CN103881627A - Foamed microporous acrylic emulsion - Google Patents
Foamed microporous acrylic emulsion Download PDFInfo
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- CN103881627A CN103881627A CN201410104366.3A CN201410104366A CN103881627A CN 103881627 A CN103881627 A CN 103881627A CN 201410104366 A CN201410104366 A CN 201410104366A CN 103881627 A CN103881627 A CN 103881627A
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Abstract
The invention discloses a foamed microporous acrylic emulsion. The formula of the foamed microporous acrylic emulsion is characterized by comprising the following raw materials in parts by weight 125-150 parts of methyl acrylate, 16-20 parts of hydroxy-propyl acrylate, 360-400 parts of ethyl acrylate, 19-25 parts of crylic acid, 1-2 parts of octadecane amine acetate, 2-5 parts of citric acid, 10-15 parts of calcium carbonate, 1-2 parts of octyltrimethylammonium chloride, 1-2 parts of methyl ester sulfonate, 1-2 parts of benzyl naphthalene sulfonate, 1-2 parts of dioctyl sulfosuccinate sodium sulfate, 1-2 parts of carboxymethylcellulose, and 1-2 parts of ortho acid benzene ester. The foamed microporous acrylic emulsion has the advantages of being available in raw material, low in cost, green and environmentally friendly, convenient to use, and good in effect.
Description
Technical field
The invention belongs to a kind of tackiness agent.
Background technology
The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.Tackiness agent (Bonding agent) is one of most important subsidiary material, and in package handling, application is very extensive.Tackiness agent is the sticking material of tool, the material of two kinds of separation can be linked together by its viscosity.The kind of tackiness agent is a lot.1. natural glue it be taken from the material of occurring in nature.Comprise the biological adhesives such as starch, protein, dextrin, gelatin, shellac, hide glue, rosin; Also comprise the mineral binders such as pitch.2. artificial tackiness agent this be to use made material, comprise the inorganic adhesives such as water glass, and the organic binder bond such as synthetic resins, synthetic rubber.Service performance divides 1. Watersoluble Adhesive to use water as the tackiness agent of solvent, mainly contains starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose etc.2. Hotmelt Adhesive makes to use after adhesive melts by heating, is a kind of solid binder.General thermoplastic resin all can use, as urethane, polystyrene, polyacrylic ester, ethene-acetate ethylene copolymer etc.3. Solvent Adhesive is water insoluble and be dissolved in the tackiness agent of certain solvent.As shellac, isoprene-isobutylene rubber etc.4. Emulsion Adhesive is many is suspension in water, as vinyl acetate resin, acrylic resin, chlorinated rubber etc.5. solvent-free liquid adhesive is thick liquid nano at normal temperatures, as epoxy resin etc.Tackiness agent is the medium between label material and bonding substrates, plays link effect.Can be divided into two kinds of permanent and removable property by its characteristic.It has multiple formulations, is applicable to different plane materiels and different occasions.Tackiness agent is the most important composition in adhesive material technology, is the key of tag application technology.The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.
Through Chinese publication retrieval, do not find the scheme identical with present patent application.
Summary of the invention:
The object of the invention is to; A kind of foaming micropore ACRYLIC EMULSION is proposed.
Foaming micropore ACRYLIC EMULSION of the present invention, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 125-150 part, Propylene glycol monoacrylate 16-20 part, ethyl propenoate 360-400 part, vinylformic acid 19-25 part, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester.
Foaming micropore ACRYLIC EMULSION preparation method of the present invention, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 125-150 part, Propylene glycol monoacrylate 16-20 part, ethyl propenoate 360-400 part, vinylformic acid 19-25 part, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Product of the present invention, can adapt to the use of various occasions, and bond strength reaches the more than 2 times of prior art.
The present invention compared with prior art its beneficial effect is: have raw material and be easy to get, work simplification, is easy to manufacture the advantage such as cost is low, and environmental protection is easy to use, and materials are more economized, effective.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited to this.
Product of the present invention is raw materials used buys acquisition.
Embodiment 1
Foaming micropore ACRYLIC EMULSION preparation method of the present invention, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 125-150 part, Propylene glycol monoacrylate 16-20 part, ethyl propenoate 360-400 part, vinylformic acid 19-25 part, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 2
Foaming micropore ACRYLIC EMULSION preparation method of the present invention, it is characterized in that: it is filled a prescription by weight, by 125 parts of methyl acrylates, 16 parts of Propylene glycol monoacrylates, 360 parts of ethyl propenoates, 19 parts, vinylformic acid, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 3
Foaming micropore ACRYLIC EMULSION preparation method of the present invention, it is characterized in that: it is filled a prescription by weight, by 150 parts of methyl acrylates, 20 parts of Propylene glycol monoacrylates, 400 parts of ethyl propenoates, 25 parts, vinylformic acid, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 4
Foaming micropore ACRYLIC EMULSION preparation method of the present invention, it is characterized in that: it is filled a prescription by weight, by 125 parts of methyl acrylates, 20 parts of Propylene glycol monoacrylates, 360 parts of ethyl propenoates, 25 parts, vinylformic acid, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 5
Foaming micropore ACRYLIC EMULSION preparation method of the present invention, it is characterized in that: it is filled a prescription by weight, by 150 parts of methyl acrylates, 16 parts of Propylene glycol monoacrylates, 400 parts of ethyl propenoates, 19 parts, vinylformic acid, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Product specification of the present invention, quality: solid content is more than 80%, and its 1% solution pH value is 7.0-7.5; Viscosity 110-120 centipoise.
Claims (2)
1. a foaming micropore ACRYLIC EMULSION, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 125-150 part, Propylene glycol monoacrylate 16-20 part, ethyl propenoate 360-400 part, vinylformic acid 19-25 part, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester.
2. a foaming micropore ACRYLIC EMULSION preparation method, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 125-150 part, Propylene glycol monoacrylate 16-20 part, ethyl propenoate 360-400 part, vinylformic acid 19-25 part, 1～2 part of octadecylamine acetate, 2～5 parts of citric acids, 10～15 parts, calcium carbonate, 1～2 part of octyl group trimethyl ammonium chloride, 1～2 part of methyl sodiosul foaliphatate, 1～2 part of benzyl naphthalene sodium sulfonate; 1～2 part, dioctyl succinate sodium sulfate, 1～2 part of carboxymethyl cellulose, 1～2 part of composition of adjacent sour front three phenyl ester; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104366.3A CN103881627B (en) | 2014-03-20 | 2014-03-20 | Foaming microporous acrylic emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104366.3A CN103881627B (en) | 2014-03-20 | 2014-03-20 | Foaming microporous acrylic emulsion |
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| Publication Number | Publication Date |
|---|---|
| CN103881627A true CN103881627A (en) | 2014-06-25 |
| CN103881627B CN103881627B (en) | 2016-08-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410104366.3A Active CN103881627B (en) | 2014-03-20 | 2014-03-20 | Foaming microporous acrylic emulsion |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008088115A1 (en) * | 2007-01-18 | 2008-07-24 | Lg Chem, Ltd. | Acrylic pressure sensitive adhesive compositions |
| CN102260478A (en) * | 2010-12-14 | 2011-11-30 | 上海凯鑫森产业投资控股有限公司 | Pressure-sensitive adhesive for PET protective film and preparation method thereof |
| CN103172797A (en) * | 2013-03-13 | 2013-06-26 | 华南师范大学 | Polyacrylate/polyester resin prepolymer in interpenetration network structure, method for preparing same and powdery coating with same |
-
2014
- 2014-03-20 CN CN201410104366.3A patent/CN103881627B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008088115A1 (en) * | 2007-01-18 | 2008-07-24 | Lg Chem, Ltd. | Acrylic pressure sensitive adhesive compositions |
| CN102260478A (en) * | 2010-12-14 | 2011-11-30 | 上海凯鑫森产业投资控股有限公司 | Pressure-sensitive adhesive for PET protective film and preparation method thereof |
| CN103172797A (en) * | 2013-03-13 | 2013-06-26 | 华南师范大学 | Polyacrylate/polyester resin prepolymer in interpenetration network structure, method for preparing same and powdery coating with same |
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| Publication number | Publication date |
|---|---|
| CN103881627B (en) | 2016-08-17 |
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Effective date of registration: 20190430 Address after: 510000 Room 710, 282 Zhongshan Avenue Middle Road, Tianhe District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Xinri Chemical Technology Co.,Ltd. Address before: 542800 No. 13 Garden Street, eight step area, Hezhou, the Guangxi Zhuang Autonomous Region Patentee before: Yang Yi |
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Effective date of registration: 20230420 Address after: 512400 Pearl Industrial Park, Nanxiong, Shaoguan, Guangdong Patentee after: Nanxiong Qiyuanda New Material Co.,Ltd. Address before: 510000 Room 710, 282 Zhongshan Avenue Middle Road, Tianhe District, Guangzhou City, Guangdong Province Patentee before: Guangzhou Xinri Chemical Technology Co.,Ltd. |