CN103031053B - Touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof - Google Patents
Touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof Download PDFInfo
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- CN103031053B CN103031053B CN201310003268.6A CN201310003268A CN103031053B CN 103031053 B CN103031053 B CN 103031053B CN 201310003268 A CN201310003268 A CN 201310003268A CN 103031053 B CN103031053 B CN 103031053B
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Abstract
The present invention is that a kind of touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof, UV solidifies peelable blue gel formula and consists of: modified acrylic ester resin 50 ~ 70 parts, acrylate monomer 20 ~ 30 parts, light curing agent 1.0-5.0 part, thixotropic agent 0.1-1.0 part, auxiliary agent 0.1-5.0 part, pigment 0.1-1.0 part; Described preparation method is: accurately take various raw material by formula rate, first modified acrylic ester resin, acrylate monomer, light curing agent, auxiliary agent, pigment are added in reactor successively and stir, to be mixed evenly after, add thixotropic agent, discharging after being uniformly dispersed.UV of the present invention solidifies peelable blue gel and is non-solvent and does not contain phthalate substance system, more safety and environmental protection.Adopt UV curing system film-forming speed fast, greatly improve the efficiency that touch-screen is produced.
Description
Technical field
The present invention relates to a kind of UV and solidify peelable blue gel and preparation method thereof, this peelable blue gel is mainly used in the temporary protection in process for manufacturing touch panel.
Background technology
Along with developing rapidly of information technology and flat panel display technology, the application of touch-screen is more and more general.The large Referral information system to public place, little of PC, panel computer, mobile phone, touch-screen is closely bound up with our life.In the production process of touch-screen, need by using peelable blue gel to carry out temporary protection repeatedly to touch-screen glass.Traditional peelable blue gel contains interference human endocrine, affects the phthalic ester plasticizer of human body reproductive performance, and application is restricted.And the technique of traditional peelable blue gel film-forming is generally 120 DEG C-150 DEG C, 20min-60min, owing to needing repeatedly temporary protection in the production process of touch-screen, thus consuming time longer in the process of peelable blue gel film-forming, affect production efficiency.
The system of UV solidification is adopted fundamentally to solve the problem, UV solidifies peelable blue gel has stopped phthalate material use from composition, environmental protection more, nontoxic, its film-forming time is short, can film-forming completely within 30 seconds, substantially increase the efficiency that touch-screen is produced.
Summary of the invention
The object of the present invention is to provide a kind of UV for touch-screen temporary protection to solidify peelable blue gel, this peelable blue gel is not containing phthalate material, more environmental protection, and the mode of UV solidification can improve the efficiency of touch-screen production.
In order to realize object of the present invention, proposing a kind of touch-screen temporary protection UV and solidifying peelable blue gel, it is composed as follows that described UV solidifies peelable blue gel formula:
Modified acrylic ester resin 50 ~ 70 parts
Acrylate monomer 20 ~ 30 parts
Light curing agent 1.0-5.0 part
Thixotropic agent 0.1-1.0 part
Auxiliary agent 0.1-5.0 part
Pigment 0.1-1.0 part.
Wherein, described modified acrylic ester resin is one or more in polyurethane-modified polyacrylate resin, aliphatic polyurethane modified acrylic ester resin, epoxy modification acrylate resin, Silicone-Modified Acrylate Resin, organic fluorine modified acrylic ester resin, polyester modification acrylic resin and polyether-modified acrylate resin;
Described acrylate monomer is one or more in (methyl) methyl acrylate, (methyl) Hydroxyethyl acrylate, (methyl) Propylene glycol monoacrylate, (methyl) vinylformic acid tetrahydrofuran ester, 2-benzene oxygen ethylmethyl acrylate, (methyl) isobornyl acrylate, (methyl) n-butyl acrylate, (methyl) lauryl acrylate, Ethylene glycol dimethacrylate, ethoxyquin double A diacrylate and 1,4 butanediol diacrylate;
Described light curing agent is one or more in bitter almond oil camphor, ethoxybenzoin, benzil ketals, benzophenone, methyl o-benzoylbenzoate, 2-isopropyl thioxanthone, sulfonic group thioxanthone and thiophenyl benzophenone;
Described thixotropic agent is one or more in fumed silica, precipitated silica, organobentonite, asbestos, kaolin and attapulgite;
Described auxiliary agent is flow agent or defoamer;
Described pigment is barba hispanica, ultramarine blue, cobalt blue or phthalocyanine blue.
The concrete formula that the present invention also proposes two kinds of UV solidification peelable blue gel is composed as follows:
Formula 1
Polyurethane-modified polyacrylate resin 30 parts
Epoxy modification acrylate resin 40 parts
Isobornyl acrylate 23 parts
Benzophenone 3.0 parts
Flow agent 1.0 parts
Defoamer 1.0 parts
Organobentonite 1.0 parts
Phthalocyanine blue 1.0 parts
Formula 2
Polyurethane-modified polyacrylate resin 30 parts
Epoxy modification acrylate resin 20 parts
Silicone-Modified Acrylate Resin 20 parts
Isobornyl methacrylate 23 parts
Benzophenone 3.0 parts
Flow agent 1.0 parts
Defoamer 1.0 parts
Precipitated silica 1.0 parts
Phthalocyanine blue 1.0 parts
The present invention also propose a kind of touch-screen temporary protection UV solidify peelable blue gel preparation method described in preparation method be: accurately take various raw material by formula rate; first modified acrylic ester resin, acrylate monomer, light curing agent, auxiliary agent, pigment are added in reactor successively and stir; to be mixed evenly after; add thixotropic agent, discharging after being uniformly dispersed.
Advantage of the present invention:
1. non-solvent and not containing phthalate substance system, more safety and environmental protection.
2.UV curing system film-forming speed is fast, greatly improves the efficiency that touch-screen is produced.
Embodiment
For making the object, technical solutions and advantages of the present invention clearly understand, below in conjunction with specific embodiment, the present invention is described in more detail.
Embodiment 1
Polyurethane-modified polyacrylate resin 30 parts
Epoxy modification acrylate resin 40 parts
Isobornyl acrylate 23 parts
Benzophenone 3.0 parts
Flow agent 1.0 parts
Defoamer 1.0 parts
Organobentonite 1.0 parts
Phthalocyanine blue 1.0 parts
Preparation method:
Various raw material is accurately taken by formula rate, first polyurethane-modified polyacrylate resin, epoxy modification acrylate resin, isobornyl acrylate, benzophenone, flow agent, defoamer, phthalocyanine blue are added in reactor successively and stir, to be mixed evenly after, add organobentonite, discharging after being uniformly dispersed.
Embodiment 2
Polyurethane-modified polyacrylate resin 30 parts
Epoxy modification acrylate resin 20 parts
Silicone-Modified Acrylate Resin 20 parts
Isobornyl methacrylate 23 parts
Benzophenone 3.0 parts
Flow agent 1.0 parts
Defoamer 1.0 parts
Precipitated silica 1.0 parts
Phthalocyanine blue 1.0 parts
Preparation method:
Various raw material is accurately taken by formula rate, first polyurethane-modified polyacrylate resin, epoxy modification acrylate resin, Silicone-Modified Acrylate Resin, isobornyl methacrylate, benzophenone, flow agent, defoamer, phthalocyanine blue are added in reactor successively and stir, to be mixed evenly after, add precipitated silica, discharging after being uniformly dispersed.
Embodiment listed by table 1 and the rear the performance test results of solidification thereof.Test result shows: peelable blue gel of the present invention has good storage stability, excellent Technological adaptability, good rippability and insulativity, can meet the processing requirement that touch-screen produces temporary protection comprehensively.
Table 1
Peelable blue gel of the present invention solves following problem:
1, environmental issue
Tradition peelable blue gel contains phthalic ester plasticizer.Research shows, phthalic ester can disturbance endocrine, makes that mankind spermatozoon quantity reduces, motor capacity is low, paramophia, and serious also can cause necrospermia and carcinoma of testis, is to cause male reproduction problems " arch-criminal ".Various countries launch respectively the use of such material of regulation limitations.In the present invention, UV solidifies peelable blue gel has stopped phthalate material use from composition, and environmental protection is more nontoxic.
2, touch-screen production efficiency problem
The technique of tradition peelable blue gel film-forming is generally 120 DEG C-150 DEG C, 20min-60min, owing to needing repeatedly temporary protection in the production process of touch-screen, thus consuming time longer in the process of peelable blue gel film-forming, affects its production efficiency.In the present invention, to solidify the peelable blue gel film-forming time short for UV, can film-forming completely within 30s, substantially increases the efficiency of touch-screen production.
According to the above results, this peelable blue gel meets the manufacturing technique requirent of touch-screen completely, more environmental protection, and can improve the production efficiency of touch-screen.
Although the present invention is own with preferred embodiment openly as above, they are not that the content that protection scope of the present invention should define with the claims of the application is as the criterion for limiting the present invention.Anyly have the knack of the art person, without departing from the spirit and scope of the present invention, the various change done or equivalently to replace, all should belong to protection scope of the present invention.
Claims (4)
1. touch-screen temporary protection UV solidifies a peelable blue gel, it is characterized in that: it is composed as follows that described UV solidifies peelable blue gel formula:
Modified acrylic ester resin 50 ~ 70 parts
Acrylate monomer 20 ~ 30 parts
Light curing agent 1.0-5.0 part
Thixotropic agent 0.1-1.0 part
Auxiliary agent 0.1-5.0 part
Pigment 0.1-1.0 part
Described modified acrylic ester resin is one or more in aliphatic polyurethane modified acrylic ester resin, Silicone-Modified Acrylate Resin, organic fluorine modified acrylic ester resin, polyester modification acrylic resin and polyether-modified acrylate resin;
Described acrylate monomer is one or more in (methyl) methyl acrylate, (methyl) Hydroxyethyl acrylate, (methyl) vinylformic acid tetrahydrofuran ester, 2-benzene oxygen ethylmethyl acrylate, (methyl) isobornyl acrylate, (methyl) n-butyl acrylate and 1,4 butanediol diacrylate;
Described light curing agent is one or more in bitter almond oil camphor, ethoxybenzoin, benzil ketals, methyl o-benzoylbenzoate, 2-isopropyl thioxanthone, sulfonic group thioxanthone and thiophenyl benzophenone;
Described thixotropic agent is one or more in fumed silica, precipitated silica, organobentonite, asbestos, kaolin and attapulgite;
Described auxiliary agent is flow agent or defoamer;
Described pigment is barba hispanica, ultramarine blue, cobalt blue or phthalocyanine blue.
2. UV according to claim 1 solidifies peelable blue gel, it is characterized in that:
It is composed as follows that described UV solidifies peelable blue gel formula:
Polyurethane-modified polyacrylate resin 30 parts
Epoxy modification acrylate resin 40 parts
Isobornyl acrylate 23 parts
Benzophenone 3.0 parts
Flow agent 1.0 parts
Defoamer 1.0 parts
Organobentonite 1.0 parts
Phthalocyanine blue 1.0 parts.
3. UV according to claim 1 solidifies peelable blue gel, it is characterized in that:
It is composed as follows that described UV solidifies peelable blue gel formula:
Polyurethane-modified polyacrylate resin 30 parts
Epoxy modification acrylate resin 20 parts
Silicone-Modified Acrylate Resin 20 parts
Isobornyl methacrylate 23 parts
Benzophenone 3.0 parts
Flow agent 1.0 parts
Defoamer 1.0 parts
Precipitated silica 1.0 parts
Phthalocyanine blue 1.0 parts.
4. a touch-screen temporary protection solidifies the preparation method of peelable blue gel with UV; it is characterized in that: described preparation method is: accurately take various raw material by formula rate; first modified acrylic ester resin, acrylate monomer, light curing agent, auxiliary agent, pigment are added in reactor successively and stir; to be mixed evenly after; add thixotropic agent, discharging after being uniformly dispersed.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310003268.6A CN103031053B (en) | 2013-01-06 | 2013-01-06 | Touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof |
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| CN201310003268.6A CN103031053B (en) | 2013-01-06 | 2013-01-06 | Touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof |
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| CN103031053A CN103031053A (en) | 2013-04-10 |
| CN103031053B true CN103031053B (en) | 2015-07-29 |
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| CN103421400B (en) * | 2013-08-30 | 2015-09-16 | 东莞市平波电子有限公司 | A kind of touch-screen UV solidifies peelable blue gel and preparation method thereof |
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| CN105602443B (en) * | 2016-01-20 | 2017-10-27 | 上海应用技术学院 | Peelable blue glue and preparation method |
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| CN108165087B (en) * | 2017-12-28 | 2021-07-23 | 中科院广州化学有限公司 | Anodic oxidation resistant protective ink and preparation method and application thereof |
| CN109161347A (en) * | 2018-08-22 | 2019-01-08 | 江苏博之高新材料科技有限公司 | A kind of anti-welding lotion of LED backlight |
| CN111019584B (en) * | 2019-12-19 | 2022-04-19 | 福建拓烯新材料科技有限公司 | Halogen-free peelable blue gel composition and preparation method thereof |
| CN111139015A (en) * | 2019-12-31 | 2020-05-12 | 天津久日新材料股份有限公司 | Environment-friendly UV LED (ultraviolet light emitting diode) curing peelable blue glue and preparation method thereof |
| CN113667394B (en) * | 2021-08-16 | 2023-06-23 | 广东希贵光固化材料有限公司 | UV illumination demolding temporary protective coating and application thereof |
| CN113773737A (en) * | 2021-09-13 | 2021-12-10 | 广东希贵光固化材料有限公司 | Temporary protective coating demoulded by oxidation-reduction |
| CN114539907A (en) * | 2022-02-24 | 2022-05-27 | 三棵树涂料股份有限公司 | UV strippable protective film for woodware and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
-
2013
- 2013-01-06 CN CN201310003268.6A patent/CN103031053B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
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Effective date of registration: 20160421 Address after: 100041 Beijing City, Shijingshan District Badachu high tech Park Park Road No. 5 Patentee after: BEIJING TIANSHAN NEW MATERIAL TECHNOLOGY CO., LTD. Address before: 100041 Beijing City, Shijingshan District Badachu high tech Park Park Road No. 5, room 101 Patentee before: Beijing Hystic New Materials Co., Ltd. |
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