CN104673163A - Epoxy stone dry hanging adhesive rapidly solidified at normal temperature and preparation method of epoxy stone dry hanging adhesive - Google Patents
Epoxy stone dry hanging adhesive rapidly solidified at normal temperature and preparation method of epoxy stone dry hanging adhesive Download PDFInfo
- Publication number
- CN104673163A CN104673163A CN201510129049.1A CN201510129049A CN104673163A CN 104673163 A CN104673163 A CN 104673163A CN 201510129049 A CN201510129049 A CN 201510129049A CN 104673163 A CN104673163 A CN 104673163A
- Authority
- CN
- China
- Prior art keywords
- epoxy
- epoxy resin
- stone material
- glycidyl ether
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to epoxy stone dry hanging adhesive. The epoxy stone dry hanging adhesive comprises resin adhesive and a curing agent, wherein the curing agent comprises components such as modified fatty amine, modified phenol-aldehyde amine, a solidification accelerant, a dispersing agent, coupling agent processed barite powder, nano light calcium carbonate and white carbon black. According to the epoxy stone dry hanging adhesive, the resin adhesive and the curing agent are uniformly mixed according to an appropriate weight ratio, the epoxy stone dry hanging adhesive can be constructed in the application period, the surface can be dried generally in 35 minutes, the epoxy stone dry hanging adhesive is greatly better than the epoxy stone dry hanging adhesive with the surface drying time of 60 minutes, the surface can be completely hardened in 2 hours, and the construction requirement of the engineering can be met.
Description
Technical field
The present invention relates to stone material dry suspending glue field, especially relate to a kind of normal temperature quick-setting epoxy stone material dry suspending glue and preparation method thereof.
Background technology
Masonry work decorative curtain wall makes buildings have more sense of the times and artistic feeling with the style of its uniqueness, thus widespread use in various building, has become urban architecture and has stepped into one of modern important symbol.Cladding is for stone material basic unit Steel Skeleton, the constructional method be connected with stone material by Steel Skeleton with Stainless Steel suspension member.Bottom Stainless Steel suspension member fixing stone and the fluting position on top, and seal with structure glue joint filling.Current China dry-hang stone has occupied sizable ratio, and the trend that tool rises year by year.Along with the fast development of stone material dry suspending, also increasing to the demand of epoxy stone material dry suspending glue.Dry-hang glue is again stone material dry suspending structure glue, should meet the standard of " dry-hang stone curtain wall epoxy adhesive " (JC887-2001) that country issues in engineering with glue.Dry-hang glue should according to the test of code requirement by cohesive strength before using.
Traditional stone material dry suspending structure glue is generally slow curing type according to many, under normal temperature construction environment condition, after the mixing of construction ratio, when 23 DEG C+2 DEG C, surface drying time usually needs 60 minutes or more, setting time is greater than 2 hours, is unfavorable for reality need engineering requiring rapid construction.Meanwhile, the solidifying agent of the epoxy stone material dry suspending glue of normal temperature construction is usually containing aliquant moisture and other impurity, not easily compatible when mixing with other components, and can be fuel-displaced after storage for some time, particularly stores more so under 35 ° of environment.When constructing dry-hang glue the mixing of two kinds of components after can active substance be caused to solidify insufficient because of fuel-displaced and affect bonding strength, the colored organism oozed out when situation is serious pollutes stone material, causes quality accident.At extreme hot weather as 38 DEG C and above construction, traditional large multi-epoxy stone material dry suspending glue has vertical flow phenomenon, is unfavorable for the strong bond of stone material and component.
Summary of the invention
Based on this, be necessary to provide a kind of can at fast setting under normal temperature condition and epoxy stone material dry suspending glue that can prevent fuel-displaced phenomenon and preparation method thereof.
A kind of epoxy stone material dry suspending glue, comprise Resin adhesive and solidifying agent, wherein, described Resin adhesive comprises each component of following weight percentage:
Described solidifying agent comprises each component of following weight percentage:
Wherein in an embodiment, described epoxy resin is one or more the mixture in bisphenol A epoxide resin, modified bisphenol A epoxy resin, bisphenol F epoxy resin, modified bisphenol F epoxy resin, dihydroxyphenyl propane/F epoxy resin and modified bisphenol A/F epoxy resin.
Wherein in an embodiment, described epoxy resin diluent is one or more the mixture in n-butyl glycidyl ether, octyl glycidyl ether, C12 ~ C14 alkyl glycidyl ether, methyl propenoic acid glycidyl ether, phenylformic acid glycidyl ether, diglycidylether, diglycidyl ether of ethylene glycol, BDO glycidyl ether, hexylene glycol glycidyl ether, neopentyl glycol glycidyl ether, Resorcinol glycidyl ether, glycerin triglycidyl ether and trihydroxymethylpropanyltri diglycidyl ether.
Wherein in an embodiment, described epoxy resin toughener is one or more mixture in carboxyl liquid nitrile rubber, end carboxyl liquid nitrile rubber, thiorubber, polyethers, polyimide, polyurethane-epoxy resin and polyether epoxy.
Wherein in an embodiment, described coupling agent treatment ground barium sulfate is the 2000 object ground barium sulfates that coupling agent KH-560 and/or KH-550 coupling processing are crossed.
Wherein in an embodiment, described nanometer light calcium carbonate is 100 ~ 400 object nanometer activation fine particle calcium carbonates.
Wherein in an embodiment, described modified fatty amine is amine value 200 ~ 400mgKOH/g, active hydrogen equivalent weight be 150 ~ 200,25 DEG C of viscosity is 1000 ~ 30000 centipoises.
Wherein in an embodiment, described modified phenolic amine is Mannich alkalescence modified phenolic amine, amine value 500-600mgKOH/g, active hydrogen equivalent weight 50 ~ 85,25 DEG C of viscosity 2000 ~ 10000 centipoises; Or modified by cardanol phenolic aldehyde amine, amine value 300-400mgKOH/g, active hydrogen equivalent weight 80 ~ 100,25 DEG C of viscosity 1000 ~ 10000 centipoises.
Wherein in an embodiment, described curing catalyst is 2,4,6-tri-(dimethylamino methyl)-phenol.
Wherein in an embodiment, described dispersion agent is the special high polymer dispersion of epoxy curing systems.
Wherein in an embodiment, described white carbon black is aerosil.
Wherein in an embodiment, described solvent is one or more mixture of methylethylketone, ethylene glycol diethyl fat, phthalic acid list ethylhexyl, ethylene glycol ether acetate, nylon acid methyl esters, nitration mixture methyl esters and diethylene glycol ether acetic ester.
A preparation method for epoxy stone material dry suspending glue, comprises the steps:
Take each feed composition of Resin adhesive and solidifying agent, wherein, the percentage composition configuration of each feed composition of described Resin adhesive is as follows:
The percentage composition of each feed composition of described solidifying agent is as follows:
Prepare described Resin adhesive: described epoxy resin, described epoxy resin diluent and described epoxy resin toughener are added successively according to raw material percentage composition each in described Resin adhesive in planetary mixer, stir vacuumizing and defoaming;
Described coupling agent treatment ground barium sulfate, described active nano light calcium carbonate and described white carbon black is added respectively again by raw material percentage composition each in described Resin adhesive, continue to stir, the cylinder cap of closed described planetary mixer behind shovel limit, vacuumizing and defoaming, vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains described Resin adhesive;
Prepare described solidifying agent: in planetary mixer, add described modified fatty amine, described modified phenolic amine, described curing catalyst, described dispersion agent and described solvent successively according to each raw material percentage composition of described solidifying agent, stir vacuumizing and defoaming;
Described coupling agent treatment ground barium sulfate, described active nano light calcium carbonate and described white carbon black is added respectively again according to raw material percentage composition each in described solidifying agent; stir the cylinder cap of closed described planetary mixer after shutting down shovel limit; vacuumizing and defoaming; vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains described solidifying agent.
Above-mentioned epoxy stone material dry suspending glue is in normal temperature construction environment, after Resin adhesive is mixed according to suitable part by weight (as 1:1) with solidifying agent, general constructed within 10 ~ 20 minutes usage periods complete can (length of usage period changes with variation of ambient temperature, general temperature is higher, usage period is shorter), surface drying (finger touches dry) is within 35 minutes, greatly be better than the epoxy stone material dry suspending glue of traditional needs 60 minutes surface drying times, and can harden completely in 2 hours (it is seamless indeformable that finger draws pressure), the construction requirement in engineering can be reached.
Embodiment
Mainly in conjunction with specific embodiments epoxy stone material dry suspending glue of the present invention and preparation method thereof is described in further detail below.
The epoxy stone material dry suspending glue of one embodiment, comprises Resin adhesive and solidifying agent.Wherein, Resin adhesive comprises each component of following weight percentage:
The weight percentage of above-mentioned epoxy resin diluent, epoxy resin toughener, coupling agent treatment ground barium sulfate, nanometer light calcium carbonate and white carbon black is 0 time different, and the gross weight percentage composition of each component is 100%.And epoxy resin is one or more the mixture in bisphenol A epoxide resin, modified bisphenol A epoxy resin, bisphenol F epoxy resin, modified bisphenol F epoxy resin, dihydroxyphenyl propane/F epoxy resin and modified bisphenol A/F epoxy resin.For obtaining good fast setting effect and balancing the adaptation of envrionment temperature, in a preferred embodiment, B-44 and/or E-44 in the bisphenol A epoxide resin of oxirane value between 0.4 ~ 0.52.
Epoxy resin diluent is one or more the mixture in n-butyl glycidyl ether, octyl glycidyl ether, C12 ~ C14 alkyl glycidyl ether, methyl propenoic acid glycidyl ether, phenylformic acid glycidyl ether, diglycidylether, diglycidyl ether of ethylene glycol, BDO glycidyl ether, hexylene glycol glycidyl ether, neopentyl glycol glycidyl ether, Resorcinol glycidyl ether, glycerin triglycidyl ether and trihydroxymethylpropanyltri diglycidyl ether.For obtaining good fast setting effect and balancing the adaptation of envrionment temperature, in a preferred embodiment, epoxy resin diluent selects C12 ~ C14 alkyl glycidyl ether (AGE) and/or octyl glycidyl ether etc.
Epoxy resin toughener is one or more mixture in the response types such as carboxyl liquid nitrile rubber, end carboxyl liquid nitrile rubber, thiorubber, polyethers, polyimide, polyurethane-epoxy resin and polyether epoxy or non-reacted toughner.For obtaining good fast setting effect and balancing the adaptation of envrionment temperature, in a preferred embodiment, end carboxyl liquid nitrile rubber is selected in epoxy toughening agent.
Coupling agent treatment ground barium sulfate is the 2000 object ground barium sulfates that coupling agent KH-560 and/or KH-550 coupling processing are crossed.Nanometer light calcium carbonate is 100 ~ 400 object nanometer activation fine particle calcium carbonates.White carbon black is aerosil.
Solidifying agent comprises each component of following weight percentage:
The gross weight percentage composition of each component of above-mentioned solidifying agent is 100%.And the modified phenolic amine Mannich that to be reactive behavior high alkalescence modified phenolic amine, amine value 500-600mgKOH/g, active hydrogen equivalent weight 50 ~ 85,25 DEG C of viscosity 2000 ~ 10000 centipoises; Or modified by cardanol phenolic aldehyde amine, amine value 300-400mgKOH/g, active hydrogen equivalent weight 80 ~ 100,25 DEG C of viscosity 1000 ~ 10000 centipoises.Though Mannich alkalescence modified phenolic amine is active high, but fragility is large, and usually contain comparatively juicy, therefore, in a preferred embodiment, modified phenolic amine selects amine value between 330 ~ 370mgKOH/g, Ahew between 90 ~ 100,25 DEG C of viscosity at 1000 ~ 1500 centipoises and the modified by cardanol phenolic aldehyde amine of water ratio not high 1%, both active high, good toughness, and water content is low.
Single use phenolic aldehyde amine curing agent, consumption too much or environment for use temperature is too high easily causes implode, and therefore, in the present embodiment, in solidifying agent, add modified fatty amine, comparatively modified phenolic amine is low for its activity, cushions modified phenolic amine with this.The modified fatty amine of present embodiment is amine value 200 ~ 400mgKOH/g, active hydrogen equivalent weight is 150 ~ 200,25 DEG C of viscosity are 1000 ~ 30000 centipoises, preferably, the modified fatty amine of amine value 200 ~ 300mgKOH/g, active hydrogen equivalent weight to be 160 ~ 200,25 DEG C of viscosity be 1000 ~ 4000 centipoises.
Curing catalyst is 2,4,6-tri-(dimethylamino methyl)-phenol (i.e. DMP-30), can accelerate initial reaction speed.
Dispersion agent is the special high polymer dispersion of epoxy curing systems, as poly carboxylic acid amine salt, band anchoring group and containing the polyacrylie-type of close pigment group or polyurethane-type high-molecular block copolymer etc.
Coupling agent treatment ground barium sulfate is the 2000 object ground barium sulfates that coupling agent KH-560 and/or KH-550 coupling processing are crossed.Ground barium sulfate, through coupling agent treatment, can solve the problem that traditional solidifying agent is easily fuel-displaced, and can be that solidifying agent obtains good mobility and stability in storage.
Nanometer light calcium carbonate is 100 ~ 400 object nanometer activation fine particle calcium carbonates.White carbon black is aerosil.Environmentally friendly solvent selected by solvent, as one or more mixture of methylethylketone, ethylene glycol diethyl fat, phthalic acid list ethylhexyl, ethylene glycol ether acetate, nylon acid methyl esters, nitration mixture methyl esters and diethylene glycol ether acetic ester.
In addition, present embodiment additionally provides a kind of preparation method of epoxy stone material dry suspending glue, comprises the steps:
Prepare Resin adhesive: epoxy resin, epoxy resin diluent and epoxy resin toughener are added successively according to raw material percentage composition each in Resin adhesive in planetary mixer, stir vacuumizing and defoaming;
Press each raw material percentage composition in Resin adhesive more respectively and add coupling agent treatment ground barium sulfate, active nano light calcium carbonate and white carbon black, continue to stir, the cylinder cap of closed planetary mixer behind shovel limit, vacuumizing and defoaming, vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains Resin adhesive.
Prepare solidifying agent: each raw material percentage composition according to solidifying agent in planetary mixer adds modified fatty amine, modified phenolic amine, curing catalyst, dispersion agent and solvent successively, stir vacuumizing and defoaming;
Coupling agent treatment ground barium sulfate, active nano light calcium carbonate and white carbon black is added respectively again according to raw material percentage composition each in solidifying agent; stir the cylinder cap of closed planetary mixer after shutting down shovel limit; vacuumizing and defoaming; vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains solidifying agent.
Be below specific embodiment part:
One, each feed composition is taken:
Shown in following table 1 is each embodiment raw material used and proportioning (weight percent), specific as follows:
Table 1
Two, preparation flow:
Prepare Resin adhesive: epoxy resin, epoxy resin diluent and epoxy resin toughener are added successively according to raw material percentage composition each in Resin adhesive in planetary mixer, stir vacuumizing and defoaming, check resistance to air loss;
Then press each raw material percentage composition in Resin adhesive respectively and add coupling agent treatment ground barium sulfate, active nano light calcium carbonate and white carbon black, continue to stir, the cylinder cap of closed planetary mixer behind shovel limit, vacuumizing and defoaming, vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains Resin adhesive.
Prepare solidifying agent: each raw material percentage composition according to solidifying agent in planetary mixer adds modified fatty amine, modified phenolic amine, curing catalyst, dispersion agent and solvent successively, stir vacuumizing and defoaming, check resistance to air loss;
Coupling agent treatment ground barium sulfate, active nano light calcium carbonate and white carbon black is added respectively again according to raw material percentage composition each in solidifying agent; stir the cylinder cap of closed planetary mixer after shutting down shovel limit; vacuumizing and defoaming; vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains solidifying agent.
Three, Performance Detection, at normal temperature 23+2 DEG C, humidity 50% time, after the ratio of Resin adhesive and solidifying agent 1:1 is by weight mixed 2 hours, Performance Detection sees the following form 2:
Table 2
Because the epoxy stone material dry suspending glue of commercially available comparative example can not harden in 2 hours, other mechanical properties cannot be tested.
The various embodiments described above prepare epoxy stone material dry suspending glue in normal temperature construction environment, after Resin adhesive is mixed according to suitable part by weight (as 1:1) with solidifying agent, general constructed within 10 ~ 20 minutes usage periods complete can (length of usage period changes with variation of ambient temperature, general temperature is higher, usage period is shorter), surface drying (finger touches dry) is within 35 minutes, greatly be better than the epoxy stone material dry suspending glue of traditional needs 60 minutes surface drying times, and can harden completely in 2 hours (it is seamless indeformable that finger draws pressure), the construction requirement in engineering can be reached.
Can understand, in other embodiments, when constructing, the weight ratio of Resin adhesive and solidifying agent is not limited to 1:1, as being 1:0.8 ~ 1.2 other ratios such as grade, and each component of Resin adhesive and solidifying agent is not limited to the concrete material above described in embodiment 1 ~ 6, also can be other materials recited above.In embodiment 1 ~ 6, the ratio of each component is only limited to some specific embodiments, is not limited to scope of the present invention, and the weight percentage data of each component is as the criterion with data area recited above.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. an epoxy stone material dry suspending glue, is characterized in that, comprises Resin adhesive and solidifying agent, and wherein, described Resin adhesive comprises each component of following weight percentage:
Described solidifying agent comprises each component of following weight percentage:
2. epoxy stone material dry suspending glue as claimed in claim 1, it is characterized in that, described epoxy resin is one or more the mixture in bisphenol A epoxide resin, modified bisphenol A epoxy resin, bisphenol F epoxy resin, modified bisphenol F epoxy resin, dihydroxyphenyl propane/F epoxy resin and modified bisphenol A/F epoxy resin.
3. epoxy stone material dry suspending glue as claimed in claim 1, it is characterized in that, described epoxy resin diluent is one or more the mixture in n-butyl glycidyl ether, octyl glycidyl ether, C12 ~ C14 alkyl glycidyl ether, methyl propenoic acid glycidyl ether, phenylformic acid glycidyl ether, diglycidylether, diglycidyl ether of ethylene glycol, BDO glycidyl ether, hexylene glycol glycidyl ether, neopentyl glycol glycidyl ether, Resorcinol glycidyl ether, glycerin triglycidyl ether and trihydroxymethylpropanyltri diglycidyl ether.
4. epoxy stone material dry suspending glue as claimed in claim 1, it is characterized in that, described epoxy resin toughener is one or more mixture in carboxyl liquid nitrile rubber, end carboxyl liquid nitrile rubber, thiorubber, polyethers, polyimide, polyurethane-epoxy resin and polyether epoxy.
5. epoxy stone material dry suspending glue as claimed in claim 1, it is characterized in that, described coupling agent treatment ground barium sulfate is the 2000 object ground barium sulfates that coupling agent KH-560 and/or KH-550 coupling processing are crossed; Described nanometer light calcium carbonate is 100 ~ 400 object nanometer activation fine particle calcium carbonates.
6. epoxy stone material dry suspending glue as claimed in claim 1, is characterized in that, described modified fatty amine is amine value 200 ~ 400mgKOH/g, active hydrogen equivalent weight be 150 ~ 200,25 DEG C of viscosity is 1000 ~ 30000 centipoises.
7. epoxy stone material dry suspending glue as claimed in claim 1, is characterized in that, described modified phenolic amine is Mannich alkalescence modified phenolic amine, amine value 500-600mgKOH/g, active hydrogen equivalent weight 50 ~ 85,25 DEG C of viscosity 2000 ~ 10000 centipoises; Or modified by cardanol phenolic aldehyde amine, amine value 300-400mgKOH/g, active hydrogen equivalent weight 80 ~ 100,25 DEG C of viscosity 1000 ~ 10000 centipoises.
8. epoxy stone material dry suspending glue as claimed in claim 1, it is characterized in that, described curing catalyst is 2,4,6-tri-(dimethylamino methyl)-phenol; Described dispersion agent is the special high polymer dispersion of epoxy curing systems.
9. epoxy stone material dry suspending glue as claimed in claim 1, it is characterized in that, described white carbon black is aerosil; Described solvent is one or more mixture of methylethylketone, ethylene glycol diethyl fat, phthalic acid list ethylhexyl, ethylene glycol ether acetate, nylon acid methyl esters, nitration mixture methyl esters and diethylene glycol ether acetic ester.
10. a preparation method for epoxy stone material dry suspending glue, is characterized in that, comprises the steps:
Take each feed composition of Resin adhesive and solidifying agent, wherein, the percentage composition configuration of each feed composition of described Resin adhesive is as follows:
The percentage composition of each feed composition of described solidifying agent is as follows:
Prepare described Resin adhesive: described epoxy resin, described epoxy resin diluent and described epoxy resin toughener are added successively according to raw material percentage composition each in described Resin adhesive in planetary mixer, stir vacuumizing and defoaming;
Described coupling agent treatment ground barium sulfate, described active nano light calcium carbonate and described white carbon black is added respectively again by raw material percentage composition each in described Resin adhesive, continue to stir, the cylinder cap of closed described planetary mixer behind shovel limit, vacuumizing and defoaming, vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains described Resin adhesive;
Prepare described solidifying agent: in planetary mixer, add described modified fatty amine, described modified phenolic amine, described curing catalyst, described dispersion agent and described solvent successively according to each raw material percentage composition of described solidifying agent, stir vacuumizing and defoaming;
Described coupling agent treatment ground barium sulfate, described active nano light calcium carbonate and described white carbon black is added respectively again according to raw material percentage composition each in described solidifying agent; stir the cylinder cap of closed described planetary mixer after shutting down shovel limit; vacuumizing and defoaming; vacuum degree control is not higher than-0.1MPa, and after stirring, namely discharging obtains described solidifying agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510129049.1A CN104673163A (en) | 2015-03-23 | 2015-03-23 | Epoxy stone dry hanging adhesive rapidly solidified at normal temperature and preparation method of epoxy stone dry hanging adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510129049.1A CN104673163A (en) | 2015-03-23 | 2015-03-23 | Epoxy stone dry hanging adhesive rapidly solidified at normal temperature and preparation method of epoxy stone dry hanging adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104673163A true CN104673163A (en) | 2015-06-03 |
Family
ID=53308768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510129049.1A Pending CN104673163A (en) | 2015-03-23 | 2015-03-23 | Epoxy stone dry hanging adhesive rapidly solidified at normal temperature and preparation method of epoxy stone dry hanging adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104673163A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753124A (en) * | 2016-12-07 | 2017-05-31 | 安徽艾蒂贝生物有限公司 | A kind of stone material special epoxy resin adhesive |
| CN109628034A (en) * | 2018-11-13 | 2019-04-16 | 武汉市科达云石护理材料有限公司 | Twice-modified calcium carbonate and contain modified calcium carbonate epoxy dry-hang glue and preparation method |
| CN109722195A (en) * | 2018-12-28 | 2019-05-07 | 怀远县赛尔商贸有限公司 | The high stone material dry suspending glue of a kind of shock resistance, shear strength |
| CN109722196A (en) * | 2018-12-28 | 2019-05-07 | 怀远县赛尔商贸有限公司 | A kind of preparation method of normal temperature cure stone material dry suspending glue |
| CN110128982A (en) * | 2019-04-01 | 2019-08-16 | 矽时代材料科技股份有限公司 | A kind of fast fixing structure glue of room temperature and preparation method thereof |
| CN113512269A (en) * | 2021-05-31 | 2021-10-19 | 张家港衡业特种树脂有限公司 | Preparation method and use method of modified epoxy resin |
| CN114033120A (en) * | 2021-11-17 | 2022-02-11 | 瑞宇建设有限公司 | Construction method for building dry-hanging stone wall |
| CN114231186A (en) * | 2021-12-15 | 2022-03-25 | 武汉市科达云石护理材料有限公司 | Fast-curing modified dry-hanging adhesive and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2210927A1 (en) * | 2007-11-08 | 2010-07-28 | Wuhan Keda Marble Protective Materials CO., LTD. | A red and green dry adhesive, a method producing the same |
| CN103571413A (en) * | 2013-11-13 | 2014-02-12 | 苏州市姑苏新型建材有限公司 | Dry-hanging stone curtain wall epoxy adhesive and preparation method thereof |
| CN103923587A (en) * | 2014-04-16 | 2014-07-16 | 杭州之江有机硅化工有限公司 | Preparation method of bicomponent stone dry-hanging glue capable of being cured at normal temperature |
-
2015
- 2015-03-23 CN CN201510129049.1A patent/CN104673163A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2210927A1 (en) * | 2007-11-08 | 2010-07-28 | Wuhan Keda Marble Protective Materials CO., LTD. | A red and green dry adhesive, a method producing the same |
| CN103571413A (en) * | 2013-11-13 | 2014-02-12 | 苏州市姑苏新型建材有限公司 | Dry-hanging stone curtain wall epoxy adhesive and preparation method thereof |
| CN103923587A (en) * | 2014-04-16 | 2014-07-16 | 杭州之江有机硅化工有限公司 | Preparation method of bicomponent stone dry-hanging glue capable of being cured at normal temperature |
Non-Patent Citations (1)
| Title |
|---|
| 李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753124A (en) * | 2016-12-07 | 2017-05-31 | 安徽艾蒂贝生物有限公司 | A kind of stone material special epoxy resin adhesive |
| CN109628034A (en) * | 2018-11-13 | 2019-04-16 | 武汉市科达云石护理材料有限公司 | Twice-modified calcium carbonate and contain modified calcium carbonate epoxy dry-hang glue and preparation method |
| CN109722195A (en) * | 2018-12-28 | 2019-05-07 | 怀远县赛尔商贸有限公司 | The high stone material dry suspending glue of a kind of shock resistance, shear strength |
| CN109722196A (en) * | 2018-12-28 | 2019-05-07 | 怀远县赛尔商贸有限公司 | A kind of preparation method of normal temperature cure stone material dry suspending glue |
| CN109722195B (en) * | 2018-12-28 | 2021-10-29 | 蚌埠赛尔时代工贸有限公司 | Stone dry-hanging adhesive with high impact resistance and high shear strength |
| CN109722196B (en) * | 2018-12-28 | 2021-10-29 | 蚌埠赛尔时代工贸有限公司 | Preparation method of normal-temperature curing stone dry hanging adhesive |
| CN110128982A (en) * | 2019-04-01 | 2019-08-16 | 矽时代材料科技股份有限公司 | A kind of fast fixing structure glue of room temperature and preparation method thereof |
| CN110128982B (en) * | 2019-04-01 | 2021-07-06 | 矽时代材料科技股份有限公司 | Normal-temperature fast-curing structural adhesive and preparation method thereof |
| CN113512269A (en) * | 2021-05-31 | 2021-10-19 | 张家港衡业特种树脂有限公司 | Preparation method and use method of modified epoxy resin |
| CN114033120A (en) * | 2021-11-17 | 2022-02-11 | 瑞宇建设有限公司 | Construction method for building dry-hanging stone wall |
| CN114231186A (en) * | 2021-12-15 | 2022-03-25 | 武汉市科达云石护理材料有限公司 | Fast-curing modified dry-hanging adhesive and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104673163A (en) | Epoxy stone dry hanging adhesive rapidly solidified at normal temperature and preparation method of epoxy stone dry hanging adhesive | |
| CN104789178B (en) | Modified bisphenol-A epoxy resin inserted bar glue in complete underwater environment and preparation method | |
| CN102993898B (en) | Epoxy protective coating and preparation method for same | |
| CN102070874B (en) | High-permeability and high-strength epoxy grouting material, preparation method thereof and application thereof | |
| CN102344647B (en) | Environmentally-friendly high-seepage epoxy grouting material and preparation method and application thereof | |
| CN109401704A (en) | A kind of high solid content water epoxy adhesive and preparation method thereof | |
| CN105017906B (en) | A kind of colorful sealing wax of water-water and preparation method thereof | |
| CN106928889A (en) | Anchoring adhesive and preparation method thereof under a kind of water at low temperature | |
| CN107216609A (en) | Fast blockage epoxide resin grouting material | |
| CN108084663B (en) | High resiliency leak stopping modified epoxy grouting material and preparation method thereof | |
| CN106010406A (en) | Modified epoxy resin anchor adhesive with high strength and toughness | |
| CN107916086B (en) | Toughening type water-based epoxy resin system and preparation method thereof | |
| CN110117486A (en) | A kind of plugging material that epoxy resin/floating bead is compound | |
| CN107418372A (en) | A kind of osmosis type Water-base epoxy waterproof paint and preparation method thereof | |
| CN105238316B (en) | Two component epoxy stone material dry suspending glue of low-temperature setting and preparation method thereof | |
| CN104017527A (en) | Method for improving bonding strength of epoxy adhesive for dry hanging of stones | |
| CN108384497A (en) | A kind of low viscosity repairing concrete crack potting compound and preparation method thereof | |
| CN104559137B (en) | High resiliency no-solvent polyurethane loss circulation material and preparation method and application | |
| CN103602301B (en) | Underwater high polymer adhesive and preparation method thereof | |
| CN107619232A (en) | Tile style waterproofing and thermal insulation of roofing adhesive mortar and preparation method thereof | |
| CN107083152A (en) | A kind of high solidification low viscosity hardware coating | |
| CN103951942B (en) | Epoxy for carbon fibre material joint filling mends soil agent and preparation method thereof | |
| CN107011749A (en) | Luxury wall binding agent | |
| CN102911628A (en) | Environment-friendly vegetable-based building adhesive and preparation method thereof | |
| CN105622899A (en) | Modified polyether amine curing agent and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150603 |
|
| RJ01 | Rejection of invention patent application after publication |