CN102985409A - 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用 - Google Patents

在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用 Download PDF

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Publication number
CN102985409A
CN102985409A CN2011800106123A CN201180010612A CN102985409A CN 102985409 A CN102985409 A CN 102985409A CN 2011800106123 A CN2011800106123 A CN 2011800106123A CN 201180010612 A CN201180010612 A CN 201180010612A CN 102985409 A CN102985409 A CN 102985409A
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China
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alkyl
aryl
randomly
formula
alkoxyl group
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Chinese (zh)
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C·马利维尔尼
L·圣-雅尔姆斯
S·戈容
T·卡托
A·J·巴塞拉杜
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Elkem Silicones France SAS
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Bluestar Silicones France SAS
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Priority to CN201711439210.0A priority Critical patent/CN108383793B/zh
Publication of CN102985409A publication Critical patent/CN102985409A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C07D233/58—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/06—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicon Polymers (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2011800106123A 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用 Pending CN102985409A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711439210.0A CN108383793B (zh) 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1050108 2010-01-08
FR1050108 2010-01-08
PCT/EP2011/050175 WO2011083146A1 (fr) 2010-01-08 2011-01-07 Procede de preparation de carbene en solution, nouvelle forme stable de carbene obtenu notamment par ce procede et applications de celle-ci en catalyse.

Related Child Applications (1)

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CN201711439210.0A Division CN108383793B (zh) 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用

Publications (1)

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CN102985409A true CN102985409A (zh) 2013-03-20

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CN201711439210.0A Active CN108383793B (zh) 2010-01-08 2011-01-07 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用

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Country Status (6)

Country Link
US (1) US9499643B2 (cg-RX-API-DMAC10.html)
EP (1) EP2542532B8 (cg-RX-API-DMAC10.html)
JP (2) JP5702403B2 (cg-RX-API-DMAC10.html)
KR (3) KR102004586B1 (cg-RX-API-DMAC10.html)
CN (2) CN102985409A (cg-RX-API-DMAC10.html)
WO (1) WO2011083146A1 (cg-RX-API-DMAC10.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107922621A (zh) * 2015-07-27 2018-04-17 美国道康宁公司 具有基于金属的n‑杂环碳烯缩合反应催化剂的聚有机硅氧烷组合物及其制备方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7945215B2 (en) 2007-02-20 2011-05-17 Adaptrum, Inc. Adaptive transmission power control for cognitive radio
JP6219820B2 (ja) * 2011-07-07 2017-10-25 ブルースター・シリコーンズ・フランス・エスアエス カルベン型触媒の存在下における脱水素縮合によって架橋可能なシリコーン組成物
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
KR102313503B1 (ko) * 2018-05-23 2021-10-15 국방과학연구소 N-헤테로고리 카벤 착화합물의 제조 방법, 이의 제조 방법으로 제조된 n-헤테로고리 카벤 착화합물 및 이를 이용한 폴리우레탄의 중합 지연 방법
KR102081916B1 (ko) * 2018-07-17 2020-02-26 전남대학교산학협력단 폴리우레탄 중합지연촉매 및 이를 이용한 폴리우레탄 중합지연방법
EP3901135A1 (en) * 2020-04-22 2021-10-27 Universität Heidelberg Sulfur extrusion from disulfides by carbenes
US11319613B2 (en) 2020-08-18 2022-05-03 Enviro Metals, LLC Metal refinement

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5077414A (en) 1990-03-29 1991-12-31 E. I. Du Pont De Nemours And Company Preparation of 1,3-disubstituted imidazolium salts
JP2001513795A (ja) 1997-03-06 2001-09-04 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 新しい触媒
GB0008707D0 (en) 2000-04-07 2000-05-31 Bp Chem Int Ltd Imidazole carbenes
DK1372844T3 (da) * 2001-03-23 2011-04-18 California Inst Of Techn Højaktive metalcarbenmetatesekatalysatorer, der er fremstillet ved anvendelse af et termisk aktiveret n-heterocyklisk carbenforstadium
FR2825709B1 (fr) 2001-06-07 2005-07-01 Rhodia Chimie Sa Composition silicone reticulable en elastomere par hydrosilylation, en presence de catalyseurs metalliques a base de carbenes, et catalyseurs de ce type
DE10149348A1 (de) * 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen
FR2864543B1 (fr) * 2003-12-30 2006-03-03 Rhodia Chimie Sa Procede de preparation de polyorganosiloxanes (pos) par polymerisation par ouverture de cycle(s) et/ou redistribution de pos, en presence de carbene(s) et compositions de pos mises en oeuvre dans ce procede
JP4538603B2 (ja) * 2004-07-08 2010-09-08 独立行政法人産業技術総合研究所 カルバミン酸エステルの製造方法
FR2900153B1 (fr) 2006-04-21 2008-07-18 Rhodia Recherches & Tech Procede de condensation de motifs silyles a l'aide d'un catalyseur de type carbene

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
ARTHUR V. KNISHEVITSKY等: "Copper(I) halide complexes of the new 4,4’-bridged heteroaromatic biscarbenes of the 1,2,4-triazole series", <JOURNAL OF ORGANOMETALLIC CHEMISTRY> *
HAO CHEN等: "Proton Affinities of N-Heterocyclic Carbene Super Bases", <ORGANIC LETTERS> *
MATTHIAS SCHOLL等: "Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands", <ORGANIC LETTERS> *
MOHAMMAD MOVASSAGHI等: "N-Heterocyclic Carbene-Catalyzed Amidation of Unactivated Esters with Amino Alcohols", 《ORGANIC LETTERS》 *
OLIVIER COULEMBIER等: "Alcohol Adducts of N-Heterocyclic Carbenes: Latent Catalysts for the Thermally-Controlled Living Polymerization of Cyclic Esters", 《MACROMOLECULES》 *
TINA M. TRNKA等: "Synthesis and Activity of Ruthenium Alkylidene Complexes Coordinated with Phosphine and N-Heterocyclic Carbene Ligands", <JOURNAL OF THE AMERICAN CHEMICAL SOCIETY> *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107922621A (zh) * 2015-07-27 2018-04-17 美国道康宁公司 具有基于金属的n‑杂环碳烯缩合反应催化剂的聚有机硅氧烷组合物及其制备方法
CN107922621B (zh) * 2015-07-27 2021-05-14 美国道康宁公司 具有基于金属的n-杂环碳烯缩合反应催化剂的聚有机硅氧烷组合物及其制备方法

Also Published As

Publication number Publication date
CN108383793B (zh) 2022-04-05
KR102004586B1 (ko) 2019-07-26
KR20180077335A (ko) 2018-07-06
US9499643B2 (en) 2016-11-22
EP2542532A1 (fr) 2013-01-09
WO2011083146A1 (fr) 2011-07-14
EP2542532B8 (fr) 2018-02-14
JP5702403B2 (ja) 2015-04-15
US20130158274A1 (en) 2013-06-20
JP2013532117A (ja) 2013-08-15
KR20150091539A (ko) 2015-08-11
KR20120104624A (ko) 2012-09-21
CN108383793A (zh) 2018-08-10
EP2542532B1 (fr) 2018-01-03
JP2015096531A (ja) 2015-05-21

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