CN103360961A - High-strength waterproof adhesive and preparation method thereof - Google Patents
High-strength waterproof adhesive and preparation method thereof Download PDFInfo
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- CN103360961A CN103360961A CN2013102800261A CN201310280026A CN103360961A CN 103360961 A CN103360961 A CN 103360961A CN 2013102800261 A CN2013102800261 A CN 2013102800261A CN 201310280026 A CN201310280026 A CN 201310280026A CN 103360961 A CN103360961 A CN 103360961A
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Abstract
The invention discloses a high-strength waterproof adhesive. The high-strength waterproof adhesive is prepared from the following materials in parts by weight: 10-12 parts of E-44 epoxy resin, 3-4 parts of diethylenetriamine, 3-4 parts of polystyrene, 3-4 parts of coumarone, 2-3 parts of titanium dioxide, 3-4 parts of acrylic acid, 4-5 parts of ethylene glycol monoethyl ether acetate, 3-4 parts of butanediol, 2-3 parts of tert-butyl peroxybenzoate, 4-5 parts of attapulgite powder, 2-3 parts of silane coupling agent KH560, 1-2 parts of morpholine, 15-17 parts of acetone and 8-10 parts of ethyl acetate. The high-strength water-absorbing adhesive disclosed by the invention is simple in material, low in price, high in adhesion strength and long in service life.
Description
Technical field
The present invention relates to a kind of chemical materials, more specifically relate to a kind of tackiness agent.
Background technology
At present, be used for cardboard box glue stick kind a lot, three-aldehyde glue and white glue with vinyl etc. are arranged.Some tackiness agent can discharge free state formaldehyde in production and application process, serious to human body and environmental hazard; Some tackiness agent, water tolerance and wet fastness are poor, easily moisture absorption in damp atmosphere, bonding strength is not high; At high temperature use to produce creep, Joint strength is descended, storing easy freezing below-5 ℃, emulsion is damaged, therefore cause its application greatly limited.The bonding strength that needs research to make new advances is high, the tackiness agent of safety and environmental protection, good stability.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of high-strength waterproof tackiness agent and preparation method thereof is provided.
Technical scheme of the present invention is as follows:
A kind of high-strength waterproof tackiness agent is characterized in that being made by the raw material of following weight part: E-44 Resins, epoxy 10-12, diethylenetriamine 3-4, polystyrene 3-4, coumarone 3-4, titanium dioxide 2-3, vinylformic acid 3-4, ethylene glycol ether acetate 4-5, butyleneglycol 3-4, peroxidized t-butyl perbenzoate 2-3, attapulgite powder 4-5, silane coupling agent KH560 2-3, morpholine 1-2, acetone 15-17, ethyl acetate 8-10.
The preparation method of described high-strength waterproof tackiness agent is characterized in that may further comprise the steps:
(1), polystyrene is added in the ethyl acetate, heating for dissolving adds vinylformic acid, ethylene glycol ether acetate, coumarone again, stirs, and adds silane coupling agent KH560 again, stirring reaction 1-2 hour;
(2), other remaining component is merged mixing, stirring reaction 40-60 minute;
(3), step (1), (2) are mixed, be heated to 60-70 ℃, stirring reaction 2-3 hour, and get final product.
High-intensity water absorbent tackiness agent of the present invention, raw material is simple, cheap, and cohesive strength is high, long service life.
Embodiment
A kind of high-strength waterproof tackiness agent is made by the raw material of following weight part (kilogram): E-44 Resins, epoxy 10, diethylenetriamine 3, polystyrene 4, coumarone 4, titanium dioxide 2, vinylformic acid 4, ethylene glycol ether acetate 5, butyleneglycol 4, peroxidized t-butyl perbenzoate 2, attapulgite powder 4, silane coupling agent KH560 2, morpholine 1, acetone 17, ethyl acetate 8.
The preparation method of described high-strength waterproof tackiness agent may further comprise the steps:
(1), polystyrene is added in the ethyl acetate, heating for dissolving adds vinylformic acid, ethylene glycol ether acetate, coumarone again, stirs, and adds silane coupling agent KH560 again, stirring reaction 1-2 hour;
(2), other remaining component is merged mixing, stirring reaction 40-60 minute;
(3), step (1), (2) are mixed, be heated to 60-70 ℃, stirring reaction 2-3 hour, and get final product.
The tackiness agent of the present invention's preparation, through detecting: after 4 hours, bonding strength reaches 26Mpa, water-tolerant.After bonding, put into 40 ℃ of water and soaked 2 hours, bonding strength is 21 Mpa.
Claims (2)
1. a high-strength waterproof tackiness agent is characterized in that being made by the raw material of following weight part: E-44 Resins, epoxy 10-12, diethylenetriamine 3-4, polystyrene 3-4, coumarone 3-4, titanium dioxide 2-3, vinylformic acid 3-4, ethylene glycol ether acetate 4-5, butyleneglycol 3-4, peroxidized t-butyl perbenzoate 2-3, attapulgite powder 4-5, silane coupling agent KH560 2-3, morpholine 1-2, acetone 15-17, ethyl acetate 8-10.
2. the preparation method of high-strength waterproof tackiness agent according to claim 1, it is characterized in that may further comprise the steps: (1), polystyrene is added in the ethyl acetate, heating for dissolving, add again vinylformic acid, ethylene glycol ether acetate, coumarone, stir, add again silane coupling agent KH560, stirring reaction 1-2 hour;
(2), other remaining component is merged mixing, stirring reaction 40-60 minute;
(3), step (1), (2) are mixed, be heated to 60-70 ℃, stirring reaction 2-3 hour, and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310280026.1A CN103360961B (en) | 2013-07-05 | 2013-07-05 | A kind of High-strength waterproof adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310280026.1A CN103360961B (en) | 2013-07-05 | 2013-07-05 | A kind of High-strength waterproof adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103360961A true CN103360961A (en) | 2013-10-23 |
| CN103360961B CN103360961B (en) | 2015-08-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310280026.1A Expired - Fee Related CN103360961B (en) | 2013-07-05 | 2013-07-05 | A kind of High-strength waterproof adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103360961B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923588A (en) * | 2014-05-01 | 2014-07-16 | 湖州中辰建设有限公司 | Novel caulking adhesive for concrete precast element |
| CN104293218A (en) * | 2014-10-16 | 2015-01-21 | 安徽省阜阳沪千人造板制造有限公司 | Phenol-formaldehyde resin adhesive for plates |
| CN104790105A (en) * | 2015-05-08 | 2015-07-22 | 南通天燕纺织器材有限公司 | Wooden shuttle |
| CN107189696A (en) * | 2017-05-25 | 2017-09-22 | 成都市容德建筑劳务有限公司 | A kind of water proof type mixed mud crack glue |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5708059A (en) * | 1994-06-30 | 1998-01-13 | Hoechst Aktiengesellschaft | Stable, aqueous epoxy resin dispersions, processes for their preparation, and their use |
| CN102051105A (en) * | 2010-12-17 | 2011-05-11 | 苏州吉人漆业有限公司 | Solvent-free coumarone modified epoxy heavy-duty anticorrosive coating |
| CN102337098A (en) * | 2011-07-19 | 2012-02-01 | 彩虹集团公司 | Sealant and preparation method thereof |
-
2013
- 2013-07-05 CN CN201310280026.1A patent/CN103360961B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5708059A (en) * | 1994-06-30 | 1998-01-13 | Hoechst Aktiengesellschaft | Stable, aqueous epoxy resin dispersions, processes for their preparation, and their use |
| CN102051105A (en) * | 2010-12-17 | 2011-05-11 | 苏州吉人漆业有限公司 | Solvent-free coumarone modified epoxy heavy-duty anticorrosive coating |
| CN102337098A (en) * | 2011-07-19 | 2012-02-01 | 彩虹集团公司 | Sealant and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 李东光: "《胶黏剂配方与生产（一）》", 31 January 2012, 化学工业出版社 * |
| 肖卫东等: "《胶黏剂生产技巧与疑难分析300例》", 31 March 2009, 化学工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923588A (en) * | 2014-05-01 | 2014-07-16 | 湖州中辰建设有限公司 | Novel caulking adhesive for concrete precast element |
| CN103923588B (en) * | 2014-05-01 | 2015-07-29 | 湖州中辰建设有限公司 | A kind of concrete precast element filleting binding agent |
| CN104293218A (en) * | 2014-10-16 | 2015-01-21 | 安徽省阜阳沪千人造板制造有限公司 | Phenol-formaldehyde resin adhesive for plates |
| CN104790105A (en) * | 2015-05-08 | 2015-07-22 | 南通天燕纺织器材有限公司 | Wooden shuttle |
| CN107189696A (en) * | 2017-05-25 | 2017-09-22 | 成都市容德建筑劳务有限公司 | A kind of water proof type mixed mud crack glue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103360961B (en) | 2015-08-26 |
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Granted publication date: 20150826 Termination date: 20190705 |