CN102892747B - 通过氢化二硝基甲苯制备甲苯二胺的方法 - Google Patents

通过氢化二硝基甲苯制备甲苯二胺的方法 Download PDF

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Publication number
CN102892747B
CN102892747B CN201180024339.XA CN201180024339A CN102892747B CN 102892747 B CN102892747 B CN 102892747B CN 201180024339 A CN201180024339 A CN 201180024339A CN 102892747 B CN102892747 B CN 102892747B
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reactor
catalyst
process according
dinitrotoluene
liquid phase
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Chinese (zh)
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CN102892747A (zh
Inventor
A·赖希勒
J·科埃略楚苏
S·内托
U·潘泽尔
S·厄伦施莱格
M·策林格尔
H·布劳恩斯伯格
S·哈斯
J·比特纳
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201180024339.XA 2010-05-17 2011-05-09 通过氢化二硝基甲苯制备甲苯二胺的方法 Active CN102892747B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10162924 2010-05-17
EP10162924.4 2010-05-17
PCT/EP2011/057427 WO2011144481A1 (de) 2010-05-17 2011-05-09 Verfahren zur herstellung von toluylendiamin durch hydrierung von dinitrotoluol

Publications (2)

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CN102892747A CN102892747A (zh) 2013-01-23
CN102892747B true CN102892747B (zh) 2014-05-21

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EP (1) EP2571844B1 (enExample)
JP (1) JP2013530140A (enExample)
KR (1) KR20130080445A (enExample)
CN (1) CN102892747B (enExample)
BR (1) BR112012027954A2 (enExample)
HU (1) HUE037511T2 (enExample)
MY (1) MY156559A (enExample)
SG (1) SG185374A1 (enExample)
WO (1) WO2011144481A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103313962B (zh) * 2010-12-06 2014-12-24 巴斯夫欧洲公司 制备芳胺的方法
US8835688B2 (en) 2011-03-16 2014-09-16 Basf Se Optimized introduction of the starting materials for a process for preparing aromatic amines by hydrogenation of nitroaromatics
US8895783B2 (en) 2012-02-07 2014-11-25 Basf Se Monitoring of the stoichiometric ratio in the reaction of nitroaromatics with hydrogen
WO2013117622A1 (de) * 2012-02-07 2013-08-15 Basf Se Überwachung des stöchiometrischen verhältnisses bei der umsetzung von nitroaromaten mit wasserstoff
US9302237B2 (en) 2013-01-11 2016-04-05 Basf Se Apparatus and process for the continuous reaction of liquids with gases
US9295971B2 (en) 2013-01-11 2016-03-29 Basf Se Apparatus and process for the continuous reaction of liquids with gases
WO2014108351A1 (de) 2013-01-11 2014-07-17 Basf Se Vorrichtung und verfahren zur kontinuierlichen umsetzung von flüssigkeiten mit gasen
CN105593205B (zh) * 2013-10-08 2017-12-12 科思创德国股份有限公司 制备二氨基甲苯的方法
CN104098475A (zh) * 2014-07-28 2014-10-15 淮安嘉诚高新化工股份有限公司 二硝基甲苯连续液相催化加氢还原生产二氨基甲苯的装置及方法
EP3523271B1 (de) * 2016-10-10 2020-12-09 Basf Se Katalysatormodifikation mit alkalimetall-, erdalkalimetall- oder seltenerdmetallionen in der kontinuierlichen flüssigphasen-hydrierung von nitroverbindungen
CN107325006A (zh) * 2017-08-04 2017-11-07 赛鼎工程有限公司 一种二硝基甲苯加氢管式增稠的工艺
CN111212827B (zh) * 2017-10-16 2023-11-17 巴斯夫欧洲公司 通过添加氨提高硝基化合物的连续氢化中的催化剂选择性
CN109053462B (zh) * 2018-08-14 2021-11-05 浙江今晖新材料股份有限公司 一种对氟苯胺的制备方法
CN116440898B (zh) * 2023-05-08 2025-02-07 中国科学院金属研究所 用于二硝基甲苯加氢反应的原子级分散Pd-Pt催化剂及其制备方法和应用

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
JPS60172947A (ja) * 1984-02-16 1985-09-06 Mitsui Toatsu Chem Inc トリレンジアミンの連続的製造方法
DE19844901C1 (de) 1998-09-30 1999-11-04 Bayer Ag Verfahren zur Dosierung von flüssigen Nitroaromaten mit mehr als einer Nitrogruppe in Reaktoren zur Sumpfphasen-Hydrierung
KR100655354B1 (ko) * 1998-12-12 2006-12-08 바스프 악티엔게젤샤프트 아민의 제조 방법
DE19909177A1 (de) 1999-03-03 2000-09-07 Kataleuna Gmbh Catalysts Katalysator zur Hydrierung funktioneller Gruppen und Verfahren zu seiner Herstellung
DE19909168A1 (de) * 1999-03-03 2000-09-07 Basf Ag Verfahren zur Herstellung von Aminen
DE19909176A1 (de) 1999-03-03 2000-09-07 Kataleuna Gmbh Catalysts Hydrierkatalysator und Verfahren zu seiner Herstellung
EP1474378B1 (de) * 2002-02-06 2005-09-07 Basf Aktiengesellschaft Verfahren zur herstellung von aminen
DE10206214A1 (de) * 2002-02-15 2003-08-28 Basf Ag Verfahren zur Herstellung von Aminen
DE10349095A1 (de) 2003-10-17 2005-05-19 Basf Ag Verfahren zur Herstellung von Aminen
CN101687181B (zh) * 2007-05-10 2012-12-12 巴斯夫欧洲公司 制备胺类的方法
CN101678335B (zh) 2007-05-29 2014-04-16 赢创德固赛有限责任公司 活化的贱金属催化剂

Also Published As

Publication number Publication date
WO2011144481A1 (de) 2011-11-24
CN102892747A (zh) 2013-01-23
KR20130080445A (ko) 2013-07-12
SG185374A1 (en) 2012-12-28
HUE037511T2 (hu) 2018-09-28
BR112012027954A2 (pt) 2017-07-25
JP2013530140A (ja) 2013-07-25
MY156559A (en) 2016-02-26
EP2571844B1 (de) 2017-10-04
EP2571844A1 (de) 2013-03-27

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