CN101445679A - UV-light solidifying paint having decorative effect and preparation method thereof - Google Patents
UV-light solidifying paint having decorative effect and preparation method thereof Download PDFInfo
- Publication number
- CN101445679A CN101445679A CNA2008101480250A CN200810148025A CN101445679A CN 101445679 A CN101445679 A CN 101445679A CN A2008101480250 A CNA2008101480250 A CN A2008101480250A CN 200810148025 A CN200810148025 A CN 200810148025A CN 101445679 A CN101445679 A CN 101445679A
- Authority
- CN
- China
- Prior art keywords
- decorative effect
- acrylate
- coating
- paint
- effect according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000694 effects Effects 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003973 paint Substances 0.000 title abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 20
- 239000003085 diluting agent Substances 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 5
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims description 30
- 238000000576 coating method Methods 0.000 claims description 30
- -1 polysiloxane Polymers 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 4
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 claims description 4
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 4
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 claims description 4
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 238000004528 spin coating Methods 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 229920006222 acrylic ester polymer Polymers 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 238000003618 dip coating Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims description 2
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 2
- 229940035429 isobutyl alcohol Drugs 0.000 claims description 2
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 2
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- ZDBOPWZPXDFCQY-UHFFFAOYSA-N phthalic acid 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C(C=1C(C(=O)O)=CC=CC1)(=O)O.C(C=C)(=O)OCCOC(C=C)=O ZDBOPWZPXDFCQY-UHFFFAOYSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 229940090181 propyl acetate Drugs 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 claims description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000010985 leather Substances 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002932 luster Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011050 natural pearl Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000011049 pearl Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- 239000012957 2-hydroxy-2-methyl-1-phenylpropanone Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- BDAHDQGVJHDLHQ-UHFFFAOYSA-N [2-(1-hydroxycyclohexyl)phenyl]-phenylmethanone Chemical compound C=1C=CC=C(C(=O)C=2C=CC=CC=2)C=1C1(O)CCCCC1 BDAHDQGVJHDLHQ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a UV-light solidifying paint having decorative effect and preparation method thereof, in particular to a light solidifying paint containing mica coated with metallic oxides as a paint. The paint is composed of the followings in proportions: the content of low polymer is 30-70wt%; the content of reactive diluent is 25-65wt%; the content of light trigger is 0.5-10wt%; the content of pearlescent pigment is 3-30wt%; the content of accessory ingredient is 0.2-8wt%; the content of solvent is 0-50wt%. As added pearlescent pigment has strong metallic performance, the prepared light solidifying paint has the character of strong pearl effect and also has very good water resisting property, higher rigidity and abrasive resistance. The paint can be applied to decoration on the surfaces of motor vehicles, electric appliance, furniture, articles for daily use, toys, walls, leather products, etc.
Description
Technical Field
The invention relates to an ultraviolet curing coating with decorative effect and a preparation method thereof, which is characterized in that pearlescent pigment is adopted to prepare the ultraviolet curing coating, and the ultraviolet curing coating has the characteristics of strong metal texture, higher hardness, higher wear resistance and the like.
Background
The pearlescent pigment is a pigment which is produced according to the physical and optical principles and is similar to the elegant luster and color of natural pearls, shells, butterflies, birds and metals, and is divided according to the functions of the pigment. The natural mica flake with a smooth surface and a low optical refractive index is used as an inner core and is coated with transparent titanium dioxide or iron oxide with a high refractive index to form a sandwich type wafer, and the color phase and luster are created by means of refraction and transmission of light, so that the natural mica flake creates a deep layering sense and a special pearl luster effect in a transparent medium, has the glittering effect of a metal pigment and has the soft color of natural pearls. In ideal applications, the pearlescent pigment is uniformly dispersed in the coating and is distributed in multiple layers parallel to the surface of the material, and incident light shows a pearlescent effect through multiple reflections and interference as in pearls. The pearlescent pigment can endow the paint with a special decorative effect, compared with aluminum powder, the pearlescent pigment has better storage stability in the paint, and the aluminum powder can generate a replacement reaction with water, so that the final luster of the paint is darkened and grayed. The excellent water resistance and chemical solvent resistance of the pearlescent pigment, excellent high temperature resistance, incombustibility, electric arc resistance, safety, non-toxicity and the like are the first choice of the decorative coating.
The ultraviolet curing coating has the advantages of high curing speed, energy conservation and environmental protection, and generally comprises an oligomer, an active diluent, a photoinitiator and other additives, wherein under the irradiation of ultraviolet light, the photoinitiator firstly absorbs the ultraviolet light and decomposes the ultraviolet light into active free radicals, and then the oligomer and the active diluent are initiated to carry out chain polymerization reaction to finally form a cross-linked cured coating. The ultraviolet curing equipment has high utilization rate, is suitable for flow line production, saves the space of a field and has high production efficiency.
Disclosure of Invention
The invention aims to provide an ultraviolet curing coating with a decorative effect and a preparation method thereof. Wherein, the pearlescent pigment in the paint has the characteristics of adjustable pearlescent effect, stable physicochemical property and the like. Meanwhile, the ultraviolet curing technology is adopted, so that the problems of large environmental hazard, high energy consumption, poor storage stability of the coating and the like in the prior art are solved, and the prepared coating has strong metal texture, higher hardness and wear resistance.
The technical scheme of the invention is as follows: the ultraviolet curing coating with decorative effect and the preparation method thereof are characterized in that the coating comprises the following components in percentage by weight:
oligomer … … … … … … … … … … … … … … … … … … … … … … … … … 30-70 wt%
Reactive diluent … … … … … … … … … … … … … … … … … … … … … … … 25-65 wt%
Photoinitiator … … … … … … … … … … … … … … … … … … … … … … … … 0.5.5-10 wt%
Pearlescent pigment … … … … … … … … … … … … … … … … … … … … … … … … 3-30 wt%
0.2 to 8 weight percent of auxiliary agent … … … … … … … … … … … … … … … … … … … … … … … … … … 0.2
Solvent … … … … … … … … … … … … … … … … … … … … … … … … … … 0-50 wt%
Wherein,
the oligomer can be selected from at least one of epoxy acrylate, polyurethane acrylate, polyester acrylate, polyether acrylate, acrylated polyacrylate or vinyl resin.
The active diluent is at least one of hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate (HEMA), N-vinyl pyrrolidone (NVP), dipropylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA), neopentyl glycol diacrylate (NPGDA), 1, 6-hexanediol diacrylate (HDDA), 1, 4-butanediol diacrylate (BDDA), phthalic acid ethylene glycol diacrylate (PDDA), trimethylolpropane triacrylate (TMPTA), pentaerythritol tetraacrylate (PETTA), dipentaerythritol pentaacrylate (DPPA), dipentaerythritol hexaacrylate (DPHA), alkoxylated acrylate, vinyl ether active diluent and methoxylated acrylate active diluent.
The photoinitiator is at least one of alpha, alpha' -dimethylbenzyl ketal, alpha-hydroxy ketone derivatives, alpha-amidoketone derivatives, acyl phosphine oxide, benzophenone + active amine and benzophenone.
The pearlescent pigment is one or more layers of mica powder coated by metal oxide, wherein: the metal oxide is at least one of titanium dioxide, ferric oxide, silicon dioxide, tin dioxide and cerium oxide, and the particle size of the metal oxide is 1-500 nm.
The auxiliary agent is at least one of a flatting agent, a defoaming agent and a wetting dispersant. Wherein the leveling agent may be selected from: polydimethyl siloxane, fluorine-containing compound, modified polysiloxane, polyether-polysiloxane copolymer, (methyl) acrylic ester polymer, fluorine modified acrylic ester or their mixture; the defoaming agent may be selected from: a silicone-free polymer solution, polydimethylsiloxane, organomodified polysiloxane, a polymer solution with siloxane end groups, or mixtures thereof; the wetting and dispersing agent may be selected from: electrically neutral polyamide and polyester mixtures, carboxyl-bearing polymer solutions, polyacrylate, polyurethane compounds or mixtures thereof.
The solvent can be at least one selected from ethyl acetate, propyl acetate, butyl acetate, isobutyl acetate, methyl ethyl ketone, ethanol, propanol, isobutyl alcohol, dicarboxylic ester, toluene, xylene, acetone, n-butanol, cyclohexanone, ethylene glycol butyl ether and propylene glycol butyl ether.
The preparation method of the ultraviolet curing coating is characterized by comprising the following steps:
(1) mixing the oligomer, the reactive diluent and the photoinitiator according to the proportion, and stirring uniformly at a certain temperature;
(2) adding pearlescent pigment into the components obtained in the step (1), adding a proper amount of wetting dispersant, flatting agent, defoaming agent or solvent according to the requirement, and stirring and mixing uniformly to obtain slurry;
(3) spraying, spin coating, dip coating or roll coating the slurry on the surface of a substrate, standing for a period of time, irradiating the coated surface with ultraviolet light, and curing to form a film.
When the ultraviolet curing coating with the decorative effect is prepared, the process is simple and convenient, only the required raw materials are mixed according to a certain proportion and are uniformly stirred, the requirement on equipment is not high, the ultraviolet curing coating is suitable for flow line production, the production efficiency is high, and the production cost is reduced. The paint prepared by the invention can be used for decorating the surfaces of automobiles, electrical appliances, furniture, daily necessities, toys, walls, leather products and the like.
Detailed Description
An ultraviolet curing coating with decorative effect and a preparation method thereof are disclosed as examples:
epoxy acrylate (CNUVE150/80, Saedoma) … … … … … … … … … … … 30g
… … … … … … … … … … 25g of aliphatic urethane acrylate (CN965, Saedoma Co., Ltd.)
… … … … … … … … … … 25g of 1, 6-hexanediol diacrylate (SR238, Saedoma Co., Ltd.)
High-purity trimethylolpropane triacrylate (SR351HP, Saedoma) … … … … … 20g
2-hydroxy-2-methyl-1-phenylpropanone (Darocur1173, Ciba Switzerland) … … … … 3g
… … … … … … … 2g of 1-hydroxycyclohexyl benzophenone (Irgacure184, Ciba Switzerland)
Pearlescent pigment (Iriododin)
/Afflair100s, Merck, Germany) … … … … … … … 15g
Leveling agent (Levelo1837, Germany modest) … … … … … … … … … … … … … … … … 0.5.5 g
Antifoaming agent (Defom2700, Germany Co., Ltd.) … … … … … … … … … … … … … … … … 0.3.3 g
Wetting and dispersing agent (Disponer912, Germany modest Co.) … … … … … … … … … … … … … … … 2g
(1) Mixing 1, 6-hexanediol diacrylate serving as an active diluent, high-purity trimethylolpropane triacrylate, Darocur1173 and Irgacur184 according to the proportion, and uniformly stirring at the constant temperature of 50 ℃; (2) and (2) uniformly stirring and mixing the components obtained in the step (1), epoxy acrylate, aliphatic polyurethane acrylate, pearlescent pigment, a flatting agent, a defoaming agent and a wetting dispersant, spin-coating the mixture on a glass plate by using a spin coater, wherein the thickness of the coating is 100 mu m, standing the glass plate at room temperature for a period of time, and then putting the glass plate into a lamp box (the power density of an ultraviolet lamp is 80w/cm, and the distance from the lamp tube is 15cm) to solidify and form a film.
And (3) testing results: the prepared paint has high curing speed, and the coating has strong pearlescent effect, high hardness and wear resistance and good water resistance.
Claims (8)
- An ultraviolet curing coating with decorative effect and a preparation method thereof are characterized in that: the coating comprises the following components in percentage by weight:oligomer … … … … … … … … … … … … … … … … … … … … … … … 30-70 wt%Reactive diluent … … … … … … … … … … … … … … … … … … … … … 25-65 wt%Photoinitiator … … … … … … … … … … … … … … … … … … … … … … 0.5.5-10 wt%Pearlescent pigment … … … … … … … … … … … … … … … … … … … … … … … 3-30 wt%0.2 to 8 weight percent of auxiliary agent … … … … … … … … … … … … … … … … … … … … … … … … 0.20-50 wt% of solvent … … … … … … … … … … … … … … … … … … … … … … … … … 0.
- The ultraviolet-curable coating material with decorative effect according to claim 1, wherein: the oligomer can be selected from at least one of epoxy acrylate, polyurethane acrylate, polyester acrylate, polyether acrylate, acrylated polyacrylate or vinyl resin.
- The ultraviolet-curable coating material with decorative effect according to claim 1, wherein: the active diluent is at least one of hydroxyethyl acrylate (HEA), hydroxyethyl methacrylate (HEMA), N-vinyl pyrrolidone (NVP), dipropylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA), neopentyl glycol diacrylate (NPGDA), 1, 6-hexanediol diacrylate (HDDA), 1, 4-butanediol diacrylate (BDDA), phthalic acid ethylene glycol diacrylate (PDDA), trimethylolpropane triacrylate (TMPTA), pentaerythritol tetraacrylate (PETTA), dipentaerythritol pentaacrylate (DPPA), dipentaerythritol hexaacrylate (DPHA), alkoxylated acrylate, vinyl ether active diluent and methoxylated acrylate active diluent.
- The UV curable coating with decorative effect according to claim 1, wherein: the photoinitiator is at least one of alpha, alpha' -dimethylbenzyl ketal, alpha-hydroxy ketone derivatives, alpha-amidoketone derivatives, acyl phosphine oxide, benzophenone + active amine and benzophenone.
- The UV curable coating with decorative effect according to claim 1, wherein: the pearlescent pigment is one or more layers of mica powder coated by metal oxide, wherein: the metal oxide is at least one of titanium dioxide, ferric oxide, silicon dioxide, tin dioxide and cerium oxide, and the particle size of the metal oxide is 1-500 nm.
- The UV curable coating with decorative effect according to claim 1, wherein: the auxiliary agent is at least one of a flatting agent, a defoaming agent and a wetting dispersant.Wherein,the leveling agent may be selected from: polydimethyl siloxane, fluorine-containing compound, modified polysiloxane, polyether-polysiloxane copolymer, (methyl) acrylic ester polymer, fluorine modified acrylic ester or their mixture;the defoaming agent may be selected from: a silicone-free polymer solution, polydimethylsiloxane, organomodified polysiloxane, a polymer solution with siloxane end groups, or mixtures thereof;the wetting and dispersing agent may be selected from: electrically neutral polyamide and polyester mixtures, carboxyl-bearing polymer solutions, polyacrylate, polyurethane compounds or mixtures thereof.
- The ultraviolet-curable coating material with decorative effect according to claim 1, wherein: the solvent can be at least one selected from ethyl acetate, propyl acetate, butyl acetate, isobutyl acetate, methyl ethyl ketone, ethanol, propanol, isobutyl alcohol, dicarboxylic ester, toluene, xylene, acetone, n-butanol, cyclohexanone, ethylene glycol butyl ether and propylene glycol butyl ether.
- The method for preparing the ultraviolet curing coating with decorative effect according to claim 1, wherein the method comprises the following steps:(1) mixing the oligomer, the reactive diluent and the photoinitiator according to the proportion, and stirring uniformly at a certain temperature;(2) adding pearlescent pigment into the components obtained in the step (1), adding a proper amount of wetting dispersant, flatting agent, defoaming agent or solvent according to the requirement, and stirring and mixing uniformly to obtain slurry;(3) spraying, spin coating, dip coating or roll coating the slurry on the surface of a substrate, standing for a period of time, irradiating the coated surface with ultraviolet light, and curing to form a film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101480250A CN101445679A (en) | 2008-12-25 | 2008-12-25 | UV-light solidifying paint having decorative effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101480250A CN101445679A (en) | 2008-12-25 | 2008-12-25 | UV-light solidifying paint having decorative effect and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101445679A true CN101445679A (en) | 2009-06-03 |
Family
ID=40741569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101480250A Pending CN101445679A (en) | 2008-12-25 | 2008-12-25 | UV-light solidifying paint having decorative effect and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101445679A (en) |
Cited By (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974284A (en) * | 2010-11-19 | 2011-02-16 | 深圳市深赛尔实业有限公司 | Ultraviolet-curable coating for front lights and preparation method |
| CN102051116A (en) * | 2011-01-18 | 2011-05-11 | 惠州市长润发涂料有限公司 | Ultraviolet-cured furniture colored paint and preparation method thereof |
| CN102070979A (en) * | 2010-12-17 | 2011-05-25 | 惠州市长润发涂料有限公司 | Vacuum ultraviolet curing coating for reflective lamp shade of automobile |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102212311A (en) * | 2011-05-09 | 2011-10-12 | 中国工程物理研究院化工材料研究所 | Colorful ultraviolet (UV) light solidifying paint |
| CN102250508A (en) * | 2011-01-19 | 2011-11-23 | 一可油墨涂料（深圳）有限公司 | Ultraviolet curing pad printing ink |
| CN102321437A (en) * | 2011-07-25 | 2012-01-18 | 珠海保税区天然宝杰数码科技材料有限公司 | Novel UV (ultraviolet)-curable decoration adhesive |
| CN102477245A (en) * | 2010-11-26 | 2012-05-30 | 湖南晟通科技集团有限公司 | Ultraviolet light curing anticorrosion paint and its preparation method |
| CN102504691A (en) * | 2011-10-29 | 2012-06-20 | 江阴市天邦涂料化工有限公司 | Special UV (Ultraviolet) fast curing coating for petroleum pipe and preparation method and construction method thereof |
| CN102516837A (en) * | 2011-12-19 | 2012-06-27 | 成都展辰化工有限公司 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
| CN103013301A (en) * | 2012-12-21 | 2013-04-03 | 无锡卡秀堡辉涂料有限公司 | Solvent type ultraviolet photocureable coating capable of shielding Wi-Fi signals and production method of photocureable coating |
| CN103242690A (en) * | 2013-05-08 | 2013-08-14 | 福州皇家地坪有限公司 | Ultraviolet quick-drying protective agent and application thereof |
| CN103709931A (en) * | 2013-12-25 | 2014-04-09 | 无锡卡秀堡辉涂料有限公司 | Coating applied to chrome carbide PVD (Physical Vapor Deposition) technology and preparation method thereof |
| CN103788844A (en) * | 2014-02-13 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | High-hardness wear-resistant UV (Ultraviolet)-curable coating material and preparation method thereof |
| CN104004431A (en) * | 2014-04-25 | 2014-08-27 | 安徽祈艾特电子科技有限公司 | Ultraviolet light-curable coating of switch cabinet, and preparation method thereof |
| CN104004451A (en) * | 2014-05-20 | 2014-08-27 | 江苏利田科技股份有限公司 | Automotive UV (Ultraviolet) light-cured camouflage coating and preparation method thereof |
| CN104017471A (en) * | 2014-06-11 | 2014-09-03 | 无锡卡秀堡辉涂料有限公司 | Stainless steel PVD (Physical Vapor Deposition) hardening coating and production method thereof |
| CN104152008A (en) * | 2014-08-22 | 2014-11-19 | 广西防城港美好涂料有限公司 | Antifouling and anti-damage inner wall coating and coating method thereof |
| CN104212310A (en) * | 2014-09-19 | 2014-12-17 | 苏州云舒新材料科技有限公司 | Protective coating for plastic material and preparation method of protective coating |
| CN104231685A (en) * | 2013-06-09 | 2014-12-24 | 展辰涂料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN104293126A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | Environment-friendly noctilucent ultraviolet-curing coating for metal building material |
| CN104293179A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | Ultraviolet light cured water paint with high weather resistance |
| CN104327217A (en) * | 2014-08-20 | 2015-02-04 | 昆山博益鑫成高分子材料有限公司 | Ultraviolet light cured non-silicon release agent and preparation method thereof |
| CN104497849A (en) * | 2015-01-07 | 2015-04-08 | 东周化学工业（昆山）有限公司 | Ultraviolet curing non-slip elastic floor paint and method |
| CN104629614A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-water-resistance ultraviolet-curing wood paint |
| CN104673064A (en) * | 2015-03-25 | 2015-06-03 | 东来涂料技术（上海）有限公司 | Single-coated UV light cured color effect paint applied to plastic substrates and preparation |
| CN104830129A (en) * | 2015-05-26 | 2015-08-12 | 李亮军 | Coating composition |
| CN104830241A (en) * | 2015-05-26 | 2015-08-12 | 李亮军 | High-strength binder composition |
| CN104927588A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Wear-resistant UV curing coating |
| CN104927626A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Ultraviolet curing coating for outer walls |
| CN104946092A (en) * | 2015-05-31 | 2015-09-30 | 湖南省金海科技有限公司 | Mute cork composite floor ultraviolet light solidification coating system |
| CN105030567A (en) * | 2015-07-31 | 2015-11-11 | 上海维凯光电新材料有限公司 | Environment-friendly UV nail polish coating composition and preparing method thereof |
| CN105331154A (en) * | 2015-11-20 | 2016-02-17 | 湖南邦弗特新材料技术有限公司 | High-weather-resistant UV (ultraviolet) coating for decorative plate and preparation method of high-weather-resistant UV coating |
| CN105400254A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Weather-proof polyester powder coating and preparation method thereof |
| CN105505136A (en) * | 2016-01-05 | 2016-04-20 | 王景泉 | UV coating prepared from cyclic carbonate synthesized polyurethane |
| CN105694635A (en) * | 2016-04-27 | 2016-06-22 | 柳州申通汽车科技有限公司 | Automobile coating and processing technology thereof |
| CN105694564A (en) * | 2016-04-27 | 2016-06-22 | 柳州申通汽车科技有限公司 | Automobile paint and processing technology thereof |
| CN105694697A (en) * | 2016-04-27 | 2016-06-22 | 柳州申通汽车科技有限公司 | Waterborne automobile nano paint and processing technology thereof |
| CN105778584A (en) * | 2016-04-27 | 2016-07-20 | 柳州申通汽车科技有限公司 | Automobile nanometer paint and preparation method thereof |
| CN105969161A (en) * | 2016-05-19 | 2016-09-28 | 深圳市嘉卓成科技发展有限公司 | High-water-resistance quick-photocuring pearlescent water-based UV paint, and preparation method and application method thereof |
| CN105985709A (en) * | 2015-02-27 | 2016-10-05 | 湖南邦弗特新材料技术有限公司 | UV forward-reverse roller-painting highlight clear surface for decorative sheet and preparation method of clear surface |
| CN106047094A (en) * | 2016-07-21 | 2016-10-26 | 苏州泰仑电子材料有限公司 | UV (Ultraviolet) cured protective film capable of reducing final viscosity and preparation method thereof |
| CN106189866A (en) * | 2016-08-10 | 2016-12-07 | 太仓市美航涂料有限公司 | The preparation method that a kind of leather purple light is coating material solidified |
| CN106221466A (en) * | 2016-08-10 | 2016-12-14 | 太仓市美航涂料有限公司 | A kind of leather purple light is coating material solidified |
| CN106279737A (en) * | 2016-08-12 | 2017-01-04 | 苏州柯创电子材料有限公司 | A kind of PET protection film with excellent anti-scratch performance |
| CN106318190A (en) * | 2016-08-23 | 2017-01-11 | 佛山阳光逸采涂料科技有限公司 | UV LED low-energy curing wooden door coating and preparation method thereof |
| CN106318137A (en) * | 2016-08-23 | 2017-01-11 | 佛山阳光逸采涂料科技有限公司 | UV LED low-energy curing cabinet coating and preparation method thereof |
| CN106634556A (en) * | 2017-01-17 | 2017-05-10 | 中山市鑫峰光固化材料有限公司 | Novel ultraviolet-curable coating and preparation and use methods thereof |
| CN106752522A (en) * | 2016-12-16 | 2017-05-31 | 武强嘉华乐器有限公司 | UV paints, the preparation method that UV draws and UV draws |
| CN106318191B (en) * | 2016-08-23 | 2018-08-07 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED low energy solidification ornament materials coating and preparation method thereof |
| CN108997925A (en) * | 2018-09-18 | 2018-12-14 | 芜湖春风新材料有限公司 | A kind of coloured dual cure UV coating of automotive upholstery |
| CN109161315A (en) * | 2018-08-07 | 2019-01-08 | 太仓佩琦涂料有限公司 | UV curing pearl coating and preparation method thereof |
| CN110698113A (en) * | 2019-10-30 | 2020-01-17 | 上海理迪道具有限公司 | Rock-imitating decorative wall and manufacturing method thereof |
| CN110936459A (en) * | 2019-12-20 | 2020-03-31 | 福州立雅家具有限公司 | Furniture antique finishing process |
| CN111117279A (en) * | 2019-12-17 | 2020-05-08 | 天津市浩迪橡塑科技有限公司 | Wear-resistant flame-retardant lightweight automobile interior trim skin material and preparation method thereof |
| CN113425055A (en) * | 2021-08-17 | 2021-09-24 | 广东海洋大学 | Method for keeping luster and color of pearl |
| CN114716906A (en) * | 2022-05-24 | 2022-07-08 | 东莞市达源塑胶科技有限公司 | Anti-oiling coating and preparation method thereof |
| CN115651505A (en) * | 2022-10-24 | 2023-01-31 | 深圳新红进科技有限公司 | High-gloss composite coating and preparation method thereof |
-
2008
- 2008-12-25 CN CNA2008101480250A patent/CN101445679A/en active Pending
Cited By (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974284A (en) * | 2010-11-19 | 2011-02-16 | 深圳市深赛尔实业有限公司 | Ultraviolet-curable coating for front lights and preparation method |
| CN101974284B (en) * | 2010-11-19 | 2014-04-02 | 深圳市深赛尔股份有限公司 | Ultraviolet-curable coating for front lights and preparation method |
| CN102477245A (en) * | 2010-11-26 | 2012-05-30 | 湖南晟通科技集团有限公司 | Ultraviolet light curing anticorrosion paint and its preparation method |
| CN102070979A (en) * | 2010-12-17 | 2011-05-25 | 惠州市长润发涂料有限公司 | Vacuum ultraviolet curing coating for reflective lamp shade of automobile |
| CN102070979B (en) * | 2010-12-17 | 2012-09-05 | 惠州市长润发涂料有限公司 | Vacuum ultraviolet curing coating for reflective lamp shade of automobile |
| CN102051116A (en) * | 2011-01-18 | 2011-05-11 | 惠州市长润发涂料有限公司 | Ultraviolet-cured furniture colored paint and preparation method thereof |
| CN102051116B (en) * | 2011-01-18 | 2012-09-05 | 惠州市长润发涂料有限公司 | Ultraviolet-cured furniture colored paint and preparation method thereof |
| CN102250508B (en) * | 2011-01-19 | 2014-02-26 | 深圳市美丽华油墨涂料有限公司 | Ultraviolet curing pad printing ink |
| CN102250508A (en) * | 2011-01-19 | 2011-11-23 | 一可油墨涂料（深圳）有限公司 | Ultraviolet curing pad printing ink |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102153899B (en) * | 2011-01-28 | 2014-07-23 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102212311A (en) * | 2011-05-09 | 2011-10-12 | 中国工程物理研究院化工材料研究所 | Colorful ultraviolet (UV) light solidifying paint |
| CN102321437A (en) * | 2011-07-25 | 2012-01-18 | 珠海保税区天然宝杰数码科技材料有限公司 | Novel UV (ultraviolet)-curable decoration adhesive |
| CN102504691A (en) * | 2011-10-29 | 2012-06-20 | 江阴市天邦涂料化工有限公司 | Special UV (Ultraviolet) fast curing coating for petroleum pipe and preparation method and construction method thereof |
| CN102516837A (en) * | 2011-12-19 | 2012-06-27 | 成都展辰化工有限公司 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
| CN103013301A (en) * | 2012-12-21 | 2013-04-03 | 无锡卡秀堡辉涂料有限公司 | Solvent type ultraviolet photocureable coating capable of shielding Wi-Fi signals and production method of photocureable coating |
| CN103013301B (en) * | 2012-12-21 | 2015-02-25 | 无锡卡秀堡辉涂料有限公司 | Solvent type ultraviolet photocureable coating capable of shielding Wi-Fi signals and production method of photocureable coating |
| CN103242690A (en) * | 2013-05-08 | 2013-08-14 | 福州皇家地坪有限公司 | Ultraviolet quick-drying protective agent and application thereof |
| CN103242690B (en) * | 2013-05-08 | 2015-10-28 | 福州皇家地坪有限公司 | A kind of ultraviolet quick-drying protective agent and application thereof |
| CN104231685B (en) * | 2013-06-09 | 2017-02-08 | 展辰新材料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN104231685A (en) * | 2013-06-09 | 2014-12-24 | 展辰涂料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN103709931A (en) * | 2013-12-25 | 2014-04-09 | 无锡卡秀堡辉涂料有限公司 | Coating applied to chrome carbide PVD (Physical Vapor Deposition) technology and preparation method thereof |
| CN103709931B (en) * | 2013-12-25 | 2016-08-17 | 无锡卡秀堡辉涂料有限公司 | A kind of coating being applied to chromium carbide PVD and preparation method thereof |
| CN103788844A (en) * | 2014-02-13 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | High-hardness wear-resistant UV (Ultraviolet)-curable coating material and preparation method thereof |
| CN104004431A (en) * | 2014-04-25 | 2014-08-27 | 安徽祈艾特电子科技有限公司 | Ultraviolet light-curable coating of switch cabinet, and preparation method thereof |
| CN104004451B (en) * | 2014-05-20 | 2017-01-18 | 江苏利田科技股份有限公司 | Automotive UV (Ultraviolet) light-cured camouflage coating and preparation method thereof |
| CN104004451A (en) * | 2014-05-20 | 2014-08-27 | 江苏利田科技股份有限公司 | Automotive UV (Ultraviolet) light-cured camouflage coating and preparation method thereof |
| CN104017471A (en) * | 2014-06-11 | 2014-09-03 | 无锡卡秀堡辉涂料有限公司 | Stainless steel PVD (Physical Vapor Deposition) hardening coating and production method thereof |
| CN104327217A (en) * | 2014-08-20 | 2015-02-04 | 昆山博益鑫成高分子材料有限公司 | Ultraviolet light cured non-silicon release agent and preparation method thereof |
| CN104327217B (en) * | 2014-08-20 | 2017-05-31 | 昆山博益鑫成高分子材料有限公司 | A kind of ultraviolet light polymerization non-silicon mould release and preparation method thereof |
| CN104152008A (en) * | 2014-08-22 | 2014-11-19 | 广西防城港美好涂料有限公司 | Antifouling and anti-damage inner wall coating and coating method thereof |
| CN104152008B (en) * | 2014-08-22 | 2016-08-24 | 广西防城港美好涂料有限公司 | The interior wall coating of a kind of antifouling antisitic defect and coating process thereof |
| CN104212310A (en) * | 2014-09-19 | 2014-12-17 | 苏州云舒新材料科技有限公司 | Protective coating for plastic material and preparation method of protective coating |
| CN104293179A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | Ultraviolet light cured water paint with high weather resistance |
| CN104293126A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | Environment-friendly noctilucent ultraviolet-curing coating for metal building material |
| CN104497849A (en) * | 2015-01-07 | 2015-04-08 | 东周化学工业（昆山）有限公司 | Ultraviolet curing non-slip elastic floor paint and method |
| CN104497849B (en) * | 2015-01-07 | 2017-05-31 | 东周化学工业（昆山）有限公司 | Ultraviolet light polymerization antiskid elastic floor paint and method |
| CN104629614A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-water-resistance ultraviolet-curing wood paint |
| CN105985709A (en) * | 2015-02-27 | 2016-10-05 | 湖南邦弗特新材料技术有限公司 | UV forward-reverse roller-painting highlight clear surface for decorative sheet and preparation method of clear surface |
| CN104673064A (en) * | 2015-03-25 | 2015-06-03 | 东来涂料技术（上海）有限公司 | Single-coated UV light cured color effect paint applied to plastic substrates and preparation |
| CN104673064B (en) * | 2015-03-25 | 2017-11-03 | 东来涂料技术（上海）有限公司 | Applied to single painting UV ultraviolet photo-curing color effects paints on plastic base material and preparation |
| CN104830241A (en) * | 2015-05-26 | 2015-08-12 | 李亮军 | High-strength binder composition |
| CN104830129A (en) * | 2015-05-26 | 2015-08-12 | 李亮军 | Coating composition |
| CN104946092A (en) * | 2015-05-31 | 2015-09-30 | 湖南省金海科技有限公司 | Mute cork composite floor ultraviolet light solidification coating system |
| CN104927626A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Ultraviolet curing coating for outer walls |
| CN104927588A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Wear-resistant UV curing coating |
| CN105030567A (en) * | 2015-07-31 | 2015-11-11 | 上海维凯光电新材料有限公司 | Environment-friendly UV nail polish coating composition and preparing method thereof |
| CN105030567B (en) * | 2015-07-31 | 2018-04-06 | 上海维凯光电新材料有限公司 | Environment-friendly type UV nail polish coating compositions and preparation method thereof |
| CN105331154A (en) * | 2015-11-20 | 2016-02-17 | 湖南邦弗特新材料技术有限公司 | High-weather-resistant UV (ultraviolet) coating for decorative plate and preparation method of high-weather-resistant UV coating |
| CN105400254B (en) * | 2015-11-27 | 2017-08-18 | 宁波双人新材料有限公司 | A kind of weatherable polyether powder coating and preparation method thereof |
| CN105400254A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Weather-proof polyester powder coating and preparation method thereof |
| CN105505136B (en) * | 2016-01-05 | 2018-04-17 | 滁州金桥德克新材料有限公司 | A kind of standby UV coating of polyurethane based on cyclic carbonate ester synthesis |
| CN105505136A (en) * | 2016-01-05 | 2016-04-20 | 王景泉 | UV coating prepared from cyclic carbonate synthesized polyurethane |
| CN105778584A (en) * | 2016-04-27 | 2016-07-20 | 柳州申通汽车科技有限公司 | Automobile nanometer paint and preparation method thereof |
| CN105694635A (en) * | 2016-04-27 | 2016-06-22 | 柳州申通汽车科技有限公司 | Automobile coating and processing technology thereof |
| CN105694564A (en) * | 2016-04-27 | 2016-06-22 | 柳州申通汽车科技有限公司 | Automobile paint and processing technology thereof |
| CN105694697A (en) * | 2016-04-27 | 2016-06-22 | 柳州申通汽车科技有限公司 | Waterborne automobile nano paint and processing technology thereof |
| CN105969161A (en) * | 2016-05-19 | 2016-09-28 | 深圳市嘉卓成科技发展有限公司 | High-water-resistance quick-photocuring pearlescent water-based UV paint, and preparation method and application method thereof |
| CN106047094B (en) * | 2016-07-21 | 2018-04-20 | 苏州泰仑电子材料有限公司 | Protective film for reducing final viscosity of UV curing types and preparation method thereof |
| CN106047094A (en) * | 2016-07-21 | 2016-10-26 | 苏州泰仑电子材料有限公司 | UV (Ultraviolet) cured protective film capable of reducing final viscosity and preparation method thereof |
| CN106189866A (en) * | 2016-08-10 | 2016-12-07 | 太仓市美航涂料有限公司 | The preparation method that a kind of leather purple light is coating material solidified |
| CN106221466A (en) * | 2016-08-10 | 2016-12-14 | 太仓市美航涂料有限公司 | A kind of leather purple light is coating material solidified |
| CN106279737A (en) * | 2016-08-12 | 2017-01-04 | 苏州柯创电子材料有限公司 | A kind of PET protection film with excellent anti-scratch performance |
| CN106318137B (en) * | 2016-08-23 | 2018-08-07 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED low energy solidification cabinet coating and preparation method thereof |
| CN106318137A (en) * | 2016-08-23 | 2017-01-11 | 佛山阳光逸采涂料科技有限公司 | UV LED low-energy curing cabinet coating and preparation method thereof |
| CN106318190A (en) * | 2016-08-23 | 2017-01-11 | 佛山阳光逸采涂料科技有限公司 | UV LED low-energy curing wooden door coating and preparation method thereof |
| CN106318190B (en) * | 2016-08-23 | 2018-07-17 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED low energy solidification timber coating and preparation method thereof |
| CN106318191B (en) * | 2016-08-23 | 2018-08-07 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED low energy solidification ornament materials coating and preparation method thereof |
| CN106752522A (en) * | 2016-12-16 | 2017-05-31 | 武强嘉华乐器有限公司 | UV paints, the preparation method that UV draws and UV draws |
| CN106634556A (en) * | 2017-01-17 | 2017-05-10 | 中山市鑫峰光固化材料有限公司 | Novel ultraviolet-curable coating and preparation and use methods thereof |
| CN109161315A (en) * | 2018-08-07 | 2019-01-08 | 太仓佩琦涂料有限公司 | UV curing pearl coating and preparation method thereof |
| CN108997925A (en) * | 2018-09-18 | 2018-12-14 | 芜湖春风新材料有限公司 | A kind of coloured dual cure UV coating of automotive upholstery |
| CN110698113A (en) * | 2019-10-30 | 2020-01-17 | 上海理迪道具有限公司 | Rock-imitating decorative wall and manufacturing method thereof |
| CN111117279A (en) * | 2019-12-17 | 2020-05-08 | 天津市浩迪橡塑科技有限公司 | Wear-resistant flame-retardant lightweight automobile interior trim skin material and preparation method thereof |
| CN110936459A (en) * | 2019-12-20 | 2020-03-31 | 福州立雅家具有限公司 | Furniture antique finishing process |
| CN113425055A (en) * | 2021-08-17 | 2021-09-24 | 广东海洋大学 | Method for keeping luster and color of pearl |
| CN113425055B (en) * | 2021-08-17 | 2023-02-07 | 广东海洋大学 | Method for keeping luster and color of pearl |
| CN114716906A (en) * | 2022-05-24 | 2022-07-08 | 东莞市达源塑胶科技有限公司 | Anti-oiling coating and preparation method thereof |
| CN115651505A (en) * | 2022-10-24 | 2023-01-31 | 深圳新红进科技有限公司 | High-gloss composite coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101445679A (en) | UV-light solidifying paint having decorative effect and preparation method thereof | |
| CN101407651B (en) | UV curing color decorative coating | |
| CN101423675A (en) | Ultraviolet curing coating for preventing static on plastic surface and method for preparing the same | |
| CN103555193B (en) | A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof | |
| CN103374259A (en) | Active energy ray-curable ink composition, inkjet recording method, decorative sheet, decorative sheet molded product, method for producing in-mold molded product, and in-mold molded product | |
| CN105440933B (en) | Electron beam curable coatings | |
| CN103450744A (en) | Actinic radiation-curing type ink composition, inkjet recording method, decorative sheet, decorative sheet molded product, process for producing in-mold molded article, and in-mold molded article | |
| CN101454351B (en) | Metal oxide composition, cured film and laminate | |
| CN103224722B (en) | Ultraviolet light polymerization fluorine carbon solar cell backside protecting film coating | |
| CN103602224B (en) | A kind of white solvent-free finish paint and its preparation method and construction technology | |
| JP5658869B2 (en) | Hard coat composition and molded article with hard coat layer formed | |
| CN104387945A (en) | Odorless staining-resistant anti-yellowing UV coated matt finish paint coating, and preparation method and construction technology thereof | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN102585157B (en) | Ultraviolet light polymerization polyfunctionality polyurethane acrylate vacuum coating surface coating resin | |
| CN102153899A (en) | Ultraviolet-curable water-based colored paint composition | |
| CN105462481A (en) | Ultraviolet-cured composition | |
| CN101827873A (en) | Photocurable resin composition | |
| CN103210008A (en) | Curable resin composition | |
| CN101544869A (en) | Packless ultraviolet curing transparent priming lacquer for woodenware | |
| CN102220084A (en) | Photocureable coating and curing method thereof | |
| CN102101945A (en) | Ultraviolet curing paint and preparation method thereof | |
| CN104263208A (en) | UV (Ultraviolet) laminated topcoat gloss coating with performances of smell removal, stain resistance and yellowing resistance as well as preparation method and construction process thereof | |
| KR20150092202A (en) | Composition for hardcoat and molded article with hardcoat layer | |
| CN103865376A (en) | UV spraying frosted paint | |
| CN103351801B (en) | A kind of coating with imitative porcelain effect for glass baseplate and coating method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090603 |