CA2791804A1 - Foam expansion agent compositions containing hydrohaloolefin and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams - Google Patents

Foam expansion agent compositions containing hydrohaloolefin and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams Download PDF

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Publication number
CA2791804A1
CA2791804A1 CA2791804A CA2791804A CA2791804A1 CA 2791804 A1 CA2791804 A1 CA 2791804A1 CA 2791804 A CA2791804 A CA 2791804A CA 2791804 A CA2791804 A CA 2791804A CA 2791804 A1 CA2791804 A1 CA 2791804A1
Authority
CA
Canada
Prior art keywords
foam
expansion agent
water
agent composition
foam expansion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2791804A
Other languages
English (en)
French (fr)
Inventor
Joseph Anthony Creazzo
Gary Loh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CA2791804A1 publication Critical patent/CA2791804A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/10—Water or water-releasing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
CA2791804A 2010-04-28 2011-04-27 Foam expansion agent compositions containing hydrohaloolefin and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams Abandoned CA2791804A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US32866810P 2010-04-28 2010-04-28
US61/328,668 2010-04-28
PCT/US2011/034065 WO2011137151A1 (en) 2010-04-28 2011-04-27 Foam expansion agent compositions containing hydrohaloolefin and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams

Publications (1)

Publication Number Publication Date
CA2791804A1 true CA2791804A1 (en) 2011-11-03

Family

ID=44227558

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2791804A Abandoned CA2791804A1 (en) 2010-04-28 2011-04-27 Foam expansion agent compositions containing hydrohaloolefin and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams

Country Status (12)

Country Link
US (1) US20110269860A1 (enExample)
EP (1) EP2563832A1 (enExample)
JP (1) JP5869557B2 (enExample)
KR (1) KR20130093004A (enExample)
CN (1) CN102906142B (enExample)
AR (1) AR081901A1 (enExample)
AU (4) AU2011245409B2 (enExample)
BR (1) BR112012027555A2 (enExample)
CA (1) CA2791804A1 (enExample)
CO (1) CO6640248A2 (enExample)
MX (1) MX2012012331A (enExample)
WO (1) WO2011137151A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2393862B1 (en) * 2009-02-03 2018-08-15 The Chemours Company FC, LLC Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US9556303B2 (en) * 2011-02-21 2017-01-31 Honeywell International Inc. Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
JP2014506947A (ja) * 2011-02-21 2014-03-20 ハネウェル・インターナショナル・インコーポレーテッド ハロゲン化オレフィン発泡剤を含むポリウレタンフォームプレミックス及びそれから製造されるフォーム
JP2016516106A (ja) * 2013-03-06 2016-06-02 ハネウェル・インターナショナル・インコーポレーテッド １，１，１，４，４，４−ヘキサフルオロ−２−ブテンを含む保存安定性発泡性組成物
CN104003639A (zh) * 2014-05-09 2014-08-27 中国铁道科学研究院铁道建筑研究所 一种水泥基材料全过程抗缩剂及其制备方法
US10144798B2 (en) 2015-12-21 2018-12-04 Covestro Llc Methods for designing polyisocyanurate foam-forming compositions, related polyisocyanurate foam-forming compositions, and foams produced thereby
WO2017127402A1 (en) * 2016-01-22 2017-07-27 The Chemours Company Fc, Llc Use of z-hfo-1,1,1,4,4,4-hexafluoro-2-butene in high temperature foaming application
CA2963751A1 (en) * 2017-02-13 2018-08-13 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
EP3636684A4 (en) * 2017-06-05 2021-03-10 Bridgestone Corporation COMPOSITION FOR THE PRODUCTION OF POLYURETHANE FOAM, POLYURETHANE FOAM AND SOUND ATTENUATOR
US10640600B2 (en) * 2018-04-24 2020-05-05 Covestro Llc Rigid polyurethane foams suitable for use as panel insulation
US10968327B2 (en) 2018-08-27 2021-04-06 Covestro Llc Methods for formulating polyisocyanurate foam-forming compositions, related polyisocyanurate foam-forming compositions, and foams produced thereby
CN109294218A (zh) * 2018-09-28 2019-02-01 上海东大聚氨酯有限公司 组合聚醚、聚氨酯泡沫原料组合物、源自其的聚氨酯泡沫及其制备方法和应用
CN119286235B (zh) * 2024-12-10 2025-04-04 山东一诺威聚氨酯股份有限公司 耐老化高阻燃聚氨酯自结皮泡沫材料及其制备方法与应用

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4394491A (en) 1980-10-08 1983-07-19 The Dow Chemical Company Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate
JPH02120338A (ja) * 1988-10-28 1990-05-08 Asahi Glass Co Ltd 発泡合成樹脂の製造方法
US5164419A (en) 1991-05-20 1992-11-17 E. I. Du Pont De Nemours And Company Blowing agent and process for preparing polyurethane foam
JPH05179043A (ja) 1991-11-18 1993-07-20 Daikin Ind Ltd フルオロブテンからなる発泡剤およびプラスチック発泡体の製造方法
US5777184A (en) 1997-06-25 1998-07-07 Alliedsignal Inc. Preparation of fluoroalkyl compounds and their derivatives
US7592494B2 (en) 2003-07-25 2009-09-22 Honeywell International Inc. Process for the manufacture of 1,3,3,3-tetrafluoropropene
US9499729B2 (en) * 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
ES2447037T3 (es) 2006-09-05 2014-03-11 E.I. Du Pont De Nemours And Company Procedimiento de fabricación de 2,3,3,3-tetrafluoropropeno
RU2006139128A (ru) 2006-11-07 2008-05-20 Е.И.Дюпон де Немур энд Компани (US) Способ получения фторированных олефинов
JP5592249B2 (ja) * 2007-03-27 2014-09-17 ダウ グローバル テクノロジーズ エルエルシー フッ素化アルケン発泡剤からの高品質ポリマー発泡体
US8618339B2 (en) 2007-04-26 2013-12-31 E I Du Pont De Nemours And Company High selectivity process to make dihydrofluoroalkenes
US7795482B2 (en) 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
EP2170980B1 (en) * 2007-07-20 2013-08-21 E. I. du Pont de Nemours and Company Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams
US9550854B2 (en) * 2007-10-12 2017-01-24 Honeywell International Inc. Amine catalysts for polyurethane foams
WO2009073487A1 (en) * 2007-11-29 2009-06-11 E. I. Du Pont De Nemours And Company Compositions and use of cis-1,1,1,4,4,4-hexafluoro-2-butene foam-forming composition in the preparation of polyisocyanate-based foams
US20110124758A1 (en) * 2008-08-13 2011-05-26 E.I. Du Pont De Nemours And Company Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and hydrocarbon and their uses in the preparation of polyisocyanate-based foams
EP2393862B1 (en) * 2009-02-03 2018-08-15 The Chemours Company FC, LLC Foam-forming compositions containing mixtures of cis-1,1,1,4,4,4-hexafluoro-2-butene and 1,1,1,3,3-pentafluoropropane and their uses in the preparation of polyisocyanate-based foams
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene

Also Published As

Publication number Publication date
BR112012027555A2 (pt) 2017-08-08
AU2016200023A1 (en) 2016-01-28
KR20130093004A (ko) 2013-08-21
CO6640248A2 (es) 2013-03-22
AR081901A1 (es) 2012-10-31
AU2017204059A1 (en) 2017-07-06
CN102906142B (zh) 2015-11-25
AU2018236730A1 (en) 2018-10-18
US20110269860A1 (en) 2011-11-03
CN102906142A (zh) 2013-01-30
AU2011245409A1 (en) 2012-08-30
MX2012012331A (es) 2012-11-21
AU2018236730B2 (en) 2019-08-01
AU2011245409B2 (en) 2015-10-01
JP2013525577A (ja) 2013-06-20
WO2011137151A1 (en) 2011-11-03
JP5869557B2 (ja) 2016-02-24
EP2563832A1 (en) 2013-03-06

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Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20160118

FZDE Discontinued

Effective date: 20180925