CN103053565A - Compound insecticidal composition containing flonicamid and dimethacarb, and application thereof - Google Patents
Compound insecticidal composition containing flonicamid and dimethacarb, and application thereof Download PDFInfo
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- CN103053565A CN103053565A CN2011103201865A CN201110320186A CN103053565A CN 103053565 A CN103053565 A CN 103053565A CN 2011103201865 A CN2011103201865 A CN 2011103201865A CN 201110320186 A CN201110320186 A CN 201110320186A CN 103053565 A CN103053565 A CN 103053565A
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- phenyl carbamate
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Abstract
The invention discloses a compound insecticidal composition containing flonicamid and dimethacarb, and an application thereof. The synergistic insecticidal composition employs flonicamid and dimethacarb as main effective components, wherein a weight ratio of flonicamid to dimethacarb is 0.1-80 : 0.5-80. The insecticidal composition can produce a relatively high synergistic interaction effect, overcomes or delays pest resistance, has fast insecticidal speed and long efficacy duration, reduces pesticide cost and has a prevention effect obviously higher than that of a single dosage. The insecticidal composition can be used for preventing homoptera pests generated on crops, and is particularly suitable for preventing rice hopper and aphid, with an effect obviously higher than that of the single dosage.
Description
Technical field
The invention belongs to pesticide field, be specifically related to compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and dimethyl phenyl carbamate and uses thereof.
Background technology
Flonicamid (flonicamid, flunicotamid), chemical name: N-cyanogen methyl. (trifluoromethyl) vitamin PP.
Flonicamid belongs to the lower toxicity insecticide variety.This agent is effective to various suckings pest, and has good osmosis.It can be from root to stem, the infiltration of leaf section, but by leaf section to stem, root osmosis relatively a little less than.
This medicament causes effect by hindering the insect act of sucking.Insect stops to suck after taking in medicament very soon, and is last hungry and dead.
Insect according to electronics sucks behavior (EMIII) parsing, and this agent can make the lancet tissue of the sucking insects such as aphid can't insert plant tissue and cause effect.10% water dispersible granules, every 667m when the insects such as vegetable aphid such as control cucumber
2Use 10% water dispersible granules 30-50g that water is sprayed.When for fruit aphids such as control apples, add water 2500-5000 with 10% water dispersible granules and doubly spray.Use proof through test and land for growing field crops, flonicamid is to various aphids, plant hopper, aleyrodid, leafhopper, fruit bat, wireworm, thrips, ant class, leaf miner, and the first-class sucking pest of springtail has special efficacy, and pests with chewing mouthparts is also had good control efficiency.
The homoptera pests such as rice fulgorid, Bemisia tabaci, aphid are under the condition of present long-term prescription, and resistance increases gradually, and the agricultural chemicals single dose descends gradually to the effect of control of insect, there is no effective preparation for the control of homoptera pest.The inventor finds that after deliberation the composite of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, finds not yet that up to now the complex insecticidal composition of relevant pymetrozine and flonicamid is used for preventing and treating the resistance homoptera pest.
The carbamate insecticide that dimethyl phenyl carbamate has two kinds of isomers to mix, the chemical name of these two kinds of isomers is respectively 3,5-3,5-dimethylphenyl methylamino formic acid esters (being again XMC) and 3,4---3,5-dimethylphenyl methylamino formic acid esters (being again Meobal).Plant hopper, leafhopper there is strong action of contace poison.Stomach poison function is arranged.Fencing speed is fast, and after the general dispenser about 30 minutes, most of insect namely fell in the water, but the residual phase only has 2-3 days.Its effect is not subjected to the impact of temperature, still has at low temperatures good preventive effect.The desinsection wide spectrum is effective to insects such as Homoptera, Lepidoptera and dipteras.
But rice fulgorid and aphid are under the condition of present long-term prescription, and resistance increases gradually, and the agricultural chemicals single dose descends gradually to the effect of control of insect.The inventor finds that after deliberation the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant flonicamid and dimethyl phenyl carbamate.
Summary of the invention
The compound pesticide compositions that the purpose of this invention is to provide a kind of fluorine-containing pyridine insect amide and dimethyl phenyl carbamate, this Pesticidal combination are the multifunctional insecticide compositions of control homoptera pest.
The compound pesticide compositions that another object of the present invention provides a kind of fluorine-containing pyridine insect amide and dimethyl phenyl carbamate is prevented and treated the application, the particularly application on the insecticidal materials of preparation control rice fulgorid and aphid on the insecticidal materials of resistance homoptera pest in preparation.
The objective of the invention is to be achieved through the following technical solutions:
The compound pesticide compositions of a kind of fluorine-containing pyridine insect amide and dimethyl phenyl carbamate, this Pesticidal combination is take flonicamid and dimethyl phenyl carbamate as main active ingredient, and wherein, the weight ratio of flonicamid and dimethyl phenyl carbamate is 0.1～80: 0.5～80.Be preferably 0.5～50: 2～50, more preferably 0.5～10: 4～30.Effective ingredient is present in the composition with the synergy effective dose in this Pesticidal combination.
In the complex composition of fluorine-containing pyridine insect amide of the present invention and dimethyl phenyl carbamate, the two weight percentage in this Pesticidal combination of flonicamid and dimethyl phenyl carbamate is 3%～80%.Be preferably 5%～55%, most preferably 10%～40%.
The compound pesticide compositions of fluorine-containing pyridine insect amide of the present invention and dimethyl phenyl carbamate take flonicamid and dimethyl phenyl carbamate as main active ingredient and insecticides adjuvant and excipient be mixed with any one formulation that allows on the agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, emulsifier 600 #, polyoxyethylene polyoxy third rare block compound (such as farming breast 33
#), polyoxyethylene nonylphenol ether is medium, excipient comprises isopropyl alcohol, vegetable oil, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent and excipient all can use separately or multiple mixing is used or with other auxiliary material and use.
Pesticidal combination of the present invention has good preventive effect to the multiple homoptera pest that rice fulgorid and aphid etc. produce resistance easily; And suppress insect to the pesticide resistance generation of unitary agent (flonicamid or dimethyl phenyl carbamate are arbitrary).
The compound pesticide compositions of above-mentioned fluorine-containing pyridine insect amide and dimethyl phenyl carbamate is prevented and treated application on the resistance homoptera pest insecticidal materials in preparation, and especially the effect on preparation control aleyrodid, rice fulgorid and aphid insecticidal materials is remarkable.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism homoptera pest such as rice fulgorid, aphid etc. have obvious synergistic function, overcome and have delayed pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the dimethyl phenyl carbamate single dose with flonicamid, produce and the use cost reduction; (6) suppress homoptera pest to the resistance enhancing of agricultural chemicals, its successful is higher than its single dose to be used.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
Taking by weighing flonicamid, dimethyl phenyl carbamate, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% flonicamid dimethyl phenyl carbamate missible oil.Concrete ratio sees Table 1,2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting the resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method
50, use LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of the composite and single dose antagonism rice fulgorid of table 1 flonicamid and dimethyl phenyl carbamate
As shown in Table 1, flonicamid and dimethyl phenyl carbamate are composite, and co-toxicity coefficient shows good synergistic function all greater than 120.Wherein mixed synergies is maximum when the ratio of flonicamid and dimethyl phenyl carbamate is 1: 1.
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance wheat aphid is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method
50, use LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of the composite and single dose antagonism wheat aphid of table 2 flonicamid and dimethyl phenyl carbamate
As shown in Table 2, flonicamid and dimethyl phenyl carbamate are composite, and the co-toxicity coefficient of wheat aphid all greater than 120, is shown good synergistic function.Wherein mixed synergies is maximum when the ratio of flonicamid and dimethyl phenyl carbamate is 1: 1, and co-toxicity coefficient is 176.50.
Embodiment 2:
Take by weighing 5g flonicamid, 50g dimethyl phenyl carbamate, phenethyl phenol polyethenoxy ether phosphate 3g, agricultural newborn 33#2g, emulsifier 600 #1g, vegetable oil 13g adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely drops into the mixing kettle high speed mixes, and forms main active ingredient weight percentage and be 55% flonicamid dimethyl phenyl carbamate aqueous emulsion.
Embodiment 3:
Take by weighing 2g flonicamid, 18g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agricultural newborn 33#2g, 600#1g, isopropyl alcohol 10g adds water to 100g.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forming main active ingredient weight percentage is 20% flonicamid dimethyl phenyl carbamate microemulsion.
Embodiment 3 is prevented and treated the Brown Planthopper test of pesticide effectiveness, the contrast medicament is 20% dimethyl phenyl carbamate EC (missible oil) and 20% flonicamid EW (aqueous emulsion), dilutes according to the extension rate of 3 li of forms, looks into behind the medicine 3 days, 7 days result, result sees Table 3:
Table 3: the composite field test results to Brown Planthopper of flonicamid-dimethyl phenyl carbamate
(annotate: every mu of water consumption is 30kg)
Field efficacy is the result show, flonicamid dimethyl phenyl carbamate composition antagonism brown planthopper has good control efficiency, and control efficiency all is better than the effect that the single dose kind is better than direct each Dan Pin of while.
Embodiment 3 is prevented and treated the wheat aphid field medicine effect test, the contrast medicament is 20% dimethyl phenyl carbamate EC (missible oil) and 20% flonicamid EW (aqueous emulsion), dilutes according to the extension rate of 3 li of forms, looks into behind the medicine 3 days, 7 days result, result sees Table 4:
Table 4: the composite field test results to wheat aphid of flonicamid dimethyl phenyl carbamate
(annotate: every mu of water consumption is 30kg)
Field efficacy is the result show, flonicamid dimethyl phenyl carbamate composition antagonism wheat aphid has good control efficiency, and control efficiency all is better than the effect that the single dose kind is better than direct each Dan Pin of while.
Embodiment 4: take by weighing 1g flonicamid, 5g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, vegetable oil to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 6% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 5: take by weighing 50g flonicamid, 20g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 70% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 6: take by weighing 2g flonicamid, 40g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 42% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 7: take by weighing 0.2g flonicamid, 50g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms the main active ingredient weight percentage of preparation and be 50.2% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 8: take by weighing 5g flonicamid, 0.5g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms the main active ingredient weight percentage of preparation and be 5.5% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 9: take by weighing 5g flonicamid, 30g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 35% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 10: take by weighing 20g flonicamid, 5g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms the main active ingredient weight percentage of preparation and be 25% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 11: take by weighing 30g flonicamid, 12g dimethyl phenyl carbamate, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and forming main active ingredient weight percentage under the effect of sand mill is 42% flonicamid dimethyl phenyl carbamate suspending agent.
Embodiment 12: take by weighing 2g flonicamid, 5g dimethyl phenyl carbamate, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g, it is 14% flonicamid dimethyl phenyl carbamate water dispersion granule that above raw material is formed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 13: take by weighing 50g flonicamid, 3g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, vegetable oil are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 53% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 14: take by weighing 2g flonicamid, 18g dimethyl phenyl carbamate, sodium lignin sulfonate 10g, Negel 2g, add to 100g with diatomite, above raw material is mixed in micronizer, form main active ingredient weight percentage and be 20% flonicamid dimethyl phenyl carbamate wetting powder.
Embodiment 15: take by weighing 7g flonicamid, 70g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms the main active ingredient weight percentage of preparation and be 77% flonicamid dimethyl phenyl carbamate missible oil.
Embodiment 16: take by weighing 60g flonicamid, 5g dimethyl phenyl carbamate, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, it is 65% flonicamid dimethyl phenyl carbamate water dispersible granules that above raw material is formed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 17: take by weighing 20g flonicamid, 20g dimethyl phenyl carbamate, nonyl phenol phosphate 5g, emulsifier 600 #4g, n-butanol 3g, 10g solvent naphtha and 20g pyrrolidones, 0.1g xanthans, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10～30 minutes, form main active ingredient weight percentage and be 40% flonicamid dimethyl phenyl carbamate aqueous emulsion.
Embodiment 18: take by weighing 60g flonicamid, 1g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 5g, emulsifier 600 #4g, the solvent naphtha of 10g and the pyrrolidones of 15g, all the other waters are supplied 100g, above-mentioned former medicine, solvent, emulsifier, cosolvent mix and blend are formed homogeneous phase transparent solution, slowly add at last entry and stir to form clear solution, be main active ingredient weight percentage and be 61% flonicamid dimethyl phenyl carbamate microemulsion.
Claims (9)
1. the compound pesticide compositions of a fluorine-containing pyridine insect amide and dimethyl phenyl carbamate is characterized in that this Pesticidal combination take flonicamid and dimethyl phenyl carbamate as main active ingredient, and wherein, the weight ratio of flonicamid and dimethyl phenyl carbamate is 0.1～80: 0.5～80.
2. Pesticidal combination according to claim 1, the weight ratio that it is characterized in that described flonicamid and dimethyl phenyl carbamate is 0.5～50: 2～50.
3. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 2 and dimethyl phenyl carbamate, the weight ratio that it is characterized in that described flonicamid and dimethyl phenyl carbamate is 0.5～10: 4～30.
4. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and dimethyl phenyl carbamate is characterized in that the two weight percentage in this compound pesticide compositions of flonicamid and dimethyl phenyl carbamate is 3%～80%.
5. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 4 and dimethyl phenyl carbamate is characterized in that the two weight percentage in this compound pesticide compositions of flonicamid and dimethyl phenyl carbamate is 5%～55%.
6. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 1 and dimethyl phenyl carbamate is characterized in that this compound pesticide compositions take flonicamid and dimethyl phenyl carbamate as main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals.
7. the compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 6 and dimethyl phenyl carbamate is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
8. the compound pesticide compositions of fluorine-containing pyridine insect amide claimed in claim 1 and dimethyl phenyl carbamate is prevented and treated the application on the insecticidal materials of resistance homoptera pest in preparation.
The compound pesticide compositions of fluorine-containing pyridine insect amide according to claim 8 and dimethyl phenyl carbamate anti-eliminate aphis in preparation, the application on the insecticidal materials of aleyrodid and plant hopper.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002037964A1 (en) * | 2000-11-10 | 2002-05-16 | Syngenta Participations Ag | Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide |
| CN101692825A (en) * | 2009-07-21 | 2010-04-14 | 深圳诺普信农化股份有限公司 | Pesticide composition containing carbosulfan and application thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002037964A1 (en) * | 2000-11-10 | 2002-05-16 | Syngenta Participations Ag | Synergistic pesticidal compositions comprising n-cyanomethyl-4-(trifluoromethyl)nicotinamide |
| CN101692825A (en) * | 2009-07-21 | 2010-04-14 | 深圳诺普信农化股份有限公司 | Pesticide composition containing carbosulfan and application thereof |
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Application publication date: 20130424 |