CN103053523B - Synergistic insecticidal composition containing flonicamid and pyridalyl and application thereof - Google Patents
Synergistic insecticidal composition containing flonicamid and pyridalyl and application thereof Download PDFInfo
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- CN103053523B CN103053523B CN201110319744.6A CN201110319744A CN103053523B CN 103053523 B CN103053523 B CN 103053523B CN 201110319744 A CN201110319744 A CN 201110319744A CN 103053523 B CN103053523 B CN 103053523B
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- pyridalyl
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- insecticidal compositions
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- 239000005926 Pyridalyl Substances 0.000 title claims abstract description 70
- 239000005900 Flonicamid Substances 0.000 title claims abstract description 68
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 title claims abstract description 55
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 230000000749 insecticidal Effects 0.000 title claims abstract description 38
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 230000002195 synergetic Effects 0.000 title claims abstract description 25
- 241000238631 Hexapoda Species 0.000 claims abstract description 13
- 241001124076 Aphididae Species 0.000 claims abstract description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 6
- 235000009566 rice Nutrition 0.000 claims abstract description 6
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000004480 active ingredient Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000000375 suspending agent Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000002917 insecticide Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 239000004530 micro-emulsion Substances 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 2
- 230000000240 adjuvant Effects 0.000 claims description 2
- 241000607479 Yersinia pestis Species 0.000 abstract description 11
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 241001498622 Cixius wagneri Species 0.000 abstract description 4
- 241000258937 Hemiptera Species 0.000 abstract description 3
- 230000001934 delay Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
- 239000003814 drug Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- -1 flunicotamid) Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 4
- 230000000361 pesticidal Effects 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 241001556089 Nilaparvata lugens Species 0.000 description 3
- 241000176086 Sogatella furcifera Species 0.000 description 3
- 238000004166 bioassay Methods 0.000 description 3
- 239000004562 water dispersible granule Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 241001414989 Thysanoptera Species 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N Tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000003042 antagnostic Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000001519 tissues Anatomy 0.000 description 2
- 241001136249 Agriotes lineatus Species 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 210000000481 Breast Anatomy 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241001427559 Collembola Species 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 241001517923 Douglasiidae Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 231100000614 Poison Toxicity 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 210000002784 Stomach Anatomy 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000001055 chewing Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 230000003111 delayed Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drugs Drugs 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000018984 mastication Effects 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N n-methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- DFPAKSUCGFBDDF-UHFFFAOYSA-N nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011708 vitamin B3 Substances 0.000 description 1
- 235000019160 vitamin B3 Nutrition 0.000 description 1
Abstract
The invention discloses a synergistic insecticidal composition containing flonicamid and pyridalyl and application thereof. The synergistic insecticidal composition comprises main effective components of flonicamid and pyridalyl in a weight ratio of 0.1-80:0.2-70. The insecticidal composition can produce high synergetic effect, overcomes and delays the insect resistance, and has high insecticidal speed, long duration and reduced use cost. The composition provided by the invention can control hemipteran pests in crops, especially rice planthopper, whiteflies and aphids, and has effect obviously higher than that of a single agent.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Synergistic insecticidal compositions and application thereof that flonicamid and pyridalyl be main active ingredient of take.
Background technology
Flonicamid (flonicamid, flunicotamid), chemical name: N-cyanogen methyl. (trifluoromethyl) vitamin PP.Flonicamid belongs to lower toxicity insecticide variety.This agent is effective to various suckings pest, and has good osmosis.It can be from root to stem, the infiltration of leaf portion, but by leaf portion to stem, root osmosis relatively a little less than.This medicament causes effect by hindering insect act of sucking.Insect stops sucking after taking in medicament very soon, last hungry and dead.
Insect according to electronics sucks behavior (EMIII) parsing, and this agent can make the lancet tissue of the sucking insects such as aphid cannot insert plant tissue and cause effect.10% water dispersible granules, every 667m when the insects such as vegetable aphid such as control cucumber
2use 10% water dispersible granules 30-50g to spray water.When preventing and treating the fruit aphids such as apple, with 10% water dispersible granules, add water 2500-5000 and doubly spray.Through test and land for growing field crops, use proof, flonicamid is to various aphids, plant hopper, aleyrodid, leafhopper, fruit bat, wireworm, thrips, ant class, leaf miner, and the first-class sucking pest of springtail has special efficacy, and pests with chewing mouthparts is also had to good control efficiency.But at present, the homoptera pests such as plant hopper and aphid are under the condition of long-term prescription, resistance increases gradually, uses separately flonicamid can not effectively prevent and treat this class pest.
Pyridalyl (pyridalyl), chemical name 2, the chloro-4-of 6-bis-(3,3-, bis-chloroallyloxyaminos) phenyl 3-[5-(trifluoromethyl-2 hydroxy pyrimidine) propyl group] ether.Structural formula is as follows:
Pyridalyl has simultaneously tags and stomach poison function, and the larva of lepidoptera pest main in agricultural production is had to very high insecticidal activity.In addition, pyridalyl also demonstrates good insecticidal activity to thrips and dipterous insect, contrary with its high activity, and pyridalyl is very low to various useful arthropodan toxicity.
Summary of the invention
The object of this invention is to provide a kind of Synergistic insecticidal compositions containing flonicamid and pyridalyl.
Another object of the present invention is to provide above-mentioned Synergistic insecticidal compositions and prevents and treats the application in resistance Semiptera insect insecticidal materials in preparation.
For achieving the above object, the present invention is composite by different two kinds of insecticidal materials flonicamids and the pyridalyl of controlling object, obtains the new and effective multifunctional insecticide composition of a class.The various pests that this Pesticidal combination easily produces resistance to rice fulgorid, aphid, diamond-back moth has good preventive effect; And suppress insect the pesticide resistance of unitary agent (flonicamid or pyridalyl) is produced.
The present invention adopts following technical scheme:
Containing a Synergistic insecticidal compositions for flonicamid and pyridalyl, it is characterized in that it is main active ingredient that this Synergistic insecticidal compositions be take flonicamid and pyridalyl, wherein, the weight ratio of flonicamid and pyridalyl is 0.1～80: 0.2～70.
In this Synergistic insecticidal compositions, the weight ratio of flonicamid and pyridalyl preferably 0.5～60: 2～50, and more preferably 1～30: 4～20.
In the present composition, the two percentage by weight that accounts for composition of flonicamid and pyridalyl is 3～80%.Be preferably 5～50%, most preferably 5～20%." % " of the present invention is mass percent.
It is main active ingredient (active component) that above-mentioned Insecticidal combinations be take flonicamid and pyridalyl, and insecticides adjuvant, excipients are mixed with any one formulation allowing on agricultural chemicals.Be preferably missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion and water dispersion granule.
Described auxiliary agent specifically can adopt usual auxiliaries, if calcium dodecyl benzene sulfonate, emulsifier 600 #, the rare block compound of polyoxyethylene polyoxy third are (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient can adopt cyclohexanone, solvent naphtha, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Auxiliary agent, excipient can alone or mixing use, also can add other auxiliary material allowing on pesticidal preparations.
Above-mentioned Pesticidal combination can be prevented and treated the application in the insecticidal materials of resistance Semiptera insect in preparation, and the control efficiency of the present composition is used apparently higher than its single dose, and described Semiptera insect refers in particular to rice fulgorid, aphid, aleyrodid.
Indoor bioassay and field control effectiveness test show that compound insecticidal medicine of the present invention has significant synergistic insecticidal action to Semiptera insect, is all significantly higher than the effect of corresponding single dose agricultural chemicals especially to the insecticidal effect of water rice hopper, aphid, aleyrodid.
Beneficial effect of the present invention: the flonicamid providing of the present invention and pyridalyl Pesticidal combination, can produce higher synergistic function, desinsection speed is fast, overcome and delayed pest resistance to insecticide, expanding prevention spectrum, has reduced drug cost simultaneously, and its successful is used higher than its single dose.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, then carry out field trial.
Embodiment 1:
Take flonicamid, pyridalyl employing conventional formulation method, be mixed with the flonicamid pyridalyl missible oil that active ingredient quality percentage composition is 30% respectively by different proportion, concrete ratio is in Table 1,2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The Toxicity Determination of table 1. flonicamid and pyridalyl composition and single dose antagonism rice fulgorid thereof:
In table, data show, after flonicamid and pyridalyl are mixed, Brown Planthopper are had to synergistic effect, and three proportioning co-toxicity coefficients listed in table are all much larger than 120, so flonicamid and pyridalyl are mixed and have significant synergies.
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistance aleyrodid is target pest, and every processing repeats 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The Toxicity Determination of table 2. flonicamid and pyridalyl Synergistic insecticidal compositions and single dose antagonism aleyrodid thereof:
In table, data show, after flonicamid and pyridalyl are mixed, aleyrodid are had to synergistic effect, and three proportioning co-toxicity coefficients listed in table are all much larger than 120, and flonicamid and pyridalyl are mixed and have significant synergies.
Adopt the sample of embodiment 2 and 3, according to every mu of ground medication 10g, 20g, 25g preparation, contrast medicament is 10% pyridalyl WP30g/ mu, 5% flonicamid AS30g/ mu, every mu of ground water 30kg control Brown Planthopper.Within after dispenser 4 days, 10 days, 15 days, 20 days, 30 days, come to an end really, and carry out data processing, the results are shown in Table 3:
Table 3: flonicamid and the field test results of pyridalyl Synergistic insecticidal compositions to Brown Planthopper
As can be known from the above table, flonicamid pyridalyl is composite is better than 10% pyridalyl wetting powder, 5% flonicamid aqua to water rice hopper drug effect, demonstrates the superiority of formula.
Adopt the sample of embodiment 2 and 3, according to every mu of ground medication 10g, 20g, 25g medicament, contrast medicament is 10% pyridalyl WP30g/ mu, 5% flonicamid AS30g/ mu, every mu of ground water 30kg, the aleyrodid on control cucumber.Within after dispenser 4 days, 10 days, 15 days, 20 days, 30 days, come to an end really, and process, the results are shown in Table 4:
Table 4: the composite field test results to aleyrodid of flonicamid-pyridalyl
As can be known from the above table, flonicamid pyridalyl is composite is better than 10% pyridalyl wetting powder, 5% flonicamid aqua to aleyrodid drug effect, demonstrates the superiority of formula.
Embodiment 2:
Take 10g flonicamid, 0.5g pyridalyl is dissolved in 8g solvent naphtha, then adds 1g ethylene glycol and 5g emulsifier 600 #, stir.Above-mentioned solution is slowly poured in excess water to gross weight 100g, under fully stirring, made 10.5% flonicamid pyridalyl aqueous emulsion.
Embodiment 3:
Take 10g flonicamid, 1g pyridalyl is dissolved in 8g solvent naphtha, then adds 1g ethylene glycol and 5g600# disodium sulfosuccinate, stir.Above-mentioned solution is slowly poured in excess water, under fully stirring, made 11% flonicamid pyridalyl aqueous emulsion.
Embodiment 4:
Take 45g flonicamid, 5g pyridalyl is dissolved in 8g solvent naphtha, then adds 1g ethylene glycol and 5g600# disodium sulfosuccinate, stir.Above-mentioned solution is slowly poured in excess water, under fully stirring, made 50% flonicamid pyridalyl aqueous emulsion.
Embodiment 5:
Take 2g flonicamid, 20g pyridalyl, emulsifier 600 #5g, phenethyl phenol polyethenoxy ether 6g, 1-METHYLPYRROLIDONE 4g, isopropyl alcohol 6g, solvent naphtha 3g, surplus is water, the method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and makes 22% flonicamid pyridalyl microemulsion.
Embodiment 6:
Take 5g flonicamid, 45g pyridalyl, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, makes 50% flonicamid pyridalyl water dispersion granule by above raw material by the method for water dispersion granule.
Embodiment 7:
Take 75g flonicamid, 0.2g pyridalyl, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is water, above raw material is prepared routinely to the method for suspending agent, made 75.2% flonicamid pyridalyl suspending agent.
Embodiment 8:
Take 10g flonicamid, 15g pyridalyl, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is water, above raw material is prepared routinely to the method for suspending agent, made 25% flonicamid pyridalyl suspending agent.
Embodiment 9:
Take 5g flonicamid, 70g pyridalyl, calcium dodecyl benzene sulfonate 4g, emulsifier 600 #4g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and makes 75% flonicamid pyridalyl missible oil.
Embodiment 10:
Take 0.1g flonicamid, 30g pyridalyl, calcium dodecyl benzene sulfonate 4g, emulsifier 600 #4g, phenethyl phenol polyethenoxy ether 6g, solvent naphtha to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and makes 30.1% flonicamid pyridalyl missible oil.
Embodiment 11:
Take 30g flonicamid, 20g pyridalyl, calcium dodecyl benzene sulfonate 4g, emulsifier 600 #5g, phenethyl phenol polyethenoxy ether 6g, solvent naphtha to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and makes 50% flonicamid pyridalyl missible oil.
Embodiment 12:
Take 60g flonicamid, 5g pyridalyl, 1g lauryl sodium sulfate, 0.5g dispersing agent NNO, kaolin to 100g, above raw material is prepared routinely to the method for wetting powder and mixed, form 65% flonicamid pyridalyl wetting powder.
Claims (7)
1. containing a Synergistic insecticidal compositions for flonicamid and pyridalyl, it is characterized in that it is active ingredient that this Synergistic insecticidal compositions be take flonicamid and pyridalyl, wherein, the weight ratio of flonicamid and pyridalyl is 10:1,15:1 or 20:1.
2. the Synergistic insecticidal compositions containing flonicamid and pyridalyl according to claim 1, is characterized in that the two weight percentage that accounts for composition of flonicamid and pyridalyl is 3 ~ 80%.
3. the Synergistic insecticidal compositions containing flonicamid and pyridalyl according to claim 2, is characterized in that the two weight percentage that accounts for composition of flonicamid and pyridalyl is 5 ~ 50%.
4. according to the Synergistic insecticidal compositions containing flonicamid and pyridalyl described in claim 1,2 or 3, it is characterized in that it take flonicamid and pyridalyl and be mixed with any one formulation allowing on agricultural chemicals as active ingredient and insecticides adjuvant.
5. the Synergistic insecticidal compositions containing flonicamid and pyridalyl according to claim 4, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
6. the Synergistic insecticidal compositions containing flonicamid and pyridalyl claimed in claim 1 is prevented and treated the application in the insecticidal materials of resistance Semiptera insect in preparation.
7. the application of the Synergistic insecticidal compositions containing flonicamid and pyridalyl claimed in claim 1 in the insecticidal materials of preparation control water rice hopper, aleyrodid, aphid.
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| CN103355306A (en) * | 2012-03-27 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing pyridalyl and amide |
| CN104521973A (en) * | 2014-12-10 | 2015-04-22 | 青岛无为保温材料有限公司 | Novel pesticide composition containing pyridalyl |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169147A (en) * | 1994-10-14 | 1997-12-31 | 住友化学工业株式会社 | Dihalopropene compounds, insecticidal/acaricidal agent contg. same, and intermediates |
| CN102017948A (en) * | 2009-09-22 | 2011-04-20 | 南京华洲药业有限公司 | Synergistic pesticide combination containing nitenpyram and pyridalyl and application of combination |
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| JP4622078B2 (en) * | 2000-10-18 | 2011-02-02 | 住友化学株式会社 | Insecticide composition and method |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1169147A (en) * | 1994-10-14 | 1997-12-31 | 住友化学工业株式会社 | Dihalopropene compounds, insecticidal/acaricidal agent contg. same, and intermediates |
| CN102017948A (en) * | 2009-09-22 | 2011-04-20 | 南京华洲药业有限公司 | Synergistic pesticide combination containing nitenpyram and pyridalyl and application of combination |
Non-Patent Citations (1)
| Title |
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| JP特开2002-128613A 2002.05.09 |
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Effective date of registration: 20180524 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |