CN105315933B - A kind of antistripping instant drying adhesive and preparation method thereof - Google Patents
A kind of antistripping instant drying adhesive and preparation method thereof Download PDFInfo
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- CN105315933B CN105315933B CN201510822329.0A CN201510822329A CN105315933B CN 105315933 B CN105315933 B CN 105315933B CN 201510822329 A CN201510822329 A CN 201510822329A CN 105315933 B CN105315933 B CN 105315933B
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- antistripping
- drying adhesive
- instant drying
- coupling agent
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- 239000004819 Drying adhesive Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000007822 coupling agent Substances 0.000 claims abstract description 25
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920000926 Galactomannan Polymers 0.000 claims abstract description 20
- 108010010803 Gelatin Proteins 0.000 claims abstract description 19
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 19
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 19
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920000159 gelatin Polymers 0.000 claims abstract description 19
- 239000008273 gelatin Substances 0.000 claims abstract description 19
- 235000019322 gelatine Nutrition 0.000 claims abstract description 19
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 19
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 19
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 19
- 229960000380 propiolactone Drugs 0.000 claims abstract description 19
- IJVRPNIWWODHHA-UHFFFAOYSA-N 2-cyanoprop-2-enoic acid Chemical compound OC(=O)C(=C)C#N IJVRPNIWWODHHA-UHFFFAOYSA-N 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 17
- 238000005292 vacuum distillation Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 11
- 230000001070 adhesive effect Effects 0.000 abstract description 11
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000003292 glue Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 241000707825 Argyrosomus regius Species 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004826 Synthetic adhesive Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
Abstract
The invention discloses a kind of antistripping instant drying adhesive, in parts by weight, including following components：30 50 parts of α cyanacrylates, 0.5 4 parts of EVA, 25 parts of β propiolactone, 0.5 1 parts of modified titanium oxide, 8 12 parts of gelatin, 5 10 parts of polyacrylate, 28 parts of galactomannans, 38 parts of hydroxyethyl cellulose, 1 1.5 parts of coupling agent.The invention also discloses the preparation method of the antistripping instant drying adhesive.Its curing rate of the antistripping instant drying adhesive is fast, and water-tolerant, impact resistance is strong, and adhesive strength is big, and peeling resistance is good, and usage amount is few, nontoxic, is conducive to environmental protection.
Description
Technical field：
The present invention relates to adhesive technical field, a kind of antistripping instant drying adhesive is specifically related to.
Background technology：
Instant drying adhesive, i.e. moment quickly then use glue, are based on α-cyanoacrylate, to add tackifier.Thickening
Agent, stabilizer, toughener, polymerization inhibitor etc., the one-component rapid curing adhesive synthesized by vanguard technology；It is a kind of
High intensity, quick sticker, can be used the high speed in multiple types material into proceeding with one's work, and be particularly suitable for being used in woodenware industry；It is right
In being brought into close contact, porous material, up to most strong then effect such as rubber-metal, plastic cement, woodenware；This glue is one single
One composition, solvent-free, it is not necessary to add the sticker of catalyst, heating or pressurization, it is only necessary to one layer of meagre glue, it just can profit
Produce high polymeric with the atmospheric humidity in air, reach it is optimal amplexiform effect, have natural glue and synthetic adhesive it
Point, it can also be divided into Organic adhesive and inorganic adhesive.Alpha-cyanoacrylate ester gum is that one pack system, low viscosity, transparent, normal temperature are quick
Curing adhesive.There is good cementitiousness to most materials, be one of important room temperature setting adhesives kind.But its
In the presence of some shortcomings, curing rate is too fast so that its impact resistance, peeling resistance are poor.
Chinese patent (201010511081.3) discloses a kind of novel epoxy reins adhesive, including epoxy resin, neighbour
Dibatyl phithalate, silicon powder, epoxide and coupling agent, the adhesive are heat-resist, excellent shock resistance, are glued
Intensity is high, and antistripping, splitting resistance are good after solidification.But its viscosity is larger, usage amount is big.
The content of the invention：
It is an object of the invention to provide a kind of antistripping instant drying adhesive, its curing rate is fast, water-tolerant, impact resistance
By force, adhesive strength is big, and peeling resistance is good, and usage amount is few, nontoxic, is conducive to environmental protection.
It is a further object to provide the preparation method of the antistripping instant drying adhesive.
To achieve the above object, the present invention uses following technical scheme：
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
30-50 parts of α-cyanoacrylate,
0.5-4 parts of EVA, 2-5 parts of beta-propiolactone,
0.5-1 parts of modified titanium oxide, 8-12 parts of gelatin,
5-10 parts of polyacrylate, 2-8 parts of galactomannans,
3-8 parts of hydroxyethyl cellulose, 1-1.5 parts of coupling agent.
As the preferred of above-mentioned technical proposal, a kind of antistripping instant drying adhesive, in parts by weight, including following components：
50 parts of α-cyanoacrylate,
1 part of EVA, 3 parts of beta-propiolactone,
0.7 part of modified titanium oxide, 9 parts of gelatin,
8 parts of polyacrylate, 5 parts of galactomannans,
6 parts of hydroxyethyl cellulose, 1.1 parts of coupling agent.
As the preferred of above-mentioned technical proposal, in the EVA, the content of vinyl acetate is 10-20%.
As the preferred of above-mentioned technical proposal, the particle size of the modified titanium oxide is 10-20nm, its method of modifying
For：Nano-titanium oxide and absolute ethyl alcohol are mixed evenly, oleic acid, under 500-1000W power, ultrasonic 20- is added
50min, is filtered, and is dried in vacuo, and grinding obtains modified titanium oxide.
As the preferred of above-mentioned technical proposal, the coupling agent is titanate coupling agent, Silane coupling agent KH550, silane
One or more mixing in coupling agent KH560.
A kind of preparation method of antistripping instant drying adhesive, comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, in 100-120
At DEG C, heating response 1-3h is cooled to 70-80 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and heating is molten
1-2h is reacted, mixed material is obtained；
(2) in the mixed material obtained to step (1), gelatin and modified titanium oxide are added, depressurizes and steams at 150-180 DEG C
Evaporate, obtain antistripping instant drying adhesive.
The invention has the advantages that：
The present invention adds modified titanium oxide and galactomannans in α-cyanoacrylate so that obtained wink does
Glue impact resistance is good, and stripper-resistance is good, and adhesive strength is greatly improved；
The instant drying adhesive curing rate that the present invention is provided is fast, and water-tolerant, low-temperature adhesion performance is good, nontoxic, is conducive to environment
Protection.
Embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
30 parts of α-cyanoacrylate,
0.5 part of EVA, 2 parts of beta-propiolactone,
0.5 part of modified titanium oxide, 8 parts of gelatin,
5 parts of polyacrylate, 2 parts of galactomannans,
3 parts of hydroxyethyl cellulose, 1 part of coupling agent.
Its preparation method comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 100 DEG C,
Heating response 1h, is cooled to 70 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and the molten reaction 1h of heating is obtained
Mixed material；
(2) gelatin and modified titanium oxide are added in the mixed material obtained to step (1), the vacuum distillation at 150 DEG C,
Obtain antistripping instant drying adhesive.
Embodiment 2
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
50 parts of α-cyanoacrylate,
4 parts of EVA, 5 parts of beta-propiolactone,
1 part of modified titanium oxide, 12 parts of gelatin,
10 parts of polyacrylate, 8 parts of galactomannans,
8 parts of hydroxyethyl cellulose, 1.5 parts of coupling agent.
Its preparation method comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 120 DEG C,
Heating response 3h, is cooled to 80 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and the molten reaction 2h of heating is obtained
Mixed material；
(2) in the mixed material obtained to step (1), gelatin and modified titanium oxide are added, depressurizes and steams at 150-180 DEG C
Evaporate, obtain antistripping instant drying adhesive.
Embodiment 3
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
35 parts of α-cyanoacrylate,
1 part of EVA, 2.5 parts of beta-propiolactone,
0.6 part of modified titanium oxide, 9 parts of gelatin,
6 parts of polyacrylate, 3 parts of galactomannans,
4 parts of hydroxyethyl cellulose, 1.1 parts of coupling agent.
Its preparation method comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 105 DEG C,
Heating response 1.5h, is cooled to 75 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and heating is molten to react 1.2h,
Obtain mixed material；
(2) gelatin and modified titanium oxide are added in the mixed material obtained to step (1), the vacuum distillation at 155 DEG C,
Obtain antistripping instant drying adhesive.
Embodiment 4
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
40 parts of α-cyanoacrylate,
1.5 parts of EVA, 3.5 parts of beta-propiolactone,
0.7 part of modified titanium oxide, 10 parts of gelatin,
7 parts of polyacrylate, 4 parts of galactomannans,
5 parts of hydroxyethyl cellulose, 1.2 parts of coupling agent.
Its preparation method comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 110 DEG C,
Heating response 1.8h, is cooled to 80 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and heating is molten to react 1.4h,
Obtain mixed material；
(2) gelatin and modified titanium oxide are added in the mixed material obtained to step (1), the vacuum distillation at 160 DEG C,
Obtain antistripping instant drying adhesive.
Embodiment 5
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
45 parts of α-cyanoacrylate,
3 parts of EVA, 4.5 parts of beta-propiolactone,
0.8 part of modified titanium oxide, 10 parts of gelatin,
8 parts of polyacrylate, 6 parts of galactomannans,
6 parts of hydroxyethyl cellulose, 1.3 parts of coupling agent.
Its preparation method comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 115 DEG C,
Heating response 1.8h, is cooled to 80 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and heating is molten to react 1.6h,
Obtain mixed material；
(2) gelatin and modified titanium oxide are added in the mixed material obtained to step (1), the vacuum distillation at 165 DEG C,
Obtain antistripping instant drying adhesive.
Embodiment 6
A kind of antistripping instant drying adhesive, in parts by weight, including following components：
48 parts of α-cyanoacrylate,
3.8 parts of EVA, 4.8 parts of beta-propiolactone,
0.9 part of modified titanium oxide, 11 parts of gelatin,
9 parts of polyacrylate, 7 parts of galactomannans,
7.5 parts of hydroxyethyl cellulose, 1.4 parts of coupling agent.
Its preparation method comprises the following steps：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 120 DEG C,
Heating response 2.5h, is cooled to 80 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, and heating is molten to react 1.8h,
Obtain mixed material；
(2) gelatin and modified titanium oxide are added in the mixed material obtained to step (1), the vacuum distillation at 175 DEG C,
Obtain antistripping instant drying adhesive.
Performance test is carried out to the antistripping instant drying adhesive that the present invention is provided below, wherein comparative example is common instant drying adhesive.
Table 1
From the point of view of table 1, instant drying adhesive impact resistance provided by the present invention is good, and peel strength is big, and water-tolerant.
Claims (5)
1. a kind of antistripping instant drying adhesive, it is characterised in that in parts by weight, including following components：
30-50 parts of α-cyanoacrylate,
0.5-4 parts of EVA, 2-5 parts of beta-propiolactone,
0.5-1 parts of modified titanium oxide, 8-12 parts of gelatin,
5-10 parts of polyacrylate, 2-8 parts of galactomannans,
3-8 parts of hydroxyethyl cellulose, 1-1.5 parts of coupling agent；
Wherein, the particle size of the modified titanium oxide is 10-20nm, and its method of modifying is：By nano-titanium oxide and anhydrous second
Alcohol is mixed evenly, and adds oleic acid, under 500-1000W power, and ultrasonic 20-50min is filtered, and is dried in vacuo, grinding,
Obtain modified titanium oxide.
2. a kind of antistripping instant drying adhesive as claimed in claim 1, it is characterised in that in parts by weight, including following components：
50 parts of α-cyanoacrylate,
1 part of EVA, 3 parts of beta-propiolactone,
0.7 part of modified titanium oxide, 9 parts of gelatin,
8 parts of polyacrylate, 5 parts of galactomannans,
6 parts of hydroxyethyl cellulose, 1.1 parts of coupling agent.
3. a kind of antistripping instant drying adhesive as claimed in claim 1, it is characterised in that in the EVA, the content of vinyl acetate is
10-20%.
4. a kind of antistripping instant drying adhesive as claimed in claim 1, it is characterised in that the coupling agent is titanate coupling agent,
One or more mixing in Silane coupling agent KH550, silane coupler KH560.
5. the preparation method of a kind of antistripping instant drying adhesive as described in Claims 1-4 is any, it is characterised in that including following
Step：
(1) α-cyanoacrylate, EVA, beta-propiolactone and polyacrylate are mixed evenly, at 100-120 DEG C,
Heating response 1-3h, is cooled to 70-80 DEG C, adds galactomannans, hydroxyethyl cellulose and coupling agent, the molten reaction 1- of heating
2h, obtains mixed material；
(2) gelatin and modified titanium oxide are added in the mixed material obtained to step (1), the vacuum distillation at 150-180 DEG C,
Obtain antistripping instant drying adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510822329.0A CN105315933B (en) | 2015-11-24 | 2015-11-24 | A kind of antistripping instant drying adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510822329.0A CN105315933B (en) | 2015-11-24 | 2015-11-24 | A kind of antistripping instant drying adhesive and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105315933A CN105315933A (en) | 2016-02-10 |
| CN105315933B true CN105315933B (en) | 2017-08-04 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107459846A (en) * | 2017-07-26 | 2017-12-12 | 柳州金特新型耐磨材料股份有限公司 | Antistripping wearable ceramic coat and preparation method thereof |
| CN109768123B (en) * | 2019-01-31 | 2022-10-14 | 泰州隆基乐叶光伏科技有限公司 | Welding method |
| CN110591569B (en) * | 2019-09-17 | 2021-08-10 | 浙江派菲特新材料科技有限公司 | Environment-friendly low-whitening instant adhesive |
| CN114395334B (en) * | 2022-03-15 | 2023-09-26 | 宁波百仕高联合工业有限公司 | Preparation method of high-water-resistance instant adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2511355A1 (en) * | 2011-04-12 | 2012-10-17 | Henkel Ireland Ltd. | Cyanoacrylate adhesive with improved water resistance |
| CN102994022A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Instant adhesive |
| CN103666293A (en) * | 2013-12-02 | 2014-03-26 | 南通瑞普埃尔生物工程有限公司 | Heat resistance instant dry adhesive and preparation method thereof |
-
2015
- 2015-11-24 CN CN201510822329.0A patent/CN105315933B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2511355A1 (en) * | 2011-04-12 | 2012-10-17 | Henkel Ireland Ltd. | Cyanoacrylate adhesive with improved water resistance |
| CN102994022A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Instant adhesive |
| CN103666293A (en) * | 2013-12-02 | 2014-03-26 | 南通瑞普埃尔生物工程有限公司 | Heat resistance instant dry adhesive and preparation method thereof |
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