CN104212310A - Protective coating for plastic material and preparation method of protective coating - Google Patents
Protective coating for plastic material and preparation method of protective coating Download PDFInfo
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- CN104212310A CN104212310A CN201410480849.3A CN201410480849A CN104212310A CN 104212310 A CN104212310 A CN 104212310A CN 201410480849 A CN201410480849 A CN 201410480849A CN 104212310 A CN104212310 A CN 104212310A
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Abstract
The invention provides a protective coating for a plastic material and a preparation method of the protective coating. The coating comprises the following components in parts by mass: 20-30 parts of epoxy acrylate, 18-28 parts of 2-hydroxyethyl methacrylate, 10-20 parts of tri(propylene glycol) diacrylate, 5-11 parts of methyl methacrylate, 25-35 parts of styrene, 8-17 parts of polycarbodiimide, 0.05-0.11 part of dibutyltin dilaurate, 7-16 parts of isopropanol, 0.7-1.1 parts of benzoin ethyl ether, 0.4-0.7 part of an anti-aging agent and 0.5-1.2 parts of a toughening agent. The coating provided by the invention has good storage stability and has high adhesive force on the plastic material; and the coating has high water resistance, anti-aging performance and toughness and is not easy to release and fade.
Description
Technical field
The present invention relates to paint field, relate in particular to protective cover and preparation method thereof for a kind of plastics matter material.
Background technology
Epoxy acrylate has excellent water tolerance, hot water resistance, resistance physical property, cohesiveness, toughness.The coating being prepared from it has good sticking power, water resisting property and package stability.
plastics matter material has a lot of purposes, can be used for preparing a lot of products.But existing plastics matter material is low with sticking power, water resisting property, toughness and the package stability of coating, and can not be effectively anti-aging, easily comes off, fades etc.
Summary of the invention
The technical problem solving: the shortcomings such as material for paint adhesion, water resisting property, toughness and package stability be low for existing plastics matter, the invention provides a kind of plastics matter material use protective cover and preparation method thereof.
Technical scheme: a kind of plastics matter material protective cover; in mass parts, contain following composition: 20～30 parts of epoxy acrylates, 18～28 parts of methacrylic acid-2-hydroxyethyl esters, 10～20 parts of tri (propylene glycol) diacrylates; 5～11 parts of methyl methacrylates; 25～35 parts of vinylbenzene, 8～17 parts of polycarbodiimides, 0.05～0.11 part of dibutyl tin laurate; 7～16 parts of Virahols; 0.7～1.1 part of Benzoin ethyl ether, 0.4～0.7 part, anti-aging agent, 0.5～1.2 part of toughner.
A kind of plastics matter material protective cover described above; in mass parts, contain following composition: 25 parts of epoxy acrylates, 23 parts of methacrylic acid-2-hydroxyethyl esters, 15 parts of tri (propylene glycol) diacrylates; 8 parts of methyl methacrylates; 30 parts of vinylbenzene, 13 parts of polycarbodiimides, 0.08 part of dibutyl tin laurate; 11 parts of Virahols; 0.9 part of Benzoin ethyl ether, 0.55 part, anti-aging agent, 0.9 part of toughner.
A kind of plastics matter material described above is as follows by the preparation process of protective cover: after first polycarbodiimide, dibutyl tin laurate and Virahol being mixed; in temperature, be to be incubated 3h at 90 ℃; then mix with epoxy acrylate, methacrylic acid-2-hydroxyethyl ester, tri (propylene glycol) diacrylate, methyl methacrylate, vinylbenzene; then mix with Benzoin ethyl ether, anti-aging agent, toughner, get product.
Beneficial effect: protective cover and preparation method thereof for a kind of plastics matter material provided by the invention, this coating has good storage stability, and high to the sticking power of plastics matter material, the water resisting property of coating, resistance to deterioration and toughness are high, and coating is not easy to come off, fade.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
embodiment 1
The present embodiment provides a kind of plastics matter material protective cover; in mass parts, contain following composition: 20 parts of epoxy acrylates, 18 parts of methacrylic acid-2-hydroxyethyl esters, 10 parts of tri (propylene glycol) diacrylates; 5 parts of methyl methacrylates; 25 parts of vinylbenzene, 8 parts of polycarbodiimides, 0.05 part of dibutyl tin laurate; 7 parts of Virahols; 0.7 part of Benzoin ethyl ether, 0.4 part, anti-aging agent, 0.5 part of toughner.
A kind of plastics matter material is as follows by the preparation process of protective cover: after first polycarbodiimide, dibutyl tin laurate and Virahol being mixed; in temperature, be to be incubated 3h at 90 ℃; then mix with epoxy acrylate, methacrylic acid-2-hydroxyethyl ester, tri (propylene glycol) diacrylate, methyl methacrylate, vinylbenzene; then mix with Benzoin ethyl ether, anti-aging agent, toughner, get product.
embodiment 2
The present embodiment provides a kind of plastics matter material protective cover; in mass parts, contain following composition: 30 parts of epoxy acrylates, 28 parts of methacrylic acid-2-hydroxyethyl esters, 20 parts of tri (propylene glycol) diacrylates; 11 parts of methyl methacrylates; 35 parts of vinylbenzene, 17 parts of polycarbodiimides, 0.11 part of dibutyl tin laurate; 16 parts of Virahols; 1.1 parts of Benzoin ethyl ethers, 0.7 part, anti-aging agent, 1.2 parts of toughner.
A kind of plastics matter material is as follows by the preparation process of protective cover: after first polycarbodiimide, dibutyl tin laurate and Virahol being mixed; in temperature, be to be incubated 3h at 90 ℃; then mix with epoxy acrylate, methacrylic acid-2-hydroxyethyl ester, tri (propylene glycol) diacrylate, methyl methacrylate, vinylbenzene; then mix with Benzoin ethyl ether, anti-aging agent, toughner, get product.
embodiment 3
The present embodiment provides a kind of plastics matter material protective cover; in mass parts, contain following composition: 25 parts of epoxy acrylates, 23 parts of methacrylic acid-2-hydroxyethyl esters, 15 parts of tri (propylene glycol) diacrylates; 8 parts of methyl methacrylates; 30 parts of vinylbenzene, 13 parts of polycarbodiimides, 0.08 part of dibutyl tin laurate; 11 parts of Virahols; 0.9 part of Benzoin ethyl ether, 0.55 part, anti-aging agent, 0.9 part of toughner.
A kind of plastics matter material is as follows by the preparation process of protective cover: after first polycarbodiimide, dibutyl tin laurate and Virahol being mixed; in temperature, be to be incubated 3h at 90 ℃; then mix with epoxy acrylate, methacrylic acid-2-hydroxyethyl ester, tri (propylene glycol) diacrylate, methyl methacrylate, vinylbenzene; then mix with Benzoin ethyl ether, anti-aging agent, toughner, get product.
The technical performance index of protective cover for a kind of plastics matter material of above-described embodiment 1～embodiment 3, its detected result is as follows:
Detected result
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, the thought according to the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (3)
1. a plastics matter material protective cover, is characterized in that, in mass parts, contains following composition: 20～30 parts of epoxy acrylates; 18～28 parts of methacrylic acid-2-hydroxyethyl esters; 10～20 parts of tri (propylene glycol) diacrylates, 5～11 parts of methyl methacrylates, 25～35 parts of vinylbenzene; 8～17 parts of polycarbodiimides; 0.05～0.11 part of dibutyl tin laurate, 7～16 parts of Virahols, 0.7～1.1 part of Benzoin ethyl ether; 0.4～0.7 part, anti-aging agent, 0.5～1.2 part of toughner.
2. a kind of plastics matter material protective cover according to claim 1, is characterized in that, contains following composition: 25 parts of epoxy acrylates in mass parts; 23 parts of methacrylic acid-2-hydroxyethyl esters; 15 parts of tri (propylene glycol) diacrylates, 8 parts of methyl methacrylates, 30 parts of vinylbenzene; 13 parts of polycarbodiimides; 0.08 part of dibutyl tin laurate, 11 parts of Virahols, 0.9 part of Benzoin ethyl ether; 0.55 part, anti-aging agent, 0.9 part of toughner.
3. the preparation method of protective cover for a kind of plastics matter material as claimed in claim 1; it is characterized in that; the preparation process of the method is as follows: after first polycarbodiimide, dibutyl tin laurate and Virahol being mixed; in temperature, be to be incubated 3h at 90 ℃; then mix with epoxy acrylate, methacrylic acid-2-hydroxyethyl ester, tri (propylene glycol) diacrylate, methyl methacrylate, vinylbenzene; then mix with Benzoin ethyl ether, anti-aging agent, toughner, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410480849.3A CN104212310A (en) | 2014-09-19 | 2014-09-19 | Protective coating for plastic material and preparation method of protective coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410480849.3A CN104212310A (en) | 2014-09-19 | 2014-09-19 | Protective coating for plastic material and preparation method of protective coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104212310A true CN104212310A (en) | 2014-12-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410480849.3A Pending CN104212310A (en) | 2014-09-19 | 2014-09-19 | Protective coating for plastic material and preparation method of protective coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN104212310A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105733391A (en) * | 2016-04-07 | 2016-07-06 | 蚌埠昆仑彩印包装有限公司 | Outer-layer protective paint for adhesive sticker |
| CN105733410A (en) * | 2016-04-07 | 2016-07-06 | 蚌埠昆仑彩印包装有限公司 | Protection coating for book edge sealing adhesive packaging box |
| CN105733377A (en) * | 2016-04-07 | 2016-07-06 | 蚌埠昆仑彩印包装有限公司 | Internal protection coating for plastic adhesive packaging box |
| CN105802492A (en) * | 2016-04-07 | 2016-07-27 | 蚌埠昆仑彩印包装有限公司 | Protective coating for outsides of packaging boxes of paper bag sealing glue |
Citations (5)
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| CN1526770A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured plastic paint |
| CN1772820A (en) * | 2004-11-10 | 2006-05-17 | 比亚迪股份有限公司 | Ultraviolet cured paint for plastics and its production process |
| CN101235229A (en) * | 2008-01-16 | 2008-08-06 | 长兴化学工业股份有限公司 | Paint composition |
| CN101338086A (en) * | 2008-08-20 | 2009-01-07 | 江苏科技大学 | Organic-inorganic hybridization coating cured by photothermal for protecting metallic surface |
| CN101445679A (en) * | 2008-12-25 | 2009-06-03 | 四川大学 | UV-light solidifying paint having decorative effect and preparation method thereof |
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2014
- 2014-09-19 CN CN201410480849.3A patent/CN104212310A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526770A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured plastic paint |
| CN1772820A (en) * | 2004-11-10 | 2006-05-17 | 比亚迪股份有限公司 | Ultraviolet cured paint for plastics and its production process |
| CN101235229A (en) * | 2008-01-16 | 2008-08-06 | 长兴化学工业股份有限公司 | Paint composition |
| CN101338086A (en) * | 2008-08-20 | 2009-01-07 | 江苏科技大学 | Organic-inorganic hybridization coating cured by photothermal for protecting metallic surface |
| CN101445679A (en) * | 2008-12-25 | 2009-06-03 | 四川大学 | UV-light solidifying paint having decorative effect and preparation method thereof |
Non-Patent Citations (2)
| Title |
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| 黄玉媛等: "《环境友好涂料制备与应用技术》", 31 January 2009, 中国纺织出版社 * |
| 黄玉媛等: "《精细化学品实用配方手册》", 31 January 2009, article "精细化学品实用配方手册", pages: 112 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105733391A (en) * | 2016-04-07 | 2016-07-06 | 蚌埠昆仑彩印包装有限公司 | Outer-layer protective paint for adhesive sticker |
| CN105733410A (en) * | 2016-04-07 | 2016-07-06 | 蚌埠昆仑彩印包装有限公司 | Protection coating for book edge sealing adhesive packaging box |
| CN105733377A (en) * | 2016-04-07 | 2016-07-06 | 蚌埠昆仑彩印包装有限公司 | Internal protection coating for plastic adhesive packaging box |
| CN105802492A (en) * | 2016-04-07 | 2016-07-27 | 蚌埠昆仑彩印包装有限公司 | Protective coating for outsides of packaging boxes of paper bag sealing glue |
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Application publication date: 20141217 |