CN103053567A - Compound insecticidal composition containing flonicamid and isoprocarb, and application thereof - Google Patents

Compound insecticidal composition containing flonicamid and isoprocarb, and application thereof Download PDF

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Publication number
CN103053567A
CN103053567A CN2011103208826A CN201110320882A CN103053567A CN 103053567 A CN103053567 A CN 103053567A CN 2011103208826 A CN2011103208826 A CN 2011103208826A CN 201110320882 A CN201110320882 A CN 201110320882A CN 103053567 A CN103053567 A CN 103053567A
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mobucin
flonicamid
pesticide compositions
compound pesticide
fluorine
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陈文明
邢平
郭崇友
夏小云
王俊东
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Abstract

The invention discloses a compound insecticidal composition containing flonicamid and isoprocarb, and an application thereof. The synergistic insecticidal composition employs flonicamid and isoprocarb as main effective components, wherein a weight ratio of flonicamid to isoprocarb is 0.1-80 : 0.5-80. The insecticidal composition can produce a relatively high synergistic interaction effect, overcomes or delays pest resistance, has fast insecticidal speed and long efficacy duration, reduces pesticide cost and has a prevention effect obviously higher than that of a single dosage. The insecticidal composition can be used for preventing homoptera pests generated on crops, and is particularly suitable for preventing rice hopper and aphid, with an effect obviously higher than that of the single dosage.

Description

Compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and Mobucin and uses thereof
Technical field
The invention belongs to pesticide field, be specifically related to compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and Mobucin and uses thereof.
Background technology
Flonicamid (flonicamid, flunicotamid), chemical name: N-cyanogen methyl. (trifluoromethyl) vitamin PP.
Flonicamid belongs to the lower toxicity insecticide variety.This agent is effective to various suckings pest, and has good osmosis.It can be from root to stem, the infiltration of leaf section, but by leaf section to stem, root osmosis relatively a little less than.
This medicament causes effect by hindering the insect act of sucking.Insect stops to suck after taking in medicament very soon, and is last hungry and dead.
Insect according to electronics sucks behavior (EMIII) parsing, and this agent can make the lancet tissue of the sucking insects such as aphid can't insert plant tissue and cause effect.10% water dispersible granules, every 667m when the insects such as vegetable aphid such as control cucumber 2Use 10% water dispersible granules 30-50g that water is sprayed.When for fruit aphids such as control apples, add water 2500-5000 with 10% water dispersible granules and doubly spray.Use proof through test and land for growing field crops, flonicamid is to various aphids, plant hopper, aleyrodid, leafhopper, fruit bat, wireworm, thrips, ant class, leaf miner, and the first-class sucking pest of springtail has special efficacy, and pests with chewing mouthparts is also had good control efficiency.
Mobucin, chemical name: methylamino formic acid-2-isopropyl phenyl ester, molecular formula: C 11H 15NO 2, structural formula is:
Figure BDA0000100485040000011
Mobucin is the insecticide that a kind of tagging property has the carbamate of systemic action concurrently.Quick-acting, but the drug effect phase is very short.Be mainly used in preventing and treating rice leafhopper, cotton leafhopper and rice fulgorid etc., and can doublely control thrips, also can prevent and treat other pests with chewing mouthparts.Very little on the Natural Spider Enemies impact, the lasting period is shorter.Harmful to honeybee.Under general concentration, to crop safety, but taro there is poisoning.Should not execute with alkaline agricultural chemicals is mixed, can not use simultaneously with Stam F-34, but use more than 10 days at the interval.
But the insect such as rice fulgorid, aphid is under the condition of present long-term prescription, and resistance increases gradually, and the agricultural chemicals single dose descends gradually to the effect of control of insect.The inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant flonicamid and Mobucin.
Summary of the invention
The compound pesticide compositions that the purpose of this invention is to provide a kind of fluorine-containing pyridine insect amide and Mobucin, this Pesticidal combination are the multifunctional insecticide compositions of control homoptera pest.
Another object of the present invention provides this Pesticidal combination and prevents and treats application on the insecticidal materials of resistance homoptera pest in preparation, particularly the application on the insecticidal materials of preparation control plant hopper, aphid.
The objective of the invention is to be achieved through the following technical solutions:
The compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and Mobucin, this Pesticidal combination is take flonicamid and Mobucin as main active ingredient, and wherein, the weight ratio of flonicamid and Mobucin is 0.1~80: 0.5~80.Be preferably 0.5~50: 2~50, more preferably 0.5~10: 4~30, most preferably be 1~10: 1~10.Effective ingredient is present in the composition with the synergy effective dose in this Pesticidal combination.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of flonicamid and Mobucin is 3%~80%.Be preferably 5%~55%, most preferably 10%~40%." % " of the present invention is mass percent.
Compound pesticide compositions of the present invention take flonicamid and Mobucin as main active ingredient and insecticides adjuvant and excipient be mixed with any one formulation that allows on the agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, emulsifier 600 #, polyoxyethylene polyoxy third rare block compound (such as farming breast 33 #), polyoxyethylene nonylphenol ether etc., excipient comprises solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and usefulness.
Compound pesticide compositions of the present invention has good preventive effect to the multiple homoptera pest that rice fulgorid and snout moth's larva etc. easily produce resistance; And suppress insect to the pesticide resistance generation of unitary agent (flonicamid or Mobucin are arbitrary).
Above-mentioned compound pesticide compositions is prevented and treated application on the resistance homoptera pest insecticidal materials in preparation, and especially the effect on preparation control plant hopper or aphid insecticidal materials is remarkable.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism homoptera pest such as rice fulgorid, aphid etc. have obvious synergistic function, overcome and have delayed pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the Mobucin single dose with flonicamid, produce and the use cost reduction; (6) suppress homoptera pest to the resistance enhancing of agricultural chemicals, its successful is higher than its single dose to be used.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
Taking by weighing flonicamid, Mobucin, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% flonicamid Mobucin missible oil.Concrete ratio sees Table 1,2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting the resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method 50, use LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of the composite and single dose antagonism rice fulgorid of table 1 flonicamid and Mobucin
Figure BDA0000100485040000031
As shown in Table 1, flonicamid and Mobucin are composite, and co-toxicity coefficient shows good synergistic function all greater than 120, wherein when flonicamid and Mobucin in the time of 1: 1 synergistic effect the most obvious.
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance wheat aphid is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method 50, use LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of the composite and single dose antagonism aphid of table 2 flonicamid and Mobucin
Figure BDA0000100485040000032
As shown in Table 2, flonicamid and Mobucin are composite, and the co-toxicity coefficient of wheat aphid all greater than 120, is shown good synergistic function, and wherein when flonicamid and Mobucin in the time of 2: 1, synergistic effect is the most obvious.
Embodiment 2: take by weighing 5g flonicamid, 50g Mobucin, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33 #2g, emulsifier 600 #1g, solvent naphtha 13g adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely drops into the mixing kettle high speed mixes, and forms main active ingredient weight percentage and be 55% flonicamid Mobucin aqueous emulsion.
Embodiment 3: take by weighing 2g flonicamid, 18g Mobucin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33 #2g, emulsifier 600 #1g, cyclohexanone 10g adds water to 100g.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 20% flonicamid Mobucin microemulsion.
Embodiment 3 is prevented and treated the Brown Planthopper test of pesticide effectiveness, the contrast medicament is 20% Mobucin WP (wetting powder) and 20% flonicamid WP (wetting powder), dilutes according to the extension rate of 3 li of forms, looks into behind the medicine 3 days, 7 days result, result sees Table 3:
Table 3: the composite field test results to Brown Planthopper of flonicamid-Mobucin
Figure BDA0000100485040000041
(annotate: every mu of water consumption is 30kg)
Field efficacy is the result show, flonicamid Mobucin composition antagonism brown planthopper has good control efficiency, and control efficiency all is better than the effect that the single dose kind is better than direct each single product of while.
Embodiment 3 is prevented and treated the cotton aphid field medicine effect test, the contrast medicament is 20% Mobucin EC (missible oil) and 20% flonicamid AS (aqua), dilutes according to the extension rate of 3 li of forms, looks into behind the medicine 3 days, 7 days result, result sees Table 4:
Table 4: the composite field test results to cotton aphid of flonicamid-Mobucin
Figure BDA0000100485040000042
Figure BDA0000100485040000051
(annotate: every mu of water consumption is 30kg)
Field efficacy is the result show, flonicamid Mobucin composition has good control efficiency to cotton aphid, and control efficiency all is better than the effect that the single dose kind is better than direct each single product of while.
Embodiment 4: take by weighing 1g flonicamid, 5g Mobucin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 6% flonicamid Mobucin missible oil.
Embodiment 5: take by weighing 50g flonicamid, 20g Mobucin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 70% flonicamid Mobucin missible oil.
Embodiment 6: take by weighing 2g flonicamid, 40g Mobucin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 42% flonicamid Mobucin missible oil.
Embodiment 7: take by weighing 0.2g flonicamid, 50g Mobucin, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 50.2% flonicamid Mobucin missible oil.
Embodiment 8: take by weighing 5g flonicamid, 0.5g Mobucin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 5.5% flonicamid Mobucin missible oil.
Embodiment 9: take by weighing 5g flonicamid, 30g Mobucin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms the main active ingredient weight percentage of system and be 35% flonicamid Mobucin missible oil.
Embodiment 10: take by weighing 20g flonicamid, 5g Mobucin, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms the main active ingredient weight percentage of preparation and be 25% flonicamid Mobucin missible oil.
Embodiment 11: take by weighing 30g flonicamid, 12g Mobucin, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and the weight percentage that forms main active ingredient under the effect of sand mill is 42% flonicamid Mobucin suspending agent.
Embodiment 12: take by weighing 2g flonicamid, 5g Mobucin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite is to 100g, and the weight percentage that above raw material is formed main active ingredient by the water dispersible granular agent method is 7% flonicamid Mobucin water dispersion granule.
Embodiment 13: take by weighing 50g flonicamid, 3g Mobucin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and the weight percentage that forms main active ingredient is 53% flonicamid Mobucin missible oil.
Embodiment 14: take by weighing 2g flonicamid, 18g Mobucin, lignin 10g, Negel 2g, add to 100g with diatomite, above raw material is mixed in micronizer, and the weight percentage that forms main active ingredient is 20% flonicamid Mobucin wetting powder.
Embodiment 15: take by weighing 7g flonicamid, 70g Mobucin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and the weight percentage that forms main active ingredient is 77% flonicamid Mobucin missible oil.
Embodiment 16: take by weighing 60g flonicamid, 5g Mobucin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin is to 100g, and the weight percentage that above raw material is formed main active ingredient by the water dispersible granular agent method is 65% flonicamid Mobucin water dispersible granules.

Claims (9)

1. the compound pesticide compositions of a fluorine-containing pyridine insect amide and Mobucin is characterized in that this Pesticidal combination take flonicamid and Mobucin as main active ingredient, and wherein, the weight ratio of flonicamid and Mobucin is 0.1~80: 0.5~80.
2. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and Mobucin, the weight ratio that it is characterized in that described flonicamid and Mobucin is 0.5~50: 2~50.
3. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 2 and Mobucin, the weight ratio that it is characterized in that described flonicamid and Mobucin is 0.5~10: 4~30.
4. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and Mobucin is characterized in that the two weight percentage in this compound pesticide compositions of flonicamid and Mobucin is 3%~80%.
5. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 4 and Mobucin is characterized in that the two weight percentage in this compound pesticide compositions of flonicamid and Mobucin is 5%~55%.
6. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and Mobucin is characterized in that this compound pesticide compositions take flonicamid and Mobucin as main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals.
7. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 6 and Mobucin is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
8. the compound pesticide compositions of fluorine-containing pyridine insect amide claimed in claim 1 and Mobucin is prevented and treated the application on the insecticidal materials of resistance homoptera pest in preparation.
The compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 8 and Mobucin anti-eliminate aphis in preparation, the application on the insecticidal materials of plant hopper.
CN2011103208826A 2011-10-20 2011-10-20 Compound insecticidal composition containing flonicamid and isoprocarb, and application thereof Pending CN103053567A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103380776A (en) * 2012-05-03 2013-11-06 陕西韦尔奇作物保护有限公司 Insecticidal composition containing flonicamid and carbamate

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002037964A1 (en) * 2000-11-10 2002-05-16 Syngenta Participations Ag Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide
CN101692825A (en) * 2009-07-21 2010-04-14 深圳诺普信农化股份有限公司 Pesticide composition containing carbosulfan and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002037964A1 (en) * 2000-11-10 2002-05-16 Syngenta Participations Ag Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide
CN101692825A (en) * 2009-07-21 2010-04-14 深圳诺普信农化股份有限公司 Pesticide composition containing carbosulfan and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103380776A (en) * 2012-05-03 2013-11-06 陕西韦尔奇作物保护有限公司 Insecticidal composition containing flonicamid and carbamate

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Application publication date: 20130424