CN105315933A - Anti-stripping cyanoacrylate adhesive and preparation method thereof - Google Patents
Anti-stripping cyanoacrylate adhesive and preparation method thereof Download PDFInfo
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- CN105315933A CN105315933A CN201510822329.0A CN201510822329A CN105315933A CN 105315933 A CN105315933 A CN 105315933A CN 201510822329 A CN201510822329 A CN 201510822329A CN 105315933 A CN105315933 A CN 105315933A
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- parts
- antistripping
- coupling agent
- titanium oxide
- drying adhesive
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- FGBJXOREULPLGL-UHFFFAOYSA-N ethyl cyanoacrylate Chemical compound CCOC(=O)C(=C)C#N FGBJXOREULPLGL-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000004830 Super Glue Substances 0.000 title abstract 5
- 239000007822 coupling agent Substances 0.000 claims abstract description 24
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 108010010803 Gelatin Proteins 0.000 claims abstract description 19
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920000159 gelatin Polymers 0.000 claims abstract description 19
- 239000008273 gelatin Substances 0.000 claims abstract description 19
- 235000019322 gelatine Nutrition 0.000 claims abstract description 19
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 19
- 229960000380 propiolactone Drugs 0.000 claims abstract description 19
- 239000004819 Drying adhesive Substances 0.000 claims description 33
- 150000002148 esters Chemical class 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 101000969770 Homo sapiens Myelin protein zero-like protein 2 Proteins 0.000 claims description 13
- 102100021272 Myelin protein zero-like protein 2 Human genes 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 8
- 239000012943 hotmelt Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 238000001291 vacuum drying Methods 0.000 claims description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 abstract 1
- 229920000926 Galactomannan Polymers 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000004513 sizing Methods 0.000 description 5
- 239000003292 glue Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 241000707825 Argyrosomus regius Species 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004826 Synthetic adhesive Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Abstract
The invention discloses an anti-stripping cyanoacrylate adhesive. The anti-stripping cyanoacrylate adhesive is prepared from, by weight, 30-50 parts of alpha-ethyl cyanoacrylate, 0.5-4 parts of EVA, 2-5 parts of beta-propiolactone, 0.5-1 part of modified titanium oxide, 8-12 parts of gelatin, 5-10 parts of polyacrylate, 2-8 parts of galactomannan, 3-8 parts of hydroxyethyl cellulose and 1-1.5 parts of coupling agent. The invention further discloses a preparation method of the anti-stripping cyanoacrylate adhesive. The anti-stripping cyanoacrylate adhesive is high in curing speed, good in water resistance, high in impact resistance, large in bonding strength, good in anti-stripping performance, small in use amount, free of toxicity and beneficial to environmental protection.
Description
Technical field:
The present invention relates to sizing agent technical field, be specifically related to a kind of antistripping instant drying adhesive.
Background technology:
Instant drying adhesive, namely moment then uses glue fast, is based on ethyl α-cyanoacrylate, adds tackifier.Thickening material, stablizer, toughner, stopper etc., the single-component fast setting sizing agent synthesized by vanguard technology; It is a kind of high strength, fast tackiness agent, and the high short-term training that can be used in multiple types material proceeds with one's work, and is particularly suitable for being used in woodenware industry; For fitting tightly, porous material, such as rubber-metal, plastic cement, woodenware etc. can reach the strongest then effect; This glue is a single composition, solvent-free, do not need the tackiness agent adding catalyst, heating or pressurization, only need meagre one deck glue, it just can utilize the atmospheric moisture in air to produce high polymeric, reach best and amplexiform effect, have natural glue and synthetic adhesive point, also can be divided into Organic adhesive and inorganic sizing agent.Alpha-cyanoacrylate ester gum is single component, low viscosity, transparent, normal temperature fast setting sizing agent.Having good viscosifying power to most material, is one of important room temperature setting adhesives kind.But it also exists some shortcomings, curing speed is too fast, makes its shock-resistance, peeling resistance poor.
Chinese patent (201010511081.3) discloses a kind of Novel epoxy reins adhesive, comprise epoxy resin, dibutyl phthalate, silicon powder, epoxy compounds and coupling agent, this sizing agent good heat resistance, excellent shock resistance, Joint strength is high, and the rear antistripping of solidification, splitting resistance are good.But its viscosity is comparatively large, and usage quantity is large.
Summary of the invention:
The object of this invention is to provide a kind of antistripping instant drying adhesive, its curing speed is fast, water-tolerant, and impact resistance is strong, and bonding strength is large, and peeling resistance is good, and usage quantity is few, nontoxic, is conducive to environment protection.
Another object of the present invention is to provide the preparation method of this antistripping instant drying adhesive.
For achieving the above object, the present invention is by the following technical solutions:
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 30-50 part,
EVA0.5-4 part, beta-propiolactone 2-5 part,
Modified titanium oxide 0.5-1 part, gelatin 8-12 part,
Polyacrylic ester 5-10 part, polygalactomannan 2-8 part,
Natvosol 3-8 part, coupling agent 1-1.5 part.
Preferred as technique scheme, a kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 50 parts,
EVA1 part, beta-propiolactone 3 parts,
Modified titanium oxide 0.7 part, 9 parts, gelatin,
Polyacrylic ester 8 parts, polygalactomannan 5 parts,
Natvosol 6 parts, coupling agent 1.1 parts.
Preferred as technique scheme, in described EVA, the content of vinyl acetate between to for plastic is 10-20%.
Preferred as technique scheme, the size of described modified titanium oxide is 10-20nm, its method of modifying is: by nano-titanium oxide and dehydrated alcohol mixing and stirring, add oleic acid, under the power of 500-1000W, ultrasonic 20-50min, filter, vacuum-drying, grinding, obtains modified titanium oxide.
Preferred as technique scheme, described coupling agent is titanate coupling agent, one or more mixing in Silane coupling agent KH550, silane coupling agent KH560.
A preparation method for antistripping instant drying adhesive, comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 100-120 DEG C, reacting by heating 1-3h, be cooled to 70-80 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1-2h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 150-180 DEG C, obtain antistripping instant drying adhesive.
The present invention has following beneficial effect:
The present invention adds modified titanium oxide and polygalactomannan in ethyl α-cyanoacrylate, and make the instant drying adhesive impact resistance that obtains good, stripper-resistance is good, and bonding strength improves greatly;
Instant drying adhesive curing speed provided by the invention is fast, and water-tolerant, low-temperature adhesion performance is good, nontoxic, is conducive to environment protection.
Embodiment:
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment, only for explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 30 parts,
EVA0.5 part, beta-propiolactone 2 parts,
Modified titanium oxide 0.5 part, 8 parts, gelatin,
Polyacrylic ester 5 parts, polygalactomannan 2 parts,
Natvosol 3 parts, coupling agent 1 part.
Its preparation method comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 100 DEG C, reacting by heating 1h, be cooled to 70 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 150 DEG C, obtain antistripping instant drying adhesive.
Embodiment 2
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 50 parts,
EVA4 part, beta-propiolactone 5 parts,
Modified titanium oxide 1 part, 12 parts, gelatin,
Polyacrylic ester 10 parts, polygalactomannan 8 parts,
Natvosol 8 parts, coupling agent 1.5 parts.
Its preparation method comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 120 DEG C, reacting by heating 3h, be cooled to 80 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 2h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 150-180 DEG C, obtain antistripping instant drying adhesive.
Embodiment 3
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 35 parts,
EVA1 part, beta-propiolactone 2.5 parts,
Modified titanium oxide 0.6 part, 9 parts, gelatin,
Polyacrylic ester 6 parts, polygalactomannan 3 parts,
Natvosol 4 parts, coupling agent 1.1 parts.
Its preparation method comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 105 DEG C, reacting by heating 1.5h, be cooled to 75 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1.2h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 155 DEG C, obtain antistripping instant drying adhesive.
Embodiment 4
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 40 parts,
EVA1.5 part, beta-propiolactone 3.5 parts,
Modified titanium oxide 0.7 part, 10 parts, gelatin,
Polyacrylic ester 7 parts, polygalactomannan 4 parts,
Natvosol 5 parts, coupling agent 1.2 parts.
Its preparation method comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 110 DEG C, reacting by heating 1.8h, be cooled to 80 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1.4h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 160 DEG C, obtain antistripping instant drying adhesive.
Embodiment 5
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 45 parts,
EVA3 part, beta-propiolactone 4.5 parts,
Modified titanium oxide 0.8 part, 10 parts, gelatin,
Polyacrylic ester 8 parts, polygalactomannan 6 parts,
Natvosol 6 parts, coupling agent 1.3 parts.
Its preparation method comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 115 DEG C, reacting by heating 1.8h, be cooled to 80 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1.6h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 165 DEG C, obtain antistripping instant drying adhesive.
Embodiment 6
A kind of antistripping instant drying adhesive, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 48 parts,
EVA3.8 part, beta-propiolactone 4.8 parts,
Modified titanium oxide 0.9 part, 11 parts, gelatin,
Polyacrylic ester 9 parts, polygalactomannan 7 parts,
Natvosol 7.5 parts, coupling agent 1.4 parts.
Its preparation method comprises the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 120 DEG C, reacting by heating 2.5h, be cooled to 80 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1.8h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 175 DEG C, obtain antistripping instant drying adhesive.
Carry out performance test to antistripping instant drying adhesive provided by the invention below, wherein comparative example is common instant drying adhesive.
Table 1
From table 1, instant drying adhesive impact resistance provided by the present invention is good, and peel strength is large, and water-tolerant.
Claims (6)
1. an antistripping instant drying adhesive, is characterized in that, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 30-50 part,
EVA0.5-4 part, beta-propiolactone 2-5 part,
Modified titanium oxide 0.5-1 part, gelatin 8-12 part,
Polyacrylic ester 5-10 part, polygalactomannan 2-8 part,
Natvosol 3-8 part, coupling agent 1-1.5 part.
2. a kind of antistripping instant drying adhesive as claimed in claim 1, is characterized in that, with parts by weight, comprises following component:
Ethyl α-cyanoacrylate 50 parts,
EVA1 part, beta-propiolactone 3 parts,
Modified titanium oxide 0.7 part, 9 parts, gelatin,
Polyacrylic ester 8 parts, polygalactomannan 5 parts,
Natvosol 6 parts, coupling agent 1.1 parts.
3. a kind of antistripping instant drying adhesive as claimed in claim 1, is characterized in that, in described EVA, the content of vinyl acetate between to for plastic is 10-20%.
4. a kind of antistripping instant drying adhesive as claimed in claim 1, it is characterized in that, the size of described modified titanium oxide is 10-20nm, and its method of modifying is: by nano-titanium oxide and dehydrated alcohol mixing and stirring, add oleic acid, under the power of 500-1000W, ultrasonic 20-50min, filters, vacuum-drying, grinding, obtains modified titanium oxide.
5. a kind of antistripping instant drying adhesive as claimed in claim 1, is characterized in that, described coupling agent is titanate coupling agent, one or more mixing in Silane coupling agent KH550, silane coupling agent KH560.
6. the preparation method of a kind of antistripping instant drying adhesive as described in as arbitrary in claim 1 to 5, is characterized in that, comprise the following steps:
(1) by ethyl α-cyanoacrylate, EVA, beta-propiolactone and polyacrylic ester mixing and stirring, at 100-120 DEG C, reacting by heating 1-3h, be cooled to 70-80 DEG C, add polygalactomannan, Natvosol and coupling agent, add hot melt reaction 1-2h, obtain mixture;
(2), in the mixture obtained to step (1), add gelatin and modified titanium oxide, underpressure distillation at 150-180 DEG C, obtain antistripping instant drying adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510822329.0A CN105315933B (en) | 2015-11-24 | 2015-11-24 | A kind of antistripping instant drying adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510822329.0A CN105315933B (en) | 2015-11-24 | 2015-11-24 | A kind of antistripping instant drying adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN105315933A true CN105315933A (en) | 2016-02-10 |
| CN105315933B CN105315933B (en) | 2017-08-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510822329.0A Expired - Fee Related CN105315933B (en) | 2015-11-24 | 2015-11-24 | A kind of antistripping instant drying adhesive and preparation method thereof |
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| Country | Link |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459846A (en) * | 2017-07-26 | 2017-12-12 | 柳州金特新型耐磨材料股份有限公司 | Antistripping wearable ceramic coat and preparation method thereof |
| CN109768123A (en) * | 2019-01-31 | 2019-05-17 | 泰州隆基乐叶光伏科技有限公司 | A kind of welding method |
| CN110591569A (en) * | 2019-09-17 | 2019-12-20 | 浙江派菲特新材料科技有限公司 | Environment-friendly low-whitening instant adhesive |
| CN114395334A (en) * | 2022-03-15 | 2022-04-26 | 宁波百仕高联合工业有限公司 | Preparation method of high-water-resistance instant adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2511355A1 (en) * | 2011-04-12 | 2012-10-17 | Henkel Ireland Ltd. | Cyanoacrylate adhesive with improved water resistance |
| CN102994022A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Instant adhesive |
| CN103666293A (en) * | 2013-12-02 | 2014-03-26 | 南通瑞普埃尔生物工程有限公司 | Heat resistance instant dry adhesive and preparation method thereof |
-
2015
- 2015-11-24 CN CN201510822329.0A patent/CN105315933B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2511355A1 (en) * | 2011-04-12 | 2012-10-17 | Henkel Ireland Ltd. | Cyanoacrylate adhesive with improved water resistance |
| CN102994022A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Instant adhesive |
| CN103666293A (en) * | 2013-12-02 | 2014-03-26 | 南通瑞普埃尔生物工程有限公司 | Heat resistance instant dry adhesive and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459846A (en) * | 2017-07-26 | 2017-12-12 | 柳州金特新型耐磨材料股份有限公司 | Antistripping wearable ceramic coat and preparation method thereof |
| CN109768123A (en) * | 2019-01-31 | 2019-05-17 | 泰州隆基乐叶光伏科技有限公司 | A kind of welding method |
| CN110591569A (en) * | 2019-09-17 | 2019-12-20 | 浙江派菲特新材料科技有限公司 | Environment-friendly low-whitening instant adhesive |
| CN114395334A (en) * | 2022-03-15 | 2022-04-26 | 宁波百仕高联合工业有限公司 | Preparation method of high-water-resistance instant adhesive |
| CN114395334B (en) * | 2022-03-15 | 2023-09-26 | 宁波百仕高联合工业有限公司 | Preparation method of high-water-resistance instant adhesive |
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| CN105315933B (en) | 2017-08-04 |
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