CN105462482B - A kind of touch-screen use can cover Protection glue of silver wire and preparation method thereof - Google Patents
A kind of touch-screen use can cover Protection glue of silver wire and preparation method thereof Download PDFInfo
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- CN105462482B CN105462482B CN201610009570.6A CN201610009570A CN105462482B CN 105462482 B CN105462482 B CN 105462482B CN 201610009570 A CN201610009570 A CN 201610009570A CN 105462482 B CN105462482 B CN 105462482B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention is that a kind of touch-screen use can cover Protection glue of silver wire and preparation method thereof, is made up of the raw material of following components by mass parts：60 ~ 70 parts of polyurethane acrylate prepolymer, 10 ~ 15 parts of acrylate monomer, 5 ~ 10 parts of Photoepolymerizationinitiater initiater, 0.5 part of defoamer, 1 part of levelling agent, 0.5 ~ 1.5 part of hyper-dispersant, 1 ~ 2 part of thixotropic agent, 0.2 ~ 0.5 part of pigment, 10 ~ 30 parts of filler.The present invention is big using elongation, pliability is good, curing rate is fast, the low 2 degree of functionality polyurethane acrylate prepolymer free from corrosion to base material of shrinkage factor, the amount for adjusting dispersant controls peeling force, monomer, Photoepolymerizationinitiater initiater, auxiliary agent, filler, pigment etc. is coordinated to be made again, after UV film-formings have pliability it is good, acid and alkali-resistance and it is easily peelable do not remain, adapt to all grounds and can cover peelable in silver wire.It is mainly used in indium oxide tin glass（ITO）Diaphragm etc., such as temporary protective film of various electric touch screens, liquid crystal panel temporary protective film.
Description
Technical field
The present invention relates to a kind of peelable Protection glue, and in particular to the UV solidifications that a kind of touch-screen use can cover silver wire are peelable
From Protection glue and preparation method thereof.
Background technology
At present, it is more and more common with the application of touch-screen, and, it is necessary to by making in the production process of touch-screen
With peelable Protection glue multiple interim protection is carried out to touching panel glass.Peelable Protection glue is mainly used in saturating in touch-screen
Bright electro-conductive glass, film ITO plated films on and silver wire on, play insulation, moistureproof and protection.
Traditional peelable Protection glue is prepared by materials such as phthalic ester plasticizer and aleurons, and adjacent benzene two
Formate ester plasticizer can disturb human endocrine, influence human body fecundity, and baking temperature is high, and time length, high energy consumption is not
Environmental protection.
Due to traditional handicraft can glass protection glue just for the transparent conducting glass in touch-screen, the ITO plated films of film
Protected, but exposed silver wire but needs covering PET film to be protected, and has both needed to increase by a procedure
Machine cost and cost of labor, again increase PET film material cost.At present, with the degree of prosperity of whole market environment
OK, the price of raw material rises, the increase of cost of labor, and a kind of UV covered in silver wire, which solidifies peelable Protection glue, turns into new
The trend of technique, cost is reduced to reach, the achievement of optimize technique.
Traditional UV cured films have pliability poor, and elongation is small, the shortcomings of being not easily stripped.
For another example the Chinese invention patent application of Application No. 201310003438.0 discloses a kind of touch-screen and protected temporarily
With UV solidification peelable blue gels and preparation method thereof, UV solidification peelable blue gel formula compositions are：Modified acrylic ester resin 50 ~ 70
Part, 20 ~ 30 parts of acrylate monomer, light curing agent 1.0-5.0 parts, thixotropic agent 0.1-1.0 parts, auxiliary agent 0.1-5.0 parts, face
Expect 0.1-1.0 parts；The preparation method is：Various raw materials are accurately weighed by formula rate, first by modified acrylic ester resin,
Acrylate monomer, light curing agent, auxiliary agent, pigment are sequentially added in reactor and stirred, it is to be mixed uniformly after, add thixotropic agent,
Discharge to prepare in this way after being uniformly dispersed and easily occur being not easily stripped, easily remain, and can not more be covered in silver wire（Acrylic acid
All there is certain adhesive force with ground after resin and acrylic monomers reaction, and silver wire contains high molecular polymer, is more easy to and sets
Fat and monomer adhere to, and are not easily stripped/separate）.
And application number 201310388295.X Chinese invention patent application discloses a kind of touch-screen UV and solidifies peelable indigo plant
Glue and preparation method thereof, this kind of touch-screen UV solidifications peelable blue gel comprise the following raw materials by weight percent：Organic fluorinated silicone changes
Property acrylic resin 10-20%, epoxy novolac acrylic resin 5-15%, amino acrylic resin 5-15%, aliphatic polyurethane third
Olefin(e) acid resin 5-15%, acrylic monomers 5-15%, light curing agent 1-5%, silica 0.1-1%, nano barium sulfate 15-25%, cunning
Stone flour 10-20%, organic pigment barba hispanica, ultramarine blue, cobalt blue or phthalocyanine blue 0.1-1%.Due to the resin in the invention easily and silver wire
On high molecular polymer easily crosslink attachment, the peeling effect on ground prepared in this approach is good, but cover
Occur, the phenomenon do not peeled off good with silver wire attachment in silver wire.
The content of the invention
To solve the above problems, the present invention is big by using elongation, pliability is good, and curing rate is fast, shrinkage factor is low, right
The free from corrosion 2 degree of functionality polyurethane acrylate prepolymer of base material, stripping is controlled by adjusting the amount of hyper-dispersant and levelling agent
From power, then coordinate monomer, Photoepolymerizationinitiater initiater, auxiliary agent, filler, pigment etc. that the peelable protection of UV types that can cover silver wire is made
Glue, has easily peelable, and ductility is good, noresidue, acid and alkali-resistance, the performances such as curing rate is fast, so as to greatly improve production efficiency
Cost of labor and material cost can be reduced again simultaneously.
The object of the present invention is achieved like this：
A kind of touch-screen use can cover the Protection glue of silver wire, it is characterized in that, it is made up of the raw material of following components by mass parts：
60 ~ 70 parts of polyurethane acrylate prepolymer；
10 ~ 15 parts of acrylate monomer；
5 ~ 10 parts of Photoepolymerizationinitiater initiater；
0.5 part of defoamer；
1 part of levelling agent；
0.5 ~ 1.5 part of hyper-dispersant；
1 ~ 2 part of thixotropic agent；
0.2 ~ 0.5 part of pigment；
10 ~ 30 parts of filler.
The present invention can also use following technical measures to solve：
The polyurethane acrylate prepolymer is 2 degree of functionality polyurethane acrylate prepolymers.
The acrylate monomer is monofunctional monomer, Ke Yishi（Methyl）Methyl acrylate,（Methyl）Acrylic acid hydroxyl second
Ester,（Methyl）Hydroxypropyl acrylate,（Methyl）One kind in acrylic acid tetrahydrofuran ester, 2- benzene oxygen ethylmethyl acrylates
Or a variety of compositions.
Photoepolymerizationinitiater initiater can be phosphinoxides or various peroxides, such as can include benzoin, benzoin
The benzoins such as methyl ether, benzoin ethyl ether, benzoin iso-propylether and benzoin alkyl ethers；Acetophenone, 2,2- dimethoxys -2-
The acetophenones such as phenyl acetophenone, 2,2- diethoxy -2- phenyl acetophenones, 1,1- dichloroacetophenones；2- methyl isophthalic acids-
[4- (methyl thio) phenyl] -2- morpholino propyl- 1- ketone, 2- benzyl -2- dimethylaminos -1- (4- morpholino benzene
Base)-butane -1,2- (dimethylamino) -2- [(4- aminomethyl phenyls) methyl] -1- [4- (4- morpholinyls) phenyl] -1-
The aminoacetophenone class such as butane；The Anthraquinones such as 2- tectoquinones, 2- EAQs, 2- tert-butyl groups anthraquinone, 1- chloroanthraquinones；2,
The thioxanthene ketone class such as 4- dimethyl thioxanthones, 2,4- diethyl thioxanthones, 2- clopenthixal ketones, 2,4- diisopropylthioxanthones；
The ketal class such as acetophenone dimethyl ketal, benzil dimethyl ketal；The benzophenones such as benzophenone；Or xanthene ketone；
(2,6- Dimethoxybenzoyls) -2,4,4- amyl groups phosphine oxide, the oxidation of double (2,4,6- trimethylbenzoyls)-phenyl
Phosphine, 2,4,6- trimethyl benzoyl diphenyl bases phosphine oxide, 2,4,6- trimethyl benzoyl diphenyl base phosphinicacid ethyl esters
Phosphinoxides such as (ethyl-2,4,6-trimethylbenzoyl diphenyl phosphinate)；And various peroxide
Class can select commercially available product, such as " IRGACURE184, IRGACURE819 of BASF JAPAN LTD. " companies manufacture,
IRGACURE907, IRGACURE369, IRGACURE379, IRGACURE389, LUCIRIN TPO etc..
The defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerine
One or two kinds of composition in ether, dimethyl silicone polymer；Can be specifically TEGO Foamex N defoamers.
The levelling agent is one kind in acrylic compounds, organic silicon and fluorocarbons class；Can be specifically TEGO
The levelling agents of Glide 450.
The hyper-dispersant be for polyester type ultra-dispersant agent, polyether-type hyper-dispersant, polyacrylate hyper-dispersant or
The one of which of TPO hyper-dispersant, can be specifically the hyper-dispersants of TEGO Dispers 685 or TEGO Dispers
One kind of 710 hyper-dispersants.
The thixotropic agent is hydrophobicity aerosil.
The pigment is phthalocyanine blue or ultramarine blue.
The filler is talcum powder or alumina powder.
The purpose of the present invention also includes a kind of method for preparing touch-screen use and can covering the Protection glue of silver wire, and its feature exists
In its preparation method is：
After weighing various raw material mixing by formula rate, it is stirred using dispersion machine after disperseing, carries out three-roller grinding,
Until below fineness 60um.
The beneficial effects of the invention are as follows：
（1）The present invention is big using elongation, and pliability is good, and curing rate is fast, low 2 function free from corrosion to base material of shrinkage factor
Polyurethane acrylate prepolymer is spent, adjusts the amount of hyper-dispersant and levelling agent to control peeling force, then coordinate monomer, photopolymerization
Initiator, auxiliary agent, filler, pigment etc. are made, and have the good acid and alkali-resistance of pliability after UV film-formings and easily peelable do not remain adaptation
All grounds.Because the collocation of hyper-dispersant and levelling agent uses so that peeling force is adjustable to be can be applied to be covered in again simultaneously
It is in silver wire and peelable, reduce material cost and cost of labor.Present invention is mainly used for indium oxide tin glass（ITO）Diaphragm
Deng such as temporary protective film of the temporary protective film of various electric touch screens, liquid crystal panel.
（2）The touch-screen of the present invention solidifies peelable Protection glue with UV, and its curing rate is fast, and efficiency high is pollution-free, ring
Protect；Elongation is big, easily peelable, does not remain, and adapts to all grounds and the covering protection of silver wire.
Embodiment
With reference to embodiment, the present invention is further described.
A kind of touch-screen use can cover the Protection glue of silver wire, be made up of the raw material of following components by mass parts：
2 60 parts of degree of functionality polyurethane acrylate prepolymers；
10 parts of 2- benzene oxygen ethylmethyl acrylate；
7 parts of IRGACURE184；
0.5 part of defoamer；
1 part of levelling agent；
1 part of hyper-dispersant；
1 part of aerosil；
0.3 part of phthalocyanine blue；
19.2 parts of talcum powder.
Wherein, IRGACURE184 is Photoepolymerizationinitiater initiater, can be during ink solidification, after absorbing ultraviolet radiant energy
Excited singlet is transitted to, jump arrives excited triplet state through being leapt up between being, in its excited singlet or triplet state, molecular structure is not in
Homolysis can occur for stable state, weak bond therein, produce primary activity free radical, trigger monomer and oligomer that polymerization occurs, hands over
Connection and graft reaction, make ink solidification into the high molecular polymer of tridimensional network in the very short time.
2 degree of functionality polyurethane acrylate prepolymers possess that elongation is big, and pliability is good, and curing rate is fast, shrinkage factor is low
The features such as corrosion-free to base material.
2- benzene oxygen ethylmethyl acrylates are a kind of good active monomer diluents of dilution effect, can adjust body
The viscosity of system, viscosity and reaction speed.
2 degree of functionality polyurethane acrylate prepolymers and acrylate monomer after Photoepolymerizationinitiater initiater initiation reaction with bottom
Material has certain adhesive force, and the ply adhesion of film forming can be influenceed by the collocation use of hyper-dispersant and levelling agent, from
And adjust the peeling force with ground or silver wire.
By above-mentioned formula rate accurately weigh various raw materials be stirred using dispersion machine it is scattered, it is to be mixed uniformly after, enter
Row three-roller is ground, until fineness 60um is once.
The present invention possesses beneficial effect：
1st, curing rate is fast, efficiency high, pollution-free, environmental protection.
2nd, elongation is big, easily peelable, does not remain, and adapts to all grounds, can adjust the size of peeling force.
3rd, silver wire can be covered, it is not necessary to protect exposed silver wire using PET film, reach save material cost and cost of labor with
And optimize technique.
Particular embodiments described above, only preferred embodiments of the present invention, such as according to the present patent application patent
The equivalent arrangements that scope is done, the technology that should be the present invention are covered.
Claims (9)
1. a kind of touch-screen use can cover the Protection glue of silver wire, it is characterized in that, it is made up of the raw material of following components by mass parts：
2 60 ~ 70 parts of degree of functionality polyurethane acrylate prepolymers；
10 ~ 15 parts of acrylate monomer；
5 ~ 10 parts of Photoepolymerizationinitiater initiater；
0.5 part of defoamer；
1 part of levelling agent；
0.5 ~ 1.5 part of hyper-dispersant；
1 ~ 2 part of thixotropic agent；
0.2 ~ 0.5 part of pigment；
10 ~ 30 parts of filler.
2. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the acrylate monomer
For monofunctional monomer, Ke Yishi（Methyl）Methyl acrylate,（Methyl）Hydroxy-ethyl acrylate,（Methyl）Hydroxypropyl acrylate,（First
Base）One or more kinds of compositions in acrylic acid tetrahydrofuran ester, 2- benzene oxygen ethylmethyl acrylates.
3. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the defoamer is polyoxy
One in ethene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, dimethyl silicone polymer
Kind or two kinds of compositions.
4. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the levelling agent is propylene
One kind in acids, organic silicon and fluorocarbons class.
5. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the hyper-dispersant is poly-
Ester type hyper-dispersant, polyether-type hyper-dispersant, the one of which of polyacrylate hyper-dispersant or TPO hyper-dispersant.
6. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the thixotropic agent is hydrophobic
Property aerosil.
7. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the pigment is phthalocyanine blue
Or ultramarine blue.
8. touch-screen use can cover the Protection glue of silver wire according to claim 1, it is characterised in that the filler is talcum powder
Or alumina powder.
A kind of 9. method for preparing touch-screen use and can covering the Protection glue of silver wire according to claim 1, it is characterised in that：Its
Preparation method is：After weighing various raw material mixing by formula rate, it is stirred using dispersion machine after disperseing, carries out three-roller and grind
Mill, until below 60 μm of fineness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610009570.6A CN105462482B (en) | 2016-01-08 | 2016-01-08 | A kind of touch-screen use can cover Protection glue of silver wire and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610009570.6A CN105462482B (en) | 2016-01-08 | 2016-01-08 | A kind of touch-screen use can cover Protection glue of silver wire and preparation method thereof |
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| CN105462482A CN105462482A (en) | 2016-04-06 |
| CN105462482B true CN105462482B (en) | 2017-12-29 |
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| CN109467974B (en) * | 2018-10-31 | 2021-10-01 | 深圳市格莱特印刷材料有限公司 | Photosensitive ink for 3D curved screen, preparation method and application thereof |
| CN112235984B (en) * | 2020-10-29 | 2022-02-18 | Oppo广东移动通信有限公司 | Shell, shell preparation method and electronic equipment |
| CN114539907A (en) * | 2022-02-24 | 2022-05-27 | 三棵树涂料股份有限公司 | UV strippable protective film for woodware and preparation method thereof |
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| CN103031053B (en) * | 2013-01-06 | 2015-07-29 | 北京海斯迪克新材料有限公司 | Touch-screen temporary protection UV solidifies peelable blue gel and preparation method thereof |
| CN103232803B (en) * | 2013-04-25 | 2015-08-05 | 深圳市美丽华油墨涂料有限公司 | A kind of UV is coating material solidified and apply |
| CN103627313B (en) * | 2013-11-29 | 2016-08-17 | 广州机械科学研究院有限公司 | A kind of peelable protection material of ultraviolet light polymerization and its preparation method and application |
| CN104479436B (en) * | 2014-11-28 | 2017-11-28 | 张家港康得新光电材料有限公司 | Peelable glue coating composition, peelable gel coating, the preparation method and application of peelable gel coating |
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Effective date of registration: 20220129 Address after: 528399 No. 24, Xincun street, Daliang street, Shunde District, Foshan City, Guangdong Province Patentee after: He Weixiong Address before: 528308 No. 31, South Road, Yongfeng Village Committee Industrial Zone, Lunjiao sub district office, Shunde District, Foshan City, Guangdong Province Patentee before: FOSHAN SHUNDE BAIRUI NEW ELECTRONIC MATERIALS Co.,Ltd. |
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Effective date of registration: 20220407 Address after: 411499 Building 1, kexinting, Xinxiang Road Street, Xiangxiang City, Xiangtan City, Hunan Province Patentee after: Hunan Zhongrui New Material Technology Co.,Ltd. Address before: 528399 No. 24, Xincun street, Daliang street, Shunde District, Foshan City, Guangdong Province Patentee before: He Weixiong |