CN102784640B - 用于co偶联反应合成草酸酯的催化剂及其制备方法 - Google Patents
用于co偶联反应合成草酸酯的催化剂及其制备方法 Download PDFInfo
- Publication number
- CN102784640B CN102784640B CN201110131440.7A CN201110131440A CN102784640B CN 102784640 B CN102784640 B CN 102784640B CN 201110131440 A CN201110131440 A CN 201110131440A CN 102784640 B CN102784640 B CN 102784640B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- preparation
- coating
- active component
- carrier coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8906—Iron and noble metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
催化剂A | 催化剂B | |
亚硝酸甲酯单程转化率,% | 98% | 92% |
草酸二甲酯选择性,% | 98.2% | 98.7% |
草酸二甲酯时空产率,g/L cat./h | 1156 | 487 |
催化剂床层径向温差,℃ | 3 | 25 |
Claims (6)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110131440.7A CN102784640B (zh) | 2011-05-20 | 2011-05-20 | 用于co偶联反应合成草酸酯的催化剂及其制备方法 |
PCT/CN2012/074052 WO2012159510A1 (zh) | 2011-05-20 | 2012-04-14 | 用于co偶联反应合成草酸酯的催化剂及其制备方法 |
JP2014510647A JP2014518760A (ja) | 2011-05-20 | 2012-04-14 | Coカップリング反応によるシュウ酸エステルの合成に用いる触媒およびその製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110131440.7A CN102784640B (zh) | 2011-05-20 | 2011-05-20 | 用于co偶联反应合成草酸酯的催化剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102784640A CN102784640A (zh) | 2012-11-21 |
CN102784640B true CN102784640B (zh) | 2014-08-20 |
Family
ID=47150338
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110131440.7A Active CN102784640B (zh) | 2011-05-20 | 2011-05-20 | 用于co偶联反应合成草酸酯的催化剂及其制备方法 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2014518760A (zh) |
CN (1) | CN102784640B (zh) |
WO (1) | WO2012159510A1 (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106914240A (zh) * | 2015-12-25 | 2017-07-04 | 上海华谊能源化工有限公司 | 一种co气相偶联合成草酸酯的催化剂及其制备方法与应用 |
CN105879924A (zh) * | 2016-04-27 | 2016-08-24 | 北京石油化工学院 | 一种负载型贵金属催化剂还原预处理的方法 |
CN112619656A (zh) * | 2020-12-17 | 2021-04-09 | 湖北楚儒同位素科技有限公司 | 一种以铜质丝网波纹填料为载体的一氧化碳转化催化剂 |
CN114029005B (zh) * | 2021-11-30 | 2024-01-30 | 华东理工大学 | 一种催化剂径向分布的堆积方法及轴向反应器 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0105480A1 (en) * | 1982-09-30 | 1984-04-18 | Union Carbide Corporation | Process for preparing a diester of oxalic acid |
CN101015800A (zh) * | 2007-02-07 | 2007-08-15 | 大连理工大学 | 催化还原氮氧化物的蜂窝状金属丝网载体催化剂及其制法 |
CN101049577A (zh) * | 2007-02-07 | 2007-10-10 | 大连理工大学 | 一种具有氧化铝涂层的蜂窝状金属丝网载体及其制备方法 |
CN101444734A (zh) * | 2008-12-12 | 2009-06-03 | 无锡威孚环保催化剂有限公司 | 净化非道路用小型柴油发动机废气的催化剂及制备方法 |
CN101850273A (zh) * | 2010-06-04 | 2010-10-06 | 天津大学 | 由co气相偶联合成草酸酯的规整催化剂及其制备方法 |
CN101851160A (zh) * | 2010-06-04 | 2010-10-06 | 天津大学 | 使用规整催化剂由co气相偶联合成草酸酯的生产方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03154617A (ja) * | 1989-11-13 | 1991-07-02 | Daido Steel Co Ltd | 排ガス浄化装置 |
JP4222839B2 (ja) * | 2003-01-06 | 2009-02-12 | 新日本製鐵株式会社 | 炭化水素の改質方法 |
JP5110249B2 (ja) * | 2005-08-11 | 2012-12-26 | 戸田工業株式会社 | 炭化水素を分解する触媒、該触媒を用いた炭化水素の分解方法及び水素の製造方法、並びに発電システム |
US7981390B2 (en) * | 2008-12-23 | 2011-07-19 | Basf Corporation | Small engine palladium catalyst article and method of making |
JP5335505B2 (ja) * | 2009-03-19 | 2013-11-06 | 旭化成ケミカルズ株式会社 | 貴金属担持物及びそれを触媒として用いるカルボン酸エステルの製造方法 |
-
2011
- 2011-05-20 CN CN201110131440.7A patent/CN102784640B/zh active Active
-
2012
- 2012-04-14 JP JP2014510647A patent/JP2014518760A/ja active Pending
- 2012-04-14 WO PCT/CN2012/074052 patent/WO2012159510A1/zh active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0105480A1 (en) * | 1982-09-30 | 1984-04-18 | Union Carbide Corporation | Process for preparing a diester of oxalic acid |
CN101015800A (zh) * | 2007-02-07 | 2007-08-15 | 大连理工大学 | 催化还原氮氧化物的蜂窝状金属丝网载体催化剂及其制法 |
CN101049577A (zh) * | 2007-02-07 | 2007-10-10 | 大连理工大学 | 一种具有氧化铝涂层的蜂窝状金属丝网载体及其制备方法 |
CN101444734A (zh) * | 2008-12-12 | 2009-06-03 | 无锡威孚环保催化剂有限公司 | 净化非道路用小型柴油发动机废气的催化剂及制备方法 |
CN101850273A (zh) * | 2010-06-04 | 2010-10-06 | 天津大学 | 由co气相偶联合成草酸酯的规整催化剂及其制备方法 |
CN101851160A (zh) * | 2010-06-04 | 2010-10-06 | 天津大学 | 使用规整催化剂由co气相偶联合成草酸酯的生产方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102784640A (zh) | 2012-11-21 |
JP2014518760A (ja) | 2014-08-07 |
WO2012159510A1 (zh) | 2012-11-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102941093B (zh) | 萘加氢制备十氢萘的催化剂及制备方法和应用 | |
CN106365995A (zh) | 一种乙酸甲酯的生产方法 | |
CN102371163A (zh) | 氧化法制不饱和醛催化剂及其制备方法 | |
CN102784640B (zh) | 用于co偶联反应合成草酸酯的催化剂及其制备方法 | |
CN101279257B (zh) | 一种用于草酸酯合成的催化剂及其制备方法和应用 | |
CN101612580A (zh) | 一种一氧化碳气相催化偶联合成草酸二乙酯催化剂及其制备方法 | |
CN102416325B (zh) | 一种异丁基酮合成催化剂的制备方法 | |
CN103769148A (zh) | 丙烯醛氧化制备丙烯酸催化剂、制备方法及其用途 | |
CN105037274B (zh) | 一种连续化合成苯并咪唑类化合物的方法 | |
CN102698761A (zh) | 一种丙酮加氢合成甲基异丁基酮催化剂的制法及用途 | |
CN102698748A (zh) | 用于co气相合成草酸酯的催化剂及其制备方法 | |
CN102580754A (zh) | 一种合成醋酸甲酯的催化剂及制法和应用 | |
CN115445612B (zh) | 脱氢催化剂及其制备方法和应用和环己烷脱氢制苯环的方法 | |
CN109772291B (zh) | 一种选择性加氢脱炔催化剂及其制备方法与应用 | |
CN106268828B (zh) | 铜基酯加氢催化剂组合物及其制备方法和应用 | |
CN102649057B (zh) | Co偶联反应制备草酸酯的催化剂 | |
CN102218304A (zh) | 一种用于生产二氟乙酰氟的催化剂及其制备方法 | |
CN102430421A (zh) | 一种用于草酸酯合成的催化剂及其制备方法 | |
CN103521235A (zh) | 由丙烯醛氧化制备丙烯酸催化剂及其制备方法 | |
CN113956164A (zh) | 高效合成伯胺的方法 | |
CN113649049A (zh) | 一种顺酐选择性加氢催化剂及其制备方法与应用方法 | |
CN102516027A (zh) | 一种丙酮加氢法联产醇和酮的催化剂级配方法 | |
CN105597741A (zh) | 用于co合成草酸二甲酯的催化剂及其制备方法及用途 | |
CN102614895B (zh) | 一正丙胺歧化反应合成二正丙胺的方法和所用催化剂 | |
CN116351429B (zh) | 一种自支撑镍镓合金催化剂及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: SHANGHAI PUJING CHEMICAL NEW MATERIALS CO., LTD. Effective date: 20140211 |
|
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20140211 Address after: 201600 Zhongshan Songjiang District Road, No. 62, building eleventh, room 1, Building 102 Applicant after: Pujing Chemical Industry (Shanghai) Limited Applicant after: Shanghai Pu Jing new chemical materials Co., Ltd Address before: 201600 Zhongshan Songjiang District Road, No. 62, building eleventh, room 1, Building 102 Applicant before: Pujing Chemical Industry (Shanghai) Limited |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: SHANGHAI PUJING CHEMICAL INDUSTRY TECHNOLOGY CO., Free format text: FORMER NAME: PUJING CHEMICAL INDUSTRY (SHA) LIMITED |
|
CP01 | Change in the name or title of a patent holder |
Address after: 201600 Zhongshan Songjiang District Road, No. 62, building eleventh, room 1, Building 102 Patentee after: PUJING CHEMICAL INDUSTRY (SHANGHAI) LIMITED Patentee after: Shanghai Pu Jing new chemical materials Co., Ltd Address before: 201600 Zhongshan Songjiang District Road, No. 62, building eleventh, room 1, Building 102 Patentee before: Pujing Chemical Industry (Shanghai) Limited Patentee before: Shanghai Pu Jing new chemical materials Co., Ltd |