CN103053566A - Compound insecticidal composition containing flonicamid and metolcarb, and application thereof - Google Patents

Compound insecticidal composition containing flonicamid and metolcarb, and application thereof Download PDF

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Publication number
CN103053566A
CN103053566A CN2011103202162A CN201110320216A CN103053566A CN 103053566 A CN103053566 A CN 103053566A CN 2011103202162 A CN2011103202162 A CN 2011103202162A CN 201110320216 A CN201110320216 A CN 201110320216A CN 103053566 A CN103053566 A CN 103053566A
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China
Prior art keywords
tolyl
mtmc
methylcarbamate
meta
flonicamid
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CN2011103202162A
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齐武
邢平
王红明
陈凤
王俊东
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN2011103202162A priority Critical patent/CN103053566A/en
Publication of CN103053566A publication Critical patent/CN103053566A/en
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Abstract

The invention discloses a compound insecticidal composition containing flonicamid and metolcarb, and an application thereof. The synergistic insecticidal composition employs flonicamid and metolcarb as main effective components, wherein a weight ratio of flonicamid to metolcarb is 0.1-80 : 0.5-80. The insecticidal composition can produce a relatively high synergistic interaction effect, overcomes or delays pest resistance, has fast insecticidal speed and long efficacy duration, reduces pesticide cost and has a prevention effect obviously higher than that of a single dosage. The insecticidal composition can be used for preventing homoptera pests generated on crops, and is particularly suitable for preventing rice hopper and aphid, with an effect obviously higher than that of the single dosage.

Description

Compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and meta-tolyl-N-methylcarbamate (MTMC) and uses thereof
Technical field
The invention belongs to pesticide field, be specifically related to compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and meta-tolyl-N-methylcarbamate (MTMC) and uses thereof.
Background technology
Flonicamid (flonicamid, flunicotamid), chemical name: N-cyanogen methyl. (trifluoromethyl) vitamin PP.
Flonicamid belongs to the lower toxicity insecticide variety.This agent is effective to various suckings pest, and has good osmosis.It can be from root to stem, the infiltration of leaf section, but by leaf section to stem, root osmosis relatively a little less than.
This medicament causes effect by hindering the insect act of sucking.Insect stops to suck after taking in medicament very soon, and is last hungry and dead.
Insect according to electronics sucks behavior (EMIII) parsing, and this agent can make the lancet tissue of the sucking insects such as aphid can't insert plant tissue and cause effect.10% water dispersible granules, every 667m when the insects such as vegetable aphid such as control cucumber 2Use 10% water dispersible granules 30-50g that water is sprayed.When for fruit aphids such as control apples, add water 2500-5000 with 10% water dispersible granules and doubly spray.Use proof through test and land for growing field crops, flonicamid is to various aphids, plant hopper, aleyrodid, leafhopper, fruit bat, wireworm, thrips, ant class, leaf miner, and the first-class sucking pest of springtail has special efficacy, and pests with chewing mouthparts is also had good control efficiency.
Meta-tolyl-N-methylcarbamate (MTMC) is a kind of carbamate insecticide.Chemical name is: a tolyl-N-methyl carbamate, and structural formula is:
Meta-tolyl-N-methylcarbamate (MTMC) has insect tags and fumigation action, and the power of knocking down is strong, and holding effect is short.Can be used to prevent and treat towering like a mountain peak lice, leafhopper, cotten aphid, thrips, cotton bollworm etc.; Control rice fulgorid, rice leafhopper, rice thrips etc. have special efficacy.To the people, animal moderate toxicity.
But rice fulgorid and aphid are under the condition of present long-term prescription, and resistance increases gradually, and the agricultural chemicals single dose descends gradually to the effect of control of insect.The inventor finds that after deliberation the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant flonicamid and meta-tolyl-N-methylcarbamate (MTMC).
Summary of the invention
The compound pesticide compositions that the purpose of this invention is to provide a kind of fluorine-containing pyridine insect amide and meta-tolyl-N-methylcarbamate (MTMC), this Pesticidal combination are the multifunctional insecticide compositions of control homoptera pest.
Another object of the present invention provides this Pesticidal combination and prevents and treats application on the insecticidal materials of resistance homoptera pest in preparation, particularly the application on the insecticidal materials of preparation control plant hopper, aleyrodid or aphid.
The objective of the invention is to be achieved through the following technical solutions:
The compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and meta-tolyl-N-methylcarbamate (MTMC), this Pesticidal combination is take flonicamid and meta-tolyl-N-methylcarbamate (MTMC) as main active ingredient, and wherein, the weight ratio of flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 0.1~80: 0.5~80.Be preferably 0.5~50: 2~50, more preferably 0.5~10: 4~30.Effective ingredient is present in the composition with the synergy effective dose in this Pesticidal combination.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 3~80%.Be preferably 5~55%, most preferably 10~40%." % " of the present invention is mass percent.
Pesticidal combination of the present invention take flonicamid and meta-tolyl-N-methylcarbamate (MTMC) as main active ingredient and insecticides adjuvant and excipient be mixed with any one formulation that allows on the agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, emulsifier 600 #, polyoxyethylene polyoxy third rare block compound (such as farming breast 33 #), polyoxyethylene nonylphenol ether etc., excipient comprises isopropyl alcohol, vegetable oil, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and usefulness.
Pesticidal combination of the present invention has good preventive effect to the multiple homoptera pest that rice fulgorid and aphid etc. produce resistance easily; And suppress insect to the pesticide resistance generation of unitary agent (flonicamid or meta-tolyl-N-methylcarbamate (MTMC) are arbitrary).
Above-mentioned Pesticidal combination is prevented and treated the application on the insecticidal materials of resistance homoptera pest in preparation, especially the effect on the insecticidal materials of preparation control aleyrodid, rice fulgorid or aphid is remarkable.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism homoptera pest such as rice fulgorid, aphid etc. have obvious synergistic function, overcome and have delayed pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the meta-tolyl-N-methylcarbamate (MTMC) single dose with flonicamid, produce and the use cost reduction; (6) suppress homoptera pest to the resistance enhancing of agricultural chemicals, its successful is higher than its single dose to be used.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
Taking by weighing flonicamid, meta-tolyl-N-methylcarbamate (MTMC), to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.Concrete ratio sees Table 1,2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting the resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method 50, use LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of the composite and single dose antagonism rice fulgorid of table 1 flonicamid and meta-tolyl-N-methylcarbamate (MTMC)
As shown in Table 1, flonicamid and meta-tolyl-N-methylcarbamate (MTMC) are composite, and co-toxicity coefficient shows good synergistic function all greater than 120.Wherein when flonicamid and meta-tolyl-N-methylcarbamate (MTMC) in the time of 1: 1 synergistic effect the most obvious.
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance wheat aphid is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method 50, use LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of the composite and single dose antagonism wheat aphid of table 2 flonicamid and meta-tolyl-N-methylcarbamate (MTMC)
As shown in Table 2, flonicamid and meta-tolyl-N-methylcarbamate (MTMC) are composite, and the co-toxicity coefficient of wheat aphid all greater than 120, is shown good synergistic function.Wherein when flonicamid and meta-tolyl-N-methylcarbamate (MTMC) in the time of 10: 1 synergistic effect the most obvious.
Embodiment 2:
Take by weighing 5g flonicamid, 50g meta-tolyl-N-methylcarbamate (MTMC), phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33 #2g, emulsifier 600 #1g, vegetable oil 13g adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely drops into the mixing kettle high speed mixes, and forms main active ingredient weight percentage and be 55% flonicamid meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsion.
Embodiment 3:
Take by weighing 2g flonicamid, 18g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33 #2g, emulsifier 600 #1g, isopropyl alcohol 10g adds water to 100g.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 20% flonicamid meta-tolyl-N-methylcarbamate (MTMC) microemulsion.
Embodiment 3 is prevented and treated the Brown Planthopper test of pesticide effectiveness, the contrast medicament is 20% meta-tolyl-N-methylcarbamate (MTMC) EC (missible oil) and 20% flonicamid EW (aqueous emulsion), dilutes according to the extension rate of 3 li of forms, looks into behind the medicine 3 days, 7 days result, result sees Table 3:
Table 3: the composite field test results to Brown Planthopper of flonicamid-meta-tolyl-N-methylcarbamate (MTMC)
(annotate: every mu of water consumption is 30kg)
Field efficacy is the result show, flonicamid meta-tolyl-N-methylcarbamate (MTMC) composition antagonism brown planthopper has good control efficiency, and control efficiency all is better than the effect that the single dose kind is better than direct each Dan Pin of while.
Embodiment 3 is prevented and treated the wheat aphid field medicine effect test, the contrast medicament is 20% meta-tolyl-N-methylcarbamate (MTMC) EC (missible oil) and 20% flonicamid EW (aqueous emulsion), dilutes according to the extension rate of 3 li of forms, looks into behind the medicine 3 days, 7 days result, result sees Table 4:
Table 4: the composite field test results to wheat aphid of flonicamid-meta-tolyl-N-methylcarbamate (MTMC)
(annotate: every mu of water consumption is 30kg)
Field efficacy is the result show, flonicamid meta-tolyl-N-methylcarbamate (MTMC) composition antagonism wheat aphid has good control efficiency, and control efficiency all is better than the effect that the single dose kind is better than direct each Dan Pin of while.
Embodiment 4:
Take by weighing 1g flonicamid, 5g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, vegetable oil to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 6% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 5: take by weighing 50g flonicamid, 20g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 70% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 6: take by weighing 2g flonicamid, 40g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 42% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 7: take by weighing 0.2g flonicamid, 50g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 50.2% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 8: take by weighing 5g flonicamid, 0.5g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 5.5% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 9: take by weighing 5g flonicamid, 30g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 35% flonicamid-meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 10: take by weighing 20g flonicamid, 5g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 25% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 11: take by weighing 30g flonicamid, 12g meta-tolyl-N-methylcarbamate (MTMC), lignosulfonates 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and the main active ingredient weight percentage of formation is 42% flonicamid meta-tolyl-N-methylcarbamate (MTMC) suspending agent under the effect of sand mill.
Embodiment 12: take by weighing 2g flonicamid, 5g meta-tolyl-N-methylcarbamate (MTMC), sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite is to 100g, and it is 7% flonicamid meta-tolyl-N-methylcarbamate (MTMC) water dispersion granule that above raw material is formed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 13: take by weighing 50g flonicamid, 3g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 53% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 14: take by weighing 2g flonicamid, 18g meta-tolyl-N-methylcarbamate (MTMC), lignin 10g, naphthalene sulfonate 2g, add to 100g with diatomite, above raw material is mixed in micronizer, form main active ingredient weight percentage and be 20% flonicamid meta-tolyl-N-methylcarbamate (MTMC) wetting powder.
Embodiment 15: take by weighing 7g flonicamid, 70g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 77% flonicamid meta-tolyl-N-methylcarbamate (MTMC) missible oil.
Embodiment 16: take by weighing 60g flonicamid, 5g meta-tolyl-N-methylcarbamate (MTMC), the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, it is 65% flonicamid Tsumacide water dispersible granule that above raw material is formed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 17: take by weighing 20g flonicamid, 20g meta-tolyl-N-methylcarbamate (MTMC), nonyl phenol phosphate 5g, emulsifier 600 #4g, n-butanol 3g, 10g solvent naphtha and 20g pyrrolidones, 0.1g xanthans, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10~30 minutes, form main active ingredient weight percentage and be 40% flonicamid meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsion.
Embodiment 18: take by weighing 60g flonicamid, 1g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 5g, emulsifier 600 #4g, the solvent naphtha of 10g and the pyrrolidones of 15g, all the other waters are supplied 100g, above-mentioned former medicine, solvent, emulsifier, cosolvent mix and blend are formed homogeneous phase transparent solution, slowly add at last entry and stir to form clear solution, be main active ingredient weight percentage and be 61% flonicamid meta-tolyl-N-methylcarbamate (MTMC) microemulsion.

Claims (9)

1. the compound pesticide compositions of a fluorine-containing pyridine insect amide and meta-tolyl-N-methylcarbamate (MTMC) is characterized in that this Pesticidal combination take flonicamid and meta-tolyl-N-methylcarbamate (MTMC) as main active ingredient, and wherein, the weight ratio of flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 0.1~80: 0.5~80.
2. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and meta-tolyl-N-methylcarbamate (MTMC), the weight ratio that it is characterized in that described flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 0.5~50: 2~50.
3. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 2 and meta-tolyl-N-methylcarbamate (MTMC), the weight ratio that it is characterized in that described flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 0.5~10: 4~30.
4. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and meta-tolyl-N-methylcarbamate (MTMC) is characterized in that the two weight percentage in this compound pesticide compositions of flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 3%~80%.
5. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 4 and meta-tolyl-N-methylcarbamate (MTMC) is characterized in that the two weight percentage in this compound pesticide compositions of flonicamid and meta-tolyl-N-methylcarbamate (MTMC) is 5%~55%.
6. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and meta-tolyl-N-methylcarbamate (MTMC) is characterized in that this compound pesticide compositions take flonicamid and meta-tolyl-N-methylcarbamate (MTMC) as main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals.
7. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 6 and meta-tolyl-N-methylcarbamate (MTMC) is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
8. the compound pesticide compositions of fluorine-containing pyridine insect amide claimed in claim 1 and meta-tolyl-N-methylcarbamate (MTMC) is prevented and treated the application on the insecticidal materials of resistance homoptera pest in preparation.
The compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 8 and meta-tolyl-N-methylcarbamate (MTMC) anti-eliminate aphis in preparation, the application on the insecticidal materials of aleyrodid or plant hopper.
CN2011103202162A 2011-10-20 2011-10-20 Compound insecticidal composition containing flonicamid and metolcarb, and application thereof Pending CN103053566A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103380776A (en) * 2012-05-03 2013-11-06 陕西韦尔奇作物保护有限公司 Insecticidal composition containing flonicamid and carbamate

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL106340A (en) * 1992-07-23 1999-03-12 Ishihara Sangyo Kaisha 3-Pyridine amide compounds and their salts processes for their production and insecticidal miticidal and nematocidal compositions containing them
CA2405773A1 (en) * 2000-04-11 2001-10-18 Bayer Aktiengesellschaft Active substance combinations having insecticidal and acaricidal properties
WO2002037964A1 (en) * 2000-11-10 2002-05-16 Syngenta Participations Ag Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL106340A (en) * 1992-07-23 1999-03-12 Ishihara Sangyo Kaisha 3-Pyridine amide compounds and their salts processes for their production and insecticidal miticidal and nematocidal compositions containing them
CA2405773A1 (en) * 2000-04-11 2001-10-18 Bayer Aktiengesellschaft Active substance combinations having insecticidal and acaricidal properties
WO2002037964A1 (en) * 2000-11-10 2002-05-16 Syngenta Participations Ag Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103380776A (en) * 2012-05-03 2013-11-06 陕西韦尔奇作物保护有限公司 Insecticidal composition containing flonicamid and carbamate

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Application publication date: 20130424