CN106752522A - UV paints, the preparation method that UV draws and UV draws - Google Patents
UV paints, the preparation method that UV draws and UV draws Download PDFInfo
- Publication number
- CN106752522A CN106752522A CN201611166501.2A CN201611166501A CN106752522A CN 106752522 A CN106752522 A CN 106752522A CN 201611166501 A CN201611166501 A CN 201611166501A CN 106752522 A CN106752522 A CN 106752522A
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- China
- Prior art keywords
- draws
- product
- picture
- parts
- paints
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D7/00—Preserving paintings, e.g. by varnishing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Painted the invention discloses a kind of UV, the surface light solidifying coating for making picture product, including：45 55 parts of acrylic resin, 40 50 parts of propylene acid monomers, 3 10 parts of light trigger, 0.5 2 parts of levelling agent；The light trigger is the ketone of 2 hydroxyl, 2 aminomethyl phenyl propane 1, and the levelling agent is main to press (2 4) by acrylate oligomer, acrylate copolymer, silicone modified polyacrylate and polysiloxanes:(2‑4):(0.5‑1.5):The quality proportioning composition of (0.5 1.5).The UV obtained using technical scheme is painted, good with solidification effect, and the cubical contraction of coating is low after solidification, adhesive force and hardness are strong, the advantage such as the resistance to yellowing of product is high, so that the picture product for obtaining has more excellent picture quality.The UV made by UV of the invention paints draws, and significantly reduces the weight of picture product, improves picture quality, improves the resistance to yellowing of product, extends life of product；Simultaneously, there is provided UV method for making picture, it is simple to operate, and ensure that making UV draw properties of product stabilization.
Description
Technical field
Technical field, more particularly to a kind of UV paints are drawn the present invention relates to UV, and the UV pictures and the UV that are made by UV paints are drawn
Preparation method.
Background technology
UV paints (Ultraviolet Curing Paint), i.e. ultraviolet photo-curing paint, and also referred to as light-initiated coating, light are solid
Change coating, be to promote decomposition of initiator under the irradiation of ultraviolet (wavelength is 320-390nm), produce free radical, trigger tree
Fat reacts, the coating of instantaneous solidification film forming, because without any volatile substance, belonging to the paint of environmental protection.UV is painted for big
The picture product of breadth, substitutes traditional glass material as cover material, and it is big, frangible to solve glass weight, in transport
And the later stage using middle cracky, cause the problem of personal accident, it is more and more extensive in the application aspect of picture product, but will
UV paint as picture cover material, exist because picture surface minute asperities and UV paint solidification caused by surface flatness,
The influence of planarization and curing performance, and then the quality of cured film and the quality of picture are directly affected, therefore to cover material UV
The research of the aspects such as solidification effect, the stable curing performance of paint is the direction of the current technical field research and development.
The content of the invention
To solve the deficiency that prior art is present, painted the invention provides a kind of UV, the cover material as picture product,
The UV paints that the cured film to be formed is smooth, smooth, and brightness is high, and adhesive force is strong, makes picture product quality and resistance to yellowing performance significantly
Improve.
To achieve the above object, painted the invention provides a kind of UV, the surface light solidifying coating for making picture product,
Including following raw material component：Acrylic resin 45-55 parts, 40-50 parts of propylene acid monomers, light trigger 3-10 parts, stream
Flat agent 0.5-2 parts；The light trigger is 2- hydroxy-2-methyl phenyl-propane -1- ketone, and the levelling agent is main by acrylate
Oligomer, acrylate copolymer, silicone modified polyacrylate and polysiloxanes press (2-4):(2-4):(0.5-
1.5):The quality proportioning composition of (0.5-1.5).
UV paints as picture product cover material of the invention, are main film forming matter with acrylic resin, are drawn by light
Hair agent triggers acrylic monomers that polymerisation occurs with acrylic resin under the irradiation of ultraviolet, and the UV for coating surface is painted
Film-forming, forms the surface light solidifying coating of picture product.To improve the curing performance of UV paints and the smooth light of solidified surface
Slippery, the present invention is from main film forming matter acrylic resin and the polymerization reaction mechanism and photo-degradation mechanism of monomeric acrylic, sieve
The light trigger and mutually suitable levelling agent of matching film forming matter are selected, by the compounding of predetermined substance, cooperative effect is reached, makes table
Face light solidifying coating has the advantage that solidification rate is fast, deeply-curing is good, while reducing the injustice because of picture surface to being solidified into
The influence of film, makes film forming matter in the process that polymerisation film-forming occurs, further enhance film body and picture adhesive force and
Hardness.Additionally, the heat endurance of UV paints, bin stability are high, there is high sensitive and initiation activity high, solidification to ultraviolet light
The cubical contraction of coating is low afterwards, adhesive force and hardness are strong, and the residual of light trigger is few, significantly improves the resistance to Huang of product
Degree, so that the picture product for obtaining has more excellent picture quality.
Used as the further restriction to above-mentioned technical proposal, the levelling agent is main by acrylate oligomer, acrylic acid
Ester copolymer, silicone modified polyacrylate and polysiloxanes press 2:2:1:1 quality proportioning composition.
Meanwhile, to be drawn present invention also offers a kind of UV, the surface light solidifying coating that the UV draws is painted by UV as described above
It is obtained.
The UV that the present invention is provided is painted into the surface light solidifying coating for making UV pictures, with significantly reducing picture product weight
Amount, improves picture quality, extends the advantage of life of product.
Used as the further restriction to above-mentioned technical proposal, the UV draws includes backplane level, and priming paint is coated with backplane level,
UV printable layers are set on the priming paint, and the surface light solidifying coating is coated on the UV printable layers.
Used as the further restriction to above-mentioned technical proposal, the weight that the UV draws is 240-300 grams/every square meter.
The structure that UV draws, the picture product more excellent to obtain environmental-protecting performance, picture quality are further limited, and makes what UV drew
Product weight is significantly reduced, life of product is greatly prolonged, and product quality is substantially improved.
Meanwhile, present invention also offers the preparation method that a kind of UV draws, comprise the following steps：
A, the deposited melamine of rolling on the backplane level that UV draws, form priming paint；
B, the setting UV printable layers on the priming paint；
C, the sprayed coating UV paints as described above on the UV printable layers, then irradiate 5-10 under the ultraviolet light of reflector space
Second, surface light solidifying coating is formed, complete UV and draw.
Used as the further restriction to above-mentioned technical proposal, the preparation method of the UV paints includes：In acrylic resin
Acrylic monomers is added, after being well mixed, initiator and levelling agent is sequentially added, stirred 1-2 hours, obtain UV paints.
The UV method for making picture that the present invention is provided, simple to operate, the UV of acquisition draws properties of product stabilization, in preparation method
Order by merging, the mixing time of each raw material components in UV paints are further limited, with the cover material that forming properties are more excellent, makes acquisition
UV draw quality more preferably.
In sum, the UV for being obtained using technical scheme is painted, the cover material as picture product, with solid
Change that speed is fast, deeply-curing is good, the cubical contraction of coating is low after solidification, adhesive force and hardness are strong, the resistance to yellowing of product is high etc.
Advantage, so that the picture product for obtaining has more excellent picture quality.The present invention is drawn by the UV that UV paints make, and is significantly reduced
The weight of picture product, improves picture quality, improves the resistance to yellowing of product, extends life of product；Simultaneously, there is provided a kind of UV draw
Preparation method, it is simple to operate, and ensure that making UV draw properties of product stabilization.
Brief description of the drawings
Fig. 1 is the structural representation that UV of the present invention draws；
Fig. 2 is the profile that UV of the present invention draws.
In figure：1st, backplane level；2nd, priming paint；3rd, UV printable layers；4th, surface light solidifying coating.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment one
The present embodiment is related to the UV for being used as surface light solidifying coating to paint, and the picture product by UV paint making and making
Method.
Embodiment 1.1
A kind of UV paint, including following weight/mass percentage composition raw material components：Acrylic resin 46%, propylene acid monomers
44%, light trigger 2- hydroxy-2-methyl phenyl-propane -1- ketone 9%, levelling agent is (by acrylate oligomer FLow300, third
Olefin(e) acid ester copolymer Rad2500, silicone modified polyacrylate Airex900 and polysiloxanes Glide450 press 3:3:
1.2:1.2 quality proportioning composition) 1%；
By UV surface light solidifying coatings of the paint as picture product, operate as follows：Add in acrylic resin
Enter acrylic monomers, be well mixed, then sequentially add light trigger and levelling agent, stir 1 hour, obtain UV paints；Will configuration
Good UV paints are sprayed on a kind of conventional big former and draw surface, then irradiate the ultraviolet light of reflector space 5 seconds, obtain picture product
Product.
The picture product of acquisition has environmentally friendly, lightweight, and brightness is high, life of product advantage long.
Embodiment 1.2
A kind of UV paint, including following weight/mass percentage composition raw material components：Acrylic resin 52%, propylene acid monomers
43%, light trigger 2- hydroxy-2-methyl phenyl-propane -1- ketone 4.5%, levelling agent (by acrylate oligomer FLow300,
Acrylate copolymer Rad2500, silicone modified polyacrylate Airex900 and polysiloxanes Glide450 press 2:
2:1:1 quality proportioning composition) 0.5%；
A kind of UV draws, as shown in Figure 1 with Figure 2, including backplane level 1, the backplane level 1 can be by two-sided triamine density board
Constitute, it is also possible to be made up of other specie densities plates, priming paint 2 is coated with backplane level 1, UV is set on the priming paint 2
Printable layer 3, and the coating surface light solidifying coating 4 on the UV printable layers 3.
The making that UV draws is operated as follows：
A, the deposited melamine of rolling in the two-sided triamine density board of UV picture backplane levels, form priming paint；
B, set on the priming paint and be printed with the UV printable layers of paintings；
C, preparation UV paints, add acrylic monomers in acrylic resin, are well mixed, and then sequentially add light trigger
And levelling agent, stir 1 hour, obtain UV paints；The UV that will have been configured paints sprayed coating on UV printable layers, then in the purple of reflector space
Irradiated under outer light 6 seconds and form surface light solidifying coating, complete the making that UV draws.
It is only 255g that the UV of acquisition draws weight per square meter, compared to glass material as cover material picture product,
Product weight is significantly reduced, and with environmental protection, brightness is high, life of product advantage long.
Embodiment 1.3
A kind of UV paint, including following weight/mass percentage composition raw material components：Acrylic resin 50%, propylene acid monomers
44%, light trigger 2- hydroxy-2-methyl phenyl-propane -1- ketone 5%, levelling agent is (by acrylate oligomer FLow300, third
Olefin(e) acid ester copolymer Rad2500, silicone modified polyacrylate Airex900 and polysiloxanes Glide450 press 2:2:
0.8:0.8 quality proportioning composition) 1%；
Make and drawn with structure identical UV in embodiment 1.2, the UV is painted for making surface light solidifying coating, by as follows
Step operation：
A, the deposited melamine of rolling in the two-sided triamine density board of UV picture backplane levels, form priming paint；
B, set on the priming paint and be printed with the UV printable layers of paintings；
C, preparation UV paints, add acrylic monomers in acrylic resin, are well mixed, and then sequentially add light trigger
And levelling agent, stir 1.5 hours, obtain UV paints；The UV that will have been configured paints sprayed coating on UV printable layers, then in reflector space
Irradiated under ultraviolet light 8 seconds and form surface light solidifying coating, complete the making that UV draws.
It is only 250g that the UV of acquisition draws weight per square meter, compared to glass material as cover material picture product,
Product weight is significantly reduced, and with environmental protection, brightness is high, life of product advantage long.
Embodiment two
The present embodiment is related to the performance of the picture product made by UV of the invention paints.
The surface brightness that the UV for making draws is detected using photometer, testing result is 110 degree of surface brightness；Use a stroke lattice
Device draws surface and carries out transverse and longitudinal frame and then with 3M tape-stripping tearings in UV, as a result shows and do not come off very.
From the above results, UV paints of the invention, the cover material as picture product is fast, deep with solidification rate
Degree is cured, environmental protection, brightness advantage high, and the cubical contraction of coating is low after solidification, adhesive force and hardness are strong, product it is resistance to
Yellowing is high, so that the picture product for obtaining has more excellent picture quality, improves the resistance to yellowing of product, extends life of product
20%.
Claims (7)
1. a kind of UV is painted, the surface light solidifying coating for making picture product, it is characterised in that including following raw material
Component：Acrylic resin 45-55 parts, 40-50 parts, light trigger 3-10 parts, levelling agent 0.5-2 parts of propylene acid monomers；The light
Initiator is 2- hydroxy-2-methyl phenyl-propane -1- ketone, and the levelling agent is main common by acrylate oligomer, acrylate
Polymers, silicone modified polyacrylate and polysiloxanes press (2-4):(2-4):(0.5-1.5):The matter of (0.5-1.5)
Amount proportioning composition.
2. UV according to claim 1 is painted, it is characterised in that the levelling agent is main by acrylate oligomer, propylene
Acid ester copolymer, silicone modified polyacrylate and polysiloxanes press 2:2:1:1 quality proportioning composition.
3. a kind of UV draws, it is characterised in that：UV paint system of the surface light solidifying coating that the UV draws as described in claim 1 or 2
.
4. UV according to claim 3 draws, it is characterised in that：The UV draws includes backplane level, and bottom is coated with backplane level
Paint, sets UV printable layers, and the surface light solidifying coating is coated on the UV printable layers on the priming paint.
5. UV according to claim 4 draws, it is characterised in that：The weight that the UV draws is 240-300 grams/every square meter.
6. the preparation method that a kind of UV draws, it is characterised in that comprise the following steps：
A, the deposited melamine of rolling on the backplane level that UV draws, form priming paint；
B, the setting UV printable layers on the priming paint；
C, the sprayed coating UV paints as claimed in claim 1 or 2 on the UV printable layers, then shine under the ultraviolet light of reflector space
Penetrate 5-10 seconds, form surface light solidifying coating, complete UV and draw.
7. the preparation method that UV according to claim 6 draws, it is characterised in that the preparation method of the UV paints includes：
Acrylic monomers is added in acrylic resin, after being well mixed, initiator and levelling agent is sequentially added, stirred 1-2 hours, obtained
To UV paints.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611166501.2A CN106752522A (en) | 2016-12-16 | 2016-12-16 | UV paints, the preparation method that UV draws and UV draws |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611166501.2A CN106752522A (en) | 2016-12-16 | 2016-12-16 | UV paints, the preparation method that UV draws and UV draws |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106752522A true CN106752522A (en) | 2017-05-31 |
Family
ID=58892956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611166501.2A Pending CN106752522A (en) | 2016-12-16 | 2016-12-16 | UV paints, the preparation method that UV draws and UV draws |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106752522A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108501133A (en) * | 2017-12-30 | 2018-09-07 | 张梦琪 | A kind of PVC veneered plywoods and its manufacturing method |
| CN109096858A (en) * | 2018-05-29 | 2018-12-28 | 定州市立业金属制品有限公司 | A kind of anticorrosive paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004307529A (en) * | 2003-04-02 | 2004-11-04 | C I Kasei Co Ltd | Yellow transparent coating, its manufacturing method and lamp using it |
| CN1746235A (en) * | 2005-10-14 | 2006-03-15 | 中国乐凯胶片集团公司 | Ultraviolet aluminium-silver size coating with light curing |
| CN101445679A (en) * | 2008-12-25 | 2009-06-03 | 四川大学 | UV-light solidifying paint having decorative effect and preparation method thereof |
| CN102582246A (en) * | 2011-12-20 | 2012-07-18 | 南京林业大学 | Ultraviolet (UV) digital jet printing manufacturing method of plate-type components of floor boards and furniture |
-
2016
- 2016-12-16 CN CN201611166501.2A patent/CN106752522A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004307529A (en) * | 2003-04-02 | 2004-11-04 | C I Kasei Co Ltd | Yellow transparent coating, its manufacturing method and lamp using it |
| CN1746235A (en) * | 2005-10-14 | 2006-03-15 | 中国乐凯胶片集团公司 | Ultraviolet aluminium-silver size coating with light curing |
| CN101445679A (en) * | 2008-12-25 | 2009-06-03 | 四川大学 | UV-light solidifying paint having decorative effect and preparation method thereof |
| CN102582246A (en) * | 2011-12-20 | 2012-07-18 | 南京林业大学 | Ultraviolet (UV) digital jet printing manufacturing method of plate-type components of floor boards and furniture |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108501133A (en) * | 2017-12-30 | 2018-09-07 | 张梦琪 | A kind of PVC veneered plywoods and its manufacturing method |
| CN109096858A (en) * | 2018-05-29 | 2018-12-28 | 定州市立业金属制品有限公司 | A kind of anticorrosive paint and preparation method thereof |
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Application publication date: 20170531 |
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| RJ01 | Rejection of invention patent application after publication |