CN102959386B - 气体分析装置、汞除去系统、气体分析方法及废气中的汞除去方法 - Google Patents

气体分析装置、汞除去系统、气体分析方法及废气中的汞除去方法 Download PDF

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Publication number
CN102959386B
CN102959386B CN201180031530.7A CN201180031530A CN102959386B CN 102959386 B CN102959386 B CN 102959386B CN 201180031530 A CN201180031530 A CN 201180031530A CN 102959386 B CN102959386 B CN 102959386B
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China
Prior art keywords
ammonium chloride
waste gas
gas
concentration
contained
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Expired - Fee Related
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CN201180031530.7A
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English (en)
Chinese (zh)
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CN102959386A (zh
Inventor
香川晴治
千代丸胜
鹈饲展行
冈本卓也
村上盛纪
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Mitsubishi Power Ltd
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Mitsubishi Heavy Industries Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/30—Controlling by gas-analysis apparatus
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2202—Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
    • G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
    • G01N23/223—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by irradiating the sample with X-rays or gamma-rays and by measuring X-ray fluorescence
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2223/00—Investigating materials by wave or particle radiation
    • G01N2223/07—Investigating materials by wave or particle radiation secondary emission
    • G01N2223/076—X-ray fluorescence

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Molecular Biology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Treating Waste Gases (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
CN201180031530.7A 2010-09-28 2011-09-22 气体分析装置、汞除去系统、气体分析方法及废气中的汞除去方法 Expired - Fee Related CN102959386B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2010217909A JP5529701B2 (ja) 2010-09-28 2010-09-28 ガス分析装置、水銀除去システム及び水銀除去方法
JP2010-217909 2010-09-28
PCT/JP2011/071710 WO2012043411A1 (ja) 2010-09-28 2011-09-22 ガス分析装置、水銀除去システム、ガス分析方法及び排ガス中の水銀除去方法

Publications (2)

Publication Number Publication Date
CN102959386A CN102959386A (zh) 2013-03-06
CN102959386B true CN102959386B (zh) 2015-09-30

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CN201180031530.7A Expired - Fee Related CN102959386B (zh) 2010-09-28 2011-09-22 气体分析装置、汞除去系统、气体分析方法及废气中的汞除去方法

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US (1) US8568673B2 (cg-RX-API-DMAC10.html)
EP (1) EP2623966B1 (cg-RX-API-DMAC10.html)
JP (1) JP5529701B2 (cg-RX-API-DMAC10.html)
CN (1) CN102959386B (cg-RX-API-DMAC10.html)
CA (1) CA2803817C (cg-RX-API-DMAC10.html)
PL (1) PL2623966T3 (cg-RX-API-DMAC10.html)
WO (1) WO2012043411A1 (cg-RX-API-DMAC10.html)

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JP5943687B2 (ja) * 2012-04-13 2016-07-05 三菱日立パワーシステムズ株式会社 濃度測定装置
CN103926833B (zh) * 2014-04-22 2016-06-08 东南大学 一种选择性催化还原脱硝装置入口参数确定方法
AU2016200890A1 (en) * 2015-02-13 2016-09-01 The Babcock & Wilcox Company Method and apparatus for removing mercury from a flue gas stream
CN104833689B (zh) * 2015-05-19 2018-05-01 钢研纳克检测技术股份有限公司 基于干法富集烟气中总汞的在线分析仪
CN105536485B (zh) * 2016-02-05 2023-12-15 浙江浙能技术研究院有限公司 一种碱法烟气卤素脱除装置及脱除方法
JP6763539B2 (ja) * 2016-03-30 2020-09-30 三菱パワー株式会社 排ガス処理システム
JP2018034085A (ja) * 2016-08-30 2018-03-08 日立造船株式会社 燃焼排ガスの処理装置
JP6854663B2 (ja) * 2017-02-15 2021-04-07 公立大学法人大阪 排ガス処理方法及び排ガス処理装置
CN109030528A (zh) * 2018-09-26 2018-12-18 云南驰宏锌锗股份有限公司 一种x射线荧光光谱分析冶炼烟尘中氟氯的方法
CN112955734A (zh) * 2018-10-18 2021-06-11 安全事务有限公司 用于探测和识别物质内的外来成分的系统和方法
CN109529621B (zh) * 2019-01-12 2024-03-12 西安交通大学 基于催化氧化和深度冷凝的半干法脱硫脱硝脱汞装置及方法
CN110243638A (zh) * 2019-05-17 2019-09-17 华电电力科学研究院有限公司 一种用于scr脱硝装置的烟气采集装置与方法
CN110420548B (zh) * 2019-09-03 2024-03-26 亚太环保股份有限公司 烟气氨法协同脱硝脱硫脱汞超低排放的装置及方法
CN111318134A (zh) * 2020-03-21 2020-06-23 山西省工业设备安装集团有限公司 一种基于在线监测技术的生活垃圾焚烧发电厂用烟气处理系统
WO2022093864A1 (en) * 2020-10-27 2022-05-05 Seekops Inc. Methods and apparatus for measuring methane emissions with an optical open-cavity methane sensor
CN113018943A (zh) * 2021-03-03 2021-06-25 魏福军 一种无纺布加工用废水过滤处理装置
CN114563236B (zh) * 2022-03-07 2023-12-22 马鞍山钢铁股份有限公司 一种焦炉烟气空气系数快速测定方法
CN116571071B (zh) * 2023-06-29 2025-08-26 中铜东南铜业有限公司 一种铜冶炼烟气脱汞工艺

Citations (2)

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US20080138264A1 (en) * 2006-12-07 2008-06-12 Mitsubishi Heavy Industries, Ltd. Method and device for removing mercury
CN101678273A (zh) * 2007-12-26 2010-03-24 三菱重工业株式会社 废气处理装置和方法

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US3578410A (en) * 1968-07-01 1971-05-11 Gen Electric Ammonia detection,following ultraviolet radiation
JPS6318251A (ja) 1986-07-11 1988-01-26 Moritetsukusu:Kk 光学的アンモニア検出素子
JPH07270284A (ja) 1994-04-01 1995-10-20 Mitsubishi Materials Corp ガスサンプリング方法
JP3572139B2 (ja) 1996-04-09 2004-09-29 三菱重工業株式会社 熱交換器及びこれを備えた排煙処理装置
JP2001198434A (ja) * 2000-01-18 2001-07-24 Mitsubishi Heavy Ind Ltd 排ガス中の水銀処理方法および排ガスの処理システム
JP2003014625A (ja) * 2001-06-28 2003-01-15 Ishikawajima Harima Heavy Ind Co Ltd Ｓｏ３，ｎｈ３同時連続濃度計
JP4838579B2 (ja) * 2005-12-21 2011-12-14 三菱重工業株式会社 水銀除去システムおよび水銀除去方法
CA2672580C (en) 2006-12-27 2015-02-03 Babcock-Hitachi Kabushiki Kaisha Exhaust gas treating method and apparatus
JP5319934B2 (ja) 2008-02-28 2013-10-16 三菱重工業株式会社 排ガス処理方法及び装置
JP5398193B2 (ja) 2008-08-07 2014-01-29 三菱重工業株式会社 排ガス処理装置、排ガス処理システム及び排ガス中の水銀酸化性能管理システム
JP5338421B2 (ja) * 2009-03-24 2013-11-13 栗田工業株式会社 燃焼排ガスの処理方法及び装置
US7906090B2 (en) * 2009-07-06 2011-03-15 Mitsubishi Heavy Industries, Ltd. Mercury reduction system and mercury reduction method of flue gas containing mercury
JP5558042B2 (ja) * 2009-08-05 2014-07-23 三菱重工業株式会社 排ガス処理装置及び排ガスの水銀除去方法

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US20080138264A1 (en) * 2006-12-07 2008-06-12 Mitsubishi Heavy Industries, Ltd. Method and device for removing mercury
CN101678273A (zh) * 2007-12-26 2010-03-24 三菱重工业株式会社 废气处理装置和方法

Also Published As

Publication number Publication date
JP2012073106A (ja) 2012-04-12
WO2012043411A1 (ja) 2012-04-05
JP5529701B2 (ja) 2014-06-25
CN102959386A (zh) 2013-03-06
EP2623966A4 (en) 2017-07-12
EP2623966A1 (en) 2013-08-07
US8568673B2 (en) 2013-10-29
PL2623966T3 (pl) 2019-04-30
US20130101487A1 (en) 2013-04-25
CA2803817C (en) 2015-03-31
EP2623966B1 (en) 2018-10-31
CA2803817A1 (en) 2012-04-05

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Owner name: MITSUBISHI HITACHI POWER SYSTEM LTD.

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Effective date: 20150228

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Effective date of registration: 20150228

Address after: Kanagawa County, Japan

Applicant after: MITSUBISHI HEAVY INDUSTRIES, Ltd.

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Applicant before: MITSUBISHI HEAVY INDUSTRIES, Ltd.

C14 Grant of patent or utility model
GR01 Patent grant
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CP01 Change in the name or title of a patent holder

Address after: Kanagawa Prefecture, Japan

Patentee after: Mitsubishi Power Co.,Ltd.

Address before: Kanagawa Prefecture, Japan

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Granted publication date: 20150930