CN102906142B - 包含氢卤代烯烃和水的泡沫膨胀剂组合物以及它们在聚氨酯和聚异氰脲酸酯聚合物泡沫的制备中的用途 - Google Patents

包含氢卤代烯烃和水的泡沫膨胀剂组合物以及它们在聚氨酯和聚异氰脲酸酯聚合物泡沫的制备中的用途 Download PDF

Info

Publication number
CN102906142B
CN102906142B CN201180020879.0A CN201180020879A CN102906142B CN 102906142 B CN102906142 B CN 102906142B CN 201180020879 A CN201180020879 A CN 201180020879A CN 102906142 B CN102906142 B CN 102906142B
Authority
CN
China
Prior art keywords
foam
water
expansion agent
agent composition
closed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201180020879.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN102906142A (zh
Inventor
J.A.克雷佐
G.洛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemours Co FC LLC
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN102906142A publication Critical patent/CN102906142A/zh
Application granted granted Critical
Publication of CN102906142B publication Critical patent/CN102906142B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/10—Water or water-releasing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN201180020879.0A 2010-04-28 2011-04-27 包含氢卤代烯烃和水的泡沫膨胀剂组合物以及它们在聚氨酯和聚异氰脲酸酯聚合物泡沫的制备中的用途 Active CN102906142B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US32866810P 2010-04-28 2010-04-28
US61/328668 2010-04-28
PCT/US2011/034065 WO2011137151A1 (en) 2010-04-28 2011-04-27 Foam expansion agent compositions containing hydrohaloolefin and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams

Publications (2)

Publication Number Publication Date
CN102906142A CN102906142A (zh) 2013-01-30
CN102906142B true CN102906142B (zh) 2015-11-25

Family

ID=44227558

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180020879.0A Active CN102906142B (zh) 2010-04-28 2011-04-27 包含氢卤代烯烃和水的泡沫膨胀剂组合物以及它们在聚氨酯和聚异氰脲酸酯聚合物泡沫的制备中的用途

Country Status (12)

Country Link
US (1) US20110269860A1 (enExample)
EP (1) EP2563832A1 (enExample)
JP (1) JP5869557B2 (enExample)
KR (1) KR20130093004A (enExample)
CN (1) CN102906142B (enExample)
AR (1) AR081901A1 (enExample)
AU (4) AU2011245409B2 (enExample)
BR (1) BR112012027555A2 (enExample)
CA (1) CA2791804A1 (enExample)
CO (1) CO6640248A2 (enExample)
MX (1) MX2012012331A (enExample)
WO (1) WO2011137151A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2393862B1 (en) * 2009-02-03 2018-08-15 The Chemours Company FC, LLC Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US9556303B2 (en) * 2011-02-21 2017-01-31 Honeywell International Inc. Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
JP2014506947A (ja) * 2011-02-21 2014-03-20 ハネウェル・インターナショナル・インコーポレーテッド ハロゲン化オレフィン発泡剤を含むポリウレタンフォームプレミックス及びそれから製造されるフォーム
JP2016516106A (ja) * 2013-03-06 2016-06-02 ハネウェル・インターナショナル・インコーポレーテッド １，１，１，４，４，４−ヘキサフルオロ−２−ブテンを含む保存安定性発泡性組成物
CN104003639A (zh) * 2014-05-09 2014-08-27 中国铁道科学研究院铁道建筑研究所 一种水泥基材料全过程抗缩剂及其制备方法
US10144798B2 (en) 2015-12-21 2018-12-04 Covestro Llc Methods for designing polyisocyanurate foam-forming compositions, related polyisocyanurate foam-forming compositions, and foams produced thereby
WO2017127402A1 (en) * 2016-01-22 2017-07-27 The Chemours Company Fc, Llc Use of z-hfo-1,1,1,4,4,4-hexafluoro-2-butene in high temperature foaming application
CA2963751A1 (en) * 2017-02-13 2018-08-13 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
EP3636684A4 (en) * 2017-06-05 2021-03-10 Bridgestone Corporation COMPOSITION FOR THE PRODUCTION OF POLYURETHANE FOAM, POLYURETHANE FOAM AND SOUND ATTENUATOR
US10640600B2 (en) * 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10968327B2 (en) 2018-08-27 2021-04-06 Covestro Llc Methods for formulating polyisocyanurate foam-forming compositions, related polyisocyanurate foam-forming compositions, and foams produced thereby
CN109294218A (zh) * 2018-09-28 2019-02-01 上海东大聚氨酯有限公司 组合聚醚、聚氨酯泡沫原料组合物、源自其的聚氨酯泡沫及其制备方法和应用
CN119286235B (zh) * 2024-12-10 2025-04-04 山东一诺威聚氨酯股份有限公司 耐老化高阻燃聚氨酯自结皮泡沫材料及其制备方法与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05179043A (ja) * 1991-11-18 1993-07-20 Daikin Ind Ltd フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法
WO2009014965A1 (en) * 2007-07-20 2009-01-29 E. I. Du Pont De Nemours And Company Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams
WO2009073487A1 (en) * 2007-11-29 2009-06-11 E. I. Du Pont De Nemours And Company Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams
CN101646724A (zh) * 2007-03-27 2010-02-10 陶氏环球技术公司 包含氟化链烯烃发泡剂的链烯基芳族聚合物泡沫体

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4394491A (en) 1980-10-08 1983-07-19 The Dow Chemical Company Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate
JPH02120338A (ja) * 1988-10-28 1990-05-08 Asahi Glass Co Ltd 発泡合成樹脂の製造方法
US5164419A (en) 1991-05-20 1992-11-17 E. I. Du Pont De Nemours And Company Blowing agent and process for preparing polyurethane foam
US5777184A (en) 1997-06-25 1998-07-07 Alliedsignal Inc. Preparation of fluoroalkyl compounds and their derivatives
US7592494B2 (en) 2003-07-25 2009-09-22 Honeywell International Inc. Process for the manufacture of 1,3,3,3-tetrafluoropropene
US9499729B2 (en) * 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
ES2447037T3 (es) 2006-09-05 2014-03-11 E.I. Du Pont De Nemours And Company Procedimiento de fabricación de 2,3,3,3-tetrafluoropropeno
RU2006139128A (ru) 2006-11-07 2008-05-20 Е.И.Дюпон де Немур энд Компани (US) Способ получения фторированных олефинов
US8618339B2 (en) 2007-04-26 2013-12-31 E I Du Pont De Nemours And Company High selectivity process to make dihydrofluoroalkenes
US7795482B2 (en) 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
US9550854B2 (en) * 2007-10-12 2017-01-24 Honeywell International Inc. Amine catalysts for polyurethane foams
US20110124758A1 (en) * 2008-08-13 2011-05-26 E.I. Du Pont De Nemours And Company Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and hydrocarbon and their uses in the preparation of polyisocyanate-based foams
EP2393862B1 (en) * 2009-02-03 2018-08-15 The Chemours Company FC, LLC Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05179043A (ja) * 1991-11-18 1993-07-20 Daikin Ind Ltd フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法
CN101646724A (zh) * 2007-03-27 2010-02-10 陶氏环球技术公司 包含氟化链烯烃发泡剂的链烯基芳族聚合物泡沫体
WO2009014965A1 (en) * 2007-07-20 2009-01-29 E. I. Du Pont De Nemours And Company Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams
WO2009073487A1 (en) * 2007-11-29 2009-06-11 E. I. Du Pont De Nemours And Company Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams

Also Published As

Publication number Publication date
BR112012027555A2 (pt) 2017-08-08
AU2016200023A1 (en) 2016-01-28
KR20130093004A (ko) 2013-08-21
CO6640248A2 (es) 2013-03-22
CA2791804A1 (en) 2011-11-03
AR081901A1 (es) 2012-10-31
AU2017204059A1 (en) 2017-07-06
AU2018236730A1 (en) 2018-10-18
US20110269860A1 (en) 2011-11-03
CN102906142A (zh) 2013-01-30
AU2011245409A1 (en) 2012-08-30
MX2012012331A (es) 2012-11-21
AU2018236730B2 (en) 2019-08-01
AU2011245409B2 (en) 2015-10-01
JP2013525577A (ja) 2013-06-20
WO2011137151A1 (en) 2011-11-03
JP5869557B2 (ja) 2016-02-24
EP2563832A1 (en) 2013-03-06

Similar Documents

Publication Publication Date Title
CN102906142B (zh) 包含氢卤代烯烃和水的泡沫膨胀剂组合物以及它们在聚氨酯和聚异氰脲酸酯聚合物泡沫的制备中的用途
AU2012346370B2 (en) Foam expansion agent compositions containing Z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
CN101743270B (zh) 包含顺式-1,1,1,4,4,4-六氟-2-丁烯泡沫形成组合物的组合物及其在制备基于多异氰酸酯的泡沫中的用途
EP2567993B1 (en) Foam-forming compositions containing an azeotropic or azeotrope-like mixture containing cis-1,1,1,4,4,4-hexafluoro-2-butene and cyclopentane and their uses in the preparation of polyisocyanate-based foams
US20100216904A1 (en) Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and at least one hydrofluoroolefin and their uses in the preparation of polyisocyanate-based foams
US20110124758A1 (en) Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and hydrocarbon and their uses in the preparation of polyisocyanate-based foams
US20100210747A1 (en) Compositions and use of trans-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams
CN102300896B (zh) 包含顺式-1,1,1,4,4,4-六氟-2-丁烯与1,1,1,3,3-五氟丙烷的混合物的泡沫形成组合物以及它们在基于多异氰酸酯的泡沫制备中的用途
WO2009089400A1 (en) Compositions and use of 2-chloro-3,3,3-trifluoropropene foam-forming composition in the preparation of polyisocyanate-based foams
AU2019200463B2 (en) Foam-forming compositions containing azeotropic or azeotrope-like mixtures containing z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyisocyanate-based foams

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20180104

Address after: Delaware, USA

Patentee after: Como Efsee Co.,Ltd.

Address before: Wilmington, Delaware, USA

Patentee before: E. I. du Pont de Nemours and Co.