apt废渣回收金属的方法 |
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CN103103358A CN103103358A (zh) | 2013-05-15 |
CN103103358B true CN103103358B (zh) | 2014-02-12 |
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CN201210479906.7A Expired - Fee Related CN103103358B (zh) | 2012-11-23 | 2012-11-23 | 一种利用apt废渣回收金属的方法 |
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Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103725892B (zh) * | 2013-12-13 | 2015-08-05 | 金川集团股份有限公司 | 一种回收稀贵熔炼炉渣中有价金属的方法 |
CN105349803B (zh) * | 2015-10-22 | 2018-05-25 | 中南大学 | 一种从含钼的磷钨酸/磷钨酸盐溶液分离钨钼的方法 |
CN105200246B (zh) * | 2015-10-22 | 2018-06-29 | 中南大学 | 一种分离钨钼的方法 |
CN105200245A (zh) * | 2015-10-22 | 2015-12-30 | 中南大学 | 一种高效分离钨钼的方法 |
CN105463194B (zh) * | 2015-12-04 | 2017-09-29 | 湖南金鑫新材料股份有限公司 | 一种钨渣的处理方法 |
CN106011483A (zh) * | 2016-07-08 | 2016-10-12 | 大余县东宏锡制品有限公司 | 一种从仲钨酸铵固体废渣中提炼的锡精工艺品制备方法 |
CN107999271A (zh) * | 2017-11-17 | 2018-05-08 | 北京有色金属研究总院 | 一种从apt钨冶炼渣综合回收有用金属的方法 |
CN108118154A (zh) * | 2017-12-23 | 2018-06-05 | 大余县东宏锡制品有限公司 | 一种利用apt废渣回收稀有金属的方法 |
CN109468468B (zh) * | 2018-11-29 | 2021-04-13 | 中南大学 | 一种综合利用和处理钼铜渣的方法 |
CN110760703B (zh) * | 2019-11-20 | 2021-09-03 | 中国有色集团(广西)平桂飞碟股份有限公司 | 从废apt粉中回收钨的方法 |
CN113336268A (zh) * | 2021-06-30 | 2021-09-03 | 长沙拓诚矿产品有限公司 | 基于钨酸生产仲钨酸铵的方法 |
CN114657373A (zh) * | 2022-03-16 | 2022-06-24 | 信丰华锐钨钼新材料有限公司 | 一种除钼树脂解吸液中nh3-n和s2-的处理方法 |
CN114672672B (zh) * | 2022-04-18 | 2024-04-16 | 江西钨业股份有限公司 | 一种从含钨溶液中回收钨酸的方法 |
CN115446322A (zh) * | 2022-09-22 | 2022-12-09 | 西北有色金属研究院 | 一种回收废旧钼靶制备钼粉的方法 |
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CN87101927A (zh) * | 1987-03-11 | 1988-09-21 | 中南工业大学 | 用钨细泥及难选低品位钨矿制取仲钨酸铵 |
CN1037882A (zh) * | 1988-04-29 | 1989-12-13 | 阿托化学公司 | 由稀盐酸制备氯化铁的方法 |
JP3625270B2 (ja) * | 2000-07-06 | 2005-03-02 | 太平洋セメント株式会社 | 廃棄物の処理方法 |
CN101333598A (zh) * | 2008-01-17 | 2008-12-31 | 郴州钻石钨制品有限责任公司 | 一种从钨冶炼产生的除钼渣中分离提取金属钨、钼的方法 |
CN101565778A (zh) * | 2009-05-22 | 2009-10-28 | 中南大学 | 一种从钨钼酸盐混合溶液中沉淀分离钨钼的方法 |
CN101696062A (zh) * | 2009-10-24 | 2010-04-21 | 刘向文 | 仲钨酸铵制备中的废水处理工艺 |
CN102061524A (zh) * | 2010-11-08 | 2011-05-18 | 崇义章源钨业股份有限公司 | 一种单晶仲钨酸铵及其制备方法 |
CN102071313A (zh) * | 2011-01-29 | 2011-05-25 | 湖南辰州矿业股份有限公司 | 一种处理仲钨酸铵生产过程中产生的含钨钼渣的方法 |
CN102212697A (zh) * | 2011-05-18 | 2011-10-12 | 湖南稀土金属材料研究院 | 钨渣处理方法 |
EP2450312A1 (en) * | 2010-11-03 | 2012-05-09 | Montanuniversität Leoben | Recovery of tungsten from waste material by ammonium leaching |
-
2012
- 2012-11-23 CN CN201210479906.7A patent/CN103103358B/zh not_active Expired - Fee Related
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN87101927A (zh) * | 1987-03-11 | 1988-09-21 | 中南工业大学 | 用钨细泥及难选低品位钨矿制取仲钨酸铵 |
CN1037882A (zh) * | 1988-04-29 | 1989-12-13 | 阿托化学公司 | 由稀盐酸制备氯化铁的方法 |
JP3625270B2 (ja) * | 2000-07-06 | 2005-03-02 | 太平洋セメント株式会社 | 廃棄物の処理方法 |
CN101333598A (zh) * | 2008-01-17 | 2008-12-31 | 郴州钻石钨制品有限责任公司 | 一种从钨冶炼产生的除钼渣中分离提取金属钨、钼的方法 |
CN101565778A (zh) * | 2009-05-22 | 2009-10-28 | 中南大学 | 一种从钨钼酸盐混合溶液中沉淀分离钨钼的方法 |
CN101696062A (zh) * | 2009-10-24 | 2010-04-21 | 刘向文 | 仲钨酸铵制备中的废水处理工艺 |
EP2450312A1 (en) * | 2010-11-03 | 2012-05-09 | Montanuniversität Leoben | Recovery of tungsten from waste material by ammonium leaching |
CN102061524A (zh) * | 2010-11-08 | 2011-05-18 | 崇义章源钨业股份有限公司 | 一种单晶仲钨酸铵及其制备方法 |
CN102071313A (zh) * | 2011-01-29 | 2011-05-25 | 湖南辰州矿业股份有限公司 | 一种处理仲钨酸铵生产过程中产生的含钨钼渣的方法 |
CN102212697A (zh) * | 2011-05-18 | 2011-10-12 | 湖南稀土金属材料研究院 | 钨渣处理方法 |
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CN103103358A (zh) | 2013-05-15 |
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