CN102687328B - 具有低降解性的复合质子传导膜以及包含其的燃料电池用膜电极组件 - Google Patents
具有低降解性的复合质子传导膜以及包含其的燃料电池用膜电极组件 Download PDFInfo
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- CN102687328B CN102687328B CN201080050903.0A CN201080050903A CN102687328B CN 102687328 B CN102687328 B CN 102687328B CN 201080050903 A CN201080050903 A CN 201080050903A CN 102687328 B CN102687328 B CN 102687328B
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- additive
- proton
- membrane
- phosphorylation
- atoms
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1041—Polymer electrolyte composites, mixtures or blends
- H01M8/1046—Mixtures of at least one polymer and at least one additive
- H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Fuel Cell (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
膜 | 1重量%A4 | 5重量%A1 | 5重量%A2 | NRE211 |
OCV寿命(小时) | 230 | 119 | 186 | 66 |
Claims (18)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/615,671 | 2009-11-10 | ||
US12/615,671 US20110111321A1 (en) | 2009-11-10 | 2009-11-10 | Composite proton conducting membrane with low degradation and membrane electrode assembly for fuel cells |
PCT/EP2010/006835 WO2011057768A2 (en) | 2009-11-10 | 2010-11-10 | Composite proton conducting membrane with low degradation and membrane electrode assembly for fuel cells |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102687328A CN102687328A (zh) | 2012-09-19 |
CN102687328B true CN102687328B (zh) | 2016-04-27 |
Family
ID=43598114
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201080050903.0A Active CN102687328B (zh) | 2009-11-10 | 2010-11-10 | 具有低降解性的复合质子传导膜以及包含其的燃料电池用膜电极组件 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20110111321A1 (zh) |
EP (1) | EP2499692B1 (zh) |
CN (1) | CN102687328B (zh) |
WO (1) | WO2011057768A2 (zh) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2888558C (en) | 2012-11-27 | 2021-06-15 | Toray Industries, Inc. | Polymer electrolyte composition, and polymer electrolyte membrane, membrane electrode assembly and polymer electrolyte fuel cell each produced using same |
KR102242718B1 (ko) | 2014-04-07 | 2021-04-22 | 도레이 카부시키가이샤 | 중합체 전해질 조성물, 및 각각 그것을 사용한 중합체 전해질 막, 촉매층을 갖는 중합체 전해질 막, 막 전극 복합체 및 중합체 전해질 연료 전지 |
KR102273035B1 (ko) | 2014-04-07 | 2021-07-06 | 도레이 카부시키가이샤 | 고분자 전해질 조성물 및 그것을 사용한 고분자 전해질막, 막전극 복합체 및 고체 고분자형 연료 전지 |
WO2016178848A1 (en) | 2015-05-01 | 2016-11-10 | Ballard Power Systems Inc. | Method of making a membrane electrode assembly |
US10566640B2 (en) | 2015-07-24 | 2020-02-18 | Daimler Ag | Composite proton conducting electrolyte with improved additives for fuel cells |
JP7411328B2 (ja) | 2016-02-03 | 2024-01-11 | カムエクス パワー エルエルシー | 双極性アイオノマー膜 |
DE102016102088A1 (de) * | 2016-02-05 | 2017-08-10 | Volkswagen Ag | Membran, Membran-Elektroden-Einheit, Brennstoffzelle und Verfahren zur Herstellung einer Membran |
WO2017175613A1 (ja) | 2016-04-06 | 2017-10-12 | 住友化学株式会社 | 複素環化合物 |
WO2018231232A1 (en) * | 2017-06-15 | 2018-12-20 | W. L. Gore & Associates, Inc. | Highly reinforced ionomer membranes for high selectivity and high strength |
KR20200027631A (ko) * | 2018-09-05 | 2020-03-13 | 현대자동차주식회사 | 내구성이 향상된 연료전지용 막-전극 접합체 및 이의 제조방법 |
US11355771B2 (en) | 2019-12-20 | 2022-06-07 | Robert Bosch Gmbh | Ion scavenging agent in fuel cell electrodes |
DE102020202199A1 (de) | 2020-02-20 | 2021-08-26 | Robert Bosch Gesellschaft mit beschränkter Haftung | Elektrochemische Zelle mit immobilisierter Übergangsmetallionen bindender Substanz |
CN112467182B (zh) * | 2020-11-30 | 2022-03-15 | 山东东岳未来氢能材料股份有限公司 | 高耐受性增强型全氟质子膜及其制备方法 |
CN112436170B (zh) * | 2020-11-30 | 2022-03-04 | 山东东岳未来氢能材料股份有限公司 | 高耐受性全氟质子膜及其制备方法 |
CN112447983B (zh) * | 2020-11-30 | 2023-06-20 | 山东东岳未来氢能材料股份有限公司 | 长寿命氢燃料电池膜电极组件及其制备方法 |
CN112467180A (zh) * | 2020-11-30 | 2021-03-09 | 山东东岳未来氢能材料股份有限公司 | 高耐受性氢燃料电池膜电极组件及其制备方法 |
CN112436168A (zh) * | 2020-11-30 | 2021-03-02 | 山东东岳未来氢能材料股份有限公司 | 长寿命增强型全氟质子膜及其制备方法 |
Family Cites Families (23)
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US4594297A (en) * | 1983-12-29 | 1986-06-10 | Uop Inc. | Fuel cell using novel electrolyte membrane |
JPH04136040A (ja) * | 1990-09-28 | 1992-05-11 | Terumo Corp | 陽イオン交換膜およびこれを用いた二酸化炭素濃度測定用電極 |
JP3656244B2 (ja) * | 1999-11-29 | 2005-06-08 | 株式会社豊田中央研究所 | 高耐久性固体高分子電解質及びその高耐久性固体高分子電解質を用いた電極−電解質接合体並びにその電極−電解質接合体を用いた電気化学デバイス |
KR100407793B1 (ko) * | 2001-09-04 | 2003-12-01 | 한국과학기술연구원 | 분리능이 있는 수소 이온 교환 복합막, 복합 용액, 그제조방법 및 이를 포함하는 연료전지 |
US7112386B2 (en) * | 2002-09-04 | 2006-09-26 | Utc Fuel Cells, Llc | Membrane electrode assemblies with hydrogen peroxide decomposition catalyst |
DE10262009A1 (de) * | 2002-10-29 | 2004-05-19 | Daimlerchrysler Ag | Polymerelektrolytmembran-Brennstoffzelle mit einer verstärkten Polymerelektrolytmembran |
US7537857B2 (en) * | 2003-12-17 | 2009-05-26 | Bdf Ip Holdings Ltd. | Reduced degradation of ion-exchange membranes in electrochemical fuel cells |
US7576165B2 (en) * | 2004-01-27 | 2009-08-18 | Georgia Institute Of Technology | Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes |
US20050221142A1 (en) * | 2004-03-23 | 2005-10-06 | Narayanan Sekharipuram R | Composite polymer electrolytes based on organosilica hybrid proton conductors for fuel cells |
US20050227135A1 (en) * | 2004-04-12 | 2005-10-13 | Elena Chalkova | Composite membrane for fuel cell and fuel cells incorporating said membranes |
US20060083976A1 (en) * | 2004-06-09 | 2006-04-20 | California Institute Of Technology | Substituted nitrogen heterocycles as proton carriers for water-free proton exchange membranes for fuel cells |
US7220509B2 (en) * | 2004-08-30 | 2007-05-22 | General Motors Corporation | Constituents and methods for protecting fuel cell components, including PEMs |
EP1788654B1 (en) * | 2004-09-09 | 2011-11-16 | Asahi Kasei Chemicals Corporation | Solid polymer electrolyte membrane and method for producing same |
JP2006269266A (ja) * | 2005-03-24 | 2006-10-05 | Asahi Kasei Chemicals Corp | 補強材を有する複合高分子固体電解質膜 |
US7579116B2 (en) * | 2005-04-01 | 2009-08-25 | Gm Global Technology Operations, Inc. | Fluoride ion scavenger for fuel cell components |
US20060228608A1 (en) * | 2005-04-11 | 2006-10-12 | Tze-Chiang Chung | High temperature and low relative humidity polymer/inorganic composite membranes for proton exchange membrane fuel cells |
JP4508954B2 (ja) * | 2005-06-08 | 2010-07-21 | 本田技研工業株式会社 | 固体高分子型燃料電池用膜−電極構造体 |
WO2008048317A1 (en) * | 2005-12-22 | 2008-04-24 | Ballard Power Systems Inc. | Water insoluble additive for improving conductivity of an ion exchange membrane |
GB0611736D0 (en) * | 2006-06-14 | 2006-07-26 | Johnson Matthey Plc | Ion-conducting membrane |
DE102006040749A1 (de) * | 2006-08-31 | 2008-03-06 | Daimler Ag | Oxidationsstabilisierte Polymer-Elektrolyt-Membranen für Brennstoffzellen |
JP2008077974A (ja) | 2006-09-21 | 2008-04-03 | Nissan Motor Co Ltd | 電極 |
US20080233455A1 (en) * | 2007-03-21 | 2008-09-25 | Valadoula Deimede | Proton conductors based on aromatic polyethers and their use as electolytes in high temperature pem fuel cells |
JP4976919B2 (ja) * | 2007-05-18 | 2012-07-18 | 本田技研工業株式会社 | 固体高分子型燃料電池用膜−電極構造体 |
-
2009
- 2009-11-10 US US12/615,671 patent/US20110111321A1/en not_active Abandoned
-
2010
- 2010-11-10 WO PCT/EP2010/006835 patent/WO2011057768A2/en active Application Filing
- 2010-11-10 EP EP10803037.0A patent/EP2499692B1/en active Active
- 2010-11-10 CN CN201080050903.0A patent/CN102687328B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
EP2499692B1 (en) | 2016-07-27 |
CN102687328A (zh) | 2012-09-19 |
WO2011057768A3 (en) | 2011-07-07 |
US20110111321A1 (en) | 2011-05-12 |
WO2011057768A2 (en) | 2011-05-19 |
EP2499692A2 (en) | 2012-09-19 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220112 Address after: Gil Chaim, German Tak mountain Patentee after: Fuel cell center Lianghe Co.,Ltd. Patentee after: Ford Motor Co. Address before: Stuttgart, Germany Patentee before: DAIMLER AG Patentee before: Ford Motor Co. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20221017 Address after: Gil Chaim, German Tak mountain Patentee after: Fuel cell center Lianghe Co.,Ltd. Address before: Gil Chaim, German Tak mountain Patentee before: Fuel cell center Lianghe Co.,Ltd. Patentee before: Ford Motor Co. |
|
TR01 | Transfer of patent right |