CN103881591B - Clorafin rosin lead tree fat flame-retarding adhesive - Google Patents

Clorafin rosin lead tree fat flame-retarding adhesive Download PDF

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Publication number
CN103881591B
CN103881591B CN201410104343.2A CN201410104343A CN103881591B CN 103881591 B CN103881591 B CN 103881591B CN 201410104343 A CN201410104343 A CN 201410104343A CN 103881591 B CN103881591 B CN 103881591B
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China
Prior art keywords
clorafin
tree fat
rosin
lead tree
rosin lead
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CN201410104343.2A
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CN103881591A (en
Inventor
杨毅
李安平
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Shanghai Xingxing Rubber Product Co., Ltd.
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杨毅
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Abstract

Clorafin rosin lead tree fat flame-retarding adhesive of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 90-120 part, rosin lead tree fat 13-30 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; Have raw material to be easy to get, cost is low, and environmental protection is easy to use, effective advantage.

Description

Clorafin rosin lead tree fat flame-retarding adhesive
Technical field
The invention belongs to a kind of tackiness agent.
Background technology
Glued joint (bonding, bonding, cementing, gluing) and refer to the technology that homogeneity or heterogeneous body surface stick with glue agent and link together to there is stress distribution continuous, lightweight, or sealing, the features such as most technological temperature is low.Glued joint the connection being specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and has great effect to high-and-new science and technology progress and people's daily life improvement.Therefore, study, all kinds of tackiness agent of development and production is very important.Tackiness agent (Bonding agent) is one of most important subsidiary material, applies very extensive in package handling.Tackiness agent is the sticking material of tool, the material that two kinds are separated can be linked together by its viscosity.The kind of tackiness agent is a lot.1. natural glue it be taken from the material of occurring in nature.Comprise the biological adhesives such as starch, protein, dextrin, gelatin, shellac, hide glue, rosin; Also the mineral binders such as pitch are comprised.2. artificial tackiness agent this be use made material, comprise the inorganic adhesives such as water glass, and the organic binder bond such as synthetic resins, synthetic rubber.Service performance divides 1. Watersoluble Adhesive to use water as the tackiness agent of solvent, mainly contains starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose etc.2. Hotmelt Adhesive uses after making adhesive melts by heating, is a kind of solid binder.General thermoplastic resin all can use, as urethane, polystyrene, polyacrylic ester, ethene-acetate ethylene copolymer etc.3. Solvent Adhesive is water insoluble and be dissolved in the tackiness agent of certain solvent.As shellac, isoprene-isobutylene rubber etc.4. Emulsion Adhesive is many is suspension in water, as vinyl acetate resin, acrylic resin, chlorinated rubber etc.5. liquid non-solvent tackiness agent is at normal temperatures in thick liquid nano, as epoxy resin etc.Tackiness agent is the medium between label material and bonding substrates, plays link effect.Permanent and removable property two kinds can be divided into by its characteristic.It has multiple formulations, is applicable to different plane materiels and different occasions.Tackiness agent is the most important composition in adhesive material technology, is the key of label utilisation technology.Glued joint (bonding, bonding, cementing, gluing) and refer to the technology that homogeneity or heterogeneous body surface stick with glue agent and link together to there is stress distribution continuous, lightweight, or sealing, the features such as most technological temperature is low.Glued joint the connection being specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and has great effect to high-and-new science and technology progress and people's daily life improvement.Therefore, study, all kinds of tackiness agent of development and production is very important.
Retrieve through Chinese publication, do not find the scheme identical with present patent application.
Summary of the invention:
The object of the invention is to; A kind of clorafin rosin lead tree fat flame-retarding adhesive is proposed.
Clorafin rosin lead tree fat flame-retarding adhesive of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 90-120 part, rosin lead tree fat 13-30 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms.
Clorafin rosin lead tree fat flame-retarding adhesive preparation method of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 90-120 part, rosin lead tree fat 13-30 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
Product of the present invention, can adapt to the use of various occasion, and bond strength reaches more than 2 times of prior art.
The present invention compared with prior art its beneficial effect is: have raw material and be easy to get, work simplification, is easy to manufacture, and cost is low, environmental protection, easy to use, the advantages such as materials are more economized, effective.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited thereto.
Product of the present invention is raw materials used buys acquisition.
Embodiment 1
Clorafin rosin lead tree fat flame-retarding adhesive preparation method of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 90-120 part, rosin lead tree fat 13-30 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 2
Clorafin rosin lead tree fat flame-retarding adhesive preparation method of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 90 parts, 13 parts, rosin lead tree fat, isobutyl acrylate 350 parts, ethyl propenoate 150 parts, 15 parts, vinylformic acid, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 3
Clorafin rosin lead tree fat flame-retarding adhesive preparation method of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 120 parts, 30 parts, rosin lead tree fat, isobutyl acrylate 400 parts, ethyl propenoate 200 parts, 20 parts, vinylformic acid, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 4
Clorafin rosin lead tree fat flame-retarding adhesive preparation method of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 90 parts, 30 parts, rosin lead tree fat, isobutyl acrylate 350 parts, ethyl propenoate 200 parts, 15 parts, vinylformic acid, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
Embodiment 5
Clorafin rosin lead tree fat flame-retarding adhesive preparation method of the present invention, it is characterized in that: its formula by weight, by methyl acrylate 120 parts, 13 parts, rosin lead tree fat, isobutyl acrylate 400 parts, ethyl propenoate 150 parts, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
Product specification of the present invention, quality: solid content more than 85%, its 1% solution pH value is 7.0-7.5.

Claims (2)

1. a clorafin rosin lead tree fat flame-retarding adhesive, it is characterized in that: its formula by weight, by methyl acrylate 90-120 part, rosin lead tree fat 13-30 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms.
2. a clorafin rosin lead tree fat flame-retarding adhesive preparation method, it is characterized in that: its formula by weight, by methyl acrylate 90-120 part, rosin lead tree fat 13-30 part, isobutyl acrylate 350-400 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, Tai-Ace S 150 1-5 part, clorafin 1-5 part, decabromodiphenyl oxide 1-5 part forms; By whole mixing of materials, react 60-90 minute at 80-90 DEG C, obtain product.
CN201410104343.2A 2014-03-20 2014-03-20 Clorafin rosin lead tree fat flame-retarding adhesive Active CN103881591B (en)

Priority Applications (1)

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CN201410104343.2A CN103881591B (en) 2014-03-20 2014-03-20 Clorafin rosin lead tree fat flame-retarding adhesive

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CN201410104343.2A CN103881591B (en) 2014-03-20 2014-03-20 Clorafin rosin lead tree fat flame-retarding adhesive

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CN103881591B true CN103881591B (en) 2015-09-30

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112266731A (en) * 2020-09-28 2021-01-26 湖南省和祥润新材料有限公司 UV-cured acrylate pressure-sensitive adhesive containing chlorinated paraffin

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1532247A (en) * 2003-03-18 2004-09-29 �����ɷ� Flame-retardant pressure sensitive adhesive, its preparing process and its use in producing pressure sensitive adhesive tape
CN102965023A (en) * 2012-12-04 2013-03-13 张雅静 Preparation method of acrylic acid modified rosin lead resin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1532247A (en) * 2003-03-18 2004-09-29 �����ɷ� Flame-retardant pressure sensitive adhesive, its preparing process and its use in producing pressure sensitive adhesive tape
CN102965023A (en) * 2012-12-04 2013-03-13 张雅静 Preparation method of acrylic acid modified rosin lead resin

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王尚义等.印刷纸的制造过程及其对质量的影响.《纸张100问》.印刷工业出版社,2006,第69页. *
骆光林.压敏胶带.《包装材料学》.印刷工业出版社,2011,282. *

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Effective date of registration: 20180910

Address after: 201600 No. 4968, Si Chen Road, Songjiang District, Shanghai

Patentee after: Shanghai Xingxing Rubber Product Co., Ltd.

Address before: 542800 No. 13 Garden Street, eight step area, Hezhou, the Guangxi Zhuang Autonomous Region

Patentee before: Yang Yi